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FR2375983A1 - Styrene! polymer and metal composite material - using polydiene polyvinyl aromatic block copolymer adhesives, for structural applications - Google Patents

Styrene! polymer and metal composite material - using polydiene polyvinyl aromatic block copolymer adhesives, for structural applications

Info

Publication number
FR2375983A1
FR2375983A1 FR7700070A FR7700070A FR2375983A1 FR 2375983 A1 FR2375983 A1 FR 2375983A1 FR 7700070 A FR7700070 A FR 7700070A FR 7700070 A FR7700070 A FR 7700070A FR 2375983 A1 FR2375983 A1 FR 2375983A1
Authority
FR
France
Prior art keywords
block copolymer
composite material
polydiene
polymer
structural applications
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7700070A
Other languages
French (fr)
Other versions
FR2375983B1 (en
Inventor
Jean-Claude Brosse
Pierre Guillaume
Guy Meyer
Claude Morisset
Christian Pinazzi
Guy Reynier
Daniele Reyx
Jean-Michel Widmaier
Constant Wippler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bpifrance Financement SA
Original Assignee
Agence National de Valorisation de la Recherche ANVAR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agence National de Valorisation de la Recherche ANVAR filed Critical Agence National de Valorisation de la Recherche ANVAR
Priority to FR7700070A priority Critical patent/FR2375983A1/en
Publication of FR2375983A1 publication Critical patent/FR2375983A1/en
Application granted granted Critical
Publication of FR2375983B1 publication Critical patent/FR2375983B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/006—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

A composite material comprises styrene polymer layer(s) bonded to metal layer(s) by an adhesive consisting of a block copolymer A-B-A, where block B comprises polydiene units of mol. wt. 10,000-100,000 and blocks A are polyvinyl-aromatic units of mol. wt. 5000-50,000. Block B is modified with a 3-6C ethylenically unsatd. carboxylic acid (anhydride). The block copolymer may be used in combination with any compatible polymer. Used for structural applications involving high stresses. The composite shows higher mechanical strength (40-80 kg/cm2) than similar materials involving conventional adhesives.
FR7700070A 1977-01-04 1977-01-04 Styrene! polymer and metal composite material - using polydiene polyvinyl aromatic block copolymer adhesives, for structural applications Granted FR2375983A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7700070A FR2375983A1 (en) 1977-01-04 1977-01-04 Styrene! polymer and metal composite material - using polydiene polyvinyl aromatic block copolymer adhesives, for structural applications

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7700070A FR2375983A1 (en) 1977-01-04 1977-01-04 Styrene! polymer and metal composite material - using polydiene polyvinyl aromatic block copolymer adhesives, for structural applications

Publications (2)

Publication Number Publication Date
FR2375983A1 true FR2375983A1 (en) 1978-07-28
FR2375983B1 FR2375983B1 (en) 1981-06-19

Family

ID=9185106

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7700070A Granted FR2375983A1 (en) 1977-01-04 1977-01-04 Styrene! polymer and metal composite material - using polydiene polyvinyl aromatic block copolymer adhesives, for structural applications

Country Status (1)

Country Link
FR (1) FR2375983A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0173379A1 (en) * 1984-08-30 1986-03-05 Shell Internationale Researchmaatschappij B.V. Process for bonding polymeric and/or metal materials
EP0389094A3 (en) * 1989-03-09 1992-01-15 Morton International, Inc. Adhesive blend of polyolefins and grafted block copolymer of polystyrene

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4341837A (en) 1978-08-11 1982-07-27 Kureha Kagaku Kogyo Kabushiki Kaisha Laminar thermoplastic resin structure
JPS5587551A (en) 1978-12-27 1980-07-02 Asahi Chemical Ind Original laminated piece

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0173379A1 (en) * 1984-08-30 1986-03-05 Shell Internationale Researchmaatschappij B.V. Process for bonding polymeric and/or metal materials
EP0389094A3 (en) * 1989-03-09 1992-01-15 Morton International, Inc. Adhesive blend of polyolefins and grafted block copolymer of polystyrene

Also Published As

Publication number Publication date
FR2375983B1 (en) 1981-06-19

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Legal Events

Date Code Title Description
ST Notification of lapse