GB1044777A - Method of polymerizing unsaturated hydrocarbons of olefin series - Google Patents
Method of polymerizing unsaturated hydrocarbons of olefin seriesInfo
- Publication number
- GB1044777A GB1044777A GB3187363A GB3187363A GB1044777A GB 1044777 A GB1044777 A GB 1044777A GB 3187363 A GB3187363 A GB 3187363A GB 3187363 A GB3187363 A GB 3187363A GB 1044777 A GB1044777 A GB 1044777A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tri
- butyl
- polymerized
- ethylene
- tin hydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000000379 polymerizing effect Effects 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 title 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 5
- DBGVGMSCBYYSLD-UHFFFAOYSA-N tributylstannane Chemical compound CCCC[SnH](CCCC)CCCC DBGVGMSCBYYSLD-UHFFFAOYSA-N 0.000 abstract 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 4
- 239000005977 Ethylene Substances 0.000 abstract 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 4
- 229910003074 TiCl4 Inorganic materials 0.000 abstract 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 3
- -1 ethylene, propylene Chemical group 0.000 abstract 3
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- APQHKWPGGHMYKJ-UHFFFAOYSA-N Tributyltin oxide Chemical compound CCCC[Sn](CCCC)(CCCC)O[Sn](CCCC)(CCCC)CCCC APQHKWPGGHMYKJ-UHFFFAOYSA-N 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- 150000003623 transition metal compounds Chemical class 0.000 abstract 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 abstract 1
- NAMYKGVDVNBCFQ-UHFFFAOYSA-N 2-bromopropane Chemical compound CC(C)Br NAMYKGVDVNBCFQ-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000004703 alkoxides Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001499 aryl bromides Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001805 chlorine compounds Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 abstract 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 abstract 1
- 229910000083 tin tetrahydride Inorganic materials 0.000 abstract 1
- CPRPKIMXLHBUGA-UHFFFAOYSA-N triethyltin Chemical compound CC[Sn](CC)CC CPRPKIMXLHBUGA-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Tri n-butyl tin hydride is prepared by reacting hexanormal butyl distannoxane (i.e. bis(tri-n-butyl tin) oxide) with methyl hydropolysiloxane and distilling the mixture under reduced pressure.ALSO:a -Olefines such as ethylene, propylene and butylene, olefines containing aromatic groups such as styrene, and conjugated dienes such as butadiene and isoprene may be homo- or copolymerized using a catalyst obtained by mixing a tin hydride compound of formula RmSnH4- m where m is 1, 2 or 3 and R is alkyl, cycloalkyl or aryl having up to 8 carbon atoms with a transition metal compound of a metal selected from Groups IVa, Va and VIa of the Mendeleef Periodic Table. The transition metal compound may be a halide, oxyhalide, alkoxide or acetylacetonate; it is preferably a chloride or an oxychloride. The catalyst components may be dissolved or suspended in an inert solvent and the mixing is preferably under an inert atmosphere. The molecular weight of the polymers may be regulated by polymerizing in the presence of hydrogen or a halogenated hydrocarbon such as ethyl bromide, n-butyl chloride and vinyl chloride. In the examples: (a) ethylene is polymerized using tri-n-butyl tin hydride and titanium tetrachloride or VOCl3 or triethyl tin hydride and TiCl4; (b) ethylene and propylene are copolymerized using tri-n-butyl tin hydride and TiCl4; (c) propylene is polymerized using tri-n-butyl tin hydride and TiCl4; (d) isoprene or styrene is polymerized using tri-n-butyl tin hydride and TiCl4; (e) ethylene is polymerized in the presence of ethyl bromide, isopropyl bromide, an aryl bromide or n-butyl chloride and the hydride, and (f) a mixture of ethylene and vinyl chloride is polymerized.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3747062 | 1962-09-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1044777A true GB1044777A (en) | 1966-10-05 |
Family
ID=12498400
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3187363A Expired GB1044777A (en) | 1962-09-05 | 1963-08-13 | Method of polymerizing unsaturated hydrocarbons of olefin series |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1520182B2 (en) |
| GB (1) | GB1044777A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5254629A (en) * | 1988-11-30 | 1993-10-19 | Shell Oil Company | Polymerization of cyclic olefins |
| US5369195A (en) * | 1988-11-30 | 1994-11-29 | Shell Oil Company | Polymerization of cyclic olefins |
| WO2002100906A1 (en) * | 2001-06-12 | 2002-12-19 | Dow Global Technologies Inc. | Use of polar monomers in olefin polymerization and polymers thereof |
-
1963
- 1963-08-13 GB GB3187363A patent/GB1044777A/en not_active Expired
- 1963-08-30 DE DE19631520182 patent/DE1520182B2/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5254629A (en) * | 1988-11-30 | 1993-10-19 | Shell Oil Company | Polymerization of cyclic olefins |
| US5369195A (en) * | 1988-11-30 | 1994-11-29 | Shell Oil Company | Polymerization of cyclic olefins |
| WO2002100906A1 (en) * | 2001-06-12 | 2002-12-19 | Dow Global Technologies Inc. | Use of polar monomers in olefin polymerization and polymers thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1520182B2 (en) | 1971-08-12 |
| DE1520182A1 (en) | 1970-01-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES230044A1 (en) | Process for polymerizing olefins wherein hydrogen is utilized as a molecular weight control agent | |
| GB790399A (en) | Improvements in or relating to process for polymerizing olefins | |
| GB1305610A (en) | ||
| GB824374A (en) | Process and catalyst for polymerization of polymerizable hydrocarbons | |
| GB873225A (en) | Improvements in or relating to olefine polymerisation processes | |
| US3474080A (en) | Catalytic process for olefin polymerization | |
| US3131171A (en) | Catalyst for the polymerization of olefins containing the product of a titanium halide and an organoaluminum compound mixed with a lower alkyl halide solution of aluminum chloride | |
| GB1044777A (en) | Method of polymerizing unsaturated hydrocarbons of olefin series | |
| GB1018778A (en) | Olefin copolymers | |
| GB887313A (en) | Polymerisation catalysts | |
| US3493554A (en) | Olefin polymerization process employing a chromate catalyst | |
| GB1473048A (en) | Process for polymerizing olefin | |
| GB872142A (en) | A process for polymerizing alpha-olefines | |
| GB906425A (en) | Process for polymerising unsaturated organic compounds, and catalysts therefor | |
| GB957473A (en) | Catalysts for polymerising unsaturated organic compounds, and a process for their manufacture | |
| GB926699A (en) | Organometallic compounds | |
| US3397194A (en) | Process for polymerization of alpha-olefins using ccl4 and air3 with (1) low temperature high ionizing radiation or (2) iron or niobium halides | |
| GB1005282A (en) | Process for the polymerisation of unsaturated hydrocarbon monomers | |
| GB824195A (en) | Improvements in the production of polymerisation products from olefinically unsaturated hydrocarbons | |
| GB795370A (en) | Production of polymers | |
| GB921256A (en) | Polymerization catalyst | |
| GB899420A (en) | Polymers and process for preparation | |
| US3394117A (en) | Polymerization catalyst | |
| US3362945A (en) | Polymerization of ethylene and catalyst comprising vinyl titanium halide and aluminum trialkyl | |
| GB971746A (en) | Olefin polymerization |