GB1048193A - Process for refining raw lactam - Google Patents
Process for refining raw lactamInfo
- Publication number
- GB1048193A GB1048193A GB1392664A GB1392664A GB1048193A GB 1048193 A GB1048193 A GB 1048193A GB 1392664 A GB1392664 A GB 1392664A GB 1392664 A GB1392664 A GB 1392664A GB 1048193 A GB1048193 A GB 1048193A
- Authority
- GB
- United Kingdom
- Prior art keywords
- lactam
- alkali
- refining raw
- raw lactam
- cycloalkanoneoxime
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003951 lactams Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title 1
- 238000007670 refining Methods 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- 239000003513 alkali Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 abstract 1
- YDLSUFFXJYEVHW-UHFFFAOYSA-N azonan-2-one Chemical compound O=C1CCCCCCCN1 YDLSUFFXJYEVHW-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001924 cycloalkanes Chemical class 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229910000027 potassium carbonate Inorganic materials 0.000 abstract 1
- 235000015320 potassium carbonate Nutrition 0.000 abstract 1
- 235000011118 potassium hydroxide Nutrition 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 235000017550 sodium carbonate Nutrition 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/16—Separation or purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Hydrogenated Pyridines (AREA)
- Polyamides (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Raw lactam, produced by subjecting a cycloalkanoneoxime obtained by the photonitrosation of a cycloalkane, to Beckmann's reaction, is refined by treating with alkali in a liquid phase and subsequently or simultaneously hydrogenating in the presence of a catalyst. The lactam may thereafter be treated with an ion exchange agent. The alkali may be NaOH, KOH, Na2CO3 or K2CO3. The hydrogenation may be carried out in water, alcohol or benzene using Ni, Co, Pt or Pd based catalysts. Examples relate to the treatment of caprolactam, capryllactam and lauryllactam. Reference has been directed by the Comptroller to Specification 1,002,424.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1876363 | 1963-04-09 | ||
| JP2376563 | 1963-05-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1048193A true GB1048193A (en) | 1966-11-16 |
Family
ID=26355489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1392664A Expired GB1048193A (en) | 1963-04-09 | 1964-04-03 | Process for refining raw lactam |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1470365C3 (en) |
| GB (1) | GB1048193A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005014538A1 (en) * | 2003-07-25 | 2005-02-17 | Dsm Ip Assets B.V. | Process for purifying caprolactam |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3925575A1 (en) * | 1989-08-02 | 1991-02-07 | Basf Ag | PROCESS FOR CONTINUOUS CLEANING OF CAPROLACTAM |
-
1964
- 1964-04-03 GB GB1392664A patent/GB1048193A/en not_active Expired
- 1964-04-09 DE DE19641470365 patent/DE1470365C3/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005014538A1 (en) * | 2003-07-25 | 2005-02-17 | Dsm Ip Assets B.V. | Process for purifying caprolactam |
| US7365195B2 (en) | 2003-07-25 | 2008-04-29 | Dsm Ip Assets B.V. | Process for purifying caprolactam |
| EA010504B1 (en) * | 2003-07-25 | 2008-10-30 | ДСМ Ай Пи ЭССЕТС Б.В. | Process for purifying caprolactam |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1470365B2 (en) | 1974-10-31 |
| DE1470365A1 (en) | 1969-05-08 |
| DE1470365C3 (en) | 1975-06-19 |
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