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FR3076745B1 - Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante - Google Patents

Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante Download PDF

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Publication number
FR3076745B1
FR3076745B1 FR1850246A FR1850246A FR3076745B1 FR 3076745 B1 FR3076745 B1 FR 3076745B1 FR 1850246 A FR1850246 A FR 1850246A FR 1850246 A FR1850246 A FR 1850246A FR 3076745 B1 FR3076745 B1 FR 3076745B1
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France
Prior art keywords
hydrosilylation
dehydrogening
catalysts
nanoparticles useful
nanoparticles
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FR1850246A
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FR3076745A1 (fr
Inventor
Valerie Meille
Chloe Thieuleux
Laurent Veyre
Iurii Suleimanov
Thomas Galeandro-Diamant
Magali Bousquie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Chimie Physique Electronique de Lyon
Elkem Silicones France SAS
Universite Claude Bernard Lyon 1
Original Assignee
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Chimie Physique Electronique de Lyon
Elkem Silicones France SAS
Universite Claude Bernard Lyon 1
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Priority to FR1850246A priority Critical patent/FR3076745B1/fr
Application filed by Centre National de la Recherche Scientifique CNRS, Ecole Superieure de Chimie Physique Electronique de Lyon, Elkem Silicones France SAS, Universite Claude Bernard Lyon 1 filed Critical Centre National de la Recherche Scientifique CNRS
Priority to CN201980008074.0A priority patent/CN111936231B/zh
Priority to PCT/FR2019/050054 priority patent/WO2019138194A1/fr
Priority to EP19703165.1A priority patent/EP3737497A1/fr
Priority to KR1020207023073A priority patent/KR102408313B1/ko
Priority to JP2020559032A priority patent/JP7003293B2/ja
Priority to US16/961,643 priority patent/US11633728B2/en
Publication of FR3076745A1 publication Critical patent/FR3076745A1/fr
Application granted granted Critical
Publication of FR3076745B1 publication Critical patent/FR3076745B1/fr
Priority to US18/123,609 priority patent/US12179187B2/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
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    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
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  • Dispersion Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La présente invention concerne des nanoparticules utilisables comme catalyseurs, notamment comme catalyseurs d'hydrosilylation et de silylation déshydrogénante. Plus spécifiquement, la présente invention concerne des nanoparticules d'au moins un métal de transition au degré d'oxydation 0, choisi parmi les métaux des colonnes 8, 9 et 10 du tableau périodique des éléments, et comprenant au moins un ligand carbonyle.
FR1850246A 2018-01-12 2018-01-12 Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante Active FR3076745B1 (fr)

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FR1850246A FR3076745B1 (fr) 2018-01-12 2018-01-12 Nanoparticules utiles comme catalyseurs d'hydrosilylation et de silylation deshydrogenante
PCT/FR2019/050054 WO2019138194A1 (fr) 2018-01-12 2019-01-11 Catalyseurs de nanoparticules de complexes co de métaux zerovalents pour l'hydrosilylation] et la silylation deshydrogenante
EP19703165.1A EP3737497A1 (fr) 2018-01-12 2019-01-11 Catalyseurs de nanoparticules de complexes co de métaux zerovalents pour l'hydrosilylation] et la silylation deshydrogenante
KR1020207023073A KR102408313B1 (ko) 2018-01-12 2019-01-11 하이드로실릴화 및 탈수소 실릴화 촉매로서 유용한 나노입자
CN201980008074.0A CN111936231B (zh) 2018-01-12 2019-01-11 可以用作硅氢加成反应和脱氢硅烷化催化剂的零价金属co络合物的纳米颗粒
JP2020559032A JP7003293B2 (ja) 2018-01-12 2019-01-11 ヒドロシリル化及び脱水素化シリル化触媒として有用なナノ粒子
US16/961,643 US11633728B2 (en) 2018-01-12 2019-01-11 Nanoparticles of CO complexes of zero-valent metals that can be used as hydrosilylation and dehydrogenative silylation catalysts
US18/123,609 US12179187B2 (en) 2018-01-12 2023-03-20 Nanoparticles of co complexes of zero-valent metals that can be used as hydrosilylation and dehydrogenative silylation catalysts

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US12371446B2 (en) 2019-12-18 2025-07-29 Dow Silicones Corporation Catalyst particles and methods for dehydrogenative silylation
CN114901669B (zh) 2019-12-18 2025-06-24 美国陶氏有机硅公司 乙烯基官能化氯硅烷和乙基官能化氯硅烷的选择性制备
WO2025133478A1 (fr) 2023-12-22 2025-06-26 Elkem Silicones France Sas Procédé de préparation d'un article comprenant une couche de mousse silicone
WO2025133477A1 (fr) 2023-12-22 2025-06-26 Elkem Silicones France Sas Gel silicone adhésif à la peau
WO2025133480A1 (fr) 2023-12-22 2025-06-26 Elkem Silicones France Sas Composition silicone réticulable par polyaddition pour la préparation d'élastomère silicone thermoconducteur
CN119387601B (zh) * 2024-10-16 2025-11-07 浙江大学 一种硅烷稳定的镍掺杂纳米零价铁颗粒、制备方法和应用

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WO2019138194A1 (fr) 2019-07-18
FR3076745A1 (fr) 2019-07-19
EP3737497A1 (fr) 2020-11-18
US20230264183A1 (en) 2023-08-24
CN111936231B (zh) 2023-10-27
US12179187B2 (en) 2024-12-31
JP2021510349A (ja) 2021-04-22
JP7003293B2 (ja) 2022-02-10
US20200353454A1 (en) 2020-11-12
US11633728B2 (en) 2023-04-25
KR102408313B1 (ko) 2022-06-15
CN111936231A (zh) 2020-11-13

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