GB1062064A - Synthetic zeolite production - Google Patents
Synthetic zeolite productionInfo
- Publication number
- GB1062064A GB1062064A GB19880/64A GB1988064A GB1062064A GB 1062064 A GB1062064 A GB 1062064A GB 19880/64 A GB19880/64 A GB 19880/64A GB 1988064 A GB1988064 A GB 1988064A GB 1062064 A GB1062064 A GB 1062064A
- Authority
- GB
- United Kingdom
- Prior art keywords
- clay
- weight
- residue
- silica sol
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010457 zeolite Substances 0.000 title abstract 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 9
- 238000010992 reflux Methods 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000004927 clay Substances 0.000 abstract 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 abstract 3
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 238000010306 acid treatment Methods 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 238000004517 catalytic hydrocracking Methods 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 abstract 1
- 239000012013 faujasite Substances 0.000 abstract 1
- 229910001683 gmelinite Inorganic materials 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- -1 platinum group metals Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229940083608 sodium hydroxide Drugs 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2838—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively)
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/06—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/37—Acid treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
Abstract
Synthetic zeolites are prepared by acid treating a montmorillonite clay, neutralizing the mix, washing with water, and heating the residue under reflux with a solution containing sodium-hydroxide and silica sol. The acid treatment may be carried out under reflux with sulphuric or hydrochloric acid in a concentration of 1 to 40% by weight, the clay to acid weight ratio being between 0.1 and 4.0 and the zinc at the reflux temperature 1/2 to 24 hours. The neutralization is preferably carried out with ammonia and the residue is water washed until it is substantially salt free. The residue may be suspended in a solution containing 15 to 35% by weight of NaOH and silica sol. containing 30% by weight of SiO2, between 700 and 900 g. of NaOH solution per 100 g. of clay and between 700 and 900 g. of silica sol. per 100 g. of clay being used and reflux being continued until crystallization is substantially complete. The product is a mixture of zeolites containing a high proportion of faujasite and zeolites of the chabazite-gmelinite series. It may be used as a catalyst or catalyst support and with the incorporation of Group VIII metals, particularly platinum group metals, may be used as cracking or hydrocracking catalysts.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB19880/64A GB1062064A (en) | 1964-05-13 | 1964-05-13 | Synthetic zeolite production |
| NL6506131A NL6506131A (en) | 1964-05-13 | 1965-05-13 | |
| SE6247/65A SE317960B (en) | 1964-05-13 | 1965-05-13 | |
| BE663904A BE663904A (en) | 1964-05-13 | 1965-05-13 | |
| DE19651542621 DE1542621A1 (en) | 1964-05-13 | 1965-05-13 | Process for the production of synthetic zeolites |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB19880/64A GB1062064A (en) | 1964-05-13 | 1964-05-13 | Synthetic zeolite production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1062064A true GB1062064A (en) | 1967-03-15 |
Family
ID=10136720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB19880/64A Expired GB1062064A (en) | 1964-05-13 | 1964-05-13 | Synthetic zeolite production |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE663904A (en) |
| DE (1) | DE1542621A1 (en) |
| GB (1) | GB1062064A (en) |
| NL (1) | NL6506131A (en) |
| SE (1) | SE317960B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4102977A (en) * | 1975-11-18 | 1978-07-25 | Mizusawa Kagaku Kogyo Kabushiki Kaisha | Process for the preparation of alkali aluminosilicate detergent builder |
| GB2125390A (en) * | 1982-08-16 | 1984-03-07 | Ici Plc | Preparation of zeolites |
| US7264789B1 (en) | 1998-07-29 | 2007-09-04 | Exxonmobil Chemical Patents Inc. | Crystalline molecular sieves |
| US9802182B2 (en) | 2013-03-13 | 2017-10-31 | Basf Corporation | Stabilized metal-exchanged SAPO material |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5347408A (en) * | 1976-10-13 | 1978-04-27 | Mizusawa Industrial Chem | Detergent builder and preparation thereof |
| EP0068817B1 (en) * | 1981-07-01 | 1984-10-03 | ENGLISH CLAYS LOVERING POCHIN & COMPANY LIMITED | Manufacture of zsm-zeolites |
-
1964
- 1964-05-13 GB GB19880/64A patent/GB1062064A/en not_active Expired
-
1965
- 1965-05-13 BE BE663904A patent/BE663904A/xx unknown
- 1965-05-13 NL NL6506131A patent/NL6506131A/xx unknown
- 1965-05-13 SE SE6247/65A patent/SE317960B/xx unknown
- 1965-05-13 DE DE19651542621 patent/DE1542621A1/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4102977A (en) * | 1975-11-18 | 1978-07-25 | Mizusawa Kagaku Kogyo Kabushiki Kaisha | Process for the preparation of alkali aluminosilicate detergent builder |
| GB2125390A (en) * | 1982-08-16 | 1984-03-07 | Ici Plc | Preparation of zeolites |
| US7264789B1 (en) | 1998-07-29 | 2007-09-04 | Exxonmobil Chemical Patents Inc. | Crystalline molecular sieves |
| US9802182B2 (en) | 2013-03-13 | 2017-10-31 | Basf Corporation | Stabilized metal-exchanged SAPO material |
| US9931620B2 (en) | 2013-03-13 | 2018-04-03 | Basf Corporation | Stabilized metal-exchanged SAPO material |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1542621A1 (en) | 1969-09-25 |
| NL6506131A (en) | 1965-11-15 |
| SE317960B (en) | 1969-12-01 |
| BE663904A (en) | 1965-11-16 |
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