FR2848878A1 - Suspension of particles useful in cosmetics, detergents, foods and plastics, produced by crosslinking an oil-in-silicone-in-water or water-in-silicone-in-water emulsion - Google Patents

Abstract

Suspension of particles produced as follows is new: preparing an internal emulsion comprising an aqueous or organic phase dispersed in a crosslinkable silicone, dispersing the internal emulsion in an aqueous phase, and crosslinking the silicone. Suspension of particles produced as follows is new: preparing an internal emulsion comprising an aqueous or organic internal phase dispersed in a crosslinkable silicone in the presence of an emulsifier comprising a particulate surfactant (optionally with a cosurfactant) or a surface-active organosiloxane block or comb polymer (I) comprising a major fraction soluble in the internal phase and a minor fraction soluble in the silicone, dispersing the internal emulsion in an aqueous external phase in the presence of an emulsifier comprising a nonionic surfactant, a nonionic amphiphilic polymer (optionally with an anionic surfactant and/or an anionic amphiphilic polymer), a particulate surfactant (optionally with a cosurfactant) or a protective colloid, and crosslinking the silicone. An Independent claim is also included for particles produced by removing the external phase from the suspension.

Description

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SUSPENSION OF PARTICLES WITH MULTIPLE PHASES
The subject of the present invention is a suspension of particles having several phases, in particular useful for the formulation, vectorization, protection, encapsulation and / or controlled release of compounds in an application medium or in a material. The particles can also be useful for modifying the mechanical properties of materials. The suspension of particles, or the particles themselves, thus find, for example, applications in the fields of cosmetic formulations, detergent formulations, or food contact products, or in the reinforcement of plastics.

 In a number of applications, it is advantageous to provide one or more compounds having particular functions, for example active materials, etc.

 As a means of providing compounds in a formulation, emulsions are known. Simple direct emulsions make it possible, for example, to provide hydrophobic compounds in an aqueous medium. Multiple emulsions are also known, such as internal phase emulsions (aqueous or organic) in the silicone intermediate phase in the aqueous phase. Although very useful, these multiple emulsions find limits for certain applications. There is indeed a need for systems with a different profile for the release of active ingredients, or resistant to more restrictive handling, use or storage conditions in order to avoid destruction of said systems.

 Thus, the invention provides a suspension of particles capable of being obtained by a process comprising the following steps: - Step 1: of a multiple emulsion comprising: - an internal emulsion comprising an aqueous or organic internal phase, dispersed in an intermediate polyorganosiloxane phase, immiscible with the internal phase, and at least one internal emulsification compound, and - an external emulsion comprising the internal emulsion, dispersed in an aqueous external phase, and at least one external emulsification compound , characterized in that: - the intermediate phase is crosslinkable and comprises a crosslinkable polyorganosiloxane system, - the internal emulsification compound is: - a particulate surfactant, optionally combined with a co-surfactant, or

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 a comb or block surfactant polymer comprising organosiloxane units, one fraction of which is soluble in the internal phase, the other in the intermediate phase, the fraction soluble in the intermediate phase being greater than the fraction soluble in the internal phase, and - the external emulsification compound is: - a nonionic surfactant, - a nonionic amphiphilic polymer, optionally combined with one or more anionic surfactants and / or anionic amphiphilic polymers, - a particulate surfactant optionally combined with a co-surfactant, or - a protective colloid, - Step 2: crosslinking of the intermediate phase.

General description of the multiple emulsion
The suspension is capable of being obtained by a process comprising a step of preparing a multiple emulsion, and a step of crosslinking.

 The multiple emulsion comprises at least three phases, and two systems of nesting emulsions. An internal phase is dispersed in the form of an emulsion (droplets) in an intermediate phase. This emulsion is hereinafter called internal emulsion. It is specified that the internal phase and the intermediate phase are not miscible. The internal emulsion comprises an internal emulsification compound. The intermediate phase, comprising the internal emulsion phase, is itself dispersed in the form of an emulsion (droplets) in an external phase. This emulsion is hereinafter called external emulsion. It is specified that the intermediate phase and the external phase are not miscible. The external emulsion comprises an external emulsification compound. It is also specified that the internal phase and the external phase may or may not be miscible. These two phases are at least mostly separated by the intermediate phase.

 By immiscible is meant any liquid which, at room temperature, has a solubility in another liquid of not more than 10% by weight.

 By phase is meant a liquid medium immiscible with at least one of the other phases. The phase generally comprises a main compound, as a vector or as an active material, optionally other active materials, to be provided in a formulation, and optionally an emulsification compound. It should be noted that the active ingredients can be included in the phase, for example in the form of a solution or a dispersion of solid particles. By emulsification compound is meant a compound intended to make compatible at least in part two phases of an emulsion system, to stabilize the droplets and to avoid coalescence. Without wanting to be linked to

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 any theory, it is mentioned that the emulsification compounds play a role at the phase interface. The choice of emulsification compounds, and the choice of the phases in which they are used, generally depends on the main compounds to be emulsified. Examples of emulsification compounds include organic or particulate surfactants, certain polymers, such as amphiphilic polymers.

Details will be given below. It is mentioned that emulsifying compounds can also be designated by the terms emulsifiers, dispersants, or surfactants.

Description of the phases
This section describes the composition of each phase of the multiple emulsion used.

Internal phase
The internal phase is an aqueous or organic phase. As the main compound of the organic internal phase, mention is made of: - organic oils / fats / waxes of animal or vegetable origin; - mineral oils / waxes; - products from alcoholysis of the above oils; - essential oils; - mono-, di- and tri-glycerides; - fatty acids, saturated or not, comprising 10 to 40 carbon atoms; - the esters of such acids and of alcohol comprising 1 to 6 carbon atoms; - monoalcohols, saturated or not, comprising 2 to 40 carbon atoms; - polyols comprising 2 and 10 carbon atoms; - polyorganosiloxane oils insoluble in the intermediate phase and devoid of polymerizable functions of the type of those present in the polyorganosiloxane (s) present in the intermediate phase.

 These compounds can be used alone or in mixtures.

 As organic oils / fats / waxes of animal origin, mention may be made, among others, of sperm whale oil, whale oil, seal oil, shark oil, cod liver oil, pork and mutton fats (tallow), perhydrosqualene, beeswax, alone or in a mixture.

 As examples of organic oils / fats / waxes of vegetable origin, there may be mentioned, inter alia, rapeseed oil, sunflower oil, peanut oil, olive oil , walnut oil, corn oil, soybean oil, avocado oil, linseed oil, hemp oil, grape seed oil, copra, palm oil, cottonseed oil, babassu oil, jojoba oil, sesame oil,

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 castor oil, macadamia oil, sweet almond oil, carnauba wax, shea butter, cocoa butter, peanut butter, alone or in a mixture.

 As regards mineral oils / waxes, there may be mentioned, inter alia, naphthenic, paraffinic (petrolatum), isoparaffinic oils, paraffinic waxes, alone or as a mixture.

 The products derived from the alcoholysis of the abovementioned oils can also be used.

 Among the essential oils that may be mentioned without intending to be limited thereto, oils and / or essences of mint, spearmint, peppermint, menthol, vanilla, cinnamon, bay leaf, anise, d 'eucalyptus, thyme, sage, cedar leaf, nutmeg, citrus (lemon, lime, grapefruit, orange), fruit (apple, pear, peach, cherry, plum, strawberry, raspberry, apricot , pineapple, grapes, etc.), alone or in mixtures.

 As regards fatty acids, the latter, saturated or unsaturated, contain 10 to 40 carbon atoms, more particularly 18 to 40 carbon atoms, and can comprise one or more ethylenic unsaturations, conjugated or not. It should be noted that said acids may comprise one or more hydroxyl groups.

 As examples of saturated fatty acids, mention may be made of palmitic, stearic and behenic acids.

 As examples of unsaturated fatty acids, there may be mentioned myristoleic, palmitoleic, oleic, erucic, linoleic, linolenic, arachidonic, ricinoleic acids, as well as their mixtures.

 As regards fatty acid esters, mention may be made of the esters of the acids listed above, for which the part deriving from the alcohol comprises 1 to 6 carbon atoms, such as methyl, ethyl, propyl, isopropyl, etc.

 As examples of alcohols, mention may be made of ethanol and those corresponding to the abovementioned acids.

 Among the suitable polyols, mention may preferably be made of glycerol.

 It is mentioned that the internal phase can comprise a silicone, or a mixture of silicones, immiscible with the intermediate phase, and non-crosslinkable.

 Finally, it is specified that it is not excluded that an internal phase comprising an organic compound as mentioned above, comprises an amount of water which does not exceed the solubility limit of water in the phase intermediate (at a temperature between 20 and 30 C).

Active matter in the internal phase
The internal phase can also comprise at least one soluble or dispersible active material, for example a hydrophobic active material which is soluble or dispersible in an organic main component.

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More particularly, the active ingredient (s) are chosen from the active ingredients which can be used in the field of skin and / or hair treatment. Among them, in particular, alone or in mixtures: - lipophilic vitamins, such as vitamin A and its derivatives, in particular its esters such as acetate, palmitate, propionate, vitamin B2, pantothenic acid, vitamin D and Vitamin E ; - UV absorbers, such as PABA type aminobenzoate derivatives and
PARA, salicylates, cinnamates, anthranilates, dibenzoylmethanes, camphor derivatives; anti-aging agents such as retinoids in particular, fat-soluble vitamins, derivatives of vitamin C such as esters of the acetate, propionate or palmitate type; ceramides, pseudoceramides, phospholipids, fatty acids, fatty alcohols, cholesterol, sterols and their mixtures. As preferred fatty acids and alcohols, mention may more particularly be made of those having linear or branched alkyl chains containing from 12 to 20 carbon atoms. It can in particular be linoleic acid; - anti-cellulite agents, such as in particular isobutylmethylxanthine and theophyline; - anti-acne agents, such as resorcinol, resorcinol acetate, benzoyl peroxide and many natural compounds; bactericides; - the antimicrobial agents can be chosen from thymol, menthol, triclosan, 4-hexylresorcinol, phenol, eucalyptol, benzoic acid, benzoic peroxide, butyl paraben; - the aromas, perfumes, essential oils such as in particular the essential oils / essences mentioned previously in the context of the description of L2, but also ambergris, benzoin, cloves, civet, jasmine, sandalwood, vetivert, musk, myrrh, iris, or aldehydes and esters such as cinnamyl acetate, cinnamaldehyde, p-methylanisole, acetaldehyde, benzaldehyde, vanillin, decanal, nerol, citral, 2,6-dimethyl octanal, 2-ethyl butyraldehyde.

 - Hair fixing and / or styling agents such as, for example, vinyl acetate / crotonate / vinyl neodecanoate copolymers, sold under the names Resyn 28-2942 and Resyn 28-2930 from National Starch.

 If the internal phase comprises one or more hydrophobic active ingredients, and if the active ingredient (s) are not also used as

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 as main compound, their content represents more particularly 10 to 50% by weight of said internal phase.

 It should be noted that the internal phase itself can be considered as a hydrophobic active material. Conversely, the active ingredient (s) can be considered as an internal phase.

Intermediate phase
The intermediate phase is crosslinkable: it comprises a crosslinkable polyorganosiloxane system. Numerous systems are known, used in various sectors, such as sealants, molding, coating of adhesive or non-stick substances on surfaces. All these systems can be used, if they can be emulsified in an aqueous phase.

Si-vinyl / Si-H
A first crosslinkable polyorganosiloxane system comprises a first polyorganosiloxane comprising one or more reactive crosslinking groups of the Si-alkenyl type, associated with at least a second polyorganosiloxane comprising one or more reactive crosslinking groups of the Si-H type, optionally a kinetics inhibitor of the crosslinking reaction, and a catalyst of the crosslinking reaction.

dans laquelle : - W est un groupe alcényle, de préférence vinyle, - Z, identique ou différent, est un groupe hydrocarboné monovalent, exempt d'action défavorable sur l'activité du catalyseur et choisi, de préférence, parmi les groupes alkyles ayant de 1 à 8 atomes de carbone inclus, avantageusement, parmi les groupes méthyle, éthyle, propyle et 3,3,3- trifluoropropyle et ainsi que parmi les groupes aryle et, avantageusement, parmi les radicaux xylyle et tolyle et phényle, - a est 1 ou 2, b est 0,1 ou 2 et a + b est compris entre 1 et 3, - et, éventuellement, des unités de formule (A.2) suivante :

The first polyorganosiloxane, comprising one or more reactive groups of the Si-alkenyl type, comprises for example: - units, comprising one or more reactive groups of the Si-alkenyl type, of the following formula (A.1):

in which: - W is an alkenyl group, preferably vinyl, - Z, identical or different, is a monovalent hydrocarbon group, free of unfavorable action on the activity of the catalyst and chosen, preferably, from alkyl groups having 1 to 8 carbon atoms included, advantageously, among the methyl, ethyl, propyl and 3,3,3-trifluoropropyl groups and also among the aryl groups and, advantageously, among the xylyl and tolyl and phenyl radicals, - a is 1 or 2, b is 0.1 or 2 and a + b is between 1 and 3, - and, optionally, units of formula (A.2) below:

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 in which Z has the same meaning as above and c has a value between 0 and 3, for example between 1 and 3.

 The first polyorganosiloxane is preferably chosen from dimethylpolysiloxanes with dimethylvinylsilyl ends, methylvinyldimethylpolysiloxane copolymers with trimethylsilyl ends, methylvinyldimethyl-polysiloxane copolymers with dimethylvinylsilyl ends, cyclic methylvinylpolysiloxanes, alone or cyclic mixtures.

dans laquelle : - L est un groupe hydrocarboné monovalent, exempt d'action défavorable sur l'activité du catalyseur choisi, de préférence, parmi les groupes alkyles ayant de 1 à 8 atomes de carbone inclus et, avantageusement, parmi les groupes méthyle, éthyle, propyle et 3,3,3-trifluoropropyle et ainsi que parmi les groupes aryles et, avantageusement, parmi les radicaux xylyle et tolyle et phényle, - d est 1 ou 2, c est 0,1 ou 2, d + c a une valeur comprise entre 1 et 3, - et éventuellement, des unités de formule suivante (B.2):

dans laquelle L a la même signification que ci-dessus et g a une valeur comprise entre 0 et 3. The second polyorganosiloxane, comprising one or more reactive groups of the Si-H type, comprises for example: - units, comprising one or more reactive groups of the Si-H type, of the following formula (B.1):

in which: - L is a monovalent hydrocarbon group, free from an unfavorable action on the activity of the catalyst chosen, preferably from alkyl groups having from 1 to 8 carbon atoms included and, advantageously, from methyl and ethyl groups , propyl and 3,3,3-trifluoropropyl and also among the aryl groups and, advantageously, among the xylyl and tolyl and phenyl radicals, - d is 1 or 2, c is 0.1 or 2, d + ca a value between 1 and 3, - and optionally, units of the following formula (B.2):

in which L has the same meaning as above and g has a value between 0 and 3.

 The second polyorganosiloxane is preferably poly (dimethylsiloxane) (methylhydrogenosiloxy) ([alpha], # - dimethylhydrogeno) siloxane.

 The first crosslinkable polyorganosiloxane system further comprises a catalyst. It is generally a metallic compound based on platinum. For example, the Karlstedt catalyst is known. We can also refer to US Patents 3,220,972, US 3,284,406, US 3,436,366, US 3,697,473, US 4,340,709.

 The system may also include an inhibitor, ie a compound slowing down the kinetics of the crosslinking reaction. They may, for example, be ethynyl cyclohexanol, tetramethylvinyltetrasiloxane, pyridine, phosphines, phosphites, unsaturated amides or acetylenic alcohols. Many inhibitors have been described.

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 The respective contents of inhibitor, if used, and of catalyst are advantageously such that the crosslinking reaction does not take place substantially before the multiple emulsion is obtained.

 The crosslinking reaction for this system is the reaction between the SiH group and the alkenyl group. It is catalyzed by the catalyst. Crosslinking is progressive, by action of the catalyst, once the first polyorganosiloxane, the second polyorganosiloxane and the catalyst are brought into contact. In the presence of an inhibitor the kinetics of the crosslinking reaction is slowed down. In this case, it may be necessary to trigger the crosslinking by elimination of the inhibitor after bringing the first polyorganosiloxane, the second polyorganosiloxane and the catalyst into contact, for example by sublimation.

et éventuellement RnSi04~n (I)
2 formules dans lesquelles les divers symboles ont la signification suivante : - les symboles R, identiques ou différents, représentent chacun un groupement de nature hydrocarbonée non hydrolysable, ce radical pouvant être : * un radical alkyle, halogénoalkyle ayant de 1 à 5 atomes de carbone et comportant de 1 à 6 atomes de chlore et/ou de fluor, * des radicaux cycloalkyles et halogénocycloalkyles ayant de 3 à 8 atomes de carbone et contenant de 1 à 4 atomes de chlore et/ou de fluor, * des radicaux aryles, alkylaryles et halogénoaryles ayant de 6 à 8 atomes de carbone et contenant de 1 à 4 atomes de chlore et/ou de fluor, * des radicaux cyanoalkyles ayant de 3 à 4 atomes de carbone ; - les symboles Z, identiques ou différents, représentent chacun un atome d'hydrogène, un groupement alkényle en C2-C6, un groupement hydroxyle, un atome hydrolysable, un groupement hydrolysable ; - n = un nombre entier égal à 0, 1, 2 ou 3 ; - x = un nombre entier égal à 0, 1, 2 ou 3 ; - y = un nombre entier égal à 0, 1, ou 2 ; Si-OH
A second crosslinkable polyorganosiloxane system comprises a polyorganosiloxane comprising one or more reactive Si-OH crosslinking groups, and a catalyst for the crosslinking reaction. Such a polyorganosiloxane comprises, for example, units of the following formula:

and possibly RnSi04 ~ n (I)
2 formulas in which the various symbols have the following meaning: - the symbols R, which are identical or different, each represent a group of non-hydrolyzable hydrocarbon nature, this radical possibly being: * an alkyl or haloalkyl radical having from 1 to 5 carbon atoms and containing from 1 to 6 chlorine and / or fluorine atoms, * cycloalkyl and halogenocycloalkyl radicals having 3 to 8 carbon atoms and containing from 1 to 4 chlorine and / or fluorine atoms, * aryl, alkylaryl radicals and haloaryls having from 6 to 8 carbon atoms and containing from 1 to 4 chlorine and / or fluorine atoms, * cyanoalkyl radicals having from 3 to 4 carbon atoms; the symbols Z, which are identical or different, each represent a hydrogen atom, a C2-C6 alkenyl group, a hydroxyl group, a hydrolysable atom, a hydrolysable group; - n = an integer equal to 0, 1, 2 or 3; - x = an integer equal to 0, 1, 2 or 3; - y = an integer equal to 0, 1, or 2;

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 - the sum x + y is between 1 and 3.

 By way of illustration, mention may be made, among the organic radicals R, directly linked to the silicon atoms: methyl groups; ethyl; propyl; isopropyl; butyl; isobutyl; n-pentyl; t-butyl; chloromethyl; dichloromethyl; a-chloroethyl; [alpha], ss-dichloroethyl; fluoromethyl; difluoromethyl; [alpha], ss-difluoroethyl; trifluoro-3,3,3 propyl; trifluoro cyclopropyl; 4,4,4-trifluorobutyl; hexafluoro-3,3,4,4,5,5 pentyl; ss-cyanoethyl; y-cyanopropyl; phenyl: p-chlorophenyl; m-chlorophenyl; 3,5-dichlorophenyl; trichlorophenyl; tetrachlorophenyl; o-, p- or m-tolyl; a, a, atrifluorotolyl; xylyles such as 2,3-dimethylphenyl, 3,4-dimethylphenyl.

 Preferably, the organic radicals R linked to the silicon atoms are methyl and phenyl radicals, these radicals possibly being halogenated or else cyanoalkyl radicals.

 The symbols Z can be hydrogen atoms, hydrolysable atoms such as halogen atoms, in particular chlorine atoms, vinyl groups, hydroxyl groups or hydrolysable groups such as for example: amino, amido, aminoxy, oxime , alkoxy, alkenyloxy, acyloxy.

 The nature of the polyorganosiloxane and therefore the relationships between the siloxyl units (I) and (II) and the distribution of these is, as is known, chosen according to the crosslinking treatment which will be carried out on the curable (or vulcanizable) composition in view of its transformation into an elastomer.

 It is possible to use a wide variety of monocomponent or bicomponent compositions which crosslink by polyaddition or polycondensation reactions in the presence of a metal catalyst and optionally an amine and a crosslinking agent.

 The two-component or single-component polyorganosiloxane compositions crosslinking at room temperature or with heat by polyaddition reactions, essentially by reaction of hydrogenosilylated groups on alkenylsilylated groups, in the general presence of a metal catalyst, preferably platinum, are described for example in patents US-A-3,220,972.3 284,406, 3,436,366.3,697,473 and 4,340,709. The polyorganosiloxanes used in these compositions generally consist of pairs based on the one hand '' a linear, branched or crosslinked polysiloxane consisting of units (II) in which the residue Z represents a C2-C8 alkenyl group and where x is at least equal to 1, optionally associated with units (1), and other part of a linear, branched or crosslinked hydrogen polysiloxane consisting of units (II) in which the remainder Z then represents a hydrogen atom and where x is at least equal 1, optionally combined with units (1).

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 The two-component or one-component polyorganosiloxane compositions crosslinking at room temperature by polycondensation reactions under the action of moisture, generally in the presence of a metal catalyst, for example a tin compound, are described for example for the one-component compositions in the patents US-A-3,065,194, 3,542,901, 3,779,986, 4,417,042, and in patent FR-A-2,638,752, and for the two-component compositions in the patents US-A-3,678,002, 3 888 815, 3 933 729 and 4 064 096. The polyorganosiloxanes used in these compositions are generally linear, branched or crosslinked polysiloxanes consisting of units (II) in which the residue Z is a hydroxyl group or a hydrolysable atom or group and where x is at least equal to 1, with the possibility of having at least one residue Z which is equal to a hydroxyl group or to an atom or to a hydrolysable group and at least one residue Z which is equal to an alkenyl group when x is equal to 2 or 3, said units (II) being optionally associated with units (1). Such compositions may also contain a crosslinking agent which is in particular a silane carrying at least three hydrolysable groups such as for example a silicate, an alkyltrialkoxysilane or an aminoalkyltrialkoxysilane.

 The polyorganosiloxane constituents of these crosslinking compositions by polyaddition or polycondensation reactions advantageously have a viscosity at 25 C at most equal to 100,000 mPa.s and, preferably, between 10 and 50,000 mPa.s.

 It is possible to use, in the case of compositions crosslinking at room temperature by polyaddition or polycondensation reactions, polyorganosiloxane constituents having a viscosity at 25 C greater than 100,000 mPa.s, such as that located in the range from a value greater than 100,000 mPa.s to 300,000 mPa.s.

 It is also possible to use, in the case of compositions which crosslink to heat using polyaddition reactions and more precisely of so-called compositions of polyaddition EVC type (EVC = Hot Vulcanizable Elastomer), polyorganosiloxane constituents, and in particular the polyorganosiloxane constituent (s) carrying alkenyl-silylated groups, having a viscosity at 25 C at least equal to 500,000 mPa.s and, preferably between 1 million mPa.s and 10 million mPa.s and even more.

 It can also be compositions curable at high temperature under the action of organic peroxides such as 2,4-dichlorobenzoyl peroxide, benzoyl peroxide, t-butyl perbenzoate, cumyl peroxide, peroxide of di-t-butyl. The polyorganosiloxane or gum used in such compositions (simply called EVC type) then consists essentially of units

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 siloxyls (1), optionally associated with units (II) in which the residue Z represents a C2 - C6 alkenyl group and in which x is equal to 1. Such EVCs are, for example, described in patents US-A-3,142 655, 3,821,140.3 836,489 and 3,839,266).

The crosslinking reaction for this system is a condensation of the SiOH groups. It is catalyzed by the catalyst. The crosslinking is progressive, by action of the catalyst, once the latter is brought into contact with the polyorganosiloxane. epoxide
A third crosslinkable polyorganosiloxane system comprises a polyorganosiloxane comprising one or more reactive epoxy crosslinking groups of formula: # Si-RC-CR2
V
O where the groups R and R2, identical or different, represent a hydrogen atom or an alkyl radical comprising 1 to 30 carbon atoms, and a photoinitiator. The photoinitiator is for example an iodonium.

 For this third system, we often speak of POS crosslinkable by cationic or radical route.

A. in the presence of an effective quantity of cationic initiator systems (thermal initiators and / or photoinitiators) - initiators of the onium borate type or of organometallic complexes, organic solvents donating protons (isopropyl alcohol, benzyl alcohol. ..),
B. and / or as the case may be in the presence of a radical initiator, via activation by actinic radiation (UV) or by electron beams.

 These POSs are for example epoxysilicones and / or vinylethersilicones, linear or cyclic.

 Such epoxy or vinyloxyfunctional POSs are described in particular in patents DE-4,009,889, EP-0 396 130, EP-0 355 381, EP-0 105 341, FR-2 110 115, FR-2 526 800.

 The functional epoxy POSs can be prepared by hydrosylylation reactions between oils with SiH units and epoxy-functional compounds such as vinyl-4-cyclohexenone or allyl-glycidyl ether.

 The vinyloxyfunctional POSs can be prepared by hydrosilylation reaction between oils with SiH units and vinyloxyfunctional compounds such as allylvinylether or allylvinyloxyethoxybenzene.

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 The crosslinking reaction for this system is triggered by exposure to radiation, for example ultraviolet radiation.

Compound of internal emulsification
In this part, internal emulsification compounds which can be used are described. As mentioned above, this can be a particulate surfactant, optionally combined with a co-surfactant, or a comb or block surfactant polymer comprising organosiloxane units, one fraction of which is soluble in the internal phase, the other in the intermediate phase, the fraction soluble in the intermediate phase being greater than the fraction soluble in the internal phase. particulate surfactant possibly associated with a co-surfactant
According to a particular embodiment of the invention, a particulate surfactant is used as internal emulsification compound, optionally combined with a cosurfactant. This mode is more particularly suited to aqueous internal phases.

The particulate surfactant is preferably chosen from solid particulate compounds, the contact angle of which is close to 0, associated with at least one costabilizer chosen from non-ionic, anionic, cationic or zwitterionic surfactants.

 The particulate surfactant is for example a precipitated silica, a colloidal silica, a silicoaluminate, zinc oxide, titanium oxide, or a mixture of these compounds, these compounds optionally comprising a surface treatment.

 The content of particulate surfactant is advantageously from 5 to 20% by weight relative to the internal emulsion, and the content of co-surfactant is from 0 to 2% by weight relative to the internal emulsion.

 According to a practical mode of preparation of the internal emulsion, the particulate surfactant is introduced as a mixture into the internal phase, if it is aqueous, and the co-surfactant, if used, is introduced as a mixture into the intermediate phase.

Comb or block surfactant copolymer
According to another embodiment of the invention, a comb or block polymer comprising organosiloxane units is used as internal emulsification compound, one fraction of which is soluble in the internal phase, the other in the intermediate phase, the fraction soluble in the intermediate phase being greater than the fraction soluble in the internal phase.

 The term “soluble” is intended to denote copolymers which, when mixed with a liquid, at a concentration of between 0.1 and 10% by weight of said liquid and

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 at 20 C, are in the form of a solution in all or part of the concentration range indicated. By solubility of a polymer fraction (of a block or part of a comb) is meant the solubility that a fraction of the same composition and of the same molecular mass would have without the other fraction. In addition, said copolymer is chosen from those which, when the internal phase are mixed, at a concentration of between 0.1 and 10% by weight of said internal phase and at 20 ° C., are in the form of a dispersion in all or part of the concentration range indicated. Finally, said copolymer used is that which, at a given concentration in the range indicated above and at 20 ° C., is present simultaneously in the form of a solution in the intermediate phase, and in the form of a dispersion in the internal phase.

 It is specified for information only, that the copolymer has a molar mass in number less than or equal to 100,000 g / mol, more particularly between 1,000 and 50,000 g / mol. The number molar mass is given here with an absolute value, and can be advantageously determined by combining MALLS analyzes (multi-angle light scattering) and gel permeation chromatography. Note that this method is particularly suitable for copolymers of any mass. For copolymers of low masses, in particular less than or equal to approximately 20,000 g / mol, it is also possible to use NMR, which also gives an absolute value for the masses of copolymer.

 The content of this comb or block copolymer is preferably 3 to 5% by weight relative to the internal phase.

The nature of the surfactant polymer used can vary depending on the nature of the internal phase. Thus, if the internal phase is an aqueous phase, preference may be given, for example, to polymers of the polyether silicone type. It is typically a polydimethylsiloxane of formula (I) or (II), optionally dispersed in a volatile polydimethylsiloxane,
CH3-Si (CH3) 2-SiO - [- Si (CH3) 2-O-] a - [- Si (CH3) RO-] b-Si (CH3) 2- CH3 (I)
CH3-Si (CH3) 2-SiO - [- Si (CH3) 2-O-] a-Si (CH3) 2- CH3 (II) in which: - 1 # a <500, - 1 # b # 100, and - R represents a group of the following formula: -CnH2n- (-OC2H4) x - (- OC3H6) yOR 'in which R' represents H or a linear or branched C1-C12 alkyl group and: - 0 # x # 50 ,

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- 0 # y # 50, - x + y # 1, and - 2 # n # 12 (n being an integer)
Preferably, the characteristics mentioned above are as follows: - 1 # a # 450, - 1 # b # 40, - 1 # x # 30, - 0 <y <30, and - y # x.

 As examples of linear or branched alkyl groups R ′, Ci, -Ci2, mention may in particular be made of methyl, ethyl, n-propyl, isopropyl, n-butyl radicals. isobutyl, pentyl and hexyl. Preferably, according to the invention, R 'represents hydrogen.

 In a preferred form, the polyether silicone has the following formula: Me3SiO- (Me2SiO) 396- (MeSiO) 4-SiMe3 # (CH2) 3-EO18-PO18-OH in which EO represents an ethylene oxide unit, and PO represents a propylene oxide unit.

 If the internal phase is a hydrophobic organic phase, block copolymers comprising at least one silicone block and at least one block comprising units derived from ethylenically unsaturated monomers may be preferred, for example. Advantageously, if each of the blocks of the copolymer represented a polymer (same size and composition as the blocks), then the monomers constituting each of the blocks would be chosen so that each polymer is soluble, under the temperature and concentration conditions mentioned above, either in the internal phase (for the polymer deriving from soluble blocks in the internal phase) or in the intermediate phase (for the polymer deriving from soluble blocks in the intermediate phase).

 More particularly, the fraction of the copolymer which is soluble in the intermediate phase derives from a polysiloxane. Preferably, the polysiloxane carries reactive functions, such as the —OH, —NH 2 functions, among others.

 As regards the soluble fraction, the internal phase, this preferably derives from the polymerization of at least one monomer chosen from the following monomers: - the esters of mono- or polycarboxylic acids, linear, branched, cyclic or aromatic, comprising at least one ethylenic unsaturation;

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 - [alpha] ss-ethylenically unsaturated nitriles, vinyl ethers, vinyl esters, vinyl aromatic monomers, vinyl or vinylidene halides; - hydrocarbon monomers, linear or branched, aromatic or not, comprising at least one ethylenic unsaturation; alone or in mixtures, as well as the macromonomers derived from such monomers.

More precisely, said monomers can be chosen from: - esters of (meth) acrylic acid with an alcohol comprising 1 to 12 carbon atoms such as methyl (meth) acrylate, ethyl (meth) acrylate, ( propyl meth) acrylate, n-butyl (meth) acrylate, t-butyl (meth) acrylate, isobutyl (meth) acrylate, 2-ethylhexyl acrylate, (meth) acrylate hydroxyethyl; - vinyl acetate (used to obtain partially or fully deacetylated polyvinyl alcohol), vinyl Versatate, vinyl propionate, vinyl chloride, vinylidene chloride, methyl vinyl ether, ethyl vinyl ether, (meth) acrylonitrile, N-vinylpyrrolidone, vinylformamide, vinylacetamide, vinylamine; - (meth) acrylamide, N-alkyl (meth) acrylamide such as isopropyl acrylamide, N-methylol (meth) acrylamide; - styrene, α-methylstyrene, vinyltoluene, butadiene, chloroprene, isoprene; alone or in mixtures, as well as the macromonomers derived from such monomers
Recall that the term macromonomer designates a macromolecule carrying one or more polymerizable functions.

 It should be noted that the fraction soluble in the internal phase of the copolymer used as stabilizer of the emulsion according to the invention can be obtained from the abovementioned monomers, combined with monomers of different chemical nature, such as by example of hydrophilic, nonionic or ionic monomers.

 As examples of ionic hydrophilic monomers, more particularly anionic or potentially anionic depending on the pH conditions, there may be mentioned in particular: - linear, branched, cyclic or aromatic mono- or polycarboxylic acids, N-substituted derivatives of such acids, monoesters of polycarboxylic acids, comprising at least one ethylenic unsaturation; - linear, branched, cyclic or aromatic vinyl carboxylic acids; - amino acids comprising one or more ethylenic unsaturations;

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 alone or as mixtures, their sulfonic or phosphonic derivatives, the macromonomers deriving from such monomers, as well as the corresponding salts.

 By way of example of monomers of this type, in acid form or in the form of an alkali metal salt (sodium, potassium), or of ammonium, there may be mentioned: - (meth) acrylic acid, acid 2 -propene 1-sulfonic, methallyl sulfonic acid, styrene sulfonic acid, a-acrylamido methylpropane sulfonic acid, 2-sulfoethylene methacylate, sulfopropyl (meth) acrylic acid, bis-sulfopropyl acid (meth ) acrylic, hydroxyethyl methacrylic acid phosphate ester; - vinyl sulfonic acid, vinylbenzene sulfonic acid, vinyl phosphonic acid, vinyl benzoic acid; - N-methacryloyl alanine, N-acryloyl-hydroxy-glycine; alone or in mixtures, as well as the macromonomers derived from such monomers.

 Among the nonionic hydrophilic monomers, there are inter alia the amides of mono- or polycarboxylic acids, linear, branched, cyclic or aromatic, comprising at least one ethylenic unsaturation or derivatives, such as (meth) acrylamide, N-methylol ( meth) acrylamide; certain esters derived from (meth) acrylic acid such as for example 2-hydroxyethyl (meth) acrylate; vinyl esters making it possible to obtain polyvinyl alcohol blocks after hydrolysis, such as vinyl acetate, vinyl versatate, vinyl propionate.

 If the copolymer entering into the composition of the emulsion is obtained in part from hydrophilic monomers, it is specified that their content is such that the copolymer meets the criteria set out above, namely the fact that a fraction of said copolymer is soluble in the internal phase, the other in the intermediate phase.

 According to a preferred embodiment of the present invention, the copolymer entering into the composition of the emulsion is a linear block polymer. Preferably, said copolymer comprises at least three blocks.

 The copolymers which can be used in the context of the present invention can be obtained, advantageously, by radical route, preferably controlled.

Preferably, such polymers can be obtained by implementing a process for the preparation by thermal activation of silicone and organic hybrid copolymers comprising units (I):
RxUySiO [4- (x + y)] / 2 (I) in which: - x is equal to 0.1, 2 or 3, y is equal to 0.1, 2 or 3 with 2 # (x + y) 3 and y is different from 0 for at least one of the units of the hybrid copolymer,

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dans lequel : - x' = 1, 2,3 ou 4 en fonction de la valence de Z, - Z, identiques ou différents, représentent un atome de carbone, soufre, oxygène, phosphore, azote et/ou une valence libre, - R1, identiques ou différents, représentent : - un groupe (i) alkyle, acyle, aryle, alcène ou alcyne éventuellement substitué, - un cycle (ii) carboné, saturé ou non, éventuellement substitué et/ou aromatique, et/ou - un hétérocycle (iii), saturé ou non, éventuellement substitué, - ces radicaux (i), (ii) et (iii) pouvant être substitués avantageusement par: des groupes phényles substitués, des groupes aromatiques substitués, ou des groupes : alkoxycarbonyle, aryloxycarbonyle (-COOR ), carboxy (-
COOH), acyloxy (-O2CR5), carbamoyle (-CONR 5 2), cyano (-CN), alkylcarbonyle, alkylarylcarbonyle, arylcarbonyle, arylalkylcarbonyle, phtalimido, maleïmido, succinimido, amidino, guanidimo, hydroxy (-OH), the symbols R, which may be identical or different, represent: a linear or branched alkyl radical containing 1 to 8 carbon atoms, optionally substituted by at least one halogen, preferably fluorine, the alkyl radicals preferably being methyl, ethyl, propyl, octyl and 3,3,3-trifluoropropyl, a cycloalkyl radical containing between 5 and 8 cyclic carbon atoms, optionally substituted, an aryl radical containing between 6 and 12 carbon atoms which can be substituted, preferably phenyl or dichlorophenyl, an aralkyl part having an alkyl part containing between 5 and 14 carbon atoms and an aryl part containing between 6 and 12 carbon atoms, optionally substituted on the aryl part by halogens, alkyls and / or alkoxyls containing 1 to 3 carbon atoms, the symbols U, identical or different, represent (II):

in which: - x '= 1, 2,3 or 4 depending on the valence of Z, - Z, identical or different, represent a carbon, sulfur, oxygen, phosphorus, nitrogen atom and / or a free valence, - R1, identical or different, represent: - an optionally substituted (i) alkyl, acyl, aryl, alkene or alkyne group, - a (ii) carbonaceous, saturated or unsaturated, optionally substituted and / or aromatic ring, and / or - a heterocycle (iii), saturated or unsaturated, optionally substituted, these radicals (i), (ii) and (iii) being able to be advantageously substituted by: substituted phenyl groups, substituted aromatic groups, or groups: alkoxycarbonyl, aryloxycarbonyl ( -COOR), carboxy (-
COOH), acyloxy (-O2CR5), carbamoyl (-CONR 5 2), cyano (-CN), alkylcarbonyl, alkylarylcarbonyl, arylcarbonyl, arylalkylcarbonyl, phthalimido, maleimido, succinimido, amidino, guanidimo, hydroxy (-OH),

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dans laquelle : - R6, R7, identiques ou non, sont choisis parmi un groupe halogène, -N02, -SO3R10, -NCO, -CN, -OR' , -SR10, -N(R' )2, -COOR'o, -O2CR10, -CON(R10)2, -NCO(R10)2 et -CnF(2n+i) avec n compris entre 1 et 20, de préférence égal à 1; - avec R10 représentant : * un atome d'hydrogène, * ou un radical alkyle, alcényle, alcynyle, cycloacényle, cycloalcynyle, alkaryle, aralkyle, hétéroaryle ou aryle éventuellement condensé à un hétérocycle aromatique ou non ; radicaux pouvant éventuellement être substitués par : . un ou plusieurs groupes identiques ou différents, choisis parmi les atomes d'halogènes, =0, =S,-OH, alcoxy, SH, thioalcoxy, NH2, mono ou di-alkylamino, CN, COOH, ester, amide, CnF(2n+i) et/ou éventuellement interrompu par un ou plusieurs atomes choisis parmi O,S,N,P; . ou un groupe hétérocyclique éventuellement substitué par un ou plusieurs groupes tels que définis précédemment ; . ou R6 et R7 forment ensemble avec l'atome de carbone auquel ils sont attachés, un groupe =0, =S, un cycle hydrocarboné ou un hétérocycle ; - et R8 et R9, identiques ou différents, représentent un groupe tel que défini ci-dessus pour R10; ou forment ensemble une chaîne 18 amino (-NR52), halogen, allyl, epoxy, alkoxy (-OR 5), S-alkyl, S-aryl, groups having a hydrophilic or ionic character such as the alkali salts of carboxylic acids, the alkali salts d 'sulfonic acid, polyalkylene oxide chains (POE, POP), cationic substituents (quaternary ammonium salts), R, identical or different, representing an alkyl or aryl group, and / or a polymer chain, - a group (iv) of formula -CnF (2n + i) with n between 1 and 20, - a group (v) of the following formula:

in which: - R6, R7, identical or not, are chosen from a halogen group, -N02, -SO3R10, -NCO, -CN, -OR ', -SR10, -N (R') 2, -COOR'o , -O2CR10, -CON (R10) 2, -NCO (R10) 2 and -CnF (2n + i) with n between 1 and 20, preferably equal to 1; - with R10 representing: * a hydrogen atom, * or an alkyl, alkenyl, alkynyl, cycloacenyl, cycloalkynyl, alkaryl, aralkyl, heteroaryl or aryl radical optionally condensed with an aromatic heterocycle or not; radicals which may optionally be substituted by:. one or more identical or different groups, chosen from halogen atoms, = 0, = S, -OH, alkoxy, SH, thioalkoxy, NH2, mono or di-alkylamino, CN, COOH, ester, amide, CnF (2n + i) and / or possibly interrupted by one or more atoms chosen from O, S, N, P; . or a heterocyclic group optionally substituted by one or more groups as defined above; . or R6 and R7 form together with the carbon atom to which they are attached, a group = 0, = S, a hydrocarbon ring or a heterocycle; - And R8 and R9, identical or different, represent a group as defined above for R10; or together form a chain

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C2-C4 hydrocarbon, optionally interrupted by a heteroatom chosen from 0, S and N; - V and V ', identical or different, represent: H, an alkyl group or a halogen, - X and X', identical or different, represent H, a halogen or a group
R4, OR4, 02COR4, NHCOH, OH, NH2, NHR4, N (R4) 2, (R4) 2N + O-,
NHCOR4, C02H, C02R4, CN, CONH2, CONHR4 or CONR42, in which R4 is chosen from alkyl, aryl, aralkyl, alkaryl, alkene or organosilyl groups, optionally perfluorinated and optionally substituted by one or more carboxyl, epoxy, hydroxyl groups, alkoxy, amino, halogen or sulfonic, -R2 and R 3, identical or different, represent: - an optionally substituted (i) alkyl, acyl, aryl, alkene or alkyne group, - a carbon (ii) ring, saturated or not, optionally substituted and / or aromatic, - a heterocycle (iii), saturated or not, optionally substituted, - a hydrogen atom, groups: alkoxycarbonyl, aryloxycarbonyl (-COOR), carboxy (-COOH), acyloxy (-O2CR5) , carbamoyl (-CONR52), cyano (-CN), alkylcarbonyl, alkylarylcarbonyl, arylcarbonyl, arylalkylcarbonyl, phthalimido, maleimido, succinimido, amidino, guanidimo, hydroxy (-OH), amino (-NR52), halogen, allyl, epoxy, alkoxy (-OR 5),
S-alkyl, S-aryl, groups having a hydrophilic or ionic character such as the alkali salts of carboxylic acids, the alkali salts of sulfonic acid, the polyalkylene oxide chains (POE, POP), the cationic substituents ( quaternary ammonium salts), R, identical or different, representing an alkyl or aryl group, and / or a polymer chain, the radicals (i), (ii) and (iii) being able to be advantageously substituted by: phenyl groups substituted, substituted aromatic groups, or groups: alkoxycarbonyl, aryloxycarbonyl (-COOR), carboxy (-
COOH), acyloxy (-O2CR5), carbamoyl (-CONR 2), cyano (-CN), alkylcarbonyl, alkylarylcarbonyl, arylcarbonyl, arylalkylcarbonyl, phthalimido, maleimido, succinimido, amidino, guanidimo, hydroxy (-OH), amino (-NR52 ), halogen, allyl, epoxy, alkoxy (-OR5), S-alkyl, S-aryl, groups having a hydrophilic or ionic character such as the alkali salts of carboxylic acids, the alkali salts of sulfonic acid, chains alkylene polyoxide (POE, POP), cationic substituents (salts

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- et un initiateur de polymérisation radicalaire. of quaternary ammonium), R, identical or different, representing an alkyl or aryl group, and / or a polymer chain, - W, identical or different, represent a divalent radical chosen from -O-, -NR4-, -NH- , -S-, - Sp, identical or different, represent a ball joint consisting of a divalent organic radical of formula - (CH2) x "'- in which x"' is between 1 and
20, this radical possibly being substituted and / or containing at least one heteroatom, - a = 0 or 1, - m # 1, and when m> 1 the repeating unitary units of index m are identical or different, process in which brings into contact: - at least one ethylenically unsaturated monomer of formula (III):
CXX '(= CV - CV') a = CH2, - a precursor silicone compound comprising units, identical or different of formula (IV): RxU'ySiO [4- (x + y)] / 2 in which: - R , x and y correspond to the values given above, and the monovalent radical U 'is according to the following formula (V):

- and a radical polymerization initiator.

 The radical polymerization initiator can be chosen from the initiators conventionally used in radical polymerization. It may, for example, be one of the following initiators: - hydrogen peroxides, such as tertiary butyl hydroperoxide, cumene hydroperoxide, t-butyl-peroxyacetate, t-butylperoxybenzoate, tbutylperoxyoctoate , t-butylperoxineodecanoate, t-butylperoxyisobutarate, lauroyl peroxide, t-amylperoxypivalte, t-butylperoxypivalate, dicumyl peroxide, benzoyl peroxide, potassium persulfate, ammonium persulfate, - compounds azo such as: 2-2'-azobis (isobutyronitrile), 2,2'-azobis (2butanenitrile), 4,4'-azobis (4-pentanoic acid), 1,1'-azobis (cyclohexane-

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 carbonitrile), 2- (t-butylazo) -2-cyanopropane, 2,2'-azobis [2-methyl-N- (1,1) bis (hydroxymethyl) -2-hydroxyethyl] propionamide, 2,2 '-azobis (2-methyl-Nhydroxyethyl] -propionamide, 2,2'-azobis (N, N'-dimethylene isobutyramidine) dichloride, 2,2'-azobis (2-amidinopropane) dichloride, 2, 2'-azobis (N, N'dimethyleneisobutyramide), 2,2'-azobis (2-methyl-N- [1,1-bis (hydroxymethyl) -2hydroxyethyl] propionamide), 2,2'-azobis (2 -methyl-N- [1,1-bis (hydroxymethyl) ethyl] propionamide), 2,2'-azobis [2-methyl-N- (2-hydroxyethyl) propionamide], 2,2'azobis (isobutyramide) dihydrate, - redox systems comprising combinations such as: mixtures of hydrogen peroxide, alkyl, peresters, percarbonates and the like and of any of the iron salts, titanous salts, formaldehyde zinc sulfoxylate or formaldehyde sodium sulfoxylate, and reducing sugars; persulfates, perborate or perchlorate of alkali metals or ammonium in combination with an alkali metal bisulfite, such as sodium metabisulfite, and reducing sugars; alkali metal persulfates in combination with an arylphosphinic acid, such as benzene phosphonic acid and the like, and reducing sugars.

 The amount of initiator to be used is determined so that the amount of radicals generated is at most 20% by mole relative to the amount of silicone precursor compound (IV), preferably at most 5% by weight. mole.

 As ethylenically unsaturated monomer, those which have been mentioned above are used to define the fraction of the copolymer soluble in the internal phase.

Let us also specify that butadiene and chloroprene correspond to the case where a = 1 in the formula (I) and (III),
For the preparation of the hybrid copolymers of formula (I) for which X = H and X '= NH2, vinylamine amides are preferably used as ethylenically unsaturated monomers, for example vinylformamide or vinylacetamide. Then the copolymer obtained is hydrolyzed at acidic or basic pH.

 For the preparation of the hybrid copolymers of formula (1) for which X = H and X ′ = OH, vinyl esters of carboxylic acid, such as for example vinyl acetate, are preferably used as ethylenically unsaturated monomers. Then the copolymer obtained is hydrolyzed at acidic or basic pH.

 The types and quantities of copolymerizable monomers used according to the present invention vary depending on the particular final application for which the hybrid copolymer is intended.

 According to a first preferred variant, the hybrid silicone and organic copolymer consists of a linear silicone skeleton comprising from 1 to 300 units of formula (1), preferably 1 to 200, and bearing from 1 to 50 U radicals, preferably 1 to 10.

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dans laquelle R2 et R3, identiques ou différents, représentent un atome d'hydrogène, un groupe cyano, allkoxycarbonyle, alkyle, acyle, aryle, alcène ou alcyne éventuellement substitué ; et W est de définition identique à celle donnée précédemment, et de préférence est égal à un atome d'oxygène. A titre d'exemples, on citera les précurseurs silicones dans lesquelles U' correspond à :

According to a second variant, at least one of the monovalent radicals U ′ is preferably of formula (VI):

in which R2 and R3, identical or different, represent a hydrogen atom, a cyano, allkoxycarbonyl, alkyl, acyl, aryl, alkene or alkyne group optionally substituted; and W is of definition identical to that given previously, and preferably is equal to an oxygen atom. By way of examples, mention will be made of the silicone precursors in which U ′ corresponds to:

According to a third variant of the invention, at least part of the monovalent radicals U 'of (s) silicone precursor (s) (IV) and therefore at least part of the groups U of the hybrid copolymer obtained are such that Z either an oxygen atom and / or a sulfur atom.

 According to a fourth variant, in addition to units of formula (1), the hybrid silicone and organic copolymer according to the invention can comprise units RxUyFzSiO [4- (x + y + z)] / 2 (XIV) in which:

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 - x is equal to 0, 1,2 or 3, y is equal to 0, 1,2 or 3 and z is equal to 1,2 or 3 with with 2 # (x + y + z) 3, - and F is a group carrying at least one function such as hydroxy, alkoxy, thiol, amine, epoxy and / or polyether.

 These groups F can optionally provide complementary and / or additional properties to the hybrid copolymers prepared according to the process of the invention. They can in particular be contained initially within the silicone precursor of formula (IV).

 In addition to hybrid copolymers with homopolymer organic segments, the process which has just been described makes it possible to prepare hybrid polymers carrying organic block groups (that is to say multiblock). For this, the process consists in repeating the implementation of the preparation process described above using: - monomers different from the previous implementation, and - in place of the precursor silicone compound (II), the hybrid copolymer comprising block patterns (I) from the previous implementation.

 According to this process for the preparation of block copolymers, when it is desired to obtain copolymers with homogeneous blocks and not with a composition gradient, and if all the successive polymerizations are carried out in the same reactor, it is essential that all the monomers used during of one step have been consumed before the polymerization of the next step begins, therefore before the new monomers are introduced.

 As for the polymerization process of monoblock copolymer, this method of polymerization of block copolymers has the advantage of leading to block copolymers having a low polydispersity index. It also makes it possible to control the molecular mass of block polymers.

dans laquelle : The precursor silicone compound of general formula (IV) used within the process for the preparation of hybrid copolymers according to the invention can be obtained by reaction: (i) of a silicone comprising units of formula (VII): RxU "ySiO [ 4- (x + y)] / 2 where the monovalent radical U "is according to the following formula (VIII):

in which :

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 - W and Sp are definitions identical to those given above, - L is an electrofuge group, for example: Br, CI-, I-, OTs-, OMs', (C6H6) - (C = O) -O-, (CH3) - (C = O) -O-, (CF3) - (C = O) -O-.

dans lesquelles : - M'+ représente K+, Na+, NR4+, ou PR4+. R étant de définition similaire à celle donnée pour R de la formule (1), - M,,2+ représente un métal alcalino-terreux tels que Ca2+, Ba2+ et Sr2++, - M'" représente Zn, Cd, m est égal à 1 ou 2, n est égal à 1,2, 3 ou 4 et de préférence m est égal à 1 et n est égal à 2. (ii) with a compound chosen from those of the following general formulas (IX), (X) or (XI):

in which: - M '+ represents K +, Na +, NR4 +, or PR4 +. R being of definition similar to that given for R of the formula (1), - M ,, 2 + represents an alkaline earth metal such as Ca2 +, Ba2 + and Sr2 ++, - M '"represents Zn, Cd, m is equal to 1 or 2, n is equal to 1,2, 3 or 4 and preferably m is equal to 1 and n is equal to 2.

This silicone of formula (VII) can in particular be obtained from (i) of a silicone comprising units of formula (XII): RxU "'ySiO [4- (x + y)] / 2 where the monovalent radical U'"is of formula (XIII): -Sp-WH and (ii) of a compound of formula:

The polymerization can be carried out in bulk, in solution or in emulsion. Preferably, it is used as an emulsion.

 Preferably, the process is carried out semi-continuously.

 The temperature can vary between room temperature and 150 C depending on the nature of the monomers used.

 In general, during the polymerization, the instantaneous content of copolymer relative to the instantaneous amount of monomer and copolymer is between 50 and 99% by weight, preferably between 75 and 99%, even more preferably between 90 and 99% .

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 This content is maintained, in known manner, by controlling the temperature, the rate of addition of the reactants and the polymerization initiator.

 Finally, the process is generally carried out in the absence of a UV source.

 It should be noted that it may be advantageous to chemically modify the xanthat ends of the copolymer obtained, by using any method known to those skilled in the art, such as for example a hydrolysis step.

 The process and the polymers obtained by this process are described in French application n 00 09722 filed on 07/25/00.

 Other methods of synthesis of this type of copolymer can be used, in particular that described in international applications WO 00/71606 and WO 00/71607.

 According to a particular embodiment of the invention, the amount of copolymer represents from 0.5 to 10% by weight of the dispersed phase, preferably between 1 and 4% by weight relative to the same reference.

 It is mentioned that the internal emulsion, if it comprises a comb or block surfactant polymer, can comprise a co-solvent of said surfactant polymer. The cosolvent is for example a volatile polyorganosiloxane. It may, for example, be a polyorganosiloxane with a viscosity preferably less than 10 centistokes, linear or cyclic, or an aliphatic C10 to C20 alkyl ester, preferably a C5 to C12 alkyl neopentanoate.

 The co-solvent content is preferably 0 to 95% by weight of the surfactant polymer.

 The content of surfactant polymer is advantageously from 1 to 10%, preferably from 3 to 5%, by weight relative to the internal phase.

External phase
The external phase is an aqueous phase.

 Compound of external emulsification The compound of external emulsification can be: - a nonionic surfactant, - a nonionic amphiphilic polymer, possibly associated with one or more anionic surfactants and / or anionic amphiphilic polymers, - a particulate surfactant possibly associated with a co-surfactant, or - a protective colloid.

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It is mentioned that according to a practical mode the external emulsification compound is introduced as a mixture into the external phase. More details are given below with respect to these compounds. particulate surfactant
According to a particular embodiment of the invention, the external emulsification compound is a particulate surfactant optionally combined with a co-surfactant. Such compounds have been described previously as internal emulsification compounds. external protective colloid
According to another particular mode of the invention, the external emulsification compound is a protective colloid. It may for example be a polyvinyl alcohol, optionally partially hydrolyzed.

 The content of protective colloid is advantageously from 3 to 30% by dry weight relative to the internal emulsion, preferably from 5 to 25%.

Nonionic surfactant
According to another particular embodiment of the invention, the external emulsification compound comprises a nonionic surfactant. It is preferably a polyalkoxylated nonionic surfactant, for example chosen from: - alkoxylated fatty alcohols - alkoxylated triglycerides - alkoxylated fatty acids - alkoxylated sorbitan esters - alkoxylated fatty amines - di (phenyl- 1 ethyl) alkoxylated phenols - the tri (1-phenylethyl) alkoxylated phenols, and - the alkoxylated alkyl phenols where the number of alkoxy units, more particularly oxyethylene and / or oxypropylene, is such that the value of HLB is greater than or equal to 10. a nonionic amphiphilic polymer
According to another particular embodiment of the invention, the external emulsification compound comprises a nonionic amphiphilic polymer. This polymer can be combined with one or more anionic surfactants and / or anionic amphiphilic polymers.

 As non-ionic amphiphilic polymers, triblock copolymers (polyethylene glycol) - (polypropylene glycol) - (polyethylene glycol) are mentioned.

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 As regards non-ionic or anionic amphiphilic polymers, a polymer comprising at least two blocks is used, one of them being hydrophilic, the other hydrophobic. What has been indicated previously in the context of the description of the non-ionic hydrophilic monomers, ionic and hydrophobic monomers usable for the preparation of comb or block copolymers.

 Said amphiphilic polymers can advantageously be obtained by so-called living or controlled radical polymerization. By way of nonlimiting examples of so-called living or controlled polymerization processes, reference may in particular be made to applications WO 98/58974, WO 00/75207 and WO 01/42312 (xanthate), WO 98/01478 (dithioesters), WO 99/03894 (nitroxides); WO 99/31144 (dithiocarbamates), WO 02/26836 (dithiocarbazates); WO 02/10223 (dithiophosphoroesters), WO 96/30421 (radical polymerization by atom transfer - ATRP).

 Amphiphilic polymers can also be obtained by anionic polymerization.

 They can likewise be prepared by bringing into play polymerizations by ring opening (in particular anionic), or by chemical modification of the polymer.

 More particularly, as regards the nonionic amphiphilic polymer, preferably polyoxyalkylenated, present in the external aqueous phase, it can be chosen from polymers which are at least partly miscible in the external aqueous phase and preferably from polyethylene glycol triblock copolymers -polypropylene glycolpolyethylene glycol.

 It is specified that polymers of the polyvinyl alcohol or polyacid acrylic / polybutylacrylate / polyacrylic acid triblock type can be used for this purpose.

 The content of nonionic surfactant and / or nonionic amphiphilic polymer is advantageously from 0.5 to 10% by weight relative to the weight of the emulsion of the internal phase in the intermediate phase, preferably from 1 to 5% by weight. weight compared to the same reference.

 As anionic surfactants which can be combined with the nonionic amphiphilic polymer, the following surfactants are mentioned: - the alkyl esters sulfonates, the alkylbenzenesulfonates, the primary or secondary alkylsulfonates, the alkylglycerol sulfonates, the sulfonated polycarboxylic acids, the paraffin sulfonates; - alkyl sulfates; - alkyl ether sulfates; - alkylamide sulfates;

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 salts of saturated or unsaturated fatty acids, N-acyl N-alkyltaurates, alkylisethionates, alkylsuccinamates and alkylsulfosuccinates, monoesters or diesters of sulfosuccinates, N-acyl sarcosinates, polyethoxycarboxylates; and - the phosphate esters of alkyl and / or of alkyl ether and / or of alkylarylether, alone or as a mixture.

More specifically, they may be compounds chosen from the following: - - the alkyl esters sulfonates, for example of formula R-CH (SO3M) -COOR ', where R represents a C8-C20, preferably C10, alkyl radical -C16, R 'an alkyl radical in C1-Ce, preferably in C1-C3 and M an alkali cation (sodium, potassium, lithium), substituted or unsubstituted ammonium (methyl-, dimethyl-, trimethyl-, tetramethylammonium, dimethylpiperidinium ...) or derivative of an alkanolamine (monoethanolamine, diethanolamine, triethanolamine ...). Mention may very particularly be made of methyl ester sulfonates whose radical R is C14-C16, alkylbenzenesulfonates, more particularly C9-C20, primary or secondary alkylsulfonates, especially C8-C22, alkylglycerol sulfonates, sulfonated polycarboxylic acids, like for example those described in GB
1082179, paraffin sulfonates; alkyl sulphates, for example of formula ROS03M, in which R represents a C10-C24, preferably C12-C20, alkyl or hydroxyalkyl radical; M representing a hydrogen atom or a cation of the same definition as above, as well as their polyalkoxylated derivatives (ethoxylates (OE), propoxylates (OP), or their combinations), such as for example sodium dodecylsulfate; - Alkyl ether sulfates, for example of formula RO (CH2CH20) nSO3M where R represents a C10-C24, preferably C12-C20, alkyl or hydroxyalkyl radical; M representing a hydrogen atom or a cation of the same definition as above, n generally varying from 1 to 4, as well as their polyalkoxylated derivatives (ethoxylated (OE), propoxylated (OP), or their combinations), such as for example laurylethersulfate with n = 2.

the alkylamide sulfates, for example of the formula RCONHR'OS03M where R represents an alkyl radical in C2-C22, preferably in C6-C20, R 'an alkyl radical in C2-C3, M representing a hydrogen atom or a cation with the same definition as above, as well as their polyalkoxylated derivatives (ethoxylated (OE), propoxylated (OP), or their combinations); the salts of saturated or unsaturated fatty acids, for example such as those in C8-C24, preferably in C14-C20, N-acyl N-alkyltaurates, alkylisethionates, alkylsuccinamates and alkylsulfosuccinates, monoesters or diesters of sulfosuccinates, N-acyl sarcosinates, polyethoxycarboxylates; and

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 - the alkyl and / or alkyl ether and / or alkylaryl ether ester phosphates.

 The content of anionic surfactant is advantageously from 0.5 to 5% by weight relative to the weight of the emulsion of the internal phase in the intermediate phase, preferably from 0.5 to 2% by weight relative to the same reference.

Thickening agent
The external phase may also include a thickening agent. They may, for example, be polymers extracted from plants and optionally modified, polysaccharides of animal, plant, bacterial origin, or mixtures thereof. Mention is made in particular of Xanthan gums and guars.

 The content of thickening agent, if present, is preferably such that said agent is soluble in the external phase, and is more particularly from 0.1 to 2% by weight relative to the external phase, preferably from 0 , 1 to 0.5% by weight relative to the external phase.

Other
In addition to the main compounds, the emulsifying agents and optionally the thickening agents, the various phases may include other ingredients.

Osmotic pressure
Thus, if the internal phase is an aqueous phase, it may be advantageous for said internal phase and the external phase to comprise at least one additive for regulating the osmotic pressure, identical or not, chosen from salts such as the alkali metal halides or alkaline earth, or the sulfates of alkali or alkaline earth metals, or among sugars, or polysaccharides, or mixtures thereof. The salt concentration in the internal phase is preferably between 0.05 and 1 molli, preferably 0.1 to 0.4 molli, and / or the sugar and / or polysaccharide concentration is preferably it than the osmotic pressure of the internal phase comprising the sugar and / or polysaccharide corresponds to the osmotic pressure of an internal aqueous phase comprising 0.05 to 1 molli of salt; the additive content in the external phase being such that the osmotic pressures of the internal and external phases are balanced.

assets
As mentioned for the internal phase, each of the phases can comprise at least one active material which is soluble or dispersible in said phase. The main compound of the phase can moreover itself be an active material. Through

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 active material means a compound having an effect on a medium for applying the particles of the particle suspension, once this compound has been released into said medium.

Emulsion structure
Internal emulsion
The weight ratio between the internal phase and the intermediate phase is advantageously from 5/95 to 95/5, more particularly from 20/80 to 90/10, and preferably from 40/60 to 80/20.

 The internal emulsion (emulsion of the internal phase in the intermediate phase) advantageously has an average droplet size of 0.01 to 50 m, more particularly from 0.1 to 20 m, and preferably from 0.1 to 10 m .

External Emulsion
The weight ratio between the internal emulsion (emulsion from the internal phase in the intermediate phase) and the external phase is advantageously from 5/95 to 60/40, preferably from 20/80 to 60/40.

 The average size of the droplets of the external emulsion in the external phase (size of droplets of intermediate phase comprising the internal phase) is advantageously from 0.1 to 500 m, more particularly from 1 to 200 μm, and preferably from 1 to 100 m.

processes
This section describes the processes for preparing the multiple emulsion (step 1) and for crosslinking (step 2). The processes for preparing the multiple emulsion may vary depending on the crosslinkable polyorganosiloxane system used. It should also be noted that the steps for preparing the multiple emulsion and for crosslinking are not necessarily sequential: crosslinking may occur, partially, during the preparation of the multiple emulsion. Thus, the crosslinking step can either be controlled by the triggering of an action (irradiation, addition or removal of chemical compounds, heating, etc.), or be controlled by the kinetics without triggering a particular action. In the latter case, it is preferable that the crosslinking kinetics be sufficiently slow, so that the crosslinking does not occur, or in any case not entirely, before the process of preparing the multiple emulsion is completed.

Preparation of multiple emulsion
The step of preparing the multiple emulsion generally comprises the following phases:

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1) The internal emulsion is first prepared by mixing, with stirring, the internal phase (preferably comprising all the ingredients which have been mentioned above), and all or part of the intermediate phase, and all or part of the compound internal emulsification. Depending on the crosslinkable polyorganosiloxane system used, it may be preferable to introduce certain ingredients of the intermediate phase after a first mixture. In the case where the continuous phase is not very viscous (viscosity less than 1 Pa. S) the stirring is preferably strong and can be, advantageously, provided by the use of an apparatus of the Ultra-Turrax type, Microfluidizer , or any high pressure homogenizer. In the case where the intermediate is viscous (viscosity greater than or equal to 1 Pa. S, preferably greater than or equal to 5 Pa.s), the stirring can advantageously be carried out by means of a frame blade. The preparation of the internal emulsion is generally carried out at a temperature between 20 and 80 C. The duration of the agitation can be determined without difficulty by a person skilled in the art and depends on the type of apparatus used. work, for example to obtain a desired droplet size.

 2) Secondly, the external emulsion is prepared by mixing, with stirring, the internal emulsion previously obtained, all or part of the external phase, and all or part of the external emulsification compound, then optionally adding a remaining part ( for example thickeners, or osmotic pressure control agents as described above, where appropriate in the form of an aqueous solution) of the external phase. Agitation can be done by means of a paddle frame.

Typically, the stirring speed is relatively slow, of the order of 40 rpm.

 It is mentioned that the emulsification compounds can be introduced into the mixtures, in the form premixed with the different phases.

Curing
The crosslinking processes of the crosslinkable polyorganosiloxane systems used have been described above, for different systems. Various specific modes of preparation of the multiple emulsions are given below, for different crosslinkable systems, and different suitable crosslinking processes.

 According to a first particular embodiment of the invention, the crosslinkable polyorganosiloxane system comprises a first polyorganosiloxane comprising one or more reactive crosslinking groups of the Si-alkenyl type, associated with at least a second polyorganosiloxane comprising one or more reactive crosslinking groups of Si-H type, possibly an inhibitor of the kinetics of the reaction

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 crosslinking, and a catalyst for the crosslinking reaction, and the multiple emulsion is obtained by a process comprising the following steps: a) the internal phase is mixed with stirring, the intermediate phase, the intermediate phase and the internal emulsification compound , said compound being optionally premixed in one of the phases, the intermediate phase comprising the first polyorganosiloxane, optionally all or part of the second polyorganosiloxane, and optionally all or part of the inhibitor, if present, to obtain the internal emulsion, b) after the internal emulsion has been added, the second polyorganosiloxane or the remaining part, optionally the inhibitor or the remaining part, and the catalyst, c) the emulsion obtained in step is mixed above, the external aqueous phase, and the external emulsification compound, with stirring.

 For this embodiment, the crosslinking of the intermediate phase is carried out by the action of the catalyst, if necessary by placing it under the temperature conditions allowing elimination of the inhibitor. It should be noted that, according to this embodiment, crosslinking may have been initiated during the preparation of the multiple emulsion.

 According to a second particular embodiment of the invention, the crosslinkable polyorganosiloxane system comprises a polyorganosiloxane comprising one or more reactive Si-OH crosslinking groups, and a catalyst for the crosslinking reaction, and the multiple emulsion is obtained by a process comprising the following steps: a) the internal phase is mixed with stirring, the intermediate phase, the intermediate phase and the internal emulsification compound, said compound being optionally premixed in one of the phases, the intermediate phase comprising the polyorganosiloxane comprising one or more Si-OH reactive crosslinking groups, to obtain an internal emulsion, b) once the internal emulsion has been obtained, the catalyst is added, c) the emulsion obtained in the preceding step is mixed, the phase external aqueous, and the external emulsifying compound, with stirring.

 For this embodiment, the crosslinking of the intermediate phase is carried out by the action of the catalyst.

 According to a third particular embodiment of the invention, the crosslinkable polyorganosiloxane system comprises one or more reactive crosslinking groups

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 epoxides and a photoinitiator, and the multiple emulsion is obtained by a process comprising the following stages: a) mixing with stirring, the internal phase the intermediate phase, the intermediate phase and the internal emulsification compound, said compound being optionally premixed in one of the phases, the intermediate phase comprising, a polyorganosiloxane comprising one or more epoxy reactive crosslinking groups, and optionally all or part of the photoinitiator, to obtain an internal emulsion, b) optionally added , once the internal emulsion has been obtained, the photoinitiator or the remaining part, c) the emulsion obtained in the preceding step, the external aqueous phase, and the external emulsification compound are mixed, with stirring.

 For this embodiment, the crosslinking of the intermediate phase is carried out by the action of ultraviolet radiation.

Drying
The suspension according to claim can be treated so as to eliminate the external phase, in order to obtain particles of crosslinked polyorganosiloxane comprising a dispersion of the internal phase. The elimination of the external phase can for example be carried out by drying. The external phase eliminated can advantageously comprise a water-soluble or water-dispersible polymer which is in solid form in the presence of a water content of at most 10% by weight relative to the weight of said polymer and whose glass transition temperature is greater than 25 C, preferably greater than 50 C. The particles thus obtained can for example be introduced into various media or various compositions in order to provide an active material therein. It may for example be an introduction into a plastic material. It is mentioned that the particles can also be introduced subsequently into a liquid medium, aqueous or not, to obtain a suspension again.

 The suspension of particles and the particles obtained from this suspension can be used in particular in cosmetic, detergent, food compositions, or in compositions of plastic materials. They can in particular be used to encapsulate perfumes, for example for compositions for personal use or for introduction into plastics.

 More particularly, the suspension according to the invention can be used in a cosmetic formulation, for example in the field of skin and / or hair treatment.

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 The content of particles is preferably such that the content of active material (s) in the cosmetic or dermatological formulation is between 0.01 and 50% by weight of said formulation.

 The cosmetic compositions which are the subject of the invention can be formulated in a large number of types of products for the skin, the hair, the eyelashes and / or the nails, the shampoos for hair or for the body, the cleaning gels. of the face or the body, liquid soaps, foaming compositions for the bath, conditioners, formulations for styling or for facilitating combing of the hair, lotions for the hands and the body, products regulating the hydration of the skin, toilet milks, make-up removing compositions, depilatory products, creams or lotions for protection against the sun and ultraviolet radiation, care creams, anti-acne preparations, make-up formulations of the mascaras type, foundations , nail polish, products intended to be applied to the lips, etc.

 Cosmetic formulations, in addition to the emulsion or dispersion according to the invention, include additives conventional in the field.

 Thus, the formulations can comprise surfactants, the content of which can vary between approximately 3-40% by weight relative to the formulation.

 Among the suitable surfactants, there may be mentioned as anionic surfactants: alkyl esters sulfonates, alkylbenzenesulfonates, primary or secondary alkylsulfonates, alkylglycerol sulfonates, sulfonated polycarboxylic acids, paraffin sulfonates; alkyl sulfates; alkyl ether sulfates; alkylamide sulfates; salts of saturated or unsaturated fatty acids, N-acyl Nalkyltaurates, alkylisethionates, alkylsuccinamates and alkylsulfosuccinates, monoesters or diesters of sulfosuccinates, N-acyl sarcosinates, polyethoxycarboxylates; and alkyl and / or alkyl ether and / or alkylarylether ester phosphates, alone or as a mixture.

 Among the nonionic surfactants which can be used in the formulations, the following are suitable: alkoxylated fatty alcohols; alkoxylated triglycerides; alkoxylated fatty acids; alkoxylated sorbitan esters; alkoxylated fatty amines; alkoxylated di (phenyl-1 ethyl) phenols; alkoxylated tri (1-phenylethyl) phenols; alkoxylated alkyl phenols; the products resulting from the condensation of ethylene oxide with a hydrophobic compound resulting from the condensation of propylene oxide with propylene glycol, such as the Pluronic sold by BASF; the products resulting from the condensation of ethylene oxide the compound resulting from the condensation of propylene oxide with ethylenediamine, such as the Tetronic sold by BASF; the

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 alkylpolyglycosides such as those described in US 4,565,647; fatty acid amides, for example C8-C20; alone or as a mixture.

 The formulations can likewise include cationic surfactants such as alkyl dimethylammonium halides, or alternatively amphoteric or zwitterionic surfactants, such as for example betaines, for example lauryl betaine (Mirataine BB from the company Rhodia Chimie); sulfo-betaines; amidoalkylbetaines, such as cocamidopropyl betaine (Mirataine BDJ from the company Rhodia Chimie); sultaines such as cocamidopropyl hydroxy sultaine (Mirataine CBS from the company Rhodia Chimie); alkylamphoacetates and alkylamphodiacetates, such as for example comprising a coconut, lauryl chain (Miranol C2M, C32 in particular, from the company Rhodia Chimie); alkylamphopropionates or alkylamphodipropionates, (Miranol C2M SF); alkyl amphohydroxypropyl sultaines (Miranol CS).

 It is thus possible to incorporate into the cosmetic composition, in the form of dispersions or solutions, bactericidal or fungicidal agents in order to improve the disinfection of the skin, such as for example triclosan; anti-dandruff agents, such as in particular zinc pyrithione or octopyrox; insecticidal agents such as natural or synthetic pyrethroids.

 The cosmetic compositions may also contain agents for protecting the skin and / or the hair against attacks by the sun and UV rays. Thus, the compositions can include sun filters which are chemical compounds which strongly absorb UV radiation, like the compounds authorized in the European directive? 76/768 / EEC, its annexes and subsequent amendments to this directive.

 The cosmetic compositions can also contain fixative resins.

 These fixing resins, when they are present, are generally present at concentrations of between 0.01 and 10%, preferably between 0.5 and 5%.

 The fixing resins used in the cosmetic compositions are more particularly chosen from the following resins:. methyl acrylate / acrylamide copolymers, polyvinylmethylether maleic anhydride copolymers, vinyl acetate / crotonic acid copolymers, octylacrylamide / methyl acrylate / butylaminoethylmethacrylate, polyvinylpyrrolidones, polyvinylpyrrolidone / methacrylate polyvinyl acetylvinyl copolymers, polyvinyl alcohol / crotonic acid, polyvinyl alcohol / maleic anhydride copolymers, hydroxypropyl celluloses, hydroxypropyl guars, polystyrene sodium sulfonates, polyvinylpyrrolidone / ethyl methacrylate / acid terpolymers

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 methacrylic, monomethyl ethers of poly (methylvinyl ether / maleic acid), polyvinylacetates grafted onto polyoxyethylene trunks (EP 219048), # copolyesters derived from acid, anhydride or from a terephthalic and / or isophthalic and / or sulfoisophthalic diester and d 'a diol, such as: - polyester copolymers based on ethylene terephthalate and / or propylene terephthalate and polyoxyethylene terephthalate units (US 3959230, US 3893929, US 4116896, US 4702857, US 4770666); - the sulfonated polyester oligomers obtained by sulfonation of an oligomer derived from ethoxylated allyl alcohol, dimethyl terephthalate and 1,2 propylene diol (US 4968451); - polyester copolymers derived from dimethyl terephthalate, isophthalic acid, dimethyl sulfoisophthalate and ethylene glycol (EP 540374) - copolymers comprising polyester units derived from dimethyl terephthalate, isophthalic acid, dimethyl sulfoisophthalate and ethylene glycol and polyorganosiloxane units (FR 2728915).

 - the sulfonated polyester oligomers obtained by condensation of isophthalic acid, of dimethyl sulfosuccinate and of diethylene glycol (FR 2236926) - the polyester copolymers based on propylene terephthalate and polyoxyethylene terephthalate units and terminated with ethyl, methyl units (US 4711730 ) or polyester oligomers terminated by alkylpolyethoxy groups (US 4702857) or anionic sulfopolyethoxy groups (US 4721580), sulfoaroyl groups (US 4877896); the polyester polyurethanes more particularly obtained by reaction of a polyester obtained from adipic acid and / or terephthalic acid and / or sulfoisophthalic acid and a diol, on a prepolymer with terminal isocyanate groups obtained at starting from a polyoxyethylene glycol and a diisocyanate (FR 2334698); # monoamines or ethoxylated polyamines, polymers of ethoxylated amines (US 4597898, EP 11984).

 Preferably, the fixing resins are chosen from polyvinylpyrrolidone (PVP), copolymers of polyvinylpyrrolidone and methyl methacrylate, copolymer of polyvinylpyrrolidone and vinyl acetate (VA), polyterephthalene copolymers of ethylene glycol / polyethylene glycol, polyterephthalate copolymers ethylene glycol / polyethylene glycol / sodium polyisophthalate sulfonate, and mixtures thereof.

 These fixative resins are preferably dispersed or dissolved in the chosen vehicle.

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 The cosmetic compositions can also contain polymeric derivatives exerting a protective function.

 These polymer derivatives can be present in amounts of the order of 0.01-10%, preferably about 0.1-5%, and most particularly of the order of 0.2-3% by weight.

 These agents can in particular be chosen from:. non-ionic cellulose derivatives such as cellulose hydroxyethers, methylcellulose, ethylcellulose, hydroxypropyl methylcellulose, hydroxybutyl methylcellulose; . polyvinyl esters grafted on polyalkylenated trunks such as polyvinylacetates grafted on polyoxyethylene trunks (EP 219048); . polyvinyl alcohols.

 The cosmetic compositions can also comprise plasticizing agents.

 Said agents, if present, can represent between 0.1 to 20% of the formulation, preferably from 1 to 15%.

 Among the particularly useful plasticizers, there may be mentioned adipates, phthalates, isophthalates, azelates, stearates, silicone copolyols, glycols, castor oil, or mixtures thereof.

 One can also advantageously add to these compositions metal sequestering agents, more particularly those sequestering calcium such as citrate ions.

 Humectants can also be incorporated into the cosmetic compositions, among which are, inter alia, glycerol, sorbitol, urea, collagen, gelatin, aloe vera, hyaluronic acid or water-soluble volatile solvents such as ethanol or propylene glycol, the contents of which can reach up to 60% by weight of the composition.

 To further reduce irritation or aggression on the scalp, it is also possible to add water-soluble or water-dispersible polymers such as collagen or certain non-allergenic derivatives of animal or vegetable proteins (wheat protein hydrolysates for example), natural hydrocolloids ( guar, carob, tara gum, etc.) or derived from fermentation processes and derivatives of these polycarbohydrates such as non-ionic modified celluloses such as, for example, hydroxyethylcellulose, or anionic such as carboxymethylcellulose; guar or carob derivatives such as their nonionic derivatives (for example hydroxypropylguar) or anionic derivatives (carboxymethylguar and carboxymethylhydroxypropylguar).

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 To these compounds, it is possible to add in combination, powders or mineral particles such as calcium carbonate, sodium bicarbonate, calcium dihydrogen phosphate, mineral oxides in powder form or in colloidal form (particles of smaller size or on the order of a micrometer, sometimes a few tens of nanometers) such as titanium dioxide, silica, aluminum salts generally used as antiperspirants, kaolin, talc, clays and their derivatives, etc. .

 Preservatives such as methyl, ethyl, propyl and butyl esters of p-hydroxybenzoic acid, sodium benzoate, GERMABEN # or any chemical agent preventing the proliferation of bacteria or molds and traditionally used cosmetic compositions, can also be introduced into the aqueous cosmetic compositions according to the invention, generally up to 0.01 to 3% by weight.

 The amount of these products is usually adjusted to avoid any proliferation of bacteria, molds or yeasts in cosmetic compositions.

 As an alternative to these chemical agents, it is sometimes possible to use agents which modify the activity of water and greatly increase the osmotic pressure, such as carbohydrates or salts.

 To protect the skin and / or the hair from the aggressions of the sun and UV rays, it is possible to add to these formulations mineral particles such as zinc oxide, titanium dioxide or cerium oxides in the form of powder or particles. colloidal, alone or in mixture. These powders can optionally be treated on the surface to increase the effectiveness of their anti-UV action or to facilitate their incorporation into cosmetic formulations or to inhibit surface photoreactivity.

 To these ingredients can be added, if necessary, and in order to increase the comfort during the use of the composition by the consumer, one or more perfumes, coloring agents among which mention may be made of the products described in Annex IV ("List of coloring agents allowed for use in cosmetic products") of European Directive No. 76/768 / EEC of July 27, 1976 known as the Cosmetic Directive, and / or opacifying agents such as pigments.

 Although this is not compulsory, the composition may also contain viscous or gelling polymers so as to adjust the texture of the composition, such as crosslinked polyacrylates (Carbopol sold by Goodrich), non-cationic cellulose derivatives such as hydroxypropylcellulose. , carboxymethylcellulose, guars and their nonionic derivatives, xanthan gum and

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 its derivatives, used alone or in combination, or the same compounds, generally in the form of water-soluble polymers modified by hydrophobic groups covalently linked to the polymer backbone as described in international application WO 92/16187 and / or water to bring the total of the constituents of the formulation to 100%.

 The cosmetic compositions may also contain polymeric dispersing agents in an amount of the order of 0.1-7% by weight, to control the hardness of calcium and magnesium, agents such as:. the water-soluble salts of polycarboxylic acids with a molecular weight by weight of the order of 2000 to 100,000 g / mol, obtained by polymerization or copolymerization of ethylenically unsaturated carboxylic acids such as acrylic acid, maleic acid or anhydride , fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid, methylenemalonic acid, and very particularly polyacrylates of molecular weight by weight of the order of 2000 to 10 000 g / mol (US 3308067), copolymers of acrylic acid and maleic anhydride with a molecular weight by weight of the order of 5000 to 75,000 g / mol (EP 66915); . polyethylene glycols, for example of molecular weight by weight of the order of 1000 to 50,000 g / mol.

Other details or advantages of the invention will appear more clearly in the light of the examples given below for information.

EXAMPLES Example 1.1. : preparation of a water in silicone emulsion Ingredients: Silicone oil 621V100 * + 100 ppm ethynyl cyclo hexanol 8. 325 g Surfactant DC5225 ** 15.75 g NaCL 0.3 g Water 52. 5 g * polyorganosiloxane comprising 1% of Si-Vinyl groups, with a viscosity of 100 mPa.s, sold by Rhodia.

** Active voltage marketed by Dow Corning.

The silicone oil and the surfactant are introduced into a beaker. The water with added salt is added gradually under Ultra Turrax (10,000 rpm) and stirring is continued 1 minute after the end of the addition. A water in silicone emulsion is obtained (internal emulsion).

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Example 1. 2.: preparation of a multiple emulsion water in silicone crosslinked in water Ingredients: Emulsion of Example 1. 1 15 g Crosslinking oil * 0.05 g Pt catalyst from Karlstedt 0.08 g Aqueous solution of PVA 10% ** 35 g Glucose 0. 2 g * polyorganosiloxane comprising 1.3% of Si-H groups.

** Rhodoviol 25/140 marketed by Rhodia The crosslinking oil and the catalyst are added to the emulsion of Example 1. 1. This mixture, after homogenization, is introduced several times into the 10% aqueous solution d 'VPA with glucose added. The system is homogenized using a pale frame (40 rpm) for approximately 40 minutes, to form an external emulsion, then heated to 60 ° C. for approximately 40 minutes to obtain crosslinking in the droplets of the external emulsion.

A multiple emulsion is observed under an optical microscope.

Example 2: To a part of the water in silicone emulsion of example 1. 1 is added the crosslinking oil of example 1. 2 and the catalyst of example 1. 2. To this mixture, after homogenization and stirring is stopped, a 10% solution of PVA (ex Rhodoviol 25/140) with glucose added, of example 1, is added. 2. The system is homogenized in the pale frame (40 rpm) for about 40 minutes and then heated to 60 ° C. for about 40 minutes to carry out the polymerization in the droplets.

The composition is as follows: Example 1 15 g Cross-linking oil 0.05 g Catalyst 0.08 g 10% PVA 35 g Glucose 0.2 g A multiple emulsion is observed under an optical microscope.

Example 3.1 Preparation of a Castor Oil in Silicone Emulsion

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 Ingredients: Silicone oil 621 V100 + 100 ppm ethynyl cyclo hexanol 24. 25 g Copolymer * 0.75 g Castor oil 25 g * copolymer described in Example 5.

The silicone oil is added to the copolymer. After homogenization, the castor oil is introduced under Ultra Turrax (10,000 rpm) and stirring is continued 1 minute after the end of the addition.

A castor oil in silicone emulsion is obtained (internal emulsion).

Example 3.2: Preparation of a multiple castor oil emulsion in crosslinked silicone in water Ingredients Emulsion of Example 2. 1 15 g Crosslinking oil * 0.24 g Karlstedt Pt catalyst 0.36 g 10% aqueous PVA solution ** 35 g Glucose 0.08 g * polyorganosiloxane comprising 1. 3% of Si-H groups.

** Rhodoviol 25/140 marketed by Rhodia The crosslinking oil and the catalyst are added to the emulsion of Example 2. 1. This mixture, after homogenization, is introduced several times into the 10% aqueous solution d 'VPA with glucose added. The system is homogenized using a pale frame (40 rpm) for approximately 40 minutes, to form an external emulsion, then heated to 60 ° C. for approximately 40 minutes to obtain crosslinking in the droplets of the external emulsion.

A multiple emulsion is observed under an optical microscope.

Example 4.1: preparation of a water in silicone emulsion Ingredients: 621V100 silicone oil + 100 ppm ethynyl cyclo hexanol 8. 325 g Tegopren 7008 surfactant in D5 * (10% solution) 15. 75 g NaCL 0.3 g Water 52.5 g * marketed by Goldschmidt

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 The silicone oil and the surfactant are introduced into a beaker. The water added with salt is introduced under Ultra Turrax (10,000 rpm) and the stirring is maintained 1 minute after the end of the addition. A water in silicone emulsion is obtained (internal emulsion) Example 4. 2: preparation of a multiple water in silicone emulsion crosslinked in water Ingredients Emulsion of Example 4. 1 15 g Crosslinking oil * 0.05 g Pt Karlstedt catalyst 0.08 g 10% PVA solution ** 35 g Glucose 0.2 g * polyorganosiloxane comprising 1. 3% of Si-H groups.

** Rhodoviol 25/140 marketed by Rhodia The crosslinking oil and the catalyst are added to the emulsion of Example 3. 1. This mixture, after homogenization, is introduced several times into the 10% aqueous solution d 'VPA with glucose added. The system is homogenized using a pale frame (40 rpm) for approximately 40 minutes, to form an external emulsion, then heated to 60 ° C. for approximately 40 minutes to obtain crosslinking in the droplets of the external emulsion.

A multiple emulsion is observed under the light microscope.

Claims (43)

 CLAIMS 1. Suspension of particles capable of being obtained by a process comprising the following stages: - Stage 1: of a multiple emulsion comprising: -an internal emulsion comprising an aqueous or organic internal phase, dispersed in a polyorganosiloxane intermediate phase, not miscible with the internal phase, and at least one internal emulsification compound, and - an external emulsion comprising the internal emulsion, dispersed in an aqueous external phase, and at least one external emulsification compound, characterized in that: - the intermediate phase is crosslinkable and comprises a crosslinkable polyorganosiloxane system, - the internal emulsification compound is: - a particulate surfactant, optionally combined with a co-surfactant, or - a comb or block surfactant polymer comprising organosiloxane units, including one fraction is soluble in the internal phase, the other in the intermediate phase, the fraction soluble in s the intermediate phase being greater than the fraction soluble in the internal phase, and - the external emulsification compound is: - a nonionic surfactant, - a nonionic amphiphilic polymer, optionally combined with one or more anionic and / or polymeric surfactants anionic amphiphiles, - a particulate surfactant possibly associated with a co-surfactant, or - a protective colloid, - Step 2: crosslinking of the intermediate phase. 2. Suspension according to claim 1 characterized in that the internal phase and / or the intermediate phase and / or the external phase comprises an active material respectively soluble or dispersible in the phase in which it is included. 3. Suspension according to one of the preceding claims, characterized in that the crosslinkable polyorganosiloxane system comprises: - either a first polyorganosiloxane comprising one or more reactive crosslinking groups of the Si-alkenyl type, associated with at least a second polyorganosiloxane comprising one or more groups Si-H type reagent cross-linking, <Desc / Clms Page number 44> O where the groups R and R2, identical or different, represent a hydrogen atom or an alkyl radical comprising 1 to 30 carbon atoms, and a photoinitiator. V If-RC-CR2  optionally an inhibitor of the kinetics of the crosslinking reaction, and a catalyst of the crosslinking reaction, - either a polyorganosiloxane comprising one or more reactive crosslinking groups Si-OH, and a catalyst of the crosslinking reaction, - or a polyorganosiloxane comprising one or more reactive epoxy crosslinking groups of formula: 4. Suspension according to one of the preceding claims, characterized in that: - the internal phase is an aqueous phase, and the comb or block surfactant polymer is a comb polymer comprising a skeleton comprising organosiloxane units, and polyether side chains , or - the internal phase is an organic phase, and the comb or block surfactant polymer is a three-block copolymer comprising a central block comprising organosiloxane units, and two hydrophobic side blocks comprising units derived from alpha-ethylenically unsaturated monomers. 5. Suspension according to one of the preceding claims, characterized in that the content of surfactant polymer is from 1 to 10%, preferably from 3 to 5%, by weight relative to the internal phase. 6. Suspension according to one of claims 1 to 3, characterized in that the content of particulate surfactant is 5 to 20% by weight relative to the internal emulsion, and in that the content of co-surfactant is 0 to 2% by weight relative to the internal emulsion. 7. Suspension according to one of the preceding claims, characterized in that the internal emulsification compound is a surfactant polymer, with at least one cosolvent. 8. Suspension according to the preceding claim, characterized in that the co-solvent is a volatile polyorganosiloxane or an aliphatic C10 to C2o alkyl ester, preferably a C5 to C12 alkyl neopentanoate <Desc / Clms Page number 45>  9. Suspension according to one of claims 7 or 8, characterized in that the co-solvent content is 0 excluded to 95% by weight of the surfactant polymer. 10. Suspension according to one of the preceding claims, characterized in that the internal phase is an organic phase chosen from: - oils / fats / organic waxes of animal or vegetable origin; - mineral oils / waxes; - products from alcoholysis of the above oils; - essential oils ; - mono-, di- and tri-glycerides; - fatty acids, saturated or not, comprising 10 to 40 carbon atoms; esters of such acids and of alcohol comprising 1 to 6 carbon atoms; - monoalcohols, saturated or not, comprising 2 to 40 carbon atoms; - polyols comprising 2 and 10 carbon atoms; - polyorganosiloxane oils insoluble in the intermediate phase and devoid of polymerizable functions of the type of those present in the polyorganosiloxane (s) present in the intermediate phase. 11. Suspension according to one of claims 3 to 10, characterized in that the first polyorganosiloxane comprising one or more reactive groups of the Si-alkenyl type comprises: - units of the following formula (A.1):

 in which: - W is an alkenyl group, preferably vinyl, - Z is a monovalent hydrocarbon group, free from any adverse action on the activity of the catalyst and preferably chosen from alkyl groups having from 1 to 8 atoms carbon included, advantageously, among the methyl, ethyl, propyl and 3,3,3-trifluoropropyl groups and also among the aryl groups and, advantageously, among the xylyl and tolyl and phenyl radicals, - a is 1 or 2, b is 0,1 or 2 and a + b is between 1 and 3, - and, optionally, units of formula (A. 2) following:

<Desc / Clms Page number 46>  in which Z has the same meaning as above and c has a value between 0 and 3, for example between 1 and 3. 12 Suspension according to the preceding claim, characterized in that the first polyorganosiloxane is chosen from dimethylpolysiloxanes with dimethylvinylsilyl ends, methylvinyldimethylpolysiloxane copolymers with trimethylsilyl ends, methylvinyldimethyl-polysiloxane copolymers with dimethylvinylsilyl ends, methyl-vinylol mixtures or methyl-vinylol mixtures. 13. Suspension according to one of claims 3 to 12, characterized in that the second polyorganosiloxane, comprising one or more reactive groups of the SiH type comprises: - units of the following formula (B.1):

 in which: - L is a monovalent hydrocarbon group, free from an unfavorable action on the activity of the catalyst chosen, preferably from alkyl groups having from 1 to 8 carbon atoms included and, advantageously, from methyl and ethyl groups , propyl and 3,3,3-trifluoropropyl and also among the aryl groups and, advantageously, among the xylyl and tolyl and phenyl radicals, - d is 1 or 2, c is 0.1 or 2, d + ca a value between 1 and 3, - and optionally, units of the following formula (B.2):

 where L has the same meaning as above and g has a value between 0 and 3. 14. Suspension according to the preceding claim, characterized in that the second polyorganosiloxane is poly (dimethylsiloxane) (methylhydrogenosiloxy) ([alpha], # - dimethylhydrogeno) siloxane. 15. Suspension according to one of claims 3 to 14, characterized in that the inhibitor is ethynyl cyclohexanol. 16. Suspension according to one of claims 3 to 15, characterized in that the catalyst is chosen from metallic compounds based on platinum. <Desc / Clms Page number 47> 17. Suspension according to one of claims 3 to 16, characterized in that the respective contents of inhibitor and catalyst are such that the crosslinking reaction does not take place substantially before obtaining the multiple emulsion. 18. Suspension according to one of the preceding claims, characterized in that the weight ratio between the internal phase and the intermediate phase is from 5/95 to 95/5, more particularly from 20/80 to 90/10, and preferably from 40/60 to 80/20. 19. Suspension according to one of the preceding claims, characterized in that the emulsion of the internal phase in the intermediate phase has an average droplet size of 0.01 to 50 m, more particularly from 0.1 to 20 m, and preferably from 0.1 to 10 m. 20. Suspension according to one of the preceding claims, characterized in that the external emulsification compound is a nonionic surfactant, preferably polyalkoxylated, chosen from at least one of the following surfactants: - alkoxylated fatty alcohols - triglycerides alkoxylated - alkoxylated fatty acids - alkoxylated sorbitan esters - alkoxylated fatty amines - alkoxylated di (phenyl-1 ethyl) phenols - alkoxylated tri (1-phenylethyl) phenols, and - alkoxylated alkyl phenols where the number of alkoxy units, more particularly oxyethylene and / or oxypropylene, is such that the value of HLB is greater than or equal to 10. 21. Suspension according to one of claims 1 to 19, characterized in that the external emulsification compound comprises an amphiphilic polymer chosen from triblock copolymers (polyethylene glycol) - (polypropylene glycol) - (polyethylene glycol). 22. Suspension according to one of the preceding claims, characterized in that the content of nonionic surfactant and / or nonionic amphiphilic polymer is from 0.5 to 10% by weight relative to the weight of the emulsion of the phase internal in the intermediate phase, preferably from 1 to 5% by weight relative to the same reference. <Desc / Clms Page number 48> 23. Suspension according to one of claims 1 to 19, characterized in that the external emulsification compound comprises at least one anionic surfactant chosen from at least one of the following surfactants: - alkyl esters sulfonates, alkylbenzenesulfonates, alkylsulfonates primary or secondary, alkyl glycerol sulfonates, sulfonated polycarboxylic acids, paraffin sulfonates; - alkyl sulfates; - alkyl ether sulfates; - alkylamide sulfates; - the salts of saturated or unsaturated fatty acids, N-acyl N-alkyltaurates, alkylisethionates, alkylsuccinamates and alkylsulfosuccinates, monoesters or diesters of sulfosuccinates, N-acyl sarcosinates, polyethoxycarboxylates; and - the phosphate esters of alkyl and / or of alkyl ether and / or of alkylarylether, alone or as a mixture. 24. Suspension according to the preceding claim, characterized in that the content of anionic surfactant is 0.5 to 5% by weight relative to the weight of the emulsion of the internal phase in the intermediate phase, preferably 0, 5 to 2% by weight with respect to the same reference. 25. Suspension according to one of claims 1 to 19, characterized in that the particulate surfactant is a precipitated silica, a colloidal silica, a silicoaluminate, zinc oxide, titanium oxide, or a mixture of these compounds, these compounds optionally comprising a surface treatment. 26. Suspension according to one of claims 1 to 19, characterized in that the protective colloid is a polyvinyl alcohol, optionally partially hydrolyzed. 27. Suspension according to one of the preceding claims, characterized in that the content of protective colloid is 3 to 30%, preferably 5 to 25%, by dry weight relative to the internal emulsion. 28. Suspension according to one of claims 1 to 9 and 11 to 27, characterized in that the internal phase is an aqueous phase, and in that the internal phase and the external phase comprise at least one additive for regulating the osmotic pressure , identical or not, chosen from salts such as the alkali metal halides or <Desc / Clms Page number 49>  alkaline earth, or alkali or alkaline earth metal sulfates, or among sugars, or polysaccharides, or mixtures thereof. 29. Suspension according to the preceding claim, characterized in that the salt concentration in the internal phase is between 0.05 and 1 mol / l, preferably 0.1 to 0.4 molli, and / or in that the sugar and / or polysaccharide concentration is such that the osmotic pressure of the internal phase comprising the sugar and / or polysaccharide corresponds to the osmotic pressure of an internal aqueous phase comprising 0.05 to 1 molli of salt; the additive content in the external phase being such that the osmotic pressures of the internal and external phases are balanced. 30. Suspension according to one of the preceding claims, characterized in that the external phase comprises at least one thickening agent chosen from polymers extracted from plants and optionally modified, polysaccharides of animal, vegetable, bacterial origin, or mixtures thereof. 31. Suspension according to the preceding claim, characterized in that the content of thickening agent is such that said agent is soluble in the external phase, and is more particularly from 0.1 to 2% by weight relative to the external phase, preferably 0.1 to 0.5% by weight relative to the external phase. 32. Suspension according to one of the preceding claims, characterized in that the weight ratio between the emulsion of the internal phase in the intermediate phase and the external phase is from 5/95 to 60/40, preferably from 20/80 to 60/40. 33. Suspension according to one of the preceding claims, characterized in that the average size of the droplets of the external emulsion is from 0.1 to 500 m, more particularly from 1 to 200 pm, and preferably from 1 to 100 m. 34. Suspension according to one of claims 3 to 33, characterized in that the multiple emulsion is obtained by a process comprising the following steps: a) the internal phase, the intermediate phase and the emulsification compound are mixed with stirring internal, said compound being optionally premixed in one of the phases, the intermediate phase comprising the first polyorganosiloxane, optionally all or part of the second polyorganosiloxane, and optionally all or part of the inhibitor, if present, to obtain the internal emulsion, <Desc / Clms Page number 50>  b) adding, once the internal emulsion obtained, the second polyorganosiloxane or the remaining part, optionally the inhibitor or the remaining part, and the catalyst, c) mixing the emulsion obtained in the previous step, the phase external aqueous, and the external emulsifying compound, with stirring. 35. Suspension according to the preceding claim, characterized in that the crosslinking of the intermediate phase is carried out by the action of the catalyst, if necessary by placing it under the temperature conditions allowing elimination of the inhibitor. 36. Suspension according to one of claims 3 to 10, and 18 to 33, characterized in that the multiple emulsion is obtained by a process comprising the following steps: a) the internal phase, the intermediate phase and with stirring the internal emulsification compound, said compound being optionally premixed in one of the phases, the intermediate phase comprising the polyorganosiloxane comprising one or more reactive cross-linking groups Si-OH, to obtain an internal emulsion, b) is added, once the internal emulsion has been obtained, the catalyst, c) the emulsion obtained in the preceding step, the external aqueous phase, and the external emulsification compound are mixed, with stirring. 37. Suspension according to the preceding claim, characterized in that the crosslinking of the intermediate phase is carried out by the action of the catalyst. 38. Suspension according to one of claims 3 to 10, and 18 to 33, characterized in that the multiple emulsion is obtained by a process comprising the following stages: a) the internal phase, the intermediate phase and with stirring the internal emulsification compound, said compound being optionally premixed in one of the phases, the intermediate phase comprising, a polyorganosiloxane comprising one or more epoxy reactive crosslinking groups, and optionally all or part of the photoinitiator, to obtain an internal emulsion, b) optionally, once the internal emulsion is obtained, the photoinitiator or the remaining part, c) the emulsion obtained in the preceding step, the external aqueous phase, and the compound are mixed external emulsification, with stirring. 39. Suspension according to the preceding claim, characterized in that the crosslinking of the intermediate phase is carried out by the action of ultraviolet radiation. <Desc / Clms Page number 51> 40. Particles capable of being obtained by elimination of the external phase of the suspension according to one of the preceding claims. 41. Particles according to claim 40 characterized in that the elimination is carried out by drying. 42. Particles according to either of Claims 40 and 41, characterized in that the eliminated external phase comprises a water-soluble or water-dispersible polymer which is in solid form in the presence of a water content of at most 10% by weight per relative to the weight of said polymer and whose glass transition temperature is greater than 25 C, preferably greater than 50 C. 43. Use of the suspension of particles according to one of claims 1 to 39, or of particles according to one of claims 40 to 42, in cosmetic, detergent, food compositions, or in compositions of plastic materials.