FR2358146A1 - Indolo-(1,5)-naphthyridine derivs. - having antianoxia and psychotropic activities - Google Patents
Indolo-(1,5)-naphthyridine derivs. - having antianoxia and psychotropic activitiesInfo
- Publication number
- FR2358146A1 FR2358146A1 FR7610773A FR7610773A FR2358146A1 FR 2358146 A1 FR2358146 A1 FR 2358146A1 FR 7610773 A FR7610773 A FR 7610773A FR 7610773 A FR7610773 A FR 7610773A FR 2358146 A1 FR2358146 A1 FR 2358146A1
- Authority
- FR
- France
- Prior art keywords
- naphthyridine
- oxo
- indolo
- methyl
- antianoxia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BARGRPPQVLTBDS-UHFFFAOYSA-N 7h-indolo[2,3-c][1,5]naphthyridine Chemical compound C1=CC=NC2=C3C4=CC=CC=C4NC3=CN=C21 BARGRPPQVLTBDS-UHFFFAOYSA-N 0.000 title 1
- 230000000506 psychotropic effect Effects 0.000 title 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 5
- -1 2-hydroxypropyl Chemical group 0.000 abstract 3
- HQMKWWYYKCFZJF-UHFFFAOYSA-N 1,5-naphthyridine-4-carboxylic acid Chemical compound C1=CN=C2C(C(=O)O)=CC=NC2=C1 HQMKWWYYKCFZJF-UHFFFAOYSA-N 0.000 abstract 1
- FLBAYUMRQUHISI-UHFFFAOYSA-N 1,8-naphthyridine Chemical compound N1=CC=CC2=CC=CN=C21 FLBAYUMRQUHISI-UHFFFAOYSA-N 0.000 abstract 1
- 101100440695 Dictyostelium discoideum corB gene Proteins 0.000 abstract 1
- 125000001539 acetonyl group Chemical group [H]C([H])([H])C(=O)C([H])([H])* 0.000 abstract 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 125000006255 cyclopropyl carbonyl group Chemical group [H]C1([H])C([H])([H])C1([H])C(*)=O 0.000 abstract 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 abstract 1
- 125000004186 cyclopropylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C1([H])[H] 0.000 abstract 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 abstract 1
- 125000001475 halogen functional group Chemical group 0.000 abstract 1
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical compound [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Landscapes
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Naphthyridine derivs. of formula (I), as racemates or optical isomers, and their suitable salts with acids are new. In (I) R1=H, 1-4C alkyl, 2-oxopropyl, 2-hydroxypropyl, 3-oxobutyl, 3-hydroxybutyl, cyclopropyl methyl, benzyl (opt. halogenated esp. by F or Cl), acetyl, cyclopropylcarbonyl, benzoyl or (CH2)nR1. R2=H, halo, CH3 or CH3O. R6=H or COR7. R3=CH3 or C2H5, and R4=OH or H and R5=H, or R3+R4=oxo and R5=H, or R3=CH3 or C2H5 and R4+R5=an additional C-C bond. n=1 or 2. R1=(m)ethoxycarbonyl or CN. R7=OH, 1-4C alkoxy, NH2(opt. substd. by 1 or 2 CH3 or by one cyclopropyl). The following cpds. are excluded: R3+R4=oxo; (a) R1=H=R6 and R2=10-CH3O and (b) R1=R2=R6=H; but when R6=alkoxycarbonyl stereoisomers are included. Dose is 10-100 mg/day. In an example methyl 1,2,3,3a,4,5,-hexahydro-3-methyl-6-oxo-6H-indolo 3,2,1-de 1,5 naphthyridine-4-carboxylate was prepd. fron Nb-methyltryptamine and diethyl alpha-formyl succinate.
Priority Applications (37)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7610773A FR2358146A1 (en) | 1976-04-13 | 1976-04-13 | Indolo-(1,5)-naphthyridine derivs. - having antianoxia and psychotropic activities |
| IN409/CAL/77A IN145423B (en) | 1976-04-13 | 1977-03-21 | |
| DD7700198314A DD129791A5 (en) | 1976-04-13 | 1977-04-07 | PROCESS FOR THE PREPARATION OF NAPHTYRIDINE DERIVATIVES |
| BE176581A BE853435A (en) | 1976-04-13 | 1977-04-08 | NAPHTYRIDINE DERIVATIVES |
| ES457692A ES457692A1 (en) | 1976-04-13 | 1977-04-11 | Procedure for preparing naftiridine derivatives. (Machine-translation by Google Translate, not legally binding) |
| IL51853A IL51853A (en) | 1976-04-13 | 1977-04-11 | 1,2,3,3a-tetrahydro(or 1,2,3,3a,4,5-hexahydro)indolo(3,2,1-de)naphthyridine derivatives,their preparation and pharmaceutical compositions containing them |
| JP52041904A JPS5823877B2 (en) | 1976-04-13 | 1977-04-11 | Naphthyridine derivatives and their production method |
| YU00948/77A YU94877A (en) | 1976-04-13 | 1977-04-11 | Process for obtaining naphthiridine derivatives |
| MT811A MTP811B (en) | 1976-04-13 | 1977-04-11 | Indolo (3,2,1-de)(1.5) naphthyzidine derivatives |
| US05/786,557 US4190657A (en) | 1976-03-11 | 1977-04-11 | Naphthyridine derivatives |
| LU77100A LU77100A1 (en) | 1976-04-13 | 1977-04-12 | |
| CA275,948A CA1072960A (en) | 1976-04-13 | 1977-04-12 | Indolo (3,2,1-de) (1,5) naphthyridine derivatives |
| MX775626U MX5340E (en) | 1976-04-13 | 1977-04-12 | PROCEDURE FOR PREPARING HEXAHYDRO DERIVATIVES 1,2,3,3A.4,5-OXO-6-6H-INDOLO (3,2,1-DE) NAFTIRIDINE |
| DK161377A DK143703C (en) | 1976-04-13 | 1977-04-12 | ANALOGY PROCEDURE FOR PREPARING 1,2,3,3A, 4,5-HEXAHYDRO-6-OXO-6H-INDOLO (3,2,1-DE) = (1,5) NAPHTHYRIDINE DERIVATIVES OR ACID ADDITION SALTS THEREOF |
| HUSI001569 HU181958B (en) | 1976-04-13 | 1977-04-12 | Process for producing new 1,2,3,3a-tetrahydro-indolo-bracket-3,2,1-d,e-bracket closed-bracket-1,5-bracket closed-naphtridine derivatives |
| CS239477A CS220313B2 (en) | 1976-04-13 | 1977-04-12 | Method of producing new naphtyridine derivatives |
| AT254277A AT352741B (en) | 1976-04-13 | 1977-04-12 | PROCESS FOR THE PREPARATION OF NEW NAPHTYRIDE DERIVATIVES, THEIR SALT AND OPTICAL ISOMERS |
| AR267179A AR214519A1 (en) | 1976-04-13 | 1977-04-12 | PROCEDURE TO OBTAIN TETRAHYDRO-1,2,3,3A-INDOL- (3,2,1-DE) NAPHTHYRIDINE |
| PT66428A PT66428B (en) | 1976-04-13 | 1977-04-12 | PROCESS FOR THE PREPARATION OF NEW NAPHTHYRIDINE DERIVATIVES |
| ZA00772209A ZA772209B (en) | 1976-04-13 | 1977-04-12 | Naphtyridine derivatives |
| AU24189/77A AU506031B2 (en) | 1976-04-13 | 1977-04-12 | Indolo(3, 2, 1-de) (1, 5) naphthyrudune derivatives |
| DE19772716190 DE2716190A1 (en) | 1976-04-13 | 1977-04-12 | NAPHTYRIDE DERIVATIVES, A PROCESS FOR THEIR MANUFACTURING, AND THESE COMPOUNDS AS MEDICINAL PRODUCTS CONTAINING ACTIVE SUBSTANCES |
| GB15165/77A GB1543283A (en) | 1976-04-13 | 1977-04-12 | Indolo-(3,2,1-de)(1,5)naphthyridine derivatives |
| NO77771263A NO146777C (en) | 1976-04-13 | 1977-04-12 | ANALOGY PROCEDURE FOR THE PREPARATION OF THERAPEUTIC ACTIVE 6H-INDOLO (3,2,1-DE) - (1,5) -NAPHYRIDINE INGREDIATES |
| CH450777A CH622795A5 (en) | 1976-04-13 | 1977-04-12 | |
| SE7704172A SE432932B (en) | 1976-04-13 | 1977-04-12 | ANALOGY PROCEDURE FOR PREPARING DERIVATIVES OF 1,2,3,3A-TETRAHYDRO-INDOLO / 3,2,1-DE / / 1,5 / NAFTYRIDINE |
| CS578381A CS220344B2 (en) | 1976-04-13 | 1977-04-12 | Method of preparing new naphtyridine derivatives |
| IE758/77A IE44989B1 (en) | 1976-04-13 | 1977-04-13 | Indolo(3,2,1-d,e)(1,5)naphthyridine derivatives |
| NZ183846A NZ183846A (en) | 1976-04-13 | 1977-04-13 | 1,2,3,3a,4,5-hexahydro-6h-indolo(3,2,1-de) (1,5)-naphthyridines |
| FI771159A FI63404C (en) | 1976-04-13 | 1977-04-13 | FRONTAL PROTECTION OF ANTANOXIC 1,2,3,3A, 4,5-HEXAHYDRO-6-OXO-6H-INDOLO (3,2,1-DE) (1,5) NAPHTHYRIDINE |
| GR53198A GR63658B (en) | 1976-04-13 | 1977-04-13 | Process for derivatives preparation of naphyridine |
| NL7704004A NL7704004A (en) | 1976-04-13 | 1977-04-13 | Indolo-(1,5)-naphthyridine derivs. - having antianoxia and psychotropic activities |
| SU772470258A SU655314A3 (en) | 1976-04-13 | 1977-04-13 | Method of obtaining naphthyridine derivatives or their stereoisomers or their salts |
| FI803790A FI803790A7 (en) | 1976-04-13 | 1977-04-13 | Method for the preparation of anoxemic 1,2,3,3a,4,5-hexahydro-6-oxo-6H-indolo[3,2,1-de/ /1,5/naphthyridines. |
| PL19737377A PL197373A1 (en) | 1976-04-13 | 1977-04-13 | METHOD OF MAKING NEW DERIVATIVES 1,2,3,3A-TETRAHYDROGENINDOLO / 3,2,1 // 1,5 / NAPHTHRIDINE |
| AT656178A AT355583B (en) | 1976-04-13 | 1978-09-11 | METHOD FOR PRODUCING NEW NAPHTYRIDINE DERIVATIVES IN THE FORM OF ITS RACEMATE OR ITS OPTICAL ISOMERS AND THEIR SALTS |
| SE8201181A SE8201181L (en) | 1976-04-13 | 1982-02-25 | PROCEDURE FOR PREPARING NEW DERIVATIVES OF 1,2,3,3A-TETRA-HYDRO-INDOLO- (3,2,1-DE) (1,5) NAFTYRIDINE |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7610773A FR2358146A1 (en) | 1976-04-13 | 1976-04-13 | Indolo-(1,5)-naphthyridine derivs. - having antianoxia and psychotropic activities |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2358146A1 true FR2358146A1 (en) | 1978-02-10 |
| FR2358146B1 FR2358146B1 (en) | 1978-12-08 |
Family
ID=9171744
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7610773A Granted FR2358146A1 (en) | 1976-03-11 | 1976-04-13 | Indolo-(1,5)-naphthyridine derivs. - having antianoxia and psychotropic activities |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE853435A (en) |
| FR (1) | FR2358146A1 (en) |
| IN (1) | IN145423B (en) |
| ZA (1) | ZA772209B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2475394A1 (en) * | 1980-02-12 | 1981-08-14 | Synthelabo | PHARMACEUTICAL COMPOSITIONS CONTAINING HEXAHYDRO-1, 2, 3, 3A, 4, 5, 6H INDOLO (3, 2, 1 - D. E) (1, 5) NAPHTHYRIDINONE - 6 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5337696A (en) * | 1976-08-26 | 1978-04-06 | Omnium Chimique Sa | Hexahydrocantinonee6 derivative |
-
1976
- 1976-04-13 FR FR7610773A patent/FR2358146A1/en active Granted
-
1977
- 1977-03-21 IN IN409/CAL/77A patent/IN145423B/en unknown
- 1977-04-08 BE BE176581A patent/BE853435A/en not_active IP Right Cessation
- 1977-04-12 ZA ZA00772209A patent/ZA772209B/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2475394A1 (en) * | 1980-02-12 | 1981-08-14 | Synthelabo | PHARMACEUTICAL COMPOSITIONS CONTAINING HEXAHYDRO-1, 2, 3, 3A, 4, 5, 6H INDOLO (3, 2, 1 - D. E) (1, 5) NAPHTHYRIDINONE - 6 |
Also Published As
| Publication number | Publication date |
|---|---|
| BE853435A (en) | 1977-10-10 |
| FR2358146B1 (en) | 1978-12-08 |
| ZA772209B (en) | 1978-03-29 |
| IN145423B (en) | 1978-10-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |