GB1040895A - Stabilised copolymers of trioxane - Google Patents
Stabilised copolymers of trioxaneInfo
- Publication number
- GB1040895A GB1040895A GB2677964A GB2677964A GB1040895A GB 1040895 A GB1040895 A GB 1040895A GB 2677964 A GB2677964 A GB 2677964A GB 2677964 A GB2677964 A GB 2677964A GB 1040895 A GB1040895 A GB 1040895A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- radical
- acid
- trioxane
- copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title abstract 2
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 title 1
- 239000002253 acid Substances 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000004414 alkyl thio group Chemical group 0.000 abstract 2
- -1 cyclic acetal Chemical class 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Chemical group 0.000 abstract 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000005626 carbonium group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000004292 cyclic ethers Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 150000002596 lactones Chemical class 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
- C08G2/06—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
- C08G2/18—Copolymerisation of aldehydes or ketones
- C08G2/24—Copolymerisation of aldehydes or ketones with acetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G4/00—Condensation polymers of aldehydes or ketones with polyalcohols; Addition polymers of heterocyclic oxygen compounds containing in the ring at least once the grouping —O—C—O—
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
Trioxane copolymers are prepared at 40 DEG to 150 DEG C., in the presence of, as catalyst, a carbonium salt of formula <FORM:1040895/C3/1> where R is alkyl, X is oxygen or sulphur, R1 and R2 are the same or different and are hydrogen, alkyl, alkoxy or alkyl mercapto and Y(-) is an anion which is formed from a Lewis acid by addition of an alkoxy radical, an alkyl mercapto radical or a halogen radical. The comonomer may be a cyclic ether, cyclic acetal, a lactone or a cyclic thio compound, e.g. oxthiolane and dioxolane. The acid salt may be produced in situ by adding a compound. <FORM:1040895/C3/2> to the polymerization mixture and then adding the ferris acid. The polymerization may take place in bulk, solution or suspension.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF0040169 | 1963-07-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1040895A true GB1040895A (en) | 1966-09-01 |
Family
ID=7098119
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2677964A Expired GB1040895A (en) | 1963-07-06 | 1964-06-29 | Stabilised copolymers of trioxane |
Country Status (6)
| Country | Link |
|---|---|
| AT (1) | AT251879B (en) |
| BE (1) | BE650133A (en) |
| CH (1) | CH469038A (en) |
| DE (1) | DE1495727A1 (en) |
| GB (1) | GB1040895A (en) |
| NL (1) | NL6407589A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102680393B1 (en) * | 2023-12-29 | 2024-07-02 | 한국폴리아세탈 주식회사 | Polyoxyalkylene resin and method for producing the same |
-
1963
- 1963-07-06 DE DE19631495727 patent/DE1495727A1/en active Pending
-
1964
- 1964-06-12 CH CH770864A patent/CH469038A/en unknown
- 1964-06-29 GB GB2677964A patent/GB1040895A/en not_active Expired
- 1964-07-01 AT AT564764A patent/AT251879B/en active
- 1964-07-03 NL NL6407589A patent/NL6407589A/xx unknown
- 1964-07-06 BE BE650133D patent/BE650133A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH469038A (en) | 1969-02-28 |
| DE1495727A1 (en) | 1969-04-10 |
| BE650133A (en) | 1964-11-03 |
| NL6407589A (en) | 1965-01-07 |
| AT251879B (en) | 1967-01-25 |
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