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GB1048112A - Process for the hydrodealkylation of alkyl aromatic compounds - Google Patents

Process for the hydrodealkylation of alkyl aromatic compounds

Info

Publication number
GB1048112A
GB1048112A GB31068/64A GB3106864A GB1048112A GB 1048112 A GB1048112 A GB 1048112A GB 31068/64 A GB31068/64 A GB 31068/64A GB 3106864 A GB3106864 A GB 3106864A GB 1048112 A GB1048112 A GB 1048112A
Authority
GB
United Kingdom
Prior art keywords
alkyl aromatic
aromatic compounds
seconds
hydrodealkylation
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31068/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gulf Research and Development Co
Original Assignee
Gulf Research and Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gulf Research and Development Co filed Critical Gulf Research and Development Co
Publication of GB1048112A publication Critical patent/GB1048112A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
    • C07C4/12—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
    • C07C4/14—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
    • C07C4/16—Thermal processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/22—Non-catalytic cracking in the presence of hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Alkyl aromatic compounds are hydrodealkylated by heating with hydrogen up to a temperature of 510 DEG C. in less than 50 seconds, preferably 1 to 10 seconds, and then raising the temperature to 621 DEG to 677 DEG C., thereafter maintaining the temperature at 621 DEG to 982 DEG C. for 1 to 400 seconds at a pressure of at least 7 kg. cm.2 gauge. Starting materials used include toluene, xylenes, trimethylbenzenes, alkyl naphthalenes and alkyl phenols. The molar ratio of hydrogen to alkyl aromatic charge may be 1.5: 1 to 20: 1.
GB31068/64A 1963-09-04 1964-08-04 Process for the hydrodealkylation of alkyl aromatic compounds Expired GB1048112A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US306598A US3284526A (en) 1963-09-04 1963-09-04 Process for thermal hydrodealkylation

Publications (1)

Publication Number Publication Date
GB1048112A true GB1048112A (en) 1966-11-09

Family

ID=23186011

Family Applications (1)

Application Number Title Priority Date Filing Date
GB31068/64A Expired GB1048112A (en) 1963-09-04 1964-08-04 Process for the hydrodealkylation of alkyl aromatic compounds

Country Status (5)

Country Link
US (1) US3284526A (en)
DE (1) DE1283212B (en)
DK (1) DK112938B (en)
GB (1) GB1048112A (en)
NL (1) NL6410268A (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2508898B1 (en) * 1981-07-03 1986-11-14 Inst Francais Du Petrole PROCESS FOR CONVERTING RICH CUTS INTO POLYAROMATIC HYDROCARBONS IN METHANE, ETHANE AND POSSIBLY BENZENE
US4806700A (en) * 1986-10-22 1989-02-21 Uop Inc. Production of benzene from light hydrocarbons
SA05260056B1 (en) * 1991-03-08 2008-03-26 شيفرون فيليبس كيميكال كمبني ال بي Hydrocarbon processing device
EP0683760B1 (en) * 1993-01-04 1999-04-14 Chevron Chemical Company LLC Dehydrogenation processes and equipment therefor
US5413700A (en) * 1993-01-04 1995-05-09 Chevron Research And Technology Company Treating oxidized steels in low-sulfur reforming processes
SA94150056B1 (en) * 1993-01-04 2005-10-15 شيفرون ريسيرتش أند تكنولوجي كمبني hydrodealkylation
USRE38532E1 (en) 1993-01-04 2004-06-08 Chevron Phillips Chemical Company Lp Hydrodealkylation processes
US6258256B1 (en) 1994-01-04 2001-07-10 Chevron Phillips Chemical Company Lp Cracking processes
US5575902A (en) * 1994-01-04 1996-11-19 Chevron Chemical Company Cracking processes
US6274113B1 (en) 1994-01-04 2001-08-14 Chevron Phillips Chemical Company Lp Increasing production in hydrocarbon conversion processes
US6419986B1 (en) 1997-01-10 2002-07-16 Chevron Phillips Chemical Company Ip Method for removing reactive metal from a reactor system
US10308733B2 (en) 2015-02-19 2019-06-04 Sabic Global Technologies B.V. Systems and methods related to the production of polyethylene
EP3294837A1 (en) 2015-05-15 2018-03-21 SABIC Global Technologies B.V. Systems and methods related to the syngas to olefin process
WO2016185334A1 (en) 2015-05-15 2016-11-24 Sabic Global Technologies B.V. Systems and methods related to the syngas to olefin process
WO2020162877A1 (en) 2019-02-04 2020-08-13 China Petroleum & Chemical Corporation Process for making phenol and xylenes

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1005945B (en) * 1951-02-07 1957-04-11 Exxon Research Engineering Co Process for the thermal dealkylation of aromatic hydrocarbons
GB790595A (en) * 1955-07-21 1958-02-12 Exxon Research Engineering Co Dealkylation of aromatic hydrocarbons
US3193595A (en) * 1962-01-31 1965-07-06 Standard Oil Co Hydrocarbon conversion

Also Published As

Publication number Publication date
US3284526A (en) 1966-11-08
DK112938B (en) 1969-02-03
DE1283212B (en) 1968-11-21
NL6410268A (en) 1965-03-05

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