FR2673075B1 - MICROEMULSIONS OF PYRETHROUIDS AND THEIR USE. - Google Patents
MICROEMULSIONS OF PYRETHROUIDS AND THEIR USE.Info
- Publication number
- FR2673075B1 FR2673075B1 FR9102374A FR9102374A FR2673075B1 FR 2673075 B1 FR2673075 B1 FR 2673075B1 FR 9102374 A FR9102374 A FR 9102374A FR 9102374 A FR9102374 A FR 9102374A FR 2673075 B1 FR2673075 B1 FR 2673075B1
- Authority
- FR
- France
- Prior art keywords
- weight
- alcohols
- surfactant
- microemulsions
- anionic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004530 micro-emulsion Substances 0.000 title abstract 3
- 239000003945 anionic surfactant Substances 0.000 abstract 3
- 239000002736 nonionic surfactant Substances 0.000 abstract 3
- 150000001298 alcohols Chemical class 0.000 abstract 2
- -1 aliphatic alcohols Chemical class 0.000 abstract 2
- 239000004064 cosurfactant Substances 0.000 abstract 2
- 239000002728 pyrethroid Substances 0.000 abstract 2
- 241000238631 Hexapoda Species 0.000 abstract 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to novel stable microemulsions of pyrethroid, characterised in that they contain: - from 0.1% to 95% by weight of at least one pyrethroid in liquid form, - from 2% to 90% by weight of a surfactant system comprising: . at least one anionic surfactant, . at least one non-ionic surfactant, . at least one cosurfactant selected from among: + aliphatic alcohols, cycloaliphatic alcohols, arylaliphatic alcohols, ether alcohols and aliphatic carboxylic acids, - and water, and in that the ratio by weight of anionic surfactant/non-ionic surfactant is from 10/90 to 90/10, and the ratio by weight of cosurfactant/anionic and non-ionic surfactants is from 0.1 to 1.5. Use of the microemulsions, if appropriate after dilution, for the control of insects, in particular in the treatment of crops or for the protection of wood.
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9102374A FR2673075B1 (en) | 1991-02-22 | 1991-02-22 | MICROEMULSIONS OF PYRETHROUIDS AND THEIR USE. |
| EP92400076A EP0500401B1 (en) | 1991-02-22 | 1992-01-13 | Microemulsions of pyrethroids and use thereof |
| DE69226543T DE69226543T2 (en) | 1991-02-22 | 1992-01-13 | Pyrethroid microemulsions and their use |
| AT92400076T ATE169454T1 (en) | 1991-02-22 | 1992-01-13 | PYRETHROID MICROEMULSIONS AND THEIR USE |
| ES92400076T ES2124246T3 (en) | 1991-02-22 | 1992-01-13 | PYRETROID MICROEMULSIONS AND THEIR USE. |
| DK92400076T DK0500401T3 (en) | 1991-02-22 | 1992-01-13 | Pyrethroid microemulsions and their use |
| CA002061427A CA2061427A1 (en) | 1991-02-22 | 1992-02-18 | Microemulsions of pyrethroides and their use |
| JP4069348A JP2631053B2 (en) | 1991-02-22 | 1992-02-20 | Pyrethroid microemulsions and their use |
| AU11163/92A AU646924B2 (en) | 1991-02-22 | 1992-02-20 | Pyrethroid microemulsions and their use |
| US07/838,669 US5334585A (en) | 1991-02-22 | 1992-02-21 | Pyrethroid microemulsion compositions and method for controlling insects therewith |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9102374A FR2673075B1 (en) | 1991-02-22 | 1991-02-22 | MICROEMULSIONS OF PYRETHROUIDS AND THEIR USE. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2673075A1 FR2673075A1 (en) | 1992-08-28 |
| FR2673075B1 true FR2673075B1 (en) | 1998-12-31 |
Family
ID=9410177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR9102374A Expired - Fee Related FR2673075B1 (en) | 1991-02-22 | 1991-02-22 | MICROEMULSIONS OF PYRETHROUIDS AND THEIR USE. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5334585A (en) |
| EP (1) | EP0500401B1 (en) |
| JP (1) | JP2631053B2 (en) |
| AT (1) | ATE169454T1 (en) |
| AU (1) | AU646924B2 (en) |
| CA (1) | CA2061427A1 (en) |
| DE (1) | DE69226543T2 (en) |
| DK (1) | DK0500401T3 (en) |
| ES (1) | ES2124246T3 (en) |
| FR (1) | FR2673075B1 (en) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5591727A (en) * | 1990-09-12 | 1997-01-07 | Perycut-Chemie Ag | Insecticidal composition |
| DE9012996U1 (en) * | 1990-09-12 | 1991-10-10 | Perycut-Chemie AG, Zürich | Insecticidal product |
| US5444078A (en) * | 1993-10-01 | 1995-08-22 | Rohm And Haas Company | Fully water-dilutable microemulsions |
| FR2720228B1 (en) * | 1994-05-24 | 1997-12-12 | Roussel Uclaf | New pesticide compositions of the "oil in water emulsion" type. |
| CN1036111C (en) * | 1994-12-27 | 1997-10-15 | 李学锋 | Insecticide composite microemulsion |
| EP0773284A1 (en) * | 1995-11-10 | 1997-05-14 | The Procter & Gamble Company | Microemulsion with high level of anionic surfactants, using branched fatty acids |
| US5877112A (en) * | 1997-08-27 | 1999-03-02 | Helena Chemical Company | Agricultural formulation |
| DE19752552A1 (en) | 1997-11-27 | 1999-06-02 | Hoechst Schering Agrevo Gmbh | Surfactant systems for liquid aqueous preparations |
| US6045816A (en) * | 1998-06-17 | 2000-04-04 | Isp Investments Inc. | Water-based microemulsion of a pyrethroid |
| GB9816697D0 (en) | 1998-07-31 | 1998-09-30 | Agrevo Uk Ltd | Liquid formulations |
| CR6136A (en) * | 1998-12-14 | 2008-11-18 | Pfizer | |
| AR030412A1 (en) * | 2000-03-22 | 2003-08-20 | Fmc Corp | NEW PROCESS TO PREPARE WATERY FORMULATIONS |
| US6582732B1 (en) * | 2000-08-15 | 2003-06-24 | Kop-Coat, Inc. | Synergistic combination of insecticides to protect wood and wood-based products from insect damage |
| US6703034B2 (en) * | 2000-12-11 | 2004-03-09 | University Of Florida | Neem oil microemulsion without cosurfactants or alcohols and a process to form the same |
| US6660768B2 (en) | 2001-02-08 | 2003-12-09 | Schering-Plough Animal Health Corporation | Parasiticidal compositions and methods of use |
| CN100351467C (en) | 2002-05-03 | 2007-11-28 | 伊梅里斯矿物有限公司 | Paper coating pigments |
| GB0504296D0 (en) * | 2005-03-02 | 2005-04-06 | Reckitt Benckiser Au Pty Ltd | Insect expellant floor cleaner additive |
| JP2009523130A (en) * | 2006-01-10 | 2009-06-18 | イノバフォーム テクノロジーズ エルエルシー | Insecticide delivery system |
| CN1807751B (en) * | 2006-01-12 | 2011-06-15 | 上海公泰纺织制品有限公司 | Method for preparing anti-insect textile by using pyrethroid-dyed synthetic fiber |
| JP5161428B2 (en) * | 2006-02-28 | 2013-03-13 | 保土谷化学工業株式会社 | High concentration pesticide water dispersion |
| BRPI0708928B1 (en) * | 2006-03-29 | 2018-02-06 | Agro-Kanesho Co., Ltd. | FORMULATION OF WASTIC PESTICIDE MICROEMULSION, USE OF FORMULATION, AND METHODS TO COMBAT HARMFUL PEST, AND TO PROTECT CROPS AND SEEDS FROM HARMFUL ATTACK OR INFESTATION |
| EP1875804A1 (en) * | 2006-07-08 | 2008-01-09 | Bayer CropScience AG | Liquid formulation containing pyrethroids |
| EP1886560A1 (en) * | 2006-08-05 | 2008-02-13 | Bayer CropScience AG | New microemulsifiable concentrates |
| UA98128C2 (en) * | 2006-11-22 | 2012-04-25 | Басф Се | Agrochemical formulation, a method for controlling harmful pests and/or phytopathogenous fungi, a method for controlling undesirable vegetation and seeds |
| ATE528991T1 (en) * | 2007-08-08 | 2011-11-15 | Basf Se | AQUEOUS MICROEMULSIONS CONTAINING ORGANIC INSECTICIDAL COMPOUNDS |
| US8404260B2 (en) * | 2008-04-02 | 2013-03-26 | Bayer Cropscience Lp | Synergistic pesticide compositions |
| WO2010010005A2 (en) * | 2008-07-24 | 2010-01-28 | Basf Se | Oil-in-water emulsion comprising solvent, water, surfactant and pesticide |
| UA106213C2 (en) * | 2008-10-10 | 2014-08-11 | Басф Се | Liquid preparations for protecting plants comprising pyraclostrobin |
| TW201018400A (en) * | 2008-10-10 | 2010-05-16 | Basf Se | Liquid aqueous plant protection formulations |
| NZ608331A (en) * | 2010-09-03 | 2015-06-26 | Arch Wood Prot Aust Pty Ltd | Formulation and method for the treatment of timber |
| US9049860B2 (en) | 2013-04-17 | 2015-06-09 | The Hartz Mountain Corporation | Ectoparasiticidal methods |
| CN105899071B (en) * | 2013-10-02 | 2020-07-24 | 瓦伦特生物科学公司 | Caprylic, nonyl and capric fatty acids and pyrethroid adulticides |
| CN105123776B (en) * | 2015-09-18 | 2019-03-08 | 广东省生物资源应用研究所 | A high-content pyrethrin insecticide |
| GB2551208B (en) * | 2016-06-09 | 2020-04-22 | Syngenta Participations Ag | Pesticidal formulation |
| US10448633B2 (en) | 2016-11-08 | 2019-10-22 | Valent Biosciences Llc | Octanoic, nonanoic and decanoic fatty acids with pyrethroid adulticides |
| JP7043220B2 (en) | 2017-10-30 | 2022-03-29 | アークレイ株式会社 | Analytical instrument and positioning method |
| AU2021107145B4 (en) * | 2021-08-24 | 2022-07-21 | Arch Wood Protection (Aust) Pty Ltd | Pyrethroid envelope timber treatment |
| KR102741274B1 (en) * | 2023-01-12 | 2024-12-13 | 글로벌인프라텍(주) | Eco-friendly fungicidal and insecticidal composition |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2719785A (en) * | 1952-06-02 | 1955-10-04 | California Research Corp | Herbicidal compositions |
| DE3111934A1 (en) * | 1981-03-26 | 1982-10-07 | Bayer Ag, 5090 Leverkusen | OIL-IN-WATER EMULSIONS, METHOD FOR THEIR PRODUCTION AND THEIR USE |
| US4536301A (en) * | 1981-08-31 | 1985-08-20 | Uop Inc. | Enhanced oil recovery |
| US4461641A (en) * | 1982-02-25 | 1984-07-24 | Ciba-Geigy Corporation | Herbicidal mixtures |
| DE3235612A1 (en) * | 1982-09-25 | 1984-03-29 | Bayer Ag, 5090 Leverkusen | MICROEMULSIONS |
| DE3343092A1 (en) * | 1983-11-29 | 1985-06-05 | Bayer Ag, 5090 Leverkusen | WATER-SOLUBLE PESTICIDAL FORMULATION |
| EP0160182B1 (en) * | 1984-04-09 | 1993-03-03 | American Cyanamid Company | Insecticidal aqueous-based micro emulsion compositions |
| GB8515389D0 (en) * | 1985-06-18 | 1985-07-17 | Ici Plc | Heterocyclic compounds |
| DE3624910A1 (en) * | 1986-07-23 | 1988-01-28 | Hoechst Ag | CONCENTRATED AQUEOUS MICROEMULSIONS |
| DE3707711A1 (en) * | 1987-03-11 | 1988-09-22 | Hoechst Ag | OIL-IN-WATER EMULSIONS, METHOD FOR THEIR PRODUCTION AND THEIR USE |
| EP0290379A3 (en) * | 1987-04-03 | 1989-02-22 | Ciba-Geigy Ag | 2-mercapto-5-pyrazinyl-1,3,4-oxadiazoles and -1,3,4-thiadiazoles, process for their preparation and their use as nematicidal agents |
| US4954338A (en) * | 1987-08-05 | 1990-09-04 | Rohm And Haas Company | Microbicidal microemulsion |
| IT1219699B (en) * | 1988-05-27 | 1990-05-24 | Geronazzo Spa | ACTIVE TENSION AGENT BASED ON (FENYL 1 ETHYL) POLYOXYKYLENE PHENOLS, ITS PREPARATION PROCEDURE AND ITS USE TO OBTAIN CONCENTRATED EMULSIFIABLE SOLUTIONS OF ACTIVE SUBSTANCES |
| JP2861076B2 (en) * | 1988-08-05 | 1999-02-24 | 住友化学工業株式会社 | Insecticidal aqueous solution |
| HU204393B (en) * | 1988-12-22 | 1992-01-28 | Chinoin Gyogyszer Es Vegyeszet | Insecticide aqouos solutions containing piretroides as active components and microemulsion compositions containing former solutions |
| FR2655276B1 (en) * | 1989-12-04 | 1992-11-27 | Rhone Poulenc Chimie | CONCENTRATED MICROEMULSIONS OF DILUABLE ORGANIC MATERIALS IN THE FORM OF STABLE EMULSIONS AND THEIR PREPARATION PROCESS. |
| JPH03287504A (en) * | 1990-04-03 | 1991-12-18 | Sankyo Co Ltd | Pest control emulsion composition for pipe spraying and pipe therefor |
-
1991
- 1991-02-22 FR FR9102374A patent/FR2673075B1/en not_active Expired - Fee Related
-
1992
- 1992-01-13 ES ES92400076T patent/ES2124246T3/en not_active Expired - Lifetime
- 1992-01-13 DE DE69226543T patent/DE69226543T2/en not_active Expired - Fee Related
- 1992-01-13 EP EP92400076A patent/EP0500401B1/en not_active Expired - Lifetime
- 1992-01-13 DK DK92400076T patent/DK0500401T3/en active
- 1992-01-13 AT AT92400076T patent/ATE169454T1/en not_active IP Right Cessation
- 1992-02-18 CA CA002061427A patent/CA2061427A1/en not_active Abandoned
- 1992-02-20 AU AU11163/92A patent/AU646924B2/en not_active Ceased
- 1992-02-20 JP JP4069348A patent/JP2631053B2/en not_active Expired - Lifetime
- 1992-02-21 US US07/838,669 patent/US5334585A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU1116392A (en) | 1992-08-27 |
| US5334585A (en) | 1994-08-02 |
| CA2061427A1 (en) | 1992-08-23 |
| ATE169454T1 (en) | 1998-08-15 |
| EP0500401B1 (en) | 1998-08-12 |
| JP2631053B2 (en) | 1997-07-16 |
| DE69226543D1 (en) | 1998-09-17 |
| FR2673075A1 (en) | 1992-08-28 |
| ES2124246T3 (en) | 1999-02-01 |
| DE69226543T2 (en) | 1999-04-29 |
| EP0500401A1 (en) | 1992-08-26 |
| JPH0592901A (en) | 1993-04-16 |
| DK0500401T3 (en) | 1999-05-17 |
| AU646924B2 (en) | 1994-03-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| CD | Change of name or company name | ||
| ST | Notification of lapse |