GB1054595A - - Google Patents
Info
- Publication number
- GB1054595A GB1054595A GB2028265A GB2028265A GB1054595A GB 1054595 A GB1054595 A GB 1054595A GB 2028265 A GB2028265 A GB 2028265A GB 2028265 A GB2028265 A GB 2028265A GB 1054595 A GB1054595 A GB 1054595A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alloy
- starting material
- inert
- hexachloropropene
- pyrolysing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- 239000000956 alloy Substances 0.000 abstract 2
- 229910045601 alloy Inorganic materials 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 239000007858 starting material Substances 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- BKWAVXQSZLEURV-UHFFFAOYSA-N 2-chloro-1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)C(Cl)C(F)(F)F BKWAVXQSZLEURV-UHFFFAOYSA-N 0.000 abstract 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 abstract 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 abstract 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 1
- VFDYKPARTDCDCU-UHFFFAOYSA-N hexachloropropene Chemical compound ClC(Cl)=C(Cl)C(Cl)(Cl)Cl VFDYKPARTDCDCU-UHFFFAOYSA-N 0.000 abstract 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 229950011008 tetrachloroethylene Drugs 0.000 abstract 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Hexafluoropropene is made by pyrolysing 2-chloro - 1,1,1,3,3,3 - hexafluoropropane at 650-850 DEG C. for 3-120 seconds. The reaction is suitably effected in a tubular reactor lined with a metal which is inert to the acidic products, e.g. Ag, Pt, an alloy of Ni, Cr and Fe, or an alloy of Ni, Mo and Fe. It is preferred to use the starting material in an undiluted form, but an inert gas, e.g. N2, He, may be added. The starting material may be made by reacting carbon tetrachloride and trichloroethylene, or chloroform and tetrachloroethylene, to give hexachloropropene which is then reacted with HF in the presence of an activated anhydrous chromium oxide catalyst. Examples are provided.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US367894A US3397248A (en) | 1964-05-15 | 1964-05-15 | Process for the preparation of hexafluoropropene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1054595A true GB1054595A (en) | 1967-01-11 |
Family
ID=23449052
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2028265A Expired GB1054595A (en) | 1964-05-15 | 1965-05-13 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3397248A (en) |
| DE (1) | DE1229515B (en) |
| FR (1) | FR1433226A (en) |
| GB (1) | GB1054595A (en) |
| NL (1) | NL6506200A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5334783A (en) * | 1988-03-14 | 1994-08-02 | Hoechst Aktiengesellschaft | Process for the preparation of hexafluoropropene |
| EP0337127B1 (en) * | 1988-03-14 | 1993-04-21 | Hoechst Aktiengesellschaft | Process for the preparation of hexafluor propene |
| US20020032356A1 (en) | 2000-07-14 | 2002-03-14 | Gelblum Peter Gideon | Synthesis of perfluoroolefins |
| US20060094911A1 (en) * | 2004-10-29 | 2006-05-04 | Rao Velliyur N M | Noncatalytic manufacture of 1,1,3,3,3-pentafluoropropene from 1,1,1,3,3,3-hexafluoropropane |
| CN111302888B (en) * | 2020-03-16 | 2022-05-13 | 天津绿菱气体有限公司 | Separation method of high-purity electronic grade hexafluoropropane isomer |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2551573A (en) * | 1945-11-30 | 1951-05-08 | Du Pont | Pyrolysis of chloro-fluoro alkanes |
| US2981763A (en) * | 1960-03-22 | 1961-04-25 | Allied Chem | Manufacture of fluorocarbons |
-
1964
- 1964-05-15 US US367894A patent/US3397248A/en not_active Expired - Lifetime
-
1965
- 1965-05-13 GB GB2028265A patent/GB1054595A/en not_active Expired
- 1965-05-14 NL NL6506200A patent/NL6506200A/xx unknown
- 1965-05-14 FR FR17135A patent/FR1433226A/en not_active Expired
- 1965-05-14 DE DEP36796A patent/DE1229515B/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| NL6506200A (en) | 1965-11-16 |
| FR1433226A (en) | 1966-03-25 |
| US3397248A (en) | 1968-08-13 |
| DE1229515B (en) | 1966-12-01 |
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