ES8506683A1 - Procedimiento de epoxidacion de cloruro del alilo o de propileno - Google Patents
Procedimiento de epoxidacion de cloruro del alilo o de propilenoInfo
- Publication number
- ES8506683A1 ES8506683A1 ES528162A ES528162A ES8506683A1 ES 8506683 A1 ES8506683 A1 ES 8506683A1 ES 528162 A ES528162 A ES 528162A ES 528162 A ES528162 A ES 528162A ES 8506683 A1 ES8506683 A1 ES 8506683A1
- Authority
- ES
- Spain
- Prior art keywords
- epoxidation
- chloride
- alylo
- propylene
- epichlorohydrine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006735 epoxidation reaction Methods 0.000 title abstract 4
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 title 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 title 1
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract 3
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- BVQVLAIMHVDZEL-UHFFFAOYSA-N 1-phenyl-1,2-propanedione Chemical compound CC(=O)C(=O)C1=CC=CC=C1 BVQVLAIMHVDZEL-UHFFFAOYSA-N 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PROCEDIMIENTO DE EPOXIDACION DE CLORURO DEL ALILO O DE PROPILENO, PARA LA OBTENCION DE EPICLORHIDRINA O DE OXIDO DE PROPILENO.CONSISTE EN IRRADIAR CON UNA LAMPARA DE MERCURIO DE MEDIA PRESION DE 450 WATIOS, UNA SOLUCION SATURADA CON OXIGENO DE CLORURO DE ALILO O DE PROPILENO EN UN DISOLVENTE APROTICO. DICHA IRRADIACION SE REALIZA EN PRESENCIA DE UN SENSIBILIZADOR BAB-DICETONICO EN CANTIDAD SUFICIENTE PARA LA EPOXIDACION DE CLORURO DE ALILO A EPICLOHIDRINA O DE PROPILENO A OXIDO DE PROPILENO. COMO SENSIBILIZADOR BAB-DICETONICO SE EMPLEA BIACETILO, BENCILO O 1-FENIL-1,2-PROPANDIONA Y COMO DISOLVENTE APROTICO PARA LA EPOXIDACION DEL CLORURO DE ALILO A EPICLORHIDRINA, SE EMPLEA BENZOL O CLORURO DE METILENO.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45081482A | 1982-12-20 | 1982-12-20 | |
| US06/502,384 US4481092A (en) | 1982-12-20 | 1983-06-08 | Photo-initiated epoxidation of allyl chloride |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES8506683A1 true ES8506683A1 (es) | 1985-08-01 |
| ES528162A0 ES528162A0 (es) | 1985-08-01 |
Family
ID=27036140
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES528162A Granted ES528162A0 (es) | 1982-12-20 | 1983-12-19 | Procedimiento de epoxidacion de cloruro del alilo o de propileno |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4481092A (es) |
| EP (1) | EP0112294B1 (es) |
| CA (1) | CA1230846A (es) |
| DE (1) | DE3373900D1 (es) |
| ES (1) | ES528162A0 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5373087A (en) * | 1990-08-17 | 1994-12-13 | The Dow Chemical Company | Unsaturated polyaminopolymers, derivatives thereof and processes for making them |
| US5278255A (en) * | 1990-08-17 | 1994-01-11 | The Dow Chemical Company | Unsaturated polyaminopolymer, derivatives thereof and processes for making |
| CN109912542B (zh) * | 2019-03-28 | 2020-11-27 | 江苏扬农化工集团有限公司 | 一种低丙烯使用量的均相体系制备环氧丙烷的方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4383904A (en) * | 1981-09-21 | 1983-05-17 | Celanese Corporation | Photochemical epoxidation |
-
1983
- 1983-06-08 US US06/502,384 patent/US4481092A/en not_active Expired - Fee Related
- 1983-12-14 EP EP83810587A patent/EP0112294B1/de not_active Expired
- 1983-12-14 DE DE8383810587T patent/DE3373900D1/de not_active Expired
- 1983-12-16 CA CA000443486A patent/CA1230846A/en not_active Expired
- 1983-12-19 ES ES528162A patent/ES528162A0/es active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE3373900D1 (en) | 1987-11-05 |
| EP0112294B1 (de) | 1987-09-30 |
| EP0112294A3 (en) | 1984-07-25 |
| EP0112294A2 (de) | 1984-06-27 |
| US4481092A (en) | 1984-11-06 |
| ES528162A0 (es) | 1985-08-01 |
| CA1230846A (en) | 1987-12-29 |
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