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FR3022161B1 - Catalyseur a phase active de nickel comalaxee mesoporeux et macroporeux ayant un diametre median macroporeux superieur a 300 nm et son utilisation en hydrogenation - Google Patents

Catalyseur a phase active de nickel comalaxee mesoporeux et macroporeux ayant un diametre median macroporeux superieur a 300 nm et son utilisation en hydrogenation Download PDF

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Publication number
FR3022161B1
FR3022161B1 FR1455430A FR1455430A FR3022161B1 FR 3022161 B1 FR3022161 B1 FR 3022161B1 FR 1455430 A FR1455430 A FR 1455430A FR 1455430 A FR1455430 A FR 1455430A FR 3022161 B1 FR3022161 B1 FR 3022161B1
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FR
France
Prior art keywords
macroporeous
active phase
nickel
catalyst
comalaxed
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Active
Application number
FR1455430A
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English (en)
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FR3022161A1 (fr
Inventor
Malika Boualleg
Anne-Claire Dubreuil
Emily Maille
Cecile Thomazeau
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1455430A priority Critical patent/FR3022161B1/fr
Priority to US15/318,611 priority patent/US10258969B2/en
Priority to CN201580031619.1A priority patent/CN106604978B/zh
Priority to EP15730988.1A priority patent/EP3154686A1/fr
Priority to PCT/EP2015/062817 priority patent/WO2015189191A1/fr
Priority to RU2017100932A priority patent/RU2683776C2/ru
Publication of FR3022161A1 publication Critical patent/FR3022161A1/fr
Application granted granted Critical
Publication of FR3022161B1 publication Critical patent/FR3022161B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/36—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J33/00—Protection of catalysts, e.g. by coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009—Preparation by separation, e.g. by filtration, decantation, screening
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C07C5/05—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/48—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/52—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1096—Aromatics or polyaromatics
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/705—Passivation

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  • Chemical & Material Sciences (AREA)
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  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
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  • Crystallography & Structural Chemistry (AREA)

Abstract

L'invention concerne un catalyseur comprenant une matrice oxyde majoritairement aluminique calcinée et une phase active comprenant du nickel, ladite phase active étant au moins en partie comalaxée au sein de ladite matrice oxyde majoritairement aluminique calcinée, la teneur en nickel étant comprise entre 5 et 65 % poids dudit élément par rapport à la masse totale du catalyseur, ladite phase active ne comprenant pas de métal du groupe VIB, les particules de nickel ayant un diamètre inférieur à 15 nm, ledit catalyseur ayant un diamètre médian mésoporeux compris entre 8 et 25 nm, un diamètre médian macroporeux supérieur à 300 nm, un volume mésoporeux mesuré par porosimétrie au mercure supérieur ou égal à 0,30 mL/g et un volume poreux total mesuré par porosimétrie au mercure supérieur ou égal à 0,34 mL/g. L'invention concerne également le procédé de préparation dudit catalyseur et son utilisation dans un procédé d'hydrogénation.
FR1455430A 2014-06-13 2014-06-13 Catalyseur a phase active de nickel comalaxee mesoporeux et macroporeux ayant un diametre median macroporeux superieur a 300 nm et son utilisation en hydrogenation Active FR3022161B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR1455430A FR3022161B1 (fr) 2014-06-13 2014-06-13 Catalyseur a phase active de nickel comalaxee mesoporeux et macroporeux ayant un diametre median macroporeux superieur a 300 nm et son utilisation en hydrogenation
US15/318,611 US10258969B2 (en) 2014-06-13 2015-06-09 Catalyst with a mesoporous and macroporous co-mixed nickel active phase having a median macropore diameter of more than 300 nm, and its use in hydrogenation
CN201580031619.1A CN106604978B (zh) 2014-06-13 2015-06-09 具有大于300纳米中值大孔直径的中孔和大孔共混镍活性相的催化剂及其在氢化中的用途
EP15730988.1A EP3154686A1 (fr) 2014-06-13 2015-06-09 Catalyseur mesoporeux et macroporeux a base de nickel obtenu par comalaxage et ayant un diametre median macroporeux superieur a 300 nm et son utilisation en hydrogenation d'hydrocarbures
PCT/EP2015/062817 WO2015189191A1 (fr) 2014-06-13 2015-06-09 Catalyseur mesoporeux et macroporeux a base de nickel obtenu par comalaxage et ayant un diametre median macroporeux superieur a 300 nm et son utilisation en hydrogenation d'hydrocarbures
RU2017100932A RU2683776C2 (ru) 2014-06-13 2015-06-09 Мезопористый и макропористый катализатор на основе никеля, полученный совместным пластицированием и имеющий медианный диаметр макропор, превышающий 300 нм, и его применение при гидрировании углеводородов

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Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3025728B1 (fr) * 2014-09-11 2018-04-20 IFP Energies Nouvelles Catalyseur mesoporeux a base de nickel et son utilisation en hydrogenation.
FR3061036B1 (fr) 2016-12-23 2021-07-02 Ifp Energies Now Solide porteur d'oxygene macroporeux a matrice ceramique d'oxydes, son procede de preparation et son utilisation pour un procede d'oxydo-reduction en boucle chimique
FR3061037B1 (fr) * 2016-12-23 2021-07-02 Ifp Energies Now Solide porteur d'oxygene a base de tectosilicates, son procede de preparation et son utilisation pour un procede d'oxydo-reduction en boucle chimique
US12281266B2 (en) 2017-02-12 2025-04-22 Magẽmã Technology LLC Heavy marine fuel oil composition
US10655074B2 (en) 2017-02-12 2020-05-19 Mag{hacek over (e)}m{hacek over (a)} Technology LLC Multi-stage process and device for reducing environmental contaminates in heavy marine fuel oil
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
US12025435B2 (en) 2017-02-12 2024-07-02 Magēmã Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil
US12071592B2 (en) 2017-02-12 2024-08-27 Magēmā Technology LLC Multi-stage process and device utilizing structured catalyst beds and reactive distillation for the production of a low sulfur heavy marine fuel oil
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
CN108786833B (zh) * 2017-05-02 2020-09-11 中国石油化工股份有限公司 一种重油加氢催化剂及其制备方法
FR3068982A1 (fr) * 2017-07-13 2019-01-18 IFP Energies Nouvelles Procede d'hydrogenation selective mettant en œuvre un catalyseur obtenu par comalaxage comprenant un support specifique
FR3068985A1 (fr) * 2017-07-13 2019-01-18 IFP Energies Nouvelles Procede d’hydrogenation des aromatiques mettant en oeuvre un catalyseur obtenu par comalaxage comprenant un support specifique
FR3068984B1 (fr) * 2017-07-13 2020-01-17 IFP Energies Nouvelles Procede d'hydrogenation des aromatiques mettant en œuvre un catalyseur obtenu par impregnation comprenant un support specifique.
FR3076747B1 (fr) * 2018-01-15 2022-06-10 Ifp Energies Now Procede de preparation d'un catalyseur particulier d'hydrogenation selective et d'hydrogenation des aromatiques par malaxage
FR3076746B1 (fr) * 2018-01-15 2022-07-01 Ifp Energies Now Procede de preparation d'un catalyseur particulier d'hydrogenation selective par malaxage et impregnation
FR3080117B1 (fr) * 2018-04-11 2020-04-03 IFP Energies Nouvelles Procede de captation de l'arsenic mettant en œuvre une masse de captation a base de particules d'oxyde de nickel
FR3083992B1 (fr) * 2018-07-23 2020-07-24 Ifp Energies Now Catalyseur comalaxe issu de solutions a base d'heteropolyanions, son procede de preparation et son utilisation en hydroconversion de charges hydrocarbonees lourdes
FR3099388B1 (fr) * 2019-07-31 2021-07-16 Ifp Energies Now Catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute et un alliage nickel cuivre
CN112717940B (zh) * 2019-10-28 2023-07-21 中国石油化工股份有限公司 用于制γ-丁内酯的催化剂及其制备方法和应用
US20250091037A1 (en) 2023-09-19 2025-03-20 Indian Oil Corporation Limited Catalyst for hydrogenation of unsaturated hydrocarbons and a method for preparation thereof

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4301037A (en) * 1980-04-01 1981-11-17 W. R. Grace & Co. Extruded alumina catalyst support having controlled distribution of pore sizes
NL190750C (nl) * 1984-06-21 1994-08-01 Unilever Nv Nikkelaluminaat katalysator, de bereiding daarvan en het hydrogeneren van onverzadigde organische verbindingen daarmee.
US4920089A (en) * 1987-05-08 1990-04-24 Unilever Patent Holdings B.V. Hydrogenation catalyst
DE4310971A1 (de) * 1993-04-03 1994-10-06 Huels Chemische Werke Ag Nickel/Aluminiumoxid-Katalysator, Verfahren zu seiner Herstellung, seine Verwendung sowie Verfahren zur Hydrierung von aromatischen Kohlenwasserstoffen mit Hilfe des Katalysators
JP3304360B2 (ja) * 1996-03-05 2002-07-22 護郎 佐藤 アルミナゾル及びその製造方法、及びそれを用いたアルミナ成型体の製造方法、及びそれによって得られたアルミナ系触媒
CA2394534C (fr) * 1999-12-21 2007-07-17 W.R. Grace & Co.-Conn. Composites d'oxyde d'aluminium a volume de pore et surface eleves, derives de trihydrate d'alumine, procedes de preparations et utilisations associes
US6589908B1 (en) * 2000-11-28 2003-07-08 Shell Oil Company Method of making alumina having bimodal pore structure, and catalysts made therefrom
RU2376059C2 (ru) * 2003-09-17 2009-12-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ и катализатор гидроконверсии тяжелого углеводородного исходного сырья
WO2009029579A1 (fr) * 2007-08-27 2009-03-05 Shell Oil Company Catalyseur d'hydrogénation d'hydrocarbures aromatiques et procédé de fabrication et d'utilisation d'un tel catalyseur

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FR3022161A1 (fr) 2015-12-18
US10258969B2 (en) 2019-04-16
WO2015189191A1 (fr) 2015-12-17
RU2017100932A (ru) 2018-07-16
EP3154686A1 (fr) 2017-04-19
US20170120224A1 (en) 2017-05-04
CN106604978B (zh) 2020-03-03
RU2017100932A3 (fr) 2018-12-14
CN106604978A (zh) 2017-04-26

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