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ES450666A1 - A PROCEDURE FOR THE PREPARATION OF THE NEW DERIVATIVES OF AMINOMETILBENZOCICLOHEPTENO. - Google Patents

A PROCEDURE FOR THE PREPARATION OF THE NEW DERIVATIVES OF AMINOMETILBENZOCICLOHEPTENO.

Info

Publication number
ES450666A1
ES450666A1 ES450666A ES450666A ES450666A1 ES 450666 A1 ES450666 A1 ES 450666A1 ES 450666 A ES450666 A ES 450666A ES 450666 A ES450666 A ES 450666A ES 450666 A1 ES450666 A1 ES 450666A1
Authority
ES
Spain
Prior art keywords
radical
hydrogen atom
formula
carbon
atom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES450666A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Publication of ES450666A1 publication Critical patent/ES450666A1/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D317/00Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/72Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 spiro-condensed with carbocyclic rings
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P25/00Drugs for disorders of the nervous system
    • A61P25/24Antidepressants
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P25/00Drugs for disorders of the nervous system
    • A61P25/26Psychostimulants, e.g. nicotine, cocaine

Landscapes

  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Neurosurgery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Neurology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Psychiatry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Biomedical Technology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Pain & Pain Management (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

A process for the preparation of the new aminomethylbenzocyclheptene derivatives, as well as their addition salts with mineral or organic acids, said derivatives responding to general formula I: **(See formula)** where X represents a hydrogen atom or a halogen atom with the exception of fluorine, said halogen atom being in position 2 or 4 on the phenyl nucleus, R represents a hydrogen atom, an alcohol radical containing from 1 to 3 carbon atoms, a phenyl radical, if appropriate substituted by a fluorine or chlorine atom, a methyl or methoxy radical, a benzyl radical or R represents with Y a benzylidene radical, and represents a hydrogen atom or, with R, a benzylidene radical, or Y forms a carbon-carbon double bond with Z, Z represents a hydrogen atom or forms a carbon-carbon double bond with Y, R1 and R2, identical or different, represent a hydrogen atom or a methyl radical, it being understood that when R1 and R2 represent a hydrogen atom, R also represents a hydrogen atom, said process being characterized by the fact that a product of formula II is dehydrated: **(See formula)** in which X, R, R1 and R2 have the meaning already indicated, to obtain a product of the formula: **(See formula)** where X, R1 and R2 have the meaning indicated above, R represents a hydrogen atom, an alcohol radical containing from 1 to 3 carbon atoms, a phenyl radical, if appropriate substituted by a fluorine atom or chlorine, a methyl or methoxy radical, a benzyl radical, or R represents with Y'a benzylidene radical, Y' represents with R a benzylidene radical or forms with Z'a carbon-carbon double bond, Z' represents a hydrogen atom or forms with Y'a carbon-carbon double bond, and by the fact that either the latter is isolated and, if desired, salified, or said product of formula I' is reduced to obtain the product of formula: **(See formula)** where X, R, R1 and R2 have the meaning already indicated, after which the latter is isolated and, if desired, salified. (Machine-translation by Google Translate, not legally binding)
ES450666A 1975-08-14 1976-08-13 A PROCEDURE FOR THE PREPARATION OF THE NEW DERIVATIVES OF AMINOMETILBENZOCICLOHEPTENO. Expired ES450666A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7525398A FR2320734A1 (en) 1975-08-14 1975-08-14 NEW DERIVATIVES OF AMINOMETHYL BENZOCYCLOHEPTENE AND THEIR SALTS, METHOD OF PREPARATION AND APPLICATION AS MEDICINAL PRODUCTS OF THESE PRODUCTS

Publications (1)

Publication Number Publication Date
ES450666A1 true ES450666A1 (en) 1977-07-16

Family

ID=9159099

Family Applications (1)

Application Number Title Priority Date Filing Date
ES450666A Expired ES450666A1 (en) 1975-08-14 1976-08-13 A PROCEDURE FOR THE PREPARATION OF THE NEW DERIVATIVES OF AMINOMETILBENZOCICLOHEPTENO.

Country Status (17)

Country Link
JP (1) JPS5223061A (en)
AT (1) AT348979B (en)
AU (1) AU504224B2 (en)
BE (1) BE845189A (en)
DD (1) DD126265A5 (en)
DE (1) DE2636432A1 (en)
DK (1) DK365676A (en)
ES (1) ES450666A1 (en)
FI (1) FI762280A7 (en)
FR (1) FR2320734A1 (en)
GB (1) GB1520579A (en)
IL (1) IL50179A (en)
LU (1) LU75604A1 (en)
NL (1) NL7609090A (en)
PT (1) PT65474B (en)
SE (1) SE7609041L (en)
ZA (1) ZA764669B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7429681B2 (en) 2005-06-14 2008-09-30 Baylor University Combretastatin analogs with tubulin binding activity

Also Published As

Publication number Publication date
ATA605876A (en) 1978-08-15
JPS5223061A (en) 1977-02-21
FR2320734A1 (en) 1977-03-11
FI762280A7 (en) 1977-02-15
ZA764669B (en) 1977-09-28
IL50179A (en) 1979-10-31
PT65474A (en) 1976-09-01
LU75604A1 (en) 1977-04-21
PT65474B (en) 1978-07-04
IL50179A0 (en) 1976-09-30
DD126265A5 (en) 1977-07-06
DK365676A (en) 1977-02-15
BE845189A (en) 1977-02-14
AU504224B2 (en) 1979-10-04
FR2320734B1 (en) 1979-01-05
AT348979B (en) 1979-03-12
AU1683876A (en) 1978-02-16
GB1520579A (en) 1978-08-09
NL7609090A (en) 1977-02-16
DE2636432A1 (en) 1977-02-24
SE7609041L (en) 1977-02-15

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