ES8101572A1 - Procedimiento para la obtencion de butirolactona - Google Patents
Procedimiento para la obtencion de butirolactonaInfo
- Publication number
- ES8101572A1 ES8101572A1 ES490988A ES490988A ES8101572A1 ES 8101572 A1 ES8101572 A1 ES 8101572A1 ES 490988 A ES490988 A ES 490988A ES 490988 A ES490988 A ES 490988A ES 8101572 A1 ES8101572 A1 ES 8101572A1
- Authority
- ES
- Spain
- Prior art keywords
- ether
- alkyl radical
- allyl
- deetherification
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 title abstract 4
- 229930188620 butyrolactone Natural products 0.000 title abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 5
- 238000005661 deetherification reaction Methods 0.000 abstract 3
- -1 iso-butylene Chemical class 0.000 abstract 3
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 238000007363 ring formation reaction Methods 0.000 abstract 2
- FHVRTMVXBVDWCK-UHFFFAOYSA-N 2-methyl-2-prop-2-enoxypropane Chemical compound CC(C)(C)OCC=C FHVRTMVXBVDWCK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 150000003509 tertiary alcohols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/32—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
- C07C43/15—Unsaturated ethers containing only non-aromatic carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
Abstract
PROCEDIMIENTO DE OBTENCION DE BUTIROLACTONA. CONSISTE EN OXIDAR UN ALDEHIDO-ETER DE FORMULA GENERAL (I), FORMANDOSE UN ACIDO-ETER SEGUIDO DE DES-ETERIFICACION Y CICLIZACION. LA DES-ETERIFICACION ES EFECTUADA EMPLEANDO UN CATALIZADOR ACIDO, TAL COMO UNA RESINA DE INTERCAMBIO IONICA ACIDA, UNA ARCILLA ACIDA, UN ALUMINO-SILICATO ACIDO Y SILICO. OPCIONALMENTE EL PROCEDIMIENTO PUEDE EFECTUARSE EN LAS SIGUIENTES OPERACIONES: 1) REACCION DE ALIL ALCOHOL CON UNA OLEFINA. 2) REACCION DEL ALIL ETER RESULTANTE CON HIDROGENO Y MONOXIDO DE CARBONO, BAJO CONDICIONES DE HIDROFORMILACION, EN PRESENCIA DE UN CATALIZADOR. 3) OXIDACION DEL ALDEHIDO-ETER RESULTANTE. 4) DES-ESTIRIFICACION, DESHIDRATACION Y CICLIZACION DEL ACIDO ETER RESULTANTE. 5) RECUPERACION DE LA BUTIROLACTONA RESULTANTE Y LA OLEFINA REGENERADA. 6) RECICLACION DE LA OLEFINA REGENERADA RESULTANTE. *FORMULA*
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB7912850 | 1979-04-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES8101572A1 true ES8101572A1 (es) | 1980-12-16 |
| ES490988A0 ES490988A0 (es) | 1980-12-16 |
Family
ID=10504515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES490988A Granted ES490988A0 (es) | 1979-04-11 | 1980-04-11 | Procedimiento para la obtencion de butirolactona |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4302394A (es) |
| EP (1) | EP0018162A1 (es) |
| JP (1) | JPS55141480A (es) |
| KR (1) | KR830002564B1 (es) |
| AU (1) | AU5734880A (es) |
| BR (1) | BR8002278A (es) |
| CA (1) | CA1146573A (es) |
| ES (1) | ES490988A0 (es) |
| PL (1) | PL223388A1 (es) |
| ZA (1) | ZA802154B (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0018161B1 (en) * | 1979-04-11 | 1983-05-25 | DAVY McKEE (LONDON) LIMITED | Aldehyde-ethers and process for their production |
| DE3009604A1 (de) * | 1980-03-13 | 1981-09-24 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von butyrolactonen |
| CH649294A5 (de) * | 1981-06-17 | 1985-05-15 | Lonza Ag | Verfahren zur herstellung von tetronsaeure. |
| CH649996A5 (de) * | 1981-06-17 | 1985-06-28 | Lonza Ag | Verfahren zur herstellung von tetronsaeure. |
| DE3210705A1 (de) * | 1982-03-24 | 1983-10-06 | Basf Ag | Verfahren zur herstellung von 3-alkyl-2,5-dihydrofuran-2-onen |
| DE3361212D1 (en) * | 1982-06-11 | 1985-12-19 | Davy Mckee London | Hydroformylation process |
| US4533756A (en) * | 1983-11-07 | 1985-08-06 | Texaco Inc. | Process for synthesis of acrylic acid precursors via hydroformylation of vinyl ether |
| JP4483156B2 (ja) * | 2002-03-28 | 2010-06-16 | 三菱化学株式会社 | ガンマブチロラクトンの精製方法 |
| WO2017175522A1 (ja) * | 2016-04-05 | 2017-10-12 | 株式会社Moresco | オキサ酸化合物 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1026355A (en) * | 1972-04-12 | 1978-02-14 | Hoechst Aktiengesellschaft | PROCESS FOR THE MANUFACTURE OF VINYL ACETIC ACID AND OPTIONALLY OF .alpha.-BUTYROLACTONE |
| US3868370A (en) * | 1973-02-09 | 1975-02-25 | Gen Electric | Process for making 4-butyrolactone |
| DE2411440B2 (de) * | 1974-03-11 | 1977-12-15 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von methacrylsaeure und butyrolacton |
-
1980
- 1980-04-09 EP EP80301130A patent/EP0018162A1/en not_active Ceased
- 1980-04-10 CA CA000349513A patent/CA1146573A/en not_active Expired
- 1980-04-10 KR KR1019800001484A patent/KR830002564B1/ko not_active Expired
- 1980-04-10 AU AU57348/80A patent/AU5734880A/en not_active Abandoned
- 1980-04-10 ZA ZA00802154A patent/ZA802154B/xx unknown
- 1980-04-11 ES ES490988A patent/ES490988A0/es active Granted
- 1980-04-11 BR BR8002278A patent/BR8002278A/pt unknown
- 1980-04-11 JP JP4855280A patent/JPS55141480A/ja active Pending
- 1980-04-11 US US06/139,592 patent/US4302394A/en not_active Expired - Lifetime
- 1980-04-11 PL PL22338880A patent/PL223388A1/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR830002749A (ko) | 1983-05-30 |
| JPS55141480A (en) | 1980-11-05 |
| PL223388A1 (es) | 1981-01-30 |
| AU5734880A (en) | 1980-10-16 |
| BR8002278A (pt) | 1980-12-02 |
| KR830002564B1 (ko) | 1983-11-14 |
| ES490988A0 (es) | 1980-12-16 |
| CA1146573A (en) | 1983-05-17 |
| US4302394A (en) | 1981-11-24 |
| EP0018162A1 (en) | 1980-10-29 |
| ZA802154B (en) | 1981-04-29 |
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