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FR3112030B1 - Utilisation d’éléments électrochimiques secondaires au lithium contenant un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer pour des applications automobiles - Google Patents

Utilisation d’éléments électrochimiques secondaires au lithium contenant un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer pour des applications automobiles Download PDF

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Publication number
FR3112030B1
FR3112030B1 FR2006764A FR2006764A FR3112030B1 FR 3112030 B1 FR3112030 B1 FR 3112030B1 FR 2006764 A FR2006764 A FR 2006764A FR 2006764 A FR2006764 A FR 2006764A FR 3112030 B1 FR3112030 B1 FR 3112030B1
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France
Prior art keywords
lithiated
iron phosphate
mixture
nickel oxide
lithium secondary
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2006764A
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English (en)
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FR3112030A1 (fr
Inventor
Cécile Tessier
Patrick Bernard
Nechev Kamen
Carine Margez
Xilin Chen
Cédric Gousset
Sylvie Herreyre
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SAFT Societe des Accumulateurs Fixes et de Traction SA
Original Assignee
SAFT Societe des Accumulateurs Fixes et de Traction SA
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Publication date
Priority to FR2006764A priority Critical patent/FR3112030B1/fr
Application filed by SAFT Societe des Accumulateurs Fixes et de Traction SA filed Critical SAFT Societe des Accumulateurs Fixes et de Traction SA
Priority to PCT/EP2021/067124 priority patent/WO2021259991A2/fr
Priority to EP23180572.2A priority patent/EP4239701A3/fr
Priority to US18/002,596 priority patent/US20230231129A1/en
Priority to EP23180570.6A priority patent/EP4239700A3/fr
Priority to EP21737000.6A priority patent/EP4173062A2/fr
Priority to CN202180045476.5A priority patent/CN115777153B/zh
Publication of FR3112030A1 publication Critical patent/FR3112030A1/fr
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Publication of FR3112030B1 publication Critical patent/FR3112030B1/fr
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48—Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/572—Means for preventing undesired use or discharge
    • H01M50/574—Devices or arrangements for the interruption of current
    • H01M50/578—Devices or arrangements for the interruption of current in response to pressure
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/572—Means for preventing undesired use or discharge
    • H01M50/574—Devices or arrangements for the interruption of current
    • H01M50/581—Devices or arrangements for the interruption of current in response to temperature
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2200/00—Safety devices for primary or secondary batteries
    • H01M2200/10—Temperature sensitive devices
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2200/00—Safety devices for primary or secondary batteries
    • H01M2200/20—Pressure-sensitive devices
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

L’utilisation d'un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer comme composition de matériaux actifs dans la cathode d'un élément électrochimique secondaire au lithium pour des applications automobiles, telles que des véhicules hybrides et électriques. Ce mélange permet de diminuer la porosité d'une cathode à base de phosphate lithié de manganèse et de fer. Il permet également d'améliorer la détectabilité d'un dégagement gazeux dans l’élément en cas de fonctionnement anormal de l’élément. Il permet d'abaisser l'impédance de l’élément, pour un faible état de charge, généralement inférieur à 30 %, et de réduire l'augmentation d'impédance de l’élément pendant la durée de vie de l’élément.
FR2006764A 2020-06-26 2020-06-26 Utilisation d’éléments électrochimiques secondaires au lithium contenant un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer pour des applications automobiles Active FR3112030B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR2006764A FR3112030B1 (fr) 2020-06-26 2020-06-26 Utilisation d’éléments électrochimiques secondaires au lithium contenant un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer pour des applications automobiles
EP23180572.2A EP4239701A3 (fr) 2020-06-26 2021-06-23 Utilisation de piles électrochimiques secondaires au lithium contenant un mélange d'oxyde de lithium-nickel et de phosphate de lithium-manganèse-fer pour des applications automobiles
US18/002,596 US20230231129A1 (en) 2020-06-26 2021-06-23 Use of lithium secondary electrochemical cells containing a blend of a lithium nickel oxide and a lithium manganese iron phosphate for automotive applications
EP23180570.6A EP4239700A3 (fr) 2020-06-26 2021-06-23 Utilisation de piles électrochimiques secondaires au lithium contenant un mélange d'oxyde de lithium-nickel et de phosphate de lithium-manganèse-fer pour des applications automobiles
PCT/EP2021/067124 WO2021259991A2 (fr) 2020-06-26 2021-06-23 Utilisation de piles électrochimiques au lithium rechargeables contenant un mélange d'un oxyde de lithium-nickel et un de lithium-fer-manganèse phosphate pour des applications automobiles
EP21737000.6A EP4173062A2 (fr) 2020-06-26 2021-06-23 Utilisation de piles électrochimiques au lithium rechargeables contenant un mélange d'un oxyde de lithium-nickel et un de lithium-fer-manganèse phosphate pour des applications automobiles
CN202180045476.5A CN115777153B (zh) 2020-06-26 2021-06-23 包含锂镍氧化物和磷酸锰铁锂的混合物的锂二次电化学电池在汽车应用中的用途

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2006764A FR3112030B1 (fr) 2020-06-26 2020-06-26 Utilisation d’éléments électrochimiques secondaires au lithium contenant un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer pour des applications automobiles
FR2006764 2020-06-26

Publications (2)

Publication Number Publication Date
FR3112030A1 FR3112030A1 (fr) 2021-12-31
FR3112030B1 true FR3112030B1 (fr) 2022-12-16

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FR2006764A Active FR3112030B1 (fr) 2020-06-26 2020-06-26 Utilisation d’éléments électrochimiques secondaires au lithium contenant un mélange d'un oxyde lithié de nickel et d'un phosphate lithié de manganèse et de fer pour des applications automobiles

Country Status (5)

Country Link
US (1) US20230231129A1 (fr)
EP (3) EP4239701A3 (fr)
CN (1) CN115777153B (fr)
FR (1) FR3112030B1 (fr)
WO (1) WO2021259991A2 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3142295B1 (fr) 2022-11-17 2025-04-18 Accumulateurs Fixes Élément électrochimique rechargeable au lithium pour applications à l'aviation

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0919654B1 (pt) * 2008-10-22 2019-07-30 Lg Chem, Ltd. Fosfato de ferro-lítio do tipo olivina, mistura de catodo e bateria secundária de lítio
JP5381024B2 (ja) * 2008-11-06 2014-01-08 株式会社Ｇｓユアサ リチウム二次電池用正極及びリチウム二次電池
JP5672113B2 (ja) * 2010-03-31 2015-02-18 株式会社Ｇｓユアサ 非水電解質二次電池
US20120231341A1 (en) * 2011-03-09 2012-09-13 Jun-Sik Kim Positive active material, and electrode and lithium battery containing the positive active material
US20140045069A1 (en) * 2011-04-28 2014-02-13 Tatsuji Numata Lithium secondary cell
KR101308677B1 (ko) * 2011-05-31 2013-09-13 주식회사 코캄 리튬 이차전지
WO2013016426A1 (fr) * 2011-07-25 2013-01-31 A123 Systems, Inc. Matières mélangées pour cathodes
US9991566B2 (en) * 2011-11-03 2018-06-05 Johnson Controls Technology Company Cathode active material for overcharge protection in secondary lithium batteries
JP6065901B2 (ja) * 2012-02-29 2017-01-25 日立化成株式会社 リチウムイオン電池
JP2014192143A (ja) * 2013-03-28 2014-10-06 Shin Kobe Electric Mach Co Ltd リチウムイオン電池
KR101938462B1 (ko) * 2013-07-09 2019-01-14 다우 글로벌 테크놀로지스 엘엘씨 리튬 금속 산화물 및 리튬 금속 포스페이트를 포함하는 혼합된 양성 활성 물질
JP6079696B2 (ja) * 2014-05-19 2017-02-15 トヨタ自動車株式会社 非水電解液二次電池
JP6596826B2 (ja) * 2015-01-15 2019-10-30 株式会社デンソー 電極及び非水電解質二次電池
FR3036538B1 (fr) * 2015-05-19 2017-05-19 Accumulateurs Fixes Electrode positive pour generateur electrochimique au lithium
JP6674631B2 (ja) * 2016-06-23 2020-04-01 トヨタ自動車株式会社 リチウムイオン二次電池
JPWO2020066909A1 (ja) * 2018-09-25 2021-08-30 東レ株式会社 二次電池用電極およびリチウムイオン二次電池

Also Published As

Publication number Publication date
WO2021259991A3 (fr) 2022-04-14
EP4239701A2 (fr) 2023-09-06
EP4239701A3 (fr) 2024-01-17
CN115777153B (zh) 2025-10-28
US20230231129A1 (en) 2023-07-20
WO2021259991A2 (fr) 2021-12-30
CN115777153A (zh) 2023-03-10
EP4239700A3 (fr) 2024-01-17
EP4173062A2 (fr) 2023-05-03
EP4239700A2 (fr) 2023-09-06
FR3112030A1 (fr) 2021-12-31

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