ES479139A1 - Un procedimiento mejorado para separar parafinas normales de una mezcla con parafinas no normales. - Google Patents
Un procedimiento mejorado para separar parafinas normales de una mezcla con parafinas no normales.Info
- Publication number
- ES479139A1 ES479139A1 ES479139A ES479139A ES479139A1 ES 479139 A1 ES479139 A1 ES 479139A1 ES 479139 A ES479139 A ES 479139A ES 479139 A ES479139 A ES 479139A ES 479139 A1 ES479139 A1 ES 479139A1
- Authority
- ES
- Spain
- Prior art keywords
- adsorption
- vapor phase
- feedstock
- bed
- normal paraffins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000926 separation method Methods 0.000 title 1
- 238000010926 purge Methods 0.000 abstract 3
- 238000001179 sorption measurement Methods 0.000 abstract 3
- 239000012808 vapor phase Substances 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 2
- 239000011800 void material Substances 0.000 abstract 2
- 239000003463 adsorbent Substances 0.000 abstract 1
- 238000003795 desorption Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
- C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
- C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Separation Of Gases By Adsorption (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Un procedimiento mejorado para separar parafinas normales de una mezcla con parafinas no normales, que comprende pasar una mezcla de material de alimentación de las mismas, en estado de vapor y a presión superior a la atmosférica. Periódicamente en secuencia a través de al menos cuatro lechos fijos de un sistema que contiene como adsorbente un tamiz molecular zeolítico que tiene diámetros efectivos de poro de sustancialmente 5 Angströms.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/892,334 US4176053A (en) | 1978-03-31 | 1978-03-31 | n-Paraffin - isoparaffin separation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES479139A1 true ES479139A1 (es) | 1980-01-01 |
Family
ID=25399808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES479139A Expired ES479139A1 (es) | 1978-03-31 | 1979-03-30 | Un procedimiento mejorado para separar parafinas normales de una mezcla con parafinas no normales. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4176053A (es) |
| EP (1) | EP0004619B1 (es) |
| JP (1) | JPS54154702A (es) |
| AT (1) | AT371096B (es) |
| BR (1) | BR7901939A (es) |
| CA (1) | CA1124187A (es) |
| DE (1) | DE2961853D1 (es) |
| ES (1) | ES479139A1 (es) |
| IN (1) | IN151100B (es) |
| MX (1) | MX153160A (es) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4309281A (en) * | 1979-12-19 | 1982-01-05 | Mobil Oil Corporation | Selective sorption by zeolites |
| US4358367A (en) * | 1980-07-07 | 1982-11-09 | Shell Oil Company | Adsorption process |
| US4359380A (en) * | 1980-08-29 | 1982-11-16 | Shell Oil Company | Adsorption process |
| US4354929A (en) * | 1980-09-30 | 1982-10-19 | Union Carbide Corporation | Process for separating normal paraffins from hydrocarbons mixtures |
| US4350583A (en) * | 1980-09-30 | 1982-09-21 | Union Carbide Corporation | Isobaric process for separating normal paraffins from hydrocarbon mixtures |
| US4374022A (en) * | 1980-09-30 | 1983-02-15 | Union Carbide Corporation | Constant pressure separation of normal paraffins from hydrocarbon mixtures |
| FR2496486B1 (fr) * | 1980-12-19 | 1985-10-11 | Elf Aquitaine | Perfectionnement au procede de separation d'un melange gazeux par utilisation d'un adsorbant selectif rapide ameliore |
| US4350501A (en) * | 1981-03-27 | 1982-09-21 | Shell Oil Company | Absorption process |
| US4529415A (en) * | 1982-09-07 | 1985-07-16 | Leslie Szirmay | Gaseous separation apparatus and process |
| US4476345A (en) * | 1982-10-14 | 1984-10-09 | Union Carbide Corporation | N-Paraffin-isoparaffin separation process using wash of recycle purge gas |
| US4436533A (en) | 1982-12-02 | 1984-03-13 | Shell Oil Company | Adsorption process |
| US4595490A (en) * | 1985-04-01 | 1986-06-17 | Union Carbide Corporation | Processing of high normal paraffin concentration naphtha feedstocks |
| US4608061A (en) * | 1985-06-28 | 1986-08-26 | Union Carbide Corporation | Normal butane/iso-butane separation |
| GB8526812D0 (en) * | 1985-10-31 | 1985-12-04 | Shell Int Research | Separating branch-from unbranched hydrocarbons |
| US4717784A (en) * | 1986-12-10 | 1988-01-05 | Shell Oil Company | Total isomerization process with mono-methyl-branched plus normal paraffin recycle stream |
| US4804802A (en) * | 1988-01-25 | 1989-02-14 | Shell Oil Company | Isomerization process with recycle of mono-methyl-branched paraffins and normal paraffins |
| US4899016A (en) * | 1988-02-11 | 1990-02-06 | Uop | Purification process for organic feedstocks |
| US4855529A (en) * | 1988-04-25 | 1989-08-08 | Shell Oil Company | Isomerization process with preliminary normal paraffin and mono-methyl paraffin feed capture step |
| US4982048A (en) * | 1989-02-24 | 1991-01-01 | Shell Oil Company | Isomerization process with preliminary normal paraffin and mono-methyl paraffin feed capture step |
| US5145815A (en) * | 1989-08-10 | 1992-09-08 | Uop | Regeneration of zeolitic molecular sieves with sulfur oxide absorption on soda-lime bed |
| US5041693A (en) * | 1989-08-10 | 1991-08-20 | Uop | Separation of normal paraffins and the regeneration of zeolitic molecular sieves used therein |
| US5026482A (en) * | 1989-09-26 | 1991-06-25 | Air Products And Chemicals, Inc. | Separation of liquid mixtures by concentration swing adsorption |
| US5292987A (en) * | 1990-08-23 | 1994-03-08 | Uop | Hydrocarbon adsorption and isomerization process |
| US5059741A (en) * | 1991-01-29 | 1991-10-22 | Shell Oil Company | C5/C6 isomerization process |
| GB9109747D0 (en) † | 1991-05-07 | 1991-06-26 | Shell Int Research | A process for the production of isoparaffins |
| FR2751641B1 (fr) * | 1996-07-26 | 1998-09-11 | Inst Francais Du Petrole | Procede de separation isoalcanes/n-alcanes par adsorption en phase gazeuse utilisant une modulation de pression et quatre adsorbeurs |
| FR2813311B1 (fr) * | 2000-08-25 | 2002-11-29 | Inst Francais Du Petrole | Procede associant hydroisomerisation et separation avec un absorbant zeolithique a structure mixte pour la production d'essences a haut indices d'octane |
| US7122496B2 (en) * | 2003-05-01 | 2006-10-17 | Bp Corporation North America Inc. | Para-xylene selective adsorbent compositions and methods |
| US7271305B2 (en) * | 2003-05-01 | 2007-09-18 | Bp Corporation North America Inc. | Method of obtaining para-xylene |
| US20090156876A1 (en) * | 2007-12-18 | 2009-06-18 | Ou John D Y | Apparatus and Process for Cracking Hydrocarbonaceous Feed Treated to Adsorb Paraffin-Insoluble Compounds |
| US8053620B2 (en) * | 2008-06-30 | 2011-11-08 | Uop Llc | Guard bed for removing contaminants from feedstock to a normal paraffin extraction unit |
| US9321971B2 (en) | 2009-06-17 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Removal of asphaltene contaminants from hydrocarbon streams using carbon based adsorbents |
| US20210277316A1 (en) * | 2020-03-07 | 2021-09-09 | Uop Llc | Process for increasing the concentration of normal hydrocarbons in a stream |
| CN112391198B (zh) * | 2020-10-30 | 2022-04-01 | 中国科学院山西煤炭化学研究所 | 一种连续分离高纯正构烷烃的方法 |
| US11807818B2 (en) | 2021-01-07 | 2023-11-07 | Saudi Arabian Oil Company | Integrated FCC and aromatic recovery complex to boost BTX and light olefin production |
| US11473022B2 (en) | 2021-01-07 | 2022-10-18 | Saudi Arabian Oil Company | Distillate hydrocracking process with an n-paraffins separation step to produce a high octane number isomerate stream and a steam pyrolysis feedstock |
| US11820949B2 (en) | 2021-01-15 | 2023-11-21 | Saudi Arabian Oil Company | Apparatus and process for the enhanced production of aromatic compounds |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3373103A (en) * | 1966-02-01 | 1968-03-12 | Texaco Inc | N-hydrocarbon separation with a molecular sieve |
| US3393097A (en) * | 1966-07-29 | 1968-07-16 | Dow Chemical Co | Primary cell having a folded magnesium anode |
| US3700589A (en) * | 1970-09-14 | 1972-10-24 | Union Carbide Corp | Isoparaffin-n-paraffin separation process |
| US3770621A (en) * | 1971-12-22 | 1973-11-06 | Union Carbide Corp | Hydrocarbon separation using a selective adsorption process with purge gas conservation |
| CA1064056A (en) * | 1974-05-16 | 1979-10-09 | Union Carbide Corporation | Hydrocarbon separation and isomerization process |
-
1978
- 1978-03-31 US US05/892,334 patent/US4176053A/en not_active Expired - Lifetime
-
1979
- 1979-03-20 CA CA323,869A patent/CA1124187A/en not_active Expired
- 1979-03-24 DE DE7979100897T patent/DE2961853D1/de not_active Expired
- 1979-03-24 EP EP79100897A patent/EP0004619B1/en not_active Expired
- 1979-03-30 IN IN212/DEL/79A patent/IN151100B/en unknown
- 1979-03-30 JP JP3715179A patent/JPS54154702A/ja active Granted
- 1979-03-30 ES ES479139A patent/ES479139A1/es not_active Expired
- 1979-03-30 BR BR7901939A patent/BR7901939A/pt unknown
- 1979-03-30 MX MX177135A patent/MX153160A/es unknown
- 1979-04-02 AT AT0243979A patent/AT371096B/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA1124187A (en) | 1982-05-25 |
| US4176053A (en) | 1979-11-27 |
| AT371096B (de) | 1983-05-25 |
| JPH0141129B2 (es) | 1989-09-04 |
| BR7901939A (pt) | 1979-10-23 |
| IN151100B (es) | 1983-02-19 |
| EP0004619B1 (en) | 1982-01-20 |
| MX153160A (es) | 1986-08-14 |
| JPS54154702A (en) | 1979-12-06 |
| DE2961853D1 (de) | 1982-03-04 |
| ATA243979A (de) | 1982-10-15 |
| EP0004619A1 (en) | 1979-10-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19970519 |