ES8104178A1 - Procedimiento para preparar acidos carboxilicos aromaticos por oxidacion de un hidrocarburo alcohil-aromatico - Google Patents
Procedimiento para preparar acidos carboxilicos aromaticos por oxidacion de un hidrocarburo alcohil-aromaticoInfo
- Publication number
- ES8104178A1 ES8104178A1 ES494563A ES494563A ES8104178A1 ES 8104178 A1 ES8104178 A1 ES 8104178A1 ES 494563 A ES494563 A ES 494563A ES 494563 A ES494563 A ES 494563A ES 8104178 A1 ES8104178 A1 ES 8104178A1
- Authority
- ES
- Spain
- Prior art keywords
- oxidation
- cobalt
- aromatic
- catalyst
- alcohyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 CARBOXYL ACIDS Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 150000001869 cobalt compounds Chemical class 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 150000002363 hafnium compounds Chemical class 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
PROCEDIMIENTO PARA PREPARAR ACIDOS CARBOXILICOS AROMATICOS POR OXIDACION DE UN HIDROCARBURO ALCOHIL-AROMATICO. LA OXIDACION TIENE LUGAR EN FASE LIQUIDA EN AUSENCIA DE UN ACIDO CARBOXILICO ALIFATICO, POR MEDIO DE UN GAS QUE CONTIENE OXIGENO MOLECULAR. SE EMPLEA UN CATALIZADOR COMPUESTO DE COBALTO SOLUBLE EN LA MEZCLA DE REACCION, ESTE CATALIZADOR TAMBIEN CONTIENE UN COMPUESTO DE ZIRCONIO Y/O HAFNIO SOLUBLE EN LA MEZCLA. ESTE PROCEDIMIENTO ES ADECUADO PARA LA OXIDACION DE TOLUENO A ACIDO BENZOICO, ASI COMO PARA LA OXIDACION DE OTROS HIDROCARBUROS ALCOXI-AROMATICOS Y OTROS ACIDOS CARBOXILICOS AROMATICOS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7906575A NL7906575A (nl) | 1979-09-01 | 1979-09-01 | Werkwijze ter bereiding van aromatische carbonzuren. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES494563A0 ES494563A0 (es) | 1981-04-01 |
| ES8104178A1 true ES8104178A1 (es) | 1981-04-01 |
Family
ID=19833770
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES494563A Expired ES8104178A1 (es) | 1979-09-01 | 1980-08-28 | Procedimiento para preparar acidos carboxilicos aromaticos por oxidacion de un hidrocarburo alcohil-aromatico |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0026507B1 (es) |
| JP (1) | JPS5655335A (es) |
| BR (1) | BR8005517A (es) |
| CA (1) | CA1146588A (es) |
| DE (1) | DE3062442D1 (es) |
| ES (1) | ES8104178A1 (es) |
| IN (1) | IN152918B (es) |
| MX (1) | MX5883E (es) |
| NL (1) | NL7906575A (es) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5951242A (ja) * | 1982-09-14 | 1984-03-24 | Toray Ind Inc | m−ニトロ安息香酸の製造法 |
| ES2104512B1 (es) * | 1995-09-21 | 1998-07-01 | Interquisa | Procedimiento industrial para la fabricacion de acidos carboxilicos aromaticos. |
| IT1289529B1 (it) * | 1996-12-27 | 1998-10-15 | Franco Codignola | Procedimento per la produzione di acidi aromatici |
| US6153790A (en) * | 1998-12-01 | 2000-11-28 | Shell Oil Company | Method to produce aromatic dicarboxylic acids using cobalt and zirconium catalysts |
| US6657067B2 (en) | 2002-03-22 | 2003-12-02 | General Electric Company | Method for the manufacture of chlorophthalic anhydride |
| US6649773B2 (en) | 2002-03-22 | 2003-11-18 | General Electric Company | Method for the manufacture of halophthalic acids and anhydrides |
| US6657068B2 (en) | 2002-03-22 | 2003-12-02 | General Electric Company | Liquid phase oxidation of halogenated ortho-xylenes |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL140508C (es) * | 1963-05-01 | |||
| JPS4896545A (es) * | 1972-03-17 | 1973-12-10 | ||
| US3920735A (en) * | 1973-05-21 | 1975-11-18 | Standard Oil Co | Zirconium enhanced activity of transition metal-bromine catalysis of di- and trimethyl benzene oxidation in liquid phase |
-
1979
- 1979-09-01 NL NL7906575A patent/NL7906575A/nl not_active Application Discontinuation
-
1980
- 1980-08-23 EP EP19800200796 patent/EP0026507B1/en not_active Expired
- 1980-08-23 DE DE8080200796T patent/DE3062442D1/de not_active Expired
- 1980-08-26 IN IN976/CAL/80A patent/IN152918B/en unknown
- 1980-08-28 ES ES494563A patent/ES8104178A1/es not_active Expired
- 1980-08-29 BR BR8005517A patent/BR8005517A/pt unknown
- 1980-08-29 MX MX900180U patent/MX5883E/es unknown
- 1980-08-29 CA CA000359362A patent/CA1146588A/en not_active Expired
- 1980-09-01 JP JP12098380A patent/JPS5655335A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| IN152918B (es) | 1984-05-05 |
| JPS5655335A (en) | 1981-05-15 |
| ES494563A0 (es) | 1981-04-01 |
| NL7906575A (nl) | 1981-03-03 |
| MX5883E (es) | 1984-08-16 |
| DE3062442D1 (en) | 1983-04-28 |
| CA1146588A (en) | 1983-05-17 |
| EP0026507A1 (en) | 1981-04-08 |
| EP0026507B1 (en) | 1983-03-23 |
| BR8005517A (pt) | 1981-03-10 |
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