GB1043360A - Production of homopolymers and copolymers of unsaturated hydrocarbons - Google Patents
Production of homopolymers and copolymers of unsaturated hydrocarbonsInfo
- Publication number
- GB1043360A GB1043360A GB210164A GB210164A GB1043360A GB 1043360 A GB1043360 A GB 1043360A GB 210164 A GB210164 A GB 210164A GB 210164 A GB210164 A GB 210164A GB 1043360 A GB1043360 A GB 1043360A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrocarbons
- homopolymers
- copolymers
- cyclooctadiene
- specified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title abstract 2
- 229920001519 homopolymer Polymers 0.000 title abstract 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 title abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 abstract 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 2
- MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 abstract 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- SMUQFGGVLNAIOZ-UHFFFAOYSA-N quinaldine Chemical compound C1=CC=CC2=NC(C)=CC=C21 SMUQFGGVLNAIOZ-UHFFFAOYSA-N 0.000 abstract 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 abstract 1
- 229910021592 Copper(II) chloride Inorganic materials 0.000 abstract 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 abstract 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 1
- 229910003074 TiCl4 Inorganic materials 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium chloride Substances Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- ZOLLIQAKMYWTBR-RYMQXAEESA-N cyclododecatriene Chemical compound C/1C\C=C\CC\C=C/CC\C=C\1 ZOLLIQAKMYWTBR-RYMQXAEESA-N 0.000 abstract 1
- CHVJITGCYZJHLR-UHFFFAOYSA-N cyclohepta-1,3,5-triene Chemical compound C1C=CC=CC=C1 CHVJITGCYZJHLR-UHFFFAOYSA-N 0.000 abstract 1
- ICPMUWPXCAVOOQ-UHFFFAOYSA-N cycloocta-1,3,5-triene Chemical compound C1CC=CC=CC=C1 ICPMUWPXCAVOOQ-UHFFFAOYSA-N 0.000 abstract 1
- KDUIUFJBNGTBMD-VXMYFEMYSA-N cyclooctatetraene Chemical compound C1=C\C=C/C=C\C=C1 KDUIUFJBNGTBMD-VXMYFEMYSA-N 0.000 abstract 1
- URYYVOIYTNXXBN-UPHRSURJSA-N cyclooctene Chemical compound C1CCC\C=C/CC1 URYYVOIYTNXXBN-UPHRSURJSA-N 0.000 abstract 1
- 239000004913 cyclooctene Substances 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 1
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000004065 semiconductor Substances 0.000 abstract 1
- PJYXVICYYHGLSW-UHFFFAOYSA-J tetrachloroplumbane Chemical compound Cl[Pb](Cl)(Cl)Cl PJYXVICYYHGLSW-UHFFFAOYSA-J 0.000 abstract 1
- 229930192474 thiophene Natural products 0.000 abstract 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Homopolymers and copolymers of unsaturated cyclic hydrocarbons (other than aromatic hydrocarbons) are produced by polymerizing them under oxidizing conditions alone or with another unsaturated cyclic hydrocarbon and/or an open-chain diolefin and/or a compound having an aromatic ring system at temperatures of from -30 DEG to 150 DEG C. and in the presence of a Friedel-Crafts catalyst. Cyclic unsaturated hydrocarbons specified are cyclooctene, cyclopentadiene, dicyclopentadiene, cyclohexadiene, cycloheptatriene, cyclooctadiene-1,3, cyclooctadiene-1,5, cyclooctatriene, cyclooctatetraene, and cyclododecatriene. Comonomers exemplified are benzene, thiophene, isoprene, quinaldine, anthracene and phenanthracene. A number of catalyst components are specified; those exemplified are Friedel Crafts catalysts-AlCl3 and TiCl4, oxidizing agents-CuCl2, FeCl3, PbCl4 and PbNO3. Polymerization may be effected in a diluent or preferably in bulk. Traces of water or alcohols may advantageously be present in the reaction mixture. The polymers formed have semiconductor properties.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB70578A DE1195497B (en) | 1963-02-01 | 1963-02-01 | Process for the preparation of homo- or copolymers of olefinically unsaturated cyclic hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1043360A true GB1043360A (en) | 1966-09-21 |
Family
ID=6976710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB210164A Expired GB1043360A (en) | 1963-02-01 | 1964-01-17 | Production of homopolymers and copolymers of unsaturated hydrocarbons |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1195497B (en) |
| GB (1) | GB1043360A (en) |
| NL (1) | NL6400706A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5028968B1 (en) * | 1969-12-30 | 1975-09-19 | ||
| US4255297A (en) * | 1977-12-22 | 1981-03-10 | Hoechst Aktiengesellschaft | Adhesive binding agents and adhesives containing them |
| US4810762A (en) * | 1985-10-28 | 1989-03-07 | Shell Oil Company | Polymer of dicyclopentadiene and a process for preparation |
| US5391670A (en) * | 1993-08-09 | 1995-02-21 | Hercules Incorporated | Alkylation resins from polycyclic aromatic compounds |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1275694A (en) * | 1959-12-07 | 1961-11-10 | Shell Int Research | Superior quality catalyst |
-
1963
- 1963-02-01 DE DEB70578A patent/DE1195497B/en active Pending
-
1964
- 1964-01-17 GB GB210164A patent/GB1043360A/en not_active Expired
- 1964-01-29 NL NL6400706A patent/NL6400706A/xx unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5028968B1 (en) * | 1969-12-30 | 1975-09-19 | ||
| US4255297A (en) * | 1977-12-22 | 1981-03-10 | Hoechst Aktiengesellschaft | Adhesive binding agents and adhesives containing them |
| US4810762A (en) * | 1985-10-28 | 1989-03-07 | Shell Oil Company | Polymer of dicyclopentadiene and a process for preparation |
| US5391670A (en) * | 1993-08-09 | 1995-02-21 | Hercules Incorporated | Alkylation resins from polycyclic aromatic compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1195497B (en) | 1965-06-24 |
| NL6400706A (en) | 1964-08-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES420650A1 (en) | Process for dry polymerization of olefins | |
| ES448202A1 (en) | Dry polymerization of olefins in reaction vessels arranged in series | |
| GB1043360A (en) | Production of homopolymers and copolymers of unsaturated hydrocarbons | |
| GB1360390A (en) | Polymerisation processes using friedel crafts catalysts | |
| GB1379150A (en) | Synthetic hydrocarbon resins their production and use | |
| GB1020563A (en) | Process for polymerizing ethylene | |
| GB967836A (en) | Copolymers of ethylene with cycloolefins and process for preparing the same | |
| GB1077349A (en) | Copolymerization of alpha olefins | |
| GB1123427A (en) | Batchwise catalytic hydrogenation of hydrocarbon resins | |
| GB1336369A (en) | Homo polymerisation of vinyl carbazole | |
| ES424778A1 (en) | Ethylene polymerisation | |
| ES368488A1 (en) | PROCEDURE FOR PREPARING RANDOM COPOLYMERS OF STYRENE AND BUTADIEN. | |
| NL7114677A (en) | Rubbery diene (co) polymers prodn - by polymerising conjugated diolefins with alfin catalyst and 1,2-diolefin mol wt regulator | |
| GB906225A (en) | Improved synthetic rubber | |
| GB1038103A (en) | Process for preparing copolymers | |
| GB890913A (en) | Improved process for the polymerisation of alpha-olefins | |
| ES312212A1 (en) | Procedure to polymerize olefins. (Machine-translation by Google Translate, not legally binding) | |
| GB935425A (en) | 1, 3-butadiene/isoprene copolymers | |
| GB1130680A (en) | Polymerisation of isobutene | |
| KOBAYASHI et al. | Plasma polymerization of saturated and unsaturated hydrocarbons(using radio frequency glow discharge) | |
| GB850472A (en) | Improved process for the preparation of resins | |
| GB1163829A (en) | Method of increasing Molecular Weight | |
| GB924550A (en) | Production of isotactic polystyrene | |
| GB1062266A (en) | Reactive polymer and process of producing same | |
| FR2148938A5 (en) | Hydrocarbon purification - redn of cyclopentadienes in isoprene using carbonyls and basic catalyst |