GB1042005A - Improvements in or relating to the manufacture of rayon paper and non-woven fabrics from viscose - Google Patents
Improvements in or relating to the manufacture of rayon paper and non-woven fabrics from viscoseInfo
- Publication number
- GB1042005A GB1042005A GB21771/63A GB2177163A GB1042005A GB 1042005 A GB1042005 A GB 1042005A GB 21771/63 A GB21771/63 A GB 21771/63A GB 2177163 A GB2177163 A GB 2177163A GB 1042005 A GB1042005 A GB 1042005A
- Authority
- GB
- United Kingdom
- Prior art keywords
- filaments
- bath
- value
- viscose
- paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000297 Rayon Polymers 0.000 title abstract 7
- 239000004745 nonwoven fabric Substances 0.000 title abstract 4
- 239000002964 rayon Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 206010042674 Swelling Diseases 0.000 abstract 5
- 230000008961 swelling Effects 0.000 abstract 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 4
- 239000006185 dispersion Substances 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 230000001112 coagulating effect Effects 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 2
- 235000011152 sodium sulphate Nutrition 0.000 abstract 2
- 238000009987 spinning Methods 0.000 abstract 2
- 239000001117 sulphuric acid Substances 0.000 abstract 2
- 235000011149 sulphuric acid Nutrition 0.000 abstract 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 abstract 2
- 235000009529 zinc sulphate Nutrition 0.000 abstract 2
- 239000011686 zinc sulphate Substances 0.000 abstract 2
- 239000011230 binding agent Substances 0.000 abstract 1
- 210000000988 bone and bone Anatomy 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000004627 regenerated cellulose Substances 0.000 abstract 1
- 238000002166 wet spinning Methods 0.000 abstract 1
- 239000002759 woven fabric Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/02—Synthetic cellulose fibres
- D21H13/08—Synthetic cellulose fibres from regenerated cellulose
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Paper (AREA)
- Nonwoven Fabrics (AREA)
Abstract
Rayon paper or a non-woven fabric is made by dispersing in water staple fibres formed from incompletely regenerated filaments obtained by wet-spinning viscose, said filaments having a "primary swelling value" of 250 to 2400% and a residual gamma value of 2 to 20 and thereafter forming paper or a non-woven fabric from the resulting dispersion. The "primary swelling value" of the filaments is determined by steeping a known weight of the bone dry filaments in water at 20 DEG C. for 5 minutes, centrifuging the swollen filaments thereby obtained at a centrifugal force of 1000G for 3 minutes and then reweighing the filaments. The "primary swelling value" is calculated according to the formula (W/WD) 100%, wherein W is the weight of the hydroextracted filaments and WD the weight of the bone-dry filaments. Incompletely regenerated cellulose suitable for the process of the invention, having a denier of 1 to 10 and a primary swelling value of 250 to 800% may be obtained by spinning viscose into an aqueous coagulating bath containing at least 250g/1 of sodium sulphate, less than 20g/1 of zinc sulphate and less than 30g/1 of sulphuric acid, and which is at a temperature of 10 to 45 DEG C., the filaments being in the bath for from 0.6 to 1.2 seconds and the bath liquor being removed from the filaments by stretching them by from 50 to 150% after their removal from the bath. Alternatively filaments suitable for the process of the invention, having a denier of 1 to 10 and a primary swelling value of 250 to 1900% may be obtained by spinning viscose the cellulose in which has a D.P. value of from 450 to 900 and which viscose has a gamma value of 60 to 100 into an aqueous coagulating bath which contains 30 to 300g/1 of sodium sulphate, 0.1 to 2.0g/1 of zinc sulphate and 3 to 25g/1 of sulphuric acid and which is maintained at 10 to 45 DEG C., the filaments being in the bath for 0.6 to 1.2 seconds and stretched by 150 to 220% after their removal from the bath. The staple fibres into which the filaments are cut may be from 2mm. to 20mm. in length. Paper and non-woven fabrics may be produced from the aqueous dispersions of the staple fibres by conventional methods. The water swollen fibres passes sufficient bonding power to render it unnecessary to add a binder, such as a synthetic high polymer, to the dispersion prior to making paper or woven fabrics therefrom.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2169562 | 1962-05-31 | ||
| JP2057463 | 1963-04-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1042005A true GB1042005A (en) | 1966-09-07 |
Family
ID=26357549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB21771/63A Expired GB1042005A (en) | 1962-05-31 | 1963-05-30 | Improvements in or relating to the manufacture of rayon paper and non-woven fabrics from viscose |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3320117A (en) |
| AT (1) | AT273657B (en) |
| BE (1) | BE633044A (en) |
| CH (1) | CH413581A (en) |
| DE (2) | DE1300824B (en) |
| GB (1) | GB1042005A (en) |
| NL (2) | NL293506A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL134509C (en) * | 1965-08-03 | |||
| US3870596A (en) * | 1971-06-22 | 1975-03-11 | Tachikawa Res Inst | Process for the preparation of dispersion water for incompletely regenerated cellulose substance |
| JPS531842B2 (en) * | 1973-06-18 | 1978-01-23 | ||
| US3901760A (en) * | 1973-12-07 | 1975-08-26 | Tachikawa Res Inst | Method for the aftertreatment of paper or nonwoven fabrics made of incompletely regenerated viscose fibers |
| US4425126A (en) | 1979-12-28 | 1984-01-10 | Johnson & Johnson Baby Products Company | Fibrous material and method of making the same using thermoplastic synthetic wood pulp fibers |
| US4392861A (en) * | 1980-10-14 | 1983-07-12 | Johnson & Johnson Baby Products Company | Two-ply fibrous facing material |
| US20020164913A1 (en) * | 2001-05-04 | 2002-11-07 | Pieters Gerogeann | Composite material |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL246561A (en) * | 1958-12-31 | |||
| US3114747A (en) * | 1959-03-26 | 1963-12-17 | Du Pont | Process for producing a fibrous regenerated cellulose precipitate |
| US3173830A (en) * | 1959-06-16 | 1965-03-16 | Courtaulds Ltd | Paper comprising collapsed regenerated cellulose fibers |
| US3156605A (en) * | 1960-03-25 | 1964-11-10 | Fmc Corp | Regenerated cellulose fiber |
| BE624034A (en) * | 1962-11-14 |
-
0
- NL NL131600D patent/NL131600C/xx active
- NL NL293506D patent/NL293506A/xx unknown
- BE BE633044D patent/BE633044A/xx unknown
-
1963
- 1963-05-24 CH CH648263A patent/CH413581A/en unknown
- 1963-05-27 DE DET24060A patent/DE1300824B/en active Pending
- 1963-05-27 DE DE19631794163 patent/DE1794163A1/en active Pending
- 1963-05-28 US US283686A patent/US3320117A/en not_active Expired - Lifetime
- 1963-05-30 AT AT439263A patent/AT273657B/en active
- 1963-05-30 GB GB21771/63A patent/GB1042005A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US3320117A (en) | 1967-05-16 |
| DE1300824B (en) | 1969-08-07 |
| NL293506A (en) | |
| NL131600C (en) | |
| BE633044A (en) | |
| AT273657B (en) | 1969-08-25 |
| CH413581A (en) | 1966-05-15 |
| DE1794163A1 (en) | 1971-01-28 |
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