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ES8307843A1 - Un procedimiento para la preparacion de un polimero-vivo. - Google Patents

Un procedimiento para la preparacion de un polimero-vivo.

Info

Publication number
ES8307843A1
ES8307843A1 ES513604A ES513604A ES8307843A1 ES 8307843 A1 ES8307843 A1 ES 8307843A1 ES 513604 A ES513604 A ES 513604A ES 513604 A ES513604 A ES 513604A ES 8307843 A1 ES8307843 A1 ES 8307843A1
Authority
ES
Spain
Prior art keywords
living
polymers
preparation
organosilicon
initiators
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES513604A
Other languages
English (en)
Other versions
ES513604A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of ES8307843A1 publication Critical patent/ES8307843A1/es
Publication of ES513604A0 publication Critical patent/ES513604A0/es
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

PROCEDIMIENTO PARA LA OBTENCION DE POLIMEROS _(VIVOS , DE FORMULA (I), EN LA QUE M ES SILICIO, ESTAÑO O GERMANIO; X, Y, Z , R Y R>1 PUEDEN SER VARIOS TIPOS DE RADICALES Y A Y B VALEN DE 0 A 10000. CONSISTE EN LA REACCION DE POLIMERIZACION DE LOS MONOMEROS DE FORMULAS (II), (III) Y SUS MEZCLAS, EN PRESENCIA DE UN INICIADOR DE FORMULA (R>1)<3MZ, EN LAS QUE Z ES UNO DE VARIOS SUSTITUYENTES ACTIVANTES Y LOS DEMAS SIMBOLOS TIENEN LOS MISMOS SIGNIFICADOS QUE EN LA FORMULA (I), Y DE UN CATALIZADOR, QUE ES FUENTE DE IONES FLUORURO, CIANURO, AZIDA O BIFLUORURO O UN ACIDO DE LEWIS. ESTOS POLIMEROS TIENEN APLICACIONES COMO INTERMEDIOS PARA LA FABRICACION DE PLASTIFICANTES, PESTICIDAS AGRICOLAS, MEDICAMENTOS, PERFUMES Y EN LA FABRICACION DE ALIMENTOS.
ES513604A 1981-06-30 1982-06-30 Un procedimiento para la preparacion de un polimero-vivo. Granted ES513604A0 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US27902581A 1981-06-30 1981-06-30

Publications (2)

Publication Number Publication Date
ES8307843A1 true ES8307843A1 (es) 1983-08-01
ES513604A0 ES513604A0 (es) 1983-08-01

Family

ID=23067360

Family Applications (1)

Application Number Title Priority Date Filing Date
ES513604A Granted ES513604A0 (es) 1981-06-30 1982-06-30 Un procedimiento para la preparacion de un polimero-vivo.

Country Status (18)

Country Link
US (1) US4681918A (es)
EP (2) EP0068887B1 (es)
JP (1) JPS5813603A (es)
KR (1) KR890004083B1 (es)
AR (1) AR241118A1 (es)
AT (1) ATE53593T1 (es)
AU (1) AU565180B2 (es)
BR (1) BR8203809A (es)
DE (2) DE3273440D1 (es)
DK (1) DK165456C (es)
ES (1) ES513604A0 (es)
GB (1) GB2102818A (es)
HK (2) HK47987A (es)
MX (1) MX174590B (es)
NO (1) NO158627C (es)
SG (1) SG22387G (es)
ZA (1) ZA824678B (es)
ZW (1) ZW13282A1 (es)

Families Citing this family (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3461810D1 (en) * 1983-05-20 1987-02-05 Allied Colloids Ltd Water soluble polymers
ES8607367A1 (es) * 1983-11-07 1986-06-16 Du Pont Un procedimiento para fabricar una composicion de recubrimiento a base de polimeros hechos de monomeros alfaolefinicos polares.
US4544724A (en) * 1984-06-19 1985-10-01 E. I. Du Pont De Nemours And Company Silylated vinyl alcohol polymers
DE3574260D1 (en) * 1984-07-05 1989-12-21 Du Pont Acrylic star polymers
GB8419805D0 (en) * 1984-08-03 1984-09-05 Allied Colloids Ltd Aqueous drilling and packer fluids
JPH0618808B2 (ja) * 1984-10-08 1994-03-16 日本合成ゴム株式会社 ビニル系重合体の製法
AU581417B2 (en) * 1984-11-16 1989-02-23 Ciba Specialty Chemicals Water Treatments Limited Water soluble polymers and dispersions containing them
US4780554A (en) * 1984-11-20 1988-10-25 Union Carbide Corporation O-silylated ketene acetals and enol ethers and method of preparation
US4656233A (en) * 1984-11-29 1987-04-07 E. I. Du Pont De Nemours And Company "Living" polymers and chain transfer-regulated polymerization process
US4605716A (en) * 1985-02-14 1986-08-12 E. I. Du Pont De Nemours And Company Lewis base-catalyzed polymerization
AU595503B2 (en) * 1985-03-01 1990-04-05 E.I. Du Pont De Nemours And Company Polymer life enhancement in oxyanion-catalyzed polymerization
US4588795A (en) * 1985-03-01 1986-05-13 E. I. Du Pont De Nemours And Company Oxyanion-catalyzed polymerization
US5110869A (en) * 1986-05-29 1992-05-05 E. I. Du Pont De Nemours And Company β-(keto or sulfonyl)esters from reaction of silyketene acetal and acyl or sulfonyl compound
US4983679A (en) * 1986-05-29 1991-01-08 E. I. Dupont De Nemours And Company β-(keto or sulfonyl)esters from reaction of silylketene acetal and acyl or sulfonyl compound
US5260424A (en) * 1986-05-29 1993-11-09 E. I. Du Pont De Nemours And Company B-(keto or sulfonyl) esters from reaction of silylketene acetal and acyl or sulfonyl compound
US4822859A (en) * 1986-06-10 1989-04-18 E. I. Du Pont De Nemours And Company Group transfer polymerization and initiators therefor
US4957973A (en) * 1986-07-08 1990-09-18 E. I. Du Pont De Nemours And Company Uncatalyzed process for preparing "living" polymers
US4728706A (en) * 1986-08-29 1988-03-01 E. I. Du Pont De Nemours And Company Titanium, zirconium- and hafnium containing initiators in the polymerization of acrylic monomers to "living" polymers
US4732955A (en) * 1986-09-29 1988-03-22 E. I. Du Pont De Nemours And Company Group transfer polymerization catalyzed by mercury compounds
AU7895387A (en) * 1986-09-29 1988-03-31 E.I. Du Pont De Nemours And Company Living polymers from unsaturated si, sn or ge initiators
US4806605A (en) * 1987-01-27 1989-02-21 E. I. Du Pont De Nemours And Company Monomers and initiators for group transfer polymerization
GB8705277D0 (en) * 1987-03-06 1987-04-08 Jenkins A D Preparing graft copolymers
EP0295401A3 (de) * 1987-04-30 1990-03-21 Wacker-Chemie Gmbh Verfahren zur Polymerisation von polaren Verbindungen
US4771116A (en) * 1987-04-30 1988-09-13 E. I. Du Pont De Nemours And Company Silylamines as additives in group transfer polymerization
US4845156A (en) * 1987-12-21 1989-07-04 E. I. Du Pont De Nemours And Company Preparation of macromonomers
GB8730131D0 (en) * 1987-12-24 1988-02-03 Ici Plc Catalysts
US5019634A (en) * 1988-02-16 1991-05-28 E. I. Du Pont De Nemours And Company Group transfer living polymer grafted to an initiator support
GB8803764D0 (en) * 1988-02-18 1988-03-16 Ici Plc Polymerisation process
GB8803765D0 (en) * 1988-02-18 1988-03-16 Ici Plc Polymerisation process
US4866145A (en) * 1988-04-01 1989-09-12 E. I. Du Pont De Nemours And Company Catalyst for group transfer polymerization
US4943648A (en) * 1988-04-01 1990-07-24 E. I. Du Pont De Nemours And Company Initiators for group transfer polymerization
US5021524A (en) * 1988-04-14 1991-06-04 E. I. Du Pont De Nemours And Company Initiator for group transfer polymerization
US5187244A (en) * 1988-07-22 1993-02-16 Mitsubishi Rayon Co., Ltd. Preparation process of block copolymers and resulting block copolymers
JPH02140211A (ja) * 1988-11-22 1990-05-29 Nippon Oil & Fats Co Ltd 分子内にペルオキシ給合を有するマレイミド系共重合体
US4906713A (en) * 1989-01-31 1990-03-06 E. I. Du Pont De Nemours And Company "Acrylic" ladder polymers
US4939211A (en) * 1989-03-01 1990-07-03 E. I. Du Pont De Nemours And Company Phosphonate-capped polymers
US4978723A (en) * 1989-03-01 1990-12-18 E. I. Du Pont De Nemours And Company Phosphonate-capped polymers
GB8914575D0 (en) * 1989-06-24 1989-08-16 Ici Plc Catalysts
GB8914574D0 (en) * 1989-06-24 1989-08-16 Ici Plc Catalysts
FR2649400B1 (fr) * 1989-07-10 1993-01-08 Norsolor Sa Copolymeres en etoile et leur procede de fabrication
US5314960A (en) * 1990-04-10 1994-05-24 Permeable Technologies, Inc. Silicone-containing polymers, oxygen permeable hydrophilic contact lenses and methods for making these lenses and treating patients with visual impairment
US5244981A (en) * 1990-04-10 1993-09-14 Permeable Technologies, Inc. Silicone-containing contact lens polymers, oxygen permeable contact lenses and methods for making these lenses and treating patients with visual impairment
US5371147A (en) * 1990-10-11 1994-12-06 Permeable Technologies, Inc. Silicone-containing acrylic star polymers, block copolymers and macromonomers
US5206295A (en) * 1991-02-25 1993-04-27 E. I. Du Pont De Nemours And Company Coating composition comprising an anhydride-containing polymer and a structured epoxy-containing polymer
EP0618956B1 (en) * 1991-12-23 2001-07-11 Albemarle Corporation Polyfunctional michael addition products and refrigeration compositions containing such products
GB2278355B (en) * 1993-05-28 1997-02-26 Kansai Paint Co Ltd Acrylic-modified epoxy-polyamine resins
US6943203B2 (en) 1998-03-02 2005-09-13 Johnson & Johnson Vision Care, Inc. Soft contact lenses
US7619040B2 (en) * 2002-02-15 2009-11-17 Ppg Industries Ohio, Inc. Compositions containing copolymers of olefinic monomers
US6784248B2 (en) * 2002-02-15 2004-08-31 Ppg Industries Ohio, Inc. Thermosetting compositions containing alternating copolymers of isobutylene type monomers
US20040143079A1 (en) * 2003-01-21 2004-07-22 Simion Coca Compositions containing copolymers of isobutylene type monomers
WO2007008575A1 (en) * 2005-07-13 2007-01-18 L'oreal Cosmetic compositions containing liposoluble polymers and tackifiers
US7884158B2 (en) * 2005-09-06 2011-02-08 L'Oré´al Cosmetic compositions containing block copolymers, tackifiers and phenylated silicones
WO2017162334A1 (en) * 2016-03-22 2017-09-28 Technische Universität München Polymerization of michael-type monomers
EP3502094A1 (de) 2017-12-21 2019-06-26 Covestro Deutschland AG Verfahren zur herstellung von telechelen polyolen aus trithiocarbonaten
TWI684607B (zh) * 2018-09-20 2020-02-11 國立清華大學 嵌段共聚物及其製備方法
JP7321185B2 (ja) * 2018-11-15 2023-08-04 住友化学株式会社 成形体及びその製造方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1057998A (en) * 1964-11-09 1967-02-08 Kurashiki Rayon Kk Process for the production of poly (methyl methacrylate)
NL7113482A (es) * 1971-10-01 1973-04-03
US3940402A (en) * 1974-09-19 1976-02-24 E. I. Dupont De Nemours And Company Tris(substituted amino) sulfonium salts
JPS5837321B2 (ja) * 1978-04-19 1983-08-16 東ソー株式会社 アニオン重合方法
US4413084A (en) * 1980-10-23 1983-11-01 Ford Motor Company Paint composition comprising hydroxy functional film former and improved stabilized flow control additive
US4396680A (en) * 1981-03-04 1983-08-02 E. I. Du Pont De Nemours And Co. Substrate coated with crater resistant acrylic enamel
US4351924A (en) * 1981-03-16 1982-09-28 E. I. Du Pont De Nemours And Company ω-, and α,ω-Hydroxyhydrocarbyl-(alkyl methacrylate) polymers and process
US4417034A (en) * 1981-06-30 1983-11-22 E. I. Du Pont De Nemours & Co. Living polymers and process for their preparation
US4598161A (en) * 1983-04-04 1986-07-01 E. I. Du Pont De Nemours And Company Tris(dialkylamino)sulfonium bifluoride catalysts

Also Published As

Publication number Publication date
GB2102818A (en) 1983-02-09
EP0068887A1 (en) 1983-01-05
AR241118A2 (es) 1991-11-15
AU8544282A (en) 1983-01-06
ZW13282A1 (en) 1982-09-29
DK292682A (da) 1982-12-31
ATE53593T1 (de) 1990-06-15
US4681918A (en) 1987-07-21
KR840000588A (ko) 1984-02-25
EP0184863A2 (en) 1986-06-18
EP0184863B1 (en) 1990-06-13
AU565180B2 (en) 1987-09-10
JPH0579685B2 (es) 1993-11-04
KR890004083B1 (ko) 1989-10-20
ZA824678B (en) 1984-03-28
MX174590B (es) 1994-05-27
EP0068887B1 (en) 1986-09-24
ES513604A0 (es) 1983-08-01
SG22387G (en) 1987-07-10
NO158627B (no) 1988-07-04
BR8203809A (pt) 1983-07-05
NO158627C (no) 1988-10-12
DK165456B (da) 1992-11-30
EP0184863A3 (en) 1986-10-22
NO822230L (no) 1983-01-03
DE3273440D1 (en) 1986-10-30
DE3280190D1 (de) 1990-07-19
JPS5813603A (ja) 1983-01-26
DK165456C (da) 1993-04-19
HK47987A (en) 1987-06-26
AR241118A1 (es) 1991-11-15
HK80490A (en) 1990-10-12

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