ES8701703A1 - Procedimiento para la produccion de butano-1,4-diol - Google Patents
Procedimiento para la produccion de butano-1,4-diolInfo
- Publication number
- ES8701703A1 ES8701703A1 ES549746A ES549746A ES8701703A1 ES 8701703 A1 ES8701703 A1 ES 8701703A1 ES 549746 A ES549746 A ES 549746A ES 549746 A ES549746 A ES 549746A ES 8701703 A1 ES8701703 A1 ES 8701703A1
- Authority
- ES
- Spain
- Prior art keywords
- ester
- butane
- hydrogenolysis
- diol
- zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 title abstract 6
- -1 diethyl maleate Chemical compound 0.000 abstract 3
- 238000007327 hydrogenolysis reaction Methods 0.000 abstract 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910017518 Cu Zn Inorganic materials 0.000 abstract 1
- 229910017752 Cu-Zn Inorganic materials 0.000 abstract 1
- 229910017813 Cu—Cr Inorganic materials 0.000 abstract 1
- 229910017943 Cu—Zn Inorganic materials 0.000 abstract 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 abstract 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 125000005907 alkyl ester group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- 238000011144 upstream manufacturing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
- C07C29/177—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of a carboxy group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/06—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
- C07D307/08—Preparation of tetrahydrofuran
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PROCEDIMIENTO PARA LA OBTENCION DE BUTANO-1,4-DIOL. COMPRENDE LA REACCION DE HIDROGENOLISIS DE UN DIALQUILESTER DE UN ACIDO C4-DICARBOXILICO, EN FORMA DE VAPOR, CON EXCESO DE HIDROGENO, EN PRESENCIA DE UN CATALIZADOR CONSTITUIDO FUNDAMENTALMENTE POR 25 A 45% DE COBRE Y 20 A 35% DE CROMO, A UNA TEMPERATURA COMPRENDIDA ENTRE 170JC Y 190JC, EN CONDICIONES ADIABATICAS; ALIMENTACION DE LA MEZCLA RESULTANTE ENFRIADA A UNA SEGUNDA ZONA DE HIDROLISIS, EN LA QUE SE DEJA REACCIONAR A UNA TEMPERATURA COMPRENDIDA ENTRE 150JC Y 190JC, EN CONDICIONES ADIABATICAS HASTA QUE SE ALCANCE EL EQUILIBRIO; Y RECUPERACION DE LA MEZCLA REACCIONAL RESULTANTE. EL BUTANO-1,4-DIOL, TIENE APLICACIONES PARA LA FABRICACION DE POLIMEROS COMO POLIBUTILENO TEREFTALATO, DE BUTIROLACTONA Y DE TETRAHIDROFURANO.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/673,797 US4584419A (en) | 1983-11-29 | 1984-11-21 | Process for the production of butane-1,4-diol |
| GB858514002A GB8514002D0 (en) | 1985-06-04 | 1985-06-04 | Process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES549746A0 ES549746A0 (es) | 1986-12-01 |
| ES8701703A1 true ES8701703A1 (es) | 1986-12-01 |
Family
ID=26289326
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES549746A Expired ES8701703A1 (es) | 1984-11-21 | 1985-11-21 | Procedimiento para la produccion de butano-1,4-diol |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0204730A1 (es) |
| JP (1) | JPH0655684B2 (es) |
| BR (1) | BR8507068A (es) |
| CA (1) | CA1249837A (es) |
| ES (1) | ES8701703A1 (es) |
| WO (1) | WO1986003189A1 (es) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3503485A1 (de) * | 1985-02-01 | 1986-08-07 | Lentia GmbH Chem. u. pharm. Erzeugnisse - Industriebedarf, 8000 München | Verfahren zur herstellung reiner dialkylsuccinate |
| GB8618892D0 (en) * | 1986-08-01 | 1986-09-10 | Davy Mckee Ltd | Process |
| EP0277168A1 (en) * | 1986-08-01 | 1988-08-10 | DAVY McKEE (LONDON) LIMITED | PROCESS FOR THE CO-PRODUCTION OF BUTANE-1,4-DIOL AND $i(GAMMA)-BUTYROLACTONE |
| GB8717989D0 (en) * | 1987-07-29 | 1987-09-03 | Davy Mckee Ltd | Catalyst |
| GB8717993D0 (en) * | 1987-07-29 | 1987-09-03 | Davy Mckee Ltd | Process |
| US4810807A (en) * | 1987-10-13 | 1989-03-07 | The Standard Oil Company | Hydrogenation of maleic anhydride to tetrahydrofuran |
| JPH02233674A (ja) * | 1989-03-07 | 1990-09-17 | Mitsubishi Kasei Corp | ラクトン類の製造法 |
| GB8917862D0 (en) * | 1989-08-04 | 1989-09-20 | Davy Mckee London | Process |
| GB8917864D0 (en) * | 1989-08-04 | 1989-09-20 | Davy Mckee London | Process |
| GB8917859D0 (en) * | 1989-08-04 | 1989-09-20 | Davy Mckee London | Process |
| DE4005293A1 (de) * | 1990-02-20 | 1991-08-22 | Basf Ag | Verfahren zur herstellung von tetrahydrofuran und -butyrolacton |
| DE4231782A1 (de) * | 1992-09-23 | 1994-03-24 | Basf Ag | Verfahren zur Herstellung von 2-Methyl-1,4-butandiol und 3-Methyltetrahydrofuran |
| US5536854A (en) * | 1993-09-21 | 1996-07-16 | Basf Aktiengesellschaft | Preparation of 2-methyl-1,4-butanediol and 3-methyltetrahydrofuran |
| GB9324782D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324785D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324752D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324823D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324784D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324786D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324783D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| GB9324753D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
| IT1273320B (it) * | 1994-02-22 | 1997-07-08 | Alusuisse Italia Spa | Procedimento per la produzione di gamma-butirrolattone |
| DE4431220A1 (de) | 1994-09-02 | 1996-03-07 | Bayer Ag | Verfahren zur Herstellung von Butandiol-1,4 aus Maleinsäureanhydrid |
| ZA973972B (en) * | 1996-05-14 | 1998-03-23 | Kvaerner Process Tech Ltd | A process for the production of at least one C4 compound selected from butane-1,4-diol, gamma-butyrolactone and tetrahydrofuran. |
| ZA973971B (en) * | 1996-05-15 | 1998-03-23 | Kvaerner Process Tech Ltd | A process for the production of at least one C4 compound selected from butane-1,4-diol, gamma-butyrolactone and tetrahydrofuran. |
| GB9724004D0 (en) | 1997-11-13 | 1998-10-21 | Kvaerner Process Tech Ltd | Process |
| GB9724195D0 (en) | 1997-11-14 | 1998-01-14 | Kvaerner Process Tech Ltd | Process |
| BE1011698A6 (fr) * | 1998-01-08 | 1999-12-07 | Pantochim Sa | Procede de production de tetrahydrofuranne, de gamma-butyrolactone et de butanediol. |
| IT1298096B1 (it) | 1998-01-09 | 1999-12-20 | Lonza Spa | Procedimento per la produzione di gamma-butirrolattone |
| IT1298535B1 (it) | 1998-02-02 | 2000-01-12 | Lonza Spa | Procedimento per la produzione di gamma-butirrolattone |
| ES2158645T3 (es) | 1998-03-23 | 2001-09-01 | Basf Ag | Procedimiento para la preparacion de 1,4-butanodiol, butirolactona y tetrahidrofurano. |
| DE19842847A1 (de) * | 1998-09-18 | 2000-03-23 | Basf Ag | Verfahren zur Herstellung von Tetrahydrofuran |
| EP1108702A1 (en) * | 1999-12-13 | 2001-06-20 | Kvaerner Process Technology Limited | Process for the co-production of aliphatic diols and cyclic ethers |
| GB0117090D0 (en) | 2001-07-12 | 2001-09-05 | Kvaerner Process Tech Ltd | Process |
| GB0329152D0 (en) | 2003-12-16 | 2004-01-21 | Davy Process Techn Ltd | Process |
| GB0803663D0 (en) | 2008-02-28 | 2008-04-09 | Davy Process Techn Ltd | Process |
| GB201318175D0 (en) | 2013-10-14 | 2013-11-27 | Johnson Matthey Davy Technologies Ltd | Process |
| GB201321611D0 (en) | 2013-12-06 | 2014-01-22 | Johnson Matthey Davy Technologies Ltd | Process |
| GB201321627D0 (en) | 2013-12-06 | 2014-01-22 | Johnson Matthey Davy Technologies Ltd | Process |
| GB201507234D0 (en) | 2015-04-28 | 2015-06-10 | Johnson Matthey Davy Technologies Ltd | Process |
| EP4073052A1 (de) * | 2019-12-10 | 2022-10-19 | Basf Se | Verfahren zur herstellung von 1,4-butandiol, gamma-butyrolacton und tetrahydrofuran in der gasphase unter vermeidung von polymeren ablagerungen |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4032458A (en) * | 1975-08-08 | 1977-06-28 | Petro-Tex Chemical Corporation | Production of 1,4-butanediol |
| GB8331793D0 (en) * | 1983-11-29 | 1984-01-04 | Davy Mckee Ltd | Process |
-
1985
- 1985-11-18 EP EP19850905648 patent/EP0204730A1/en not_active Withdrawn
- 1985-11-18 WO PCT/GB1985/000524 patent/WO1986003189A1/en not_active Ceased
- 1985-11-18 JP JP61500083A patent/JPH0655684B2/ja not_active Expired - Lifetime
- 1985-11-18 BR BR8507068A patent/BR8507068A/pt unknown
- 1985-11-21 ES ES549746A patent/ES8701703A1/es not_active Expired
- 1985-11-21 CA CA000495906A patent/CA1249837A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0655684B2 (ja) | 1994-07-27 |
| WO1986003189A1 (en) | 1986-06-05 |
| JPS62501702A (ja) | 1987-07-09 |
| ES549746A0 (es) | 1986-12-01 |
| BR8507068A (pt) | 1987-07-14 |
| EP0204730A1 (en) | 1986-12-17 |
| CA1249837A (en) | 1989-02-07 |
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