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FR3095651B1 - Particules nanocomposites conductrices étirables - Google Patents

Particules nanocomposites conductrices étirables Download PDF

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Publication number
FR3095651B1
FR3095651B1 FR1904606A FR1904606A FR3095651B1 FR 3095651 B1 FR3095651 B1 FR 3095651B1 FR 1904606 A FR1904606 A FR 1904606A FR 1904606 A FR1904606 A FR 1904606A FR 3095651 B1 FR3095651 B1 FR 3095651B1
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FR
France
Prior art keywords
nanocomposite particles
conductive nanocomposite
stretchable conductive
relates
stretchable support
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1904606A
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English (en)
Other versions
FR3095651A1 (fr
Inventor
Stéphanie Reynaud
Pierre Marcasuzaa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Universite de Pau et des Pays de lAdour
Original Assignee
Centre National de la Recherche Scientifique CNRS
Universite de Pau et des Pays de lAdour
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Universite de Pau et des Pays de lAdour filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR1904606A priority Critical patent/FR3095651B1/fr
Priority to CA3138032A priority patent/CA3138032A1/fr
Priority to JP2021562313A priority patent/JP2022530377A/ja
Priority to PCT/EP2020/062011 priority patent/WO2020221853A1/fr
Priority to EP20724029.2A priority patent/EP3963015A1/fr
Priority to US17/442,424 priority patent/US11810688B2/en
Publication of FR3095651A1 publication Critical patent/FR3095651A1/fr
Application granted granted Critical
Publication of FR3095651B1 publication Critical patent/FR3095651B1/fr
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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/52Electrically conductive inks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02Polyamines
    • C08G73/026Wholly aromatic polyamines
    • C08G73/0266Polyanilines or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/046Reinforcing macromolecular compounds with loose or coherent fibrous material with synthetic macromolecular fibrous material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24Homopolymers or copolymers of amides or imides
    • C08L33/26Homopolymers or copolymers of acrylamide or methacrylamide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/02Polyamines
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D179/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
    • C09D179/02Polyamines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/24Homopolymers or copolymers of amides or imides
    • C08J2333/26Homopolymers or copolymers of acrylamide or methacrylamide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2379/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
    • C08J2379/02Polyamines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Laminated Bodies (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

La présente invention concerne l’utilisation de particules nanocomposites électriquement conductrices comprenant un cœur constitué d’un homopolymère de polyacrylate d’alkyle en C1-C6 ou d’un copolymère d’acrylate d’alkyle en C1-C6 et d’un comonomère amide α,β insaturé, une écorce constituée de polyaniline, et un tensioactif non ionique pour réaliser une impression sur un support étirable. Elle concerne également un support étirable imprimé obtenu selon l’invention et utilisable par exemple dans le domaine de l’électronique imprimée ou des vêtements connectés.Figure pour l’abrégé : Pas de figure
FR1904606A 2019-05-02 2019-05-02 Particules nanocomposites conductrices étirables Active FR3095651B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR1904606A FR3095651B1 (fr) 2019-05-02 2019-05-02 Particules nanocomposites conductrices étirables
CA3138032A CA3138032A1 (fr) 2019-05-02 2020-04-30 Particules nanocomposites conductrices etirables
JP2021562313A JP2022530377A (ja) 2019-05-02 2020-04-30 伸縮性のある導電性ナノコンポジット粒子
PCT/EP2020/062011 WO2020221853A1 (fr) 2019-05-02 2020-04-30 Particules nanocomposites conductrices étirables
EP20724029.2A EP3963015A1 (fr) 2019-05-02 2020-04-30 Particules nanocomposites conductrices étirables
US17/442,424 US11810688B2 (en) 2019-05-02 2020-04-30 Stretchable conductive nanocomposite particles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1904606A FR3095651B1 (fr) 2019-05-02 2019-05-02 Particules nanocomposites conductrices étirables
FR1904606 2019-05-02

Publications (2)

Publication Number Publication Date
FR3095651A1 FR3095651A1 (fr) 2020-11-06
FR3095651B1 true FR3095651B1 (fr) 2021-12-03

Family

ID=67999785

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1904606A Active FR3095651B1 (fr) 2019-05-02 2019-05-02 Particules nanocomposites conductrices étirables

Country Status (6)

Country Link
US (1) US11810688B2 (fr)
EP (1) EP3963015A1 (fr)
JP (1) JP2022530377A (fr)
CA (1) CA3138032A1 (fr)
FR (1) FR3095651B1 (fr)
WO (1) WO2020221853A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118355080A (zh) * 2021-12-02 2024-07-16 爱克发有限公司 喷墨打印用树脂颗粒分散体
CN114773823B (zh) * 2022-04-18 2024-02-23 中国科学技术大学 粘弹性高分子复合导电材料及其制备方法和应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000174400A (ja) * 1998-12-10 2000-06-23 Alps Electric Co Ltd フレキシブルプリント基板
JP2001023437A (ja) * 1999-07-09 2001-01-26 Hitachi Chem Co Ltd ポリアニリン系ペースト、これを用いた固体電解コンデンサの製造法及び固体電解コンデンサ
US7033639B2 (en) * 2001-05-16 2006-04-25 Rohm And Haas Company Polyaniline coating composition
FR2889197B1 (fr) * 2005-07-29 2010-12-24 Univ Pau Et Des Pays De L Adour Particules nanocomposites electriquement conductrices possedant un coeur de polyacrylate d'alkyle et une ecorce de polyaniline
WO2007111996A2 (fr) * 2006-03-24 2007-10-04 Clemson University Encre polymère conductrice
KR101890308B1 (ko) * 2011-06-07 2018-08-21 주식회사 한국엔티켐 다층구조의 전도성 나노입자 및 이의 제조방법
FR2993098B1 (fr) * 2012-07-09 2019-11-01 Commissariat A L'energie Atomique Et Aux Energies Alternatives Collecteur de courant pour batterie lithium
US9922746B2 (en) * 2013-03-01 2018-03-20 The Regents Of The University Of Michigan Stretchable composite conductors for flexible electronics, stretchable plasmonic devices, optical filters, and implantable devices and methods for manufacture thereof
EP3118069A1 (fr) 2015-07-17 2017-01-18 U-Shin Deutschland Zugangssysteme GmbH Dispositif de verrouillage de colonne de direction électrique
JP6973087B2 (ja) * 2016-02-12 2021-11-24 東洋紡株式会社 衣服型電子機器、および衣服型電子機器の製造方法
KR102248989B1 (ko) * 2016-09-30 2021-05-06 세키스이가세이힝코교가부시키가이샤 도전성 수지 입자 및 그 용도

Also Published As

Publication number Publication date
JP2022530377A (ja) 2022-06-29
WO2020221853A1 (fr) 2020-11-05
FR3095651A1 (fr) 2020-11-06
US11810688B2 (en) 2023-11-07
EP3963015A1 (fr) 2022-03-09
CA3138032A1 (fr) 2020-11-05
US20220189653A1 (en) 2022-06-16

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