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GB1062324A - Anti-fouling paint - Google Patents

Anti-fouling paint

Info

Publication number
GB1062324A
GB1062324A GB14565/64A GB1456564A GB1062324A GB 1062324 A GB1062324 A GB 1062324A GB 14565/64 A GB14565/64 A GB 14565/64A GB 1456564 A GB1456564 A GB 1456564A GB 1062324 A GB1062324 A GB 1062324A
Authority
GB
United Kingdom
Prior art keywords
tin
methyl
tri
butyl
copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB14565/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
NOF Corp
Original Assignee
Nitto Chemical Industry Co Ltd
Nippon Oil and Fats Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nitto Chemical Industry Co Ltd, Nippon Oil and Fats Co Ltd filed Critical Nitto Chemical Industry Co Ltd
Publication of GB1062324A publication Critical patent/GB1062324A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1637—Macromolecular compounds
    • C09D5/1643—Macromolecular compounds containing tin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F30/00—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F30/04—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Anti-fouling paints comprise as poisonous component a homopolymer or copolymer of an organotin compound of the formula <FORM:1062324/C4-C5/1> wherein R1, R2 and R3, which may be the same or different, represent a C2-6 alkyl radical or a phenyl radical, and R4 and R5, which may be the same or different, represent hydrogen or a methyl, ethyl or phenyl radical. Preferably, R4 is hydrogen or methyl and R5 is hydrogen. Various comonomers are listed for the organotin compounds; copolymers specifically exemplified are those in which the comonomers are (a) vinyl acetate and (b) methacrylic acid-n-butyl acrylate. The paint may contain conventional binders, solvents, bodying agents, pigments etc.; components specified are ferric oxide, talc, titanium dioxide, cuprous oxide, carbon black, chrome yellow, phthalocyanine blue, rosin, bodied linseed oil, xylene, methyl isobutyl ketone, vinyl chloride-vinyl acetate copolymer and methyl methacrylate-octyl acrylate-styrene copolymer.ALSO:Anti-fouling paints comprise as poisonous component a homopolymer or copolymer of an organotin compound of the formula <FORM:1062324/C3/1> wherein R1, R2 and R3, which may be the same or different, represent a C2- 6 alkyl radical or a phenyl radical, and R4 and R5, which may be the same or different, represent hydrogen or a methyl, ethyl or phenyl radical. Preferably, R4 is hydrogen or methyl and R5 is hydrogen. Suitable comonomers include vinyl chloride, vinyl acetate, vinylidene chloride, styrene, a -methylstyrene, vinyl toluene, 2-vinyl furan, acrylic acid and methacrylic acid and their alkyl esters, acrylonitrile, acrylamide, glycidyl methacrylate, maleic acid, fumaric acid, divinyl benzene and mixtures thereof. The paint may contain conventional binders, solvents, bodying agents, pigments etc.; components specified are ferric oxide, talc, titanium dioxide, cuprous oxide, carbon black, chrome yellow, phthalocyanine blue, rosin, bodied linseed oil, xylene, methyl isobutyl ketone, vinyl chloride-vinyl acetate copolymer and methyl methacrylate-octyl acrylate-styrene copolymer. The poisons used in the examples are tri-n-butyl tin methacrylate polymer, tri-n-propyl tin acrylate polymer, tri - n - butyl tin methacrylatevinyl acetate copolymer, tri-n-amyl tin acrylate polymer, tri - n - butyl tin methacrylate-methacrylic acid - n - butyl acrylate copolymer, tri - n - amyl tin methacrylate polymer, triphenyl tin methacrylate polymer, di-n-butyl n-amyl tin methacrylate polymer and di-n-butyl phenyl tin acrylate polymer. The organo tin polymers can be prepared by polymerizing the corresponding monomer(s) in a liquid medium such as toluene or xylene and in the presence of a catalyst, e.g. an organic peroxide.
GB14565/64A 1963-04-15 1964-04-08 Anti-fouling paint Expired GB1062324A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1941163 1963-04-15

Publications (1)

Publication Number Publication Date
GB1062324A true GB1062324A (en) 1967-03-22

Family

ID=11998494

Family Applications (1)

Application Number Title Priority Date Filing Date
GB14565/64A Expired GB1062324A (en) 1963-04-15 1964-04-08 Anti-fouling paint

Country Status (5)

Country Link
BE (1) BE646406A (en)
DE (1) DE1519252A1 (en)
DK (1) DK106389C (en)
GB (1) GB1062324A (en)
NL (1) NL6404034A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4082709A (en) * 1974-01-31 1978-04-04 The United States Of America As Represented By The Secretary Of The Navy Low leaching antifouling organometallic polyesters
US4139515A (en) * 1976-11-16 1979-02-13 The International Paint Co. Ltd. Anti-fouling paint containing a copolymer of a triorganotin salt of an unsaturated carboxylic acid
US4260535A (en) * 1979-09-04 1981-04-07 M&T Chemicals Inc. Antifoulant composition and method
US4270953A (en) 1978-03-09 1981-06-02 Kansai Paint Co., Ltd. Two component antifouling paint
US4298384A (en) * 1978-07-23 1981-11-03 Yeda Research And Development Company, Ltd. Antifouling paints for marine use
US4407997A (en) 1980-10-29 1983-10-04 The International Paint Company Limited Marine paint
EP0091039A3 (en) * 1982-04-06 1984-07-18 Nitto Kasei Co., Ltd. Anti-fouling agent
US4543127A (en) * 1984-05-07 1985-09-24 The Dow Chemical Company Organotin-fumed silica derivatives for use as biocidal compositions
US4914141A (en) * 1983-12-30 1990-04-03 Nippon Oil And Fats, Co., Ltd. Antifouling paint containing polymer of ethylenically unsaturated organotin monomer
US5053077A (en) * 1988-06-30 1991-10-01 Crompton Design Manufacturing Limited Fire resistant paint or coating using frits

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1457590A (en) * 1974-04-03 1976-12-08 Int Paint Co Marine paint
US4121034A (en) * 1976-11-02 1978-10-17 M&T Chemicals Inc. Biologically active triorganotin copolymers
US4197233A (en) * 1978-03-15 1980-04-08 Kennecott Copper Corporation Anti-fouling and anti-sliming coating material
JPS6157661A (en) * 1984-08-29 1986-03-24 Kobe Paint Kk Sealing composition for ship bottom paint

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4082709A (en) * 1974-01-31 1978-04-04 The United States Of America As Represented By The Secretary Of The Navy Low leaching antifouling organometallic polyesters
US4139515A (en) * 1976-11-16 1979-02-13 The International Paint Co. Ltd. Anti-fouling paint containing a copolymer of a triorganotin salt of an unsaturated carboxylic acid
US4270953A (en) 1978-03-09 1981-06-02 Kansai Paint Co., Ltd. Two component antifouling paint
US4298384A (en) * 1978-07-23 1981-11-03 Yeda Research And Development Company, Ltd. Antifouling paints for marine use
US4260535A (en) * 1979-09-04 1981-04-07 M&T Chemicals Inc. Antifoulant composition and method
US4407997A (en) 1980-10-29 1983-10-04 The International Paint Company Limited Marine paint
EP0091039A3 (en) * 1982-04-06 1984-07-18 Nitto Kasei Co., Ltd. Anti-fouling agent
US4914141A (en) * 1983-12-30 1990-04-03 Nippon Oil And Fats, Co., Ltd. Antifouling paint containing polymer of ethylenically unsaturated organotin monomer
US4543127A (en) * 1984-05-07 1985-09-24 The Dow Chemical Company Organotin-fumed silica derivatives for use as biocidal compositions
US5053077A (en) * 1988-06-30 1991-10-01 Crompton Design Manufacturing Limited Fire resistant paint or coating using frits

Also Published As

Publication number Publication date
NL6404034A (en) 1964-10-16
BE646406A (en) 1964-07-31
DE1519252A1 (en) 1970-02-19
DK106389C (en) 1967-01-30

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