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ES8603365A1 - Un procedimiento para preparar hidrocarburos de 5 o mas ato-mos de carbono a partir de hidrocarburos de 4 o menos atomosde carbono - Google Patents

Un procedimiento para preparar hidrocarburos de 5 o mas ato-mos de carbono a partir de hidrocarburos de 4 o menos atomosde carbono

Info

Publication number
ES8603365A1
ES8603365A1 ES542490A ES542490A ES8603365A1 ES 8603365 A1 ES8603365 A1 ES 8603365A1 ES 542490 A ES542490 A ES 542490A ES 542490 A ES542490 A ES 542490A ES 8603365 A1 ES8603365 A1 ES 8603365A1
Authority
ES
Spain
Prior art keywords
hydrocarbons
carbon
carbon dioxide
mixt
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES542490A
Other languages
English (en)
Other versions
ES542490A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Publication of ES542490A0 publication Critical patent/ES542490A0/es
Publication of ES8603365A1 publication Critical patent/ES8603365A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0455—Reaction conditions
    • C07C1/046—Numerical values of parameters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0485—Set-up of reactors or accessories; Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S208/00—Mineral oils: processes and products
    • Y10S208/95—Processing of "fischer-tropsch" crude

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

PROCEDIMIENTO PARA PREPARAR HIDRCARBUROS DE 5 O MAS ATOMOS DE CARBONO A PARTIR DE HIDROCARBUROS DE 4 O MENOS ATOMOS DE CARBONO. CONSISTE EN CONVERTIR HIDROCARBUROS DE C 1 A 4, PROCEDENTES DE GAS NATURAL, EN HIDROCARBUROS DE C 5 O MAS, HACIENDO REACCIONAR, A UNA PRESION DE 10 A 100 BARES, A UNA TEMPERATURA DE 125 A 300JC, Y EN PRESENCIA DE UN CATALIZADOR, HIDROCARBUROS DE C 1 A 4, DIOXIDO DE CARBONO, VAPOR DE AGUA, MONOXIDO DE CARBONO, E HIDROGENO MOLECULAR EN LAS RELACIONES SIGUIENTES: A) RELACION MOLAR DE H2/CO, 0,25-2,25; B) CO2/C 1 A 4, MAYOR DE 0,1 Y MENOR A 10 MOL-G.CO2/AT-G-C; C) VAPOR DE AGUA/C 1 A 4, MAYOR DE 0,1 Y MENOR A 1 MOL-G.H2O/AT-G-C; Y D) CO2/VAPOR DE AGUA, TAL QUE 2(A) B 3(B) I 3. SIENDO EL CATALIZADOR FORMADO POR UN MINERAL CON 3-60 PARTES DE COBALTO, 0,1-100 PARTES DE CIRCONIO, TITANIO, O CROMO, Y 100 PARTES DE SOPORTE (ALUMINA, SILICE O SILICE-ALUMINA).
ES542490A 1984-04-25 1985-04-23 Un procedimiento para preparar hidrocarburos de 5 o mas ato-mos de carbono a partir de hidrocarburos de 4 o menos atomosde carbono Expired ES8603365A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL8401332 1984-04-25

Publications (2)

Publication Number Publication Date
ES542490A0 ES542490A0 (es) 1985-12-16
ES8603365A1 true ES8603365A1 (es) 1985-12-16

Family

ID=19843857

Family Applications (1)

Application Number Title Priority Date Filing Date
ES542490A Expired ES8603365A1 (es) 1984-04-25 1985-04-23 Un procedimiento para preparar hidrocarburos de 5 o mas ato-mos de carbono a partir de hidrocarburos de 4 o menos atomosde carbono

Country Status (11)

Country Link
US (1) US4640766A (es)
EP (1) EP0159759B1 (es)
JP (1) JPS60235889A (es)
AU (1) AU570107B2 (es)
BR (1) BR8501923A (es)
CA (1) CA1241667A (es)
DE (1) DE3569232D1 (es)
ES (1) ES8603365A1 (es)
GB (1) GB2157707B (es)
NZ (1) NZ211875A (es)
ZA (1) ZA853006B (es)

Families Citing this family (22)

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Publication number Priority date Publication date Assignee Title
US5324335A (en) * 1986-05-08 1994-06-28 Rentech, Inc. Process for the production of hydrocarbons
US4874732A (en) * 1987-07-13 1989-10-17 Uop Cobalt Fischer-Tropsch catalysts having improved selectivity
US4833170A (en) * 1988-02-05 1989-05-23 Gtg, Inc. Process and apparatus for the production of heavier hydrocarbons from gaseous light hydrocarbons
US5053581A (en) * 1988-06-27 1991-10-01 Exxon Research & Engineering Company Process for recycling and purifying condensate from a hydrocarbon or alcohol synthesis process
US5109027A (en) * 1989-06-13 1992-04-28 Amoco Corporation Catalytic process for producing olefins or higher alcohols from synthesis gas
AU638741B2 (en) * 1989-09-11 1993-07-08 Broken Hill Proprietary Company Limited, The Catalyst for conversion of synthesis gas into hydrocarbons
NZ242569A (en) † 1991-05-30 1994-07-26 British Petroleum Co Plc Process for the conversion of natural gas into higher hydrocarbons by reforming combined with a fischer-tropsch process
ZA945891B (en) * 1993-09-07 1995-06-13 Boc Group Inc Production of hydrogen and carbon monoxide from oxyfuel furnace off-gas
US5741440A (en) * 1994-02-28 1998-04-21 Eastman Chemical Company Production of hydrogen and carbon monoxide
DK0840561T3 (da) * 1995-06-12 2002-09-09 Moll Ind Inc Børste til forbedret fastholdelse af børstehårsbundter og forankringstråd dertil
BR9709857A (pt) * 1996-06-21 2002-05-21 Syntroleum Corp processo e sistema de produção de gás de sìntese
MY118075A (en) 1996-07-09 2004-08-30 Syntroleum Corp Process for converting gas to liquids
US5950732A (en) * 1997-04-02 1999-09-14 Syntroleum Corporation System and method for hydrate recovery
US6011073A (en) * 1997-10-10 2000-01-04 Syntroleum Corporation System and method for converting light hydrocarbons to heavier hydrocarbons with separation of water into oxygen and hydrogen
US6794417B2 (en) 2002-06-19 2004-09-21 Syntroleum Corporation System and method for treatment of water and disposal of contaminants produced by converting lighter hydrocarbons into heavier hydrocarbon
ATE546508T1 (de) * 2005-03-16 2012-03-15 Fuelcor Llc Systeme und verfahren zur herstellung synthetischer kohlenwasserstoffverbindungen
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
US7906559B2 (en) * 2007-06-21 2011-03-15 University Of Southern California Conversion of carbon dioxide to methanol and/or dimethyl ether using bi-reforming of methane or natural gas
AU2010245167A1 (en) 2009-04-28 2011-10-13 University Of Southern California Efficient and environmentally friendly processing of heavy oils to methanol and derived products
US8697759B1 (en) 2012-10-09 2014-04-15 University Of Southern California Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming
US9180436B1 (en) 2013-11-19 2015-11-10 Emerging Fuels Technology, Inc. Optimized fischer-tropsch catalyst
US9358526B2 (en) 2013-11-19 2016-06-07 Emerging Fuels Technology, Inc. Optimized fischer-tropsch catalyst

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3904744A (en) * 1973-10-01 1975-09-09 Exxon Research Engineering Co Process for the production of hydrogen-containing gases
US4098339A (en) * 1976-06-21 1978-07-04 Mobil Oil Corporation Utilization of low BTU natural gas
US4279830A (en) * 1977-08-22 1981-07-21 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors
NL8003313A (nl) * 1980-06-06 1982-01-04 Shell Int Research Werkwijze voor de bereiding van middeldestillaten.
ZA827420B (en) * 1981-10-17 1984-05-30 British Petroleum Co Plc Process for the production of oxygenated hydrocarbons by the catalytic conversion of synthesis gas
DE3375913D1 (en) * 1982-11-22 1988-04-14 Shell Int Research Process for the preparation of hydrocarbons
DE3365337D1 (en) * 1982-11-22 1986-09-18 Shell Int Research Process for the preparation of a fischer-tropsch catalyst, a catalyst so prepared and use of this catalyst in the preparation of hydrocarbons
US4471145A (en) * 1982-12-01 1984-09-11 Mobil Oil Corporation Process for syngas conversions to liquid hydrocarbon products utilizing zeolite Beta
US4500417A (en) * 1982-12-28 1985-02-19 Mobil Oil Corporation Conversion of Fischer-Tropsch products
US4522939A (en) * 1983-05-31 1985-06-11 Shell Oil Company Preparation of catalyst for producing middle distillates from syngas
IN161735B (es) * 1983-09-12 1988-01-30 Shell Int Research
CA1234158A (en) * 1983-11-15 1988-03-15 Johannes K. Minderhoud Process for the preparation of hydrocarbons
CA1240708A (en) * 1983-11-15 1988-08-16 Johannes K. Minderhoud Process for the preparation of hydrocarbons

Also Published As

Publication number Publication date
BR8501923A (pt) 1985-12-24
ES542490A0 (es) 1985-12-16
AU4161785A (en) 1985-10-31
ZA853006B (en) 1985-11-27
US4640766A (en) 1987-02-03
GB8510286D0 (en) 1985-05-30
JPS60235889A (ja) 1985-11-22
CA1241667A (en) 1988-09-06
GB2157707B (en) 1987-12-16
NZ211875A (en) 1987-07-31
EP0159759A3 (en) 1986-02-19
AU570107B2 (en) 1988-03-03
GB2157707A (en) 1985-10-30
DE3569232D1 (en) 1989-05-11
EP0159759B1 (en) 1989-04-05
EP0159759A2 (en) 1985-10-30

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