ES8101652A1 - Un metodo para la limpieza quimica de una incrustacion sul- furada soluble en acidos de una superficie metalica - Google Patents
Un metodo para la limpieza quimica de una incrustacion sul- furada soluble en acidos de una superficie metalicaInfo
- Publication number
- ES8101652A1 ES8101652A1 ES486622A ES486622A ES8101652A1 ES 8101652 A1 ES8101652 A1 ES 8101652A1 ES 486622 A ES486622 A ES 486622A ES 486622 A ES486622 A ES 486622A ES 8101652 A1 ES8101652 A1 ES 8101652A1
- Authority
- ES
- Spain
- Prior art keywords
- metal surfaces
- containing scale
- removing sulfide
- sulfide
- scale
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 title abstract 2
- 239000002184 metal Substances 0.000 title abstract 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000011260 aqueous acid Substances 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S507/00—Earth boring, well treating, and oil field chemistry
- Y10S507/927—Well cleaning fluid
- Y10S507/932—Cleaning sulfur deposits
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S507/00—Earth boring, well treating, and oil field chemistry
- Y10S507/939—Corrosion inhibitor
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
PROCEDIMIENTO DE LIMPIEZA DE UNA INCRUSTRACION SULFURADA SOLUBLE EN ACIDOS. CONSISTE EN HACER REACCIONAR LA INCRUSTRACION CON UNA COMPOSICION ACUOSA, CONTENIENDO LAS SIGUIENTES SUSTANCIAS: A) UN ACIDO NO OXIDANTE ACUOSO, TAL COMO EL CLORHIDRICO, SULFURICO,FOSFORICO, FORMICO, GLICOLICO O CITRICO. B) UN ALDEHIDO GENERADO <<IN SITU>> POR REACCION DE DISOLUCION CON HEXAMETILEN TETRAAMINA; DICHO ALDEHIDO PUEDE SER FORMALDEHIDO, PARAFORMALDEHIDO, ACETALDEHIDO, GLIOXAL, BETA-HIDROXIBUTIRALDEHIDO O METIL-3-CICLOHEXEN CARBOXALDEHIDO. LA CONCENTRACION DEL ALDEHIDO ESTA COMPRENDIDA ENTRE EL 1 Y EL 10 POR 100 DEL PESO DE LA COMPOSICION LIMPIADORA. C) UN INHIBIDOR DE LA CORROSION ACIDA, BASADO EN AMINA. LA TEMPERATURA DE LA COMPOSICION ES DE 60 A 71GC.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/967,047 US4220550A (en) | 1978-12-06 | 1978-12-06 | Composition and method for removing sulfide-containing scale from metal surfaces |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES8101652A1 true ES8101652A1 (es) | 1980-12-16 |
| ES486622A0 ES486622A0 (es) | 1980-12-16 |
Family
ID=25512232
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES486622A Granted ES486622A0 (es) | 1978-12-06 | 1979-12-05 | Un metodo para la limpieza quimica de una incrustacion sul- furada soluble en acidos de una superficie metalica |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4220550A (es) |
| EP (1) | EP0012478B1 (es) |
| JP (1) | JPS5579881A (es) |
| BR (1) | BR7907921A (es) |
| CA (1) | CA1118667A (es) |
| DE (1) | DE2967398D1 (es) |
| ES (1) | ES486622A0 (es) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4289639A (en) * | 1980-10-03 | 1981-09-15 | The Dow Chemical Company | Method and composition for removing sulfide-containing scale from metal surfaces |
| US4381950A (en) * | 1981-05-22 | 1983-05-03 | Halliburton Company | Method for removing iron sulfide scale from metal surfaces |
| US4351673A (en) * | 1981-05-22 | 1982-09-28 | Halliburton Company | Method for removing iron sulfide scale from metal surfaces |
| CH653466A5 (de) * | 1981-09-01 | 1985-12-31 | Industrieorientierte Forsch | Verfahren zur dekontamination von stahloberflaechen und entsorgung der radioaktiven stoffe. |
| US4493775A (en) * | 1983-09-30 | 1985-01-15 | The Dow Chemical Company | Method and composition for corrosion |
| US4637899A (en) * | 1984-01-30 | 1987-01-20 | Dowell Schlumberger Incorporated | Corrosion inhibitors for cleaning solutions |
| US4666625A (en) * | 1984-11-27 | 1987-05-19 | The Drackett Company | Method of cleaning clogged drains |
| US4778617A (en) * | 1984-11-27 | 1988-10-18 | The Drackett Company | Acid cleaner composition |
| US5120471A (en) * | 1985-08-14 | 1992-06-09 | Dowell Schlumberger Incorporated | Process and composition for protecting chrome steel |
| US4680127A (en) * | 1985-12-13 | 1987-07-14 | Betz Laboratories, Inc. | Method of scavenging hydrogen sulfide |
| FR2651500A1 (fr) * | 1989-09-05 | 1991-03-08 | Hoechst France | Nouvelles emulsions eau dans huile et leur application a l'elimination du sulfure d'hydrogene. |
| US5284635A (en) * | 1989-09-05 | 1994-02-08 | Societe Francaise Hoechst | Process for the elimination of hydrogen sulfide by using water-in-oil emulsions |
| DE4002132A1 (de) * | 1990-01-25 | 1991-08-01 | Hoechst Ag | Verfahren zum abfangen von schwefelwasserstoff mit glyoxal |
| US5527395A (en) * | 1991-05-16 | 1996-06-18 | H.E.R.C. Products Incorporated | Method of cleaning and maintaining potable water distribution pipe systems with a heated cleaning solution |
| US5360488A (en) * | 1993-03-23 | 1994-11-01 | H.E.R.C. Products Incorporated | Method of cleaning and maintaining water distribution pipe systems |
| US5885364A (en) * | 1991-05-16 | 1999-03-23 | H.E.R.C. Products Incorporated | Method of cleaning and maintaining potable water distribution pipe systems |
| US5800629A (en) * | 1997-03-06 | 1998-09-01 | H.E.R.C. Products Incorporated | Pipe system cleaning and in-line treatment of spent cleaning solution |
| US6076536A (en) | 1998-10-07 | 2000-06-20 | H.E.R.C. Products Incorporated | Cleaning and passivating water distribution systems |
| US6068056A (en) * | 1999-10-13 | 2000-05-30 | Schlumberger Technology Corporation | Well treatment fluids comprising mixed aldehydes |
| US6666975B1 (en) | 2002-10-04 | 2003-12-23 | Ge Betz, Inc. | Method of reducing hydrogen sulfide odor emissions from an aqueous medium |
| US6887840B2 (en) * | 2003-01-21 | 2005-05-03 | Milborn Enterprises Llc | Iron sulfide clean-up composition and method |
| US7255796B2 (en) | 2004-07-08 | 2007-08-14 | General Electric Company | Method of preventing hydrogen sulfide odor generation in an aqueous medium |
| US20060073112A1 (en) * | 2004-10-01 | 2006-04-06 | Whitekettle Wilson K | Method of preventing hydrogen sulfide odor generation in an aqueous medium |
| JP4596909B2 (ja) * | 2004-12-28 | 2010-12-15 | 朝日化学工業株式会社 | 酸洗促進剤、酸洗液組成物および酸洗方法 |
| US20070131625A1 (en) * | 2005-12-12 | 2007-06-14 | General Electric Company | Methods of inhibiting biogenic sulfide formation in aqueous systems |
| US20090068059A1 (en) * | 2007-09-12 | 2009-03-12 | Whitekettle Wilson K | Method of preventing hydrogen sulfide odor generation in an aqueous medium |
| US20090320877A1 (en) * | 2008-06-30 | 2009-12-31 | Bradley Steven A | Process and composition for removing a scale deposit |
| CA2639030C (en) * | 2008-07-23 | 2015-12-01 | Shaun T. Mesher | Mutual solvent system and method for improved oil and gas permeability in high temperature formations |
| PE20130057A1 (es) * | 2009-12-31 | 2013-02-04 | Dorf Ketal Chemicals India Private Ltd | Aditivo y metodo para la eliminacion de impurezas formadas debido a compuestos de azufre en petroleos crudos que contienen naftenato de calcio |
| US8357306B2 (en) * | 2010-12-20 | 2013-01-22 | Baker Hughes Incorporated | Non-nitrogen sulfide sweeteners |
| MX2011005186A (es) * | 2011-05-17 | 2012-11-27 | Geo Estratos S A De C V | Compuesto estabilizado eliminador e inhibidor de incrustaciones en tuberías. |
| US9394396B2 (en) | 2011-06-21 | 2016-07-19 | Baker Hughes Incorporated | Hydrogen sulfide scavenger for use in hydrocarbons |
| GB2552284B (en) | 2015-04-20 | 2022-04-13 | Halliburton Energy Services Inc | Compositions, systems, and methods for removing iron sulfide scale from oilfield components |
| WO2016171652A1 (en) | 2015-04-20 | 2016-10-27 | Halliburton Energy Services, Inc. | Compositions, systems, and methods for removing iron sulfide scale from oilfield components using methyl acrylate |
| US10151715B2 (en) | 2015-09-03 | 2018-12-11 | Saudi Arabian Oil Company | Nano-level evaluation of kerogen-rich reservoir rock |
| US9869649B2 (en) | 2015-09-03 | 2018-01-16 | Saudi Arabian Oil Company | Nano-level evaluation of kerogen-rich reservoir rock |
| US10451601B2 (en) | 2016-06-28 | 2019-10-22 | Saudi Arabian Oil Company | Nano-indentation test to determine mechanical properties of reservoir rock |
| WO2018204259A1 (en) | 2017-05-02 | 2018-11-08 | Saudi Arabian Oil Company | Synthetic source rocks |
| US10501679B2 (en) | 2018-01-31 | 2019-12-10 | Saudi Arabian Oil Company | Iron sulfide dissolver |
| US10520407B2 (en) | 2018-03-01 | 2019-12-31 | Saudi Arabian Oil Company | Nano-indentation tests to characterize hydraulic fractures |
| US11573159B2 (en) | 2019-01-08 | 2023-02-07 | Saudi Arabian Oil Company | Identifying fracture barriers for hydraulic fracturing |
| US11492541B2 (en) | 2019-07-24 | 2022-11-08 | Saudi Arabian Oil Company | Organic salts of oxidizing anions as energetic materials |
| US11319478B2 (en) | 2019-07-24 | 2022-05-03 | Saudi Arabian Oil Company | Oxidizing gasses for carbon dioxide-based fracturing fluids |
| CA3057217A1 (en) * | 2019-10-02 | 2021-04-02 | Fluid Energy Group Ltd. | Composition useful in metal sulfide scale removal |
| WO2021138355A1 (en) | 2019-12-31 | 2021-07-08 | Saudi Arabian Oil Company | Viscoelastic-surfactant fracturing fluids having oxidizer |
| US11352548B2 (en) | 2019-12-31 | 2022-06-07 | Saudi Arabian Oil Company | Viscoelastic-surfactant treatment fluids having oxidizer |
| US11339321B2 (en) | 2019-12-31 | 2022-05-24 | Saudi Arabian Oil Company | Reactive hydraulic fracturing fluid |
| US11365344B2 (en) | 2020-01-17 | 2022-06-21 | Saudi Arabian Oil Company | Delivery of halogens to a subterranean formation |
| US11473009B2 (en) | 2020-01-17 | 2022-10-18 | Saudi Arabian Oil Company | Delivery of halogens to a subterranean formation |
| US11473001B2 (en) | 2020-01-17 | 2022-10-18 | Saudi Arabian Oil Company | Delivery of halogens to a subterranean formation |
| US11268373B2 (en) | 2020-01-17 | 2022-03-08 | Saudi Arabian Oil Company | Estimating natural fracture properties based on production from hydraulically fractured wells |
| US11549894B2 (en) | 2020-04-06 | 2023-01-10 | Saudi Arabian Oil Company | Determination of depositional environments |
| US11578263B2 (en) | 2020-05-12 | 2023-02-14 | Saudi Arabian Oil Company | Ceramic-coated proppant |
| US11326439B2 (en) | 2020-05-15 | 2022-05-10 | Saudi Arabian Oil Company | Compositions, systems, and methods for iron sulfide scale identification, prevention, and reduction |
| US11270048B2 (en) | 2020-06-26 | 2022-03-08 | Saudi Arabian Oil Company | Calibration and simulation of a wellbore liner |
| US11542815B2 (en) | 2020-11-30 | 2023-01-03 | Saudi Arabian Oil Company | Determining effect of oxidative hydraulic fracturing |
| US11649702B2 (en) | 2020-12-03 | 2023-05-16 | Saudi Arabian Oil Company | Wellbore shaped perforation assembly |
| US12071814B2 (en) | 2020-12-07 | 2024-08-27 | Saudi Arabian Oil Company | Wellbore notching assembly |
| US12071589B2 (en) | 2021-10-07 | 2024-08-27 | Saudi Arabian Oil Company | Water-soluble graphene oxide nanosheet assisted high temperature fracturing fluid |
| US11619127B1 (en) | 2021-12-06 | 2023-04-04 | Saudi Arabian Oil Company | Wellhead acoustic insulation to monitor hydraulic fracturing |
| US12025589B2 (en) | 2021-12-06 | 2024-07-02 | Saudi Arabian Oil Company | Indentation method to measure multiple rock properties |
| US12012550B2 (en) | 2021-12-13 | 2024-06-18 | Saudi Arabian Oil Company | Attenuated acid formulations for acid stimulation |
| US11885790B2 (en) | 2021-12-13 | 2024-01-30 | Saudi Arabian Oil Company | Source productivity assay integrating pyrolysis data and X-ray diffraction data |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR828295A (fr) * | 1937-10-26 | 1938-05-13 | Procédé d'amélioration de bains acides utilisés en métallurgie | |
| US2606873A (en) * | 1950-02-27 | 1952-08-12 | Dow Chemical Co | Composition for removing scale deposits from ferrous metal surfaces |
| CH331455A (de) * | 1954-04-09 | 1958-07-31 | Siegel & Co | Reinigungsmittel für Edelmetalle, Kupfer und seine Legierungen |
| GB803541A (en) * | 1956-05-06 | 1958-10-29 | Technion Res & Dev Foundation | Improvements in acid inhibitors |
| US3077454A (en) * | 1960-07-14 | 1963-02-12 | Dow Chemical Co | Compositions for inhibiting corrosion |
| US3335090A (en) * | 1964-04-15 | 1967-08-08 | Air Reduction | Corrosion inhibition with propargyl benzylamine |
| US3514410A (en) * | 1967-07-28 | 1970-05-26 | Halliburton Co | Prevention of ferric ion corrosion using acid cleaning solution containing hydrogen sulfide and an aldehyde corrosion inhibitor |
| FR1547732A (fr) * | 1967-10-19 | 1968-11-29 | Dow Chemical Co | Procédé d'enlèvement des dépôts de sulfure ferreux de surfaces métalliques |
| US3669613A (en) * | 1970-04-27 | 1972-06-13 | Halliburton Co | Method for inhibiting sulfide cracking of metals with a hydrogen sulfide-aldehyde reaction product |
-
1978
- 1978-12-06 US US05/967,047 patent/US4220550A/en not_active Expired - Lifetime
-
1979
- 1979-12-05 ES ES486622A patent/ES486622A0/es active Granted
- 1979-12-05 CA CA000341239A patent/CA1118667A/en not_active Expired
- 1979-12-05 DE DE7979200728T patent/DE2967398D1/de not_active Expired
- 1979-12-05 BR BR7907921A patent/BR7907921A/pt not_active IP Right Cessation
- 1979-12-05 EP EP79200728A patent/EP0012478B1/en not_active Expired
- 1979-12-06 JP JP15748879A patent/JPS5579881A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| CA1118667A (en) | 1982-02-23 |
| JPS5579881A (en) | 1980-06-16 |
| DE2967398D1 (en) | 1985-03-28 |
| EP0012478A3 (en) | 1980-09-17 |
| US4220550A (en) | 1980-09-02 |
| ES486622A0 (es) | 1980-12-16 |
| EP0012478B1 (en) | 1985-02-20 |
| JPS6121314B2 (es) | 1986-05-26 |
| EP0012478A2 (en) | 1980-06-25 |
| BR7907921A (pt) | 1980-07-22 |
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