FR2160269A1 - Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal - Google Patents
Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catalInfo
- Publication number
- FR2160269A1 FR2160269A1 FR7141069A FR7141069A FR2160269A1 FR 2160269 A1 FR2160269 A1 FR 2160269A1 FR 7141069 A FR7141069 A FR 7141069A FR 7141069 A FR7141069 A FR 7141069A FR 2160269 A1 FR2160269 A1 FR 2160269A1
- Authority
- FR
- France
- Prior art keywords
- contg
- regeneration
- pref
- gas
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003197 catalytic effect Effects 0.000 title abstract 3
- 230000008929 regeneration Effects 0.000 title abstract 3
- 238000011069 regeneration method Methods 0.000 title abstract 3
- 229930195733 hydrocarbon Natural products 0.000 title abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000007789 gas Substances 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 150000001350 alkyl halides Chemical class 0.000 abstract 1
- 238000001833 catalytic reforming Methods 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000000197 pyrolysis Methods 0.000 abstract 1
- 238000002407 reforming Methods 0.000 abstract 1
- 238000004230 steam cracking Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/10—Catalytic reforming with moving catalysts
- C10G35/12—Catalytic reforming with moving catalysts according to the "moving-bed" method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/12—Treating with free oxygen-containing gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/42—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using halogen-containing material
- B01J38/44—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using halogen-containing material and adding simultaneously or subsequently free oxygen; using oxyhalogen compound
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
- B01J8/12—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
- B01J8/12—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow
- B01J8/125—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow with multiple sections one above the other separated by distribution aids, e.g. reaction and regeneration sections
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The catalyst, consisting of 1 metal of gp. VIa, VIIa or VIII on a carrier, circulates through a reactor contg. >=2 catalytic zones arranged vertically above each other and is progressively drawn off from the last zone, regenerated and recycled to the other end so that the activity remains substantially constant at any point. Pref. the regenerated catalyst goes to the top of a second similar reactor in which the treatment of the hydrocarbon charge from the first is continued, is drawn off from the bottom and lifted to the top of the first reactor, through which it then circulates. Volume of the catalytic zones pref. increases in the direction in which the charge moves. Regeneration is pref. by combustion in O2 contg. gas, oxychlorination with gas contg. O2 and halogen, hydrogen halide or alkyl halide, treatment with O2-contg. gas and finally reduction in H2. The process is esp. suitable for reforming and and prodn. of aromatics from petrols obtained by pyrolysis, cracking, steam-cracking, catalytic reforming or from naphthenes. It permits continuous operation without interruption for catalyst regeneration.
Priority Applications (27)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7141069A FR2160269A1 (en) | 1971-11-16 | 1971-11-16 | Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal |
| FR7204055A FR2170899A2 (en) | 1971-11-16 | 1972-02-07 | Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal |
| FR7208731A FR2175549A2 (en) | 1971-11-16 | 1972-03-13 | Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal |
| BE790431D BE790431A (en) | 1971-11-16 | 1972-10-23 | METHOD AND APPARATUS FOR HYDROCARBON CONVERSION PROCESSES |
| ZA727952A ZA727952B (en) | 1971-11-16 | 1972-11-10 | Process and apparatus for hydrocarbon conversion |
| DE2255497A DE2255497A1 (en) | 1971-11-16 | 1972-11-13 | METHOD AND DEVICE FOR THE CONTINUOUS CONVERSION OF HYDROCARBONS |
| DE2265608A DE2265608C2 (en) | 1971-11-16 | 1972-11-13 | |
| GB5238572A GB1364616A (en) | 1971-11-16 | 1972-11-13 | Process for hydrocarbon conversion |
| GB2190473A GB1364617A (en) | 1971-11-16 | 1972-11-13 | Apparatus for hydrocarbon conversion |
| AR245130A AR229665A1 (en) | 1971-11-16 | 1972-11-14 | PROCEDURE FOR THE CONTINUOUS CONVERSION OF HYDROCARBONS IN THE PRESENCE OF A GRANULATED CATALYST CONTAINING A SUPPORT AND AT LEAST ONE METAL SELECTED BETWEEN THE GROUP MADE UP OF METALS FROM THE VIA, VIIA AND VIII GROUPS OF THE PERIODIC SYSTEM OF THE ELEMENTS AND APPARATUS FOR LA PUTAAC OF SUCH PROCEDURE |
| SE7214827A SE394687B (en) | 1971-11-16 | 1972-11-15 | PROCEDURE AND DEVICE FOR CONTINUOUS CONVERSION OF THE CARBON IN THE PRESENCE OF A GRAIN CATALYST, WHERE THE WHEAT AND THE CARBON ARE GUIDED THROUGH AT LEAST TWO CATALYTIC ELEMENT ZONES, WHICH ARE ESSENTIAL ... |
| AT969272A AT334492B (en) | 1971-11-16 | 1972-11-15 | METHOD AND DEVICE FOR THE CONTINUOUS CONVERSION OF HYDROCARBONS |
| NO4148/72A NO137555C (en) | 1971-11-16 | 1972-11-15 | PROCEDURE AND APPARATUS FOR CONTINUOUS CONVERSION OF HYDROCARBONS |
| ES408625A ES408625A1 (en) | 1971-11-16 | 1972-11-15 | Moving bed catalytic process for hydrocarbon conversion |
| CA156,758A CA980281A (en) | 1971-11-16 | 1972-11-15 | Procede et appareillage pour procedes de conversions d'hydrocarbures |
| EG468/72A EG10731A (en) | 1971-11-16 | 1972-11-15 | Process and apparatus for hydrocarbons conversion |
| IT31715/72A IT974673B (en) | 1971-11-16 | 1972-11-16 | PROCESS AND EQUIPMENT FOR HYDROCARBON CONVERSION PROCESSES |
| NLAANVRAGE7215493,A NL173764C (en) | 1971-11-16 | 1972-11-16 | PROCESS FOR THE CONTINUOUS CONVERSION OF HYDROCARBONS. |
| JP47115483A JPS5248601B2 (en) | 1971-11-16 | 1972-11-16 | |
| NO751262A NO139608C (en) | 1971-11-16 | 1975-04-10 | PROCEDURE FOR CATALYTIC CONVERSION OF HYDROCARBONS USING A DIVIDED STREAM OF CATALYST TRANSPORT RECYCLING HYDROGEN |
| SE7506318A SE408804B (en) | 1971-11-16 | 1975-06-03 | PROCEDURE FOR CONTINUOUS CONVERSION OF THE PISTON IN THE PRESENCE OF A GRAIN CATALYST, WHERE THE WHEAT AND THE PISTON ARE GUIDED THROUGH AT TWO CATALYTIC ELEMENTARY ZONES, WHICH ARE SIGNIFICANTLY VERTICAL .. |
| JP12926776A JPS52107005A (en) | 1971-11-16 | 1976-10-26 | Apparatus for continuously converting hydrocarbon |
| JP12926876A JPS52107006A (en) | 1971-11-16 | 1976-10-26 | Method of transporting granular catalyst in continuous convertion method of hydrocarbon |
| JP12926676A JPS52107004A (en) | 1971-11-16 | 1976-10-26 | Method of continuously converting hydrocarbon |
| US05/741,744 US4133743A (en) | 1971-11-16 | 1976-11-15 | Moving bed catalytic process for hydrocarbon conversion |
| US05/966,994 US4233268A (en) | 1971-11-16 | 1978-12-06 | Apparatus for hydrocarbon conversion |
| US05/966,995 US4210519A (en) | 1971-11-16 | 1978-12-06 | Process and apparatus for hydrocarbon conversion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7141069A FR2160269A1 (en) | 1971-11-16 | 1971-11-16 | Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2160269A1 true FR2160269A1 (en) | 1973-06-29 |
| FR2160269B1 FR2160269B1 (en) | 1974-05-10 |
Family
ID=9085879
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7141069A Granted FR2160269A1 (en) | 1971-11-16 | 1971-11-16 | Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal |
Country Status (3)
| Country | Link |
|---|---|
| JP (3) | JPS52107005A (en) |
| FR (1) | FR2160269A1 (en) |
| ZA (1) | ZA727952B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2801841A1 (en) * | 1977-01-20 | 1978-07-27 | Inst Francais Du Petrol | Continuous catalytic conversion of hydrocarbon feed - with redn. and sulphiding of regenerated catalyst in zones sepd. from reactor (NL 24.7.78) |
| WO2003000399A3 (en) * | 2001-06-22 | 2003-10-09 | Uop Llc | Reaction and regeneration system |
| US7803326B2 (en) | 2007-08-01 | 2010-09-28 | Uop Llc | Hydrocarbon conversion unit including a reaction zone receiving transferred catalyst |
| EP2995380A1 (en) | 2014-09-10 | 2016-03-16 | IFP Energies nouvelles | Catalyst regenerator |
| EP2995379A1 (en) | 2014-09-10 | 2016-03-16 | IFP Energies nouvelles | Regenerator capable of regenerating catalysts under various operating conditions |
| WO2024040092A1 (en) * | 2022-08-18 | 2024-02-22 | Chevron Phillips Chemical Company Lp | Use of a continuous catalyst regeneration type reformer for the aromax® catalyst process |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2946660B1 (en) * | 2009-06-10 | 2011-07-22 | Inst Francais Du Petrole | METHOD FOR PREGENERATIVE REFORMING OF SPECIES COMPRISING THE RECYCLING OF AT LEAST ONE PART OF THE EFFLUENT OF THE CATALYST REDUCTION PHASE. |
| US10046310B2 (en) | 2015-10-05 | 2018-08-14 | GM Global Technology Operations LLC | Catalytic converters with age-suppressing catalysts |
| US10159960B2 (en) | 2016-10-25 | 2018-12-25 | GM Global Technology Operations LLC | Catalysts with atomically dispersed platinum group metal complexes |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2689821A (en) * | 1950-10-17 | 1954-09-21 | Union Oil Co | Hydrocarbon conversion process |
| US2695815A (en) * | 1951-02-16 | 1954-11-30 | Socony Vacuum Oil Co Inc | Method of and apparatus for pneumatic transfer of granular contact material in moving bed hydrocarbon conversion processes |
| US2756193A (en) * | 1951-02-16 | 1956-07-24 | Socony Mobil Oil Co Inc | Hydrocarbon conversion process and apparatus therefor |
| US2716050A (en) * | 1951-04-19 | 1955-08-23 | Socony Mobil Oil Co Inc | Method of stopping the pneumatic transfer of granular material in a moving bed hydrocarbon conversion system |
| US2914466A (en) * | 1955-01-20 | 1959-11-24 | Union Oil Co | Multiple zone fluid-solids contact system employing a dense phase pneumatic solids conveyance technique |
| US2958650A (en) * | 1955-07-28 | 1960-11-01 | Houdry Process Corp | Removing contaminants from catalyst particles |
| US3470090A (en) * | 1967-09-25 | 1969-09-30 | Universal Oil Prod Co | Method for operating a non-regenerative fixed bed reforming process |
| US3647680A (en) * | 1969-09-25 | 1972-03-07 | Universal Oil Prod Co | Continuous reforming-regeneration process |
-
1971
- 1971-11-16 FR FR7141069A patent/FR2160269A1/en active Granted
-
1972
- 1972-11-10 ZA ZA727952A patent/ZA727952B/en unknown
-
1976
- 1976-10-26 JP JP12926776A patent/JPS52107005A/en active Granted
- 1976-10-26 JP JP12926876A patent/JPS52107006A/en active Granted
- 1976-10-26 JP JP12926676A patent/JPS52107004A/en active Granted
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2801841A1 (en) * | 1977-01-20 | 1978-07-27 | Inst Francais Du Petrol | Continuous catalytic conversion of hydrocarbon feed - with redn. and sulphiding of regenerated catalyst in zones sepd. from reactor (NL 24.7.78) |
| WO2003000399A3 (en) * | 2001-06-22 | 2003-10-09 | Uop Llc | Reaction and regeneration system |
| US6884400B1 (en) | 2001-06-22 | 2005-04-26 | Uop Llc | Reaction and regeneration system |
| US7803326B2 (en) | 2007-08-01 | 2010-09-28 | Uop Llc | Hydrocarbon conversion unit including a reaction zone receiving transferred catalyst |
| EP2995380A1 (en) | 2014-09-10 | 2016-03-16 | IFP Energies nouvelles | Catalyst regenerator |
| EP2995379A1 (en) | 2014-09-10 | 2016-03-16 | IFP Energies nouvelles | Regenerator capable of regenerating catalysts under various operating conditions |
| WO2024040092A1 (en) * | 2022-08-18 | 2024-02-22 | Chevron Phillips Chemical Company Lp | Use of a continuous catalyst regeneration type reformer for the aromax® catalyst process |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS52107006A (en) | 1977-09-08 |
| JPS5640194B2 (en) | 1981-09-18 |
| JPS52107005A (en) | 1977-09-08 |
| FR2160269B1 (en) | 1974-05-10 |
| JPS5640195B2 (en) | 1981-09-18 |
| JPS5747952B2 (en) | 1982-10-13 |
| ZA727952B (en) | 1973-07-25 |
| JPS52107004A (en) | 1977-09-08 |
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