ES551816A0 - Metodo de controlar plagas de insectos. - Google Patents
Metodo de controlar plagas de insectos.Info
- Publication number
- ES551816A0 ES551816A0 ES551816A ES551816A ES551816A0 ES 551816 A0 ES551816 A0 ES 551816A0 ES 551816 A ES551816 A ES 551816A ES 551816 A ES551816 A ES 551816A ES 551816 A0 ES551816 A0 ES 551816A0
- Authority
- ES
- Spain
- Prior art keywords
- butoxy
- alkyl
- hydrogen
- alkylenoxy
- alkylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 241000238631 Hexapoda Species 0.000 title 1
- -1 hydroxy, mercapto, amino Chemical group 0.000 abstract 6
- 150000002431 hydrogen Chemical class 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 2
- 239000004480 active ingredient Substances 0.000 abstract 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 125000005083 alkoxyalkoxy group Chemical group 0.000 abstract 1
- 125000005530 alkylenedioxy group Chemical group 0.000 abstract 1
- 125000005336 allyloxy group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004438 haloalkoxy group Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000005113 hydroxyalkoxy group Chemical group 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/04—Ortho-condensed systems
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
- A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
- C07D311/58—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
- C07D311/58—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4
- C07D311/64—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4 with oxygen atoms directly attached in position 8
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
- C07D311/58—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4
- C07D311/70—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4 with two hydrocarbon radicals attached in position 2 and elements other than carbon and hydrogen in position 6
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyrane Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Photoreceptors In Electrophotography (AREA)
- Saccharide Compounds (AREA)
- Oscillators With Electromechanical Resonators (AREA)
- Amplifiers (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
- Developing Agents For Electrophotography (AREA)
- Measurement And Recording Of Electrical Phenomena And Electrical Characteristics Of The Living Body (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU83504A HU194214B (en) | 1983-02-15 | 1983-02-15 | Process for producing 7-alkoxy-2h-chromene derivatives and insecticide and nematocide compositions containing them as active components |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES8708112A1 ES8708112A1 (es) | 1987-10-16 |
| ES551816A0 true ES551816A0 (es) | 1987-10-16 |
Family
ID=10949885
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES529746A Expired ES8700855A1 (es) | 1983-02-15 | 1984-02-15 | Procedimiento de preparar derivados cromenicos |
| ES551816A Expired ES8708112A1 (es) | 1983-02-15 | 1986-01-31 | Metodo de controlar plagas de insectos. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES529746A Expired ES8700855A1 (es) | 1983-02-15 | 1984-02-15 | Procedimiento de preparar derivados cromenicos |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4716238A (es) |
| EP (2) | EP0208147A3 (es) |
| JP (1) | JPS59210077A (es) |
| AT (1) | ATE32461T1 (es) |
| AU (1) | AU580729B2 (es) |
| CS (1) | CS261865B2 (es) |
| DD (1) | DD219363A5 (es) |
| DE (1) | DE3469299D1 (es) |
| DK (1) | DK70284A (es) |
| ES (2) | ES8700855A1 (es) |
| FI (1) | FI840585A7 (es) |
| HU (1) | HU194214B (es) |
| IL (1) | IL70926A (es) |
| PL (1) | PL246226A1 (es) |
| PT (1) | PT78110B (es) |
| SU (1) | SU1468418A3 (es) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HU194855B (en) * | 1983-02-16 | 1988-03-28 | Alkaloida Vegyeszeti Gyar | Process for producing chromene derivatives, insecticide and nematocide compositions containing chromene derivatives as active components |
| JPS6051189A (ja) * | 1983-08-30 | 1985-03-22 | Sankyo Co Ltd | チアゾリジン誘導体およびその製造法 |
| GB8323293D0 (en) * | 1983-08-31 | 1983-10-05 | Zyma Sa | Substituted flavene and thioflavene derivatives |
| JP2514945B2 (ja) * | 1987-02-05 | 1996-07-10 | 三井石油化学工業株式会社 | 芳香族アミン誘導体 |
| HU207861B (en) * | 1989-07-21 | 1993-06-28 | Alkaloida Vegyeszeti Gyar | Process for producing benzopirane derivative of blood pressure lowering activity |
| US5223629A (en) * | 1989-07-21 | 1993-06-29 | Alkaloida Vegyeszeti Gyar | Process for the preparation of anti-hypertensive benzopyran |
| FR2760748A1 (fr) * | 1997-03-14 | 1998-09-18 | Rhodia Chimie Sa | Procede de preparation de 2h-1-benzopyranes |
| FR2766820B1 (fr) * | 1997-07-31 | 1999-10-22 | Rhodia Chimie Sa | Procede de preparation de 2h-1-benzopyranes et intermediaires de synthese utiles dans la mise en oeuvre du procede |
| ITTO20030140U1 (it) * | 2003-09-16 | 2005-03-17 | Interfila Srl | Matita cosmetica |
| US7514461B2 (en) | 2003-09-19 | 2009-04-07 | Edison Pharmaceuticals, Inc. | Chroman derivatives |
| WO2014137811A1 (en) | 2013-03-05 | 2014-09-12 | The United States Of America, As Represented By The Secretary Of Agriculture | Compositions and methods for repelling blood-sucking and biting insects, ticks and mites |
| CN106749147B (zh) * | 2016-12-01 | 2018-12-07 | 南昌大学 | 降血糖化合物及其制备方法、用途 |
| KR102692932B1 (ko) * | 2019-07-30 | 2024-08-07 | 주식회사 글라세움 | 2-((6-(히드록시메틸)크로멘-5-일)옥시)-1-페닐에타논 유도체의 합성 방법 |
| KR102505284B1 (ko) * | 2020-07-20 | 2023-03-03 | 항저우 두이 테크놀로지 컴퍼니 리미티드 | 치환된 크로마논 유도체의 제조방법 |
| CN112939919B (zh) * | 2021-03-11 | 2023-02-03 | 西华大学 | 2-氨基苯并吡喃类化合物及其在农药中的应用 |
| CN113004240B (zh) * | 2021-03-11 | 2023-02-03 | 西华大学 | 苯并吡喃类化合物及其在农药中的用途 |
| CN113024500B (zh) * | 2021-03-11 | 2023-02-03 | 西华大学 | 6,8-二溴苯并吡喃衍生物及其在农药中的应用 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH213149A (de) * | 1939-07-28 | 1941-01-15 | Hoffmann La Roche | Verfahren zur Darstellung von d,l-a-Tocopherol. |
| US2354492A (en) * | 1941-11-26 | 1944-07-25 | Adams Roger | Marihuana active compound |
| US4542150A (en) * | 1975-09-17 | 1985-09-17 | Cornell Research Foundation, Inc. | Anti-juvenile hormones |
| BR7606195A (pt) * | 1975-09-17 | 1977-06-14 | Cornell Res Foundation Inc | Processo para tratar insetos para inibir a atividade hormonal juvenil,e processo para produzir um composto de cromeno |
| NL7513616A (en) * | 1975-11-21 | 1977-05-24 | Beecham Group Ltd | (Thio)chroman and tetralin basic ethers - with anorexigenic and antidepressant activity |
| JPS5424895A (en) * | 1977-07-28 | 1979-02-24 | Eisai Co Ltd | Pyranochromone derivatives and remedies for allergic disorder |
| JPS5540637A (en) * | 1978-09-19 | 1980-03-22 | Mitsui Petrochem Ind Ltd | Preparation of chromene |
| US4162326A (en) * | 1978-09-27 | 1979-07-24 | Stauffer Chemical Company | Insect control agents |
| JPS565475A (en) * | 1979-06-27 | 1981-01-20 | Mitsui Petrochem Ind Ltd | Polyalkyl-7-hydroxy-4h-chromene and its preparation |
| JPS57109779A (en) * | 1980-12-27 | 1982-07-08 | Kumiai Chem Ind Co Ltd | Polyalkyl-5-hydroxy-2h-chromene and its preparation |
-
1983
- 1983-02-15 HU HU83504A patent/HU194214B/hu not_active IP Right Cessation
-
1984
- 1984-01-13 CS CS841011A patent/CS261865B2/cs unknown
- 1984-02-10 IL IL70926A patent/IL70926A/xx unknown
- 1984-02-14 FI FI840585A patent/FI840585A7/fi not_active Application Discontinuation
- 1984-02-14 SU SU843703452A patent/SU1468418A3/ru active
- 1984-02-14 DD DD84260074A patent/DD219363A5/de not_active IP Right Cessation
- 1984-02-14 US US06/580,097 patent/US4716238A/en not_active Expired - Fee Related
- 1984-02-15 AU AU24601/84A patent/AU580729B2/en not_active Ceased
- 1984-02-15 DE DE8484101540T patent/DE3469299D1/de not_active Expired
- 1984-02-15 DK DK70284A patent/DK70284A/da not_active Application Discontinuation
- 1984-02-15 AT AT84101540T patent/ATE32461T1/de not_active IP Right Cessation
- 1984-02-15 PT PT78110A patent/PT78110B/pt not_active IP Right Cessation
- 1984-02-15 ES ES529746A patent/ES8700855A1/es not_active Expired
- 1984-02-15 EP EP86107710A patent/EP0208147A3/de not_active Ceased
- 1984-02-15 PL PL24622684A patent/PL246226A1/xx unknown
- 1984-02-15 JP JP59026912A patent/JPS59210077A/ja active Pending
- 1984-02-15 EP EP84101540A patent/EP0118794B1/de not_active Expired
-
1986
- 1986-01-31 ES ES551816A patent/ES8708112A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| PT78110B (en) | 1986-04-30 |
| EP0118794B1 (de) | 1988-02-10 |
| DK70284A (da) | 1984-08-16 |
| EP0208147A2 (de) | 1987-01-14 |
| ATE32461T1 (de) | 1988-02-15 |
| PT78110A (en) | 1984-03-01 |
| IL70926A (en) | 1989-08-15 |
| DE3469299D1 (de) | 1988-03-17 |
| ES8708112A1 (es) | 1987-10-16 |
| FI840585A0 (fi) | 1984-02-14 |
| US4716238A (en) | 1987-12-29 |
| EP0208147A3 (de) | 1987-11-04 |
| IL70926A0 (en) | 1984-05-31 |
| AU580729B2 (en) | 1989-02-02 |
| ES529746A0 (es) | 1986-11-16 |
| FI840585A7 (fi) | 1984-08-16 |
| PL246226A1 (en) | 1985-07-30 |
| AU2460184A (en) | 1984-08-23 |
| CS101184A2 (en) | 1988-07-15 |
| DK70284D0 (da) | 1984-02-15 |
| HU194214B (en) | 1988-01-28 |
| JPS59210077A (ja) | 1984-11-28 |
| EP0118794A1 (de) | 1984-09-19 |
| SU1468418A3 (ru) | 1989-03-23 |
| CS261865B2 (en) | 1989-02-10 |
| DD219363A5 (de) | 1985-03-06 |
| ES8700855A1 (es) | 1986-11-16 |
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| Date | Code | Title | Description |
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| FD1A | Patent lapsed |
Effective date: 19970303 |