ES456011A1 - Un metodo mejorado para preparar polimeros biologicamente activos. - Google Patents
Un metodo mejorado para preparar polimeros biologicamente activos.Info
- Publication number
- ES456011A1 ES456011A1 ES456011A ES456011A ES456011A1 ES 456011 A1 ES456011 A1 ES 456011A1 ES 456011 A ES456011 A ES 456011A ES 456011 A ES456011 A ES 456011A ES 456011 A1 ES456011 A1 ES 456011A1
- Authority
- ES
- Spain
- Prior art keywords
- biologically active
- triorganotin
- acrylates
- active copolymers
- copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 title 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 239000003139 biocide Substances 0.000 abstract 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1637—Macromolecular compounds
- C09D5/1643—Macromolecular compounds containing tin
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Cephalosporin Compounds (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
Un método mejorado para preparar polímeros biológicamente activos por reacción de al menos un compuesto de triorganoestaño solubilizado de la fórmula general: **(Fórmula)** con al menos un manómetro solubilizado de la fórmula general. A una temperatura comprendida entre 50 y 100 ºC y en presencia de un disolvente orgánico para los monómeros y de una cantidad efectiva de un iniciador de polimerización de radical libre, donde R1 representa un radical alcohilo que contiene de 1 a 8 átomos de carbono, un radical ciclohexilo o un radical fenilo, R2 y R4 se seleccionan individualmente de entre hidrógeno y radicales metilo, y R3 representa un radical alcohilo que contiene de 1 a 18 átomos de carbono, un radical ciclohexilo o un radical fenilo, en el que la mejora consiste en hacer reaccionar dichos monómeros en un disolvente orgánico que contiene de 50 a 100% en volumen de al menos un hidrocarburo líquido alifático o cicloalifático que contiene de 5 a 16 átomos de carbono, estando constituida cualquier porción restante de dicho disolvente orgánico esencialmente por al menos un hidrocarburo aromático líquido.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/720,950 US4064338A (en) | 1976-09-07 | 1976-09-07 | Method for preparing biologically active copolymers of triorganotin acrylates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES456011A1 true ES456011A1 (es) | 1978-02-01 |
Family
ID=24895904
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES456011A Expired ES456011A1 (es) | 1976-09-07 | 1977-02-17 | Un metodo mejorado para preparar polimeros biologicamente activos. |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US4064338A (es) |
| JP (1) | JPS5331789A (es) |
| AU (1) | AU504779B2 (es) |
| BE (1) | BE850702A (es) |
| BR (1) | BR7701168A (es) |
| CA (1) | CA1085548A (es) |
| DE (1) | DE2705440C2 (es) |
| DK (1) | DK151344C (es) |
| ES (1) | ES456011A1 (es) |
| FR (1) | FR2363589A1 (es) |
| GB (1) | GB1516965A (es) |
| GR (1) | GR63132B (es) |
| IT (1) | IT1072376B (es) |
| MX (1) | MX4261E (es) |
| NL (1) | NL185285C (es) |
| NO (1) | NO146204C (es) |
| NZ (1) | NZ183340A (es) |
| PL (1) | PL102361B1 (es) |
| PT (1) | PT66148A (es) |
| SE (1) | SE425499B (es) |
| YU (1) | YU51677A (es) |
| ZA (1) | ZA77617B (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5430226A (en) * | 1977-08-10 | 1979-03-06 | Chugoku Marine Paints | Antifouling agent for foullproof coating material |
| US4174339A (en) * | 1977-11-18 | 1979-11-13 | Chugoku Marine Paints Ltd. | Anti-fouling paint composition |
| US4344875A (en) * | 1981-06-26 | 1982-08-17 | The United States Of America As Represented By The Secretary Of The Navy | Organotin antifouling coating with epoxy and polyacrylate compositions |
| FR2508915B1 (fr) * | 1981-07-03 | 1985-10-18 | France Etat | Telomeres organometalliques, procedes de preparation et compositions biocides obtenues |
| JPS59142263A (ja) * | 1983-02-03 | 1984-08-15 | Chugoku Toryo Kk | 防汚塗料 |
| US4532269A (en) * | 1984-03-23 | 1985-07-30 | M&T Chemicals Inc. | Erodible terpolymer from tributyl tin acrylate or methacrylate and paints for fouling control |
| US4524190A (en) * | 1984-05-14 | 1985-06-18 | The United States Of America As Represented By The Secretary Of The Navy | Process for preparation of cross-linked poly(tri-n-butyltin)methacrylate with simultaneous particle size reduction |
| US4670481A (en) * | 1986-02-14 | 1987-06-02 | Ameron, Inc. | Organotin acrylate and organotin polysiloxane antifouling coating composition |
| DE3901073A1 (de) * | 1989-01-16 | 1990-07-19 | Basf Ag | Betondachstein |
| JP2664974B2 (ja) * | 1989-01-27 | 1997-10-22 | 東芝シリコーン株式会社 | 徐溶性コーティング材用ビヒクル |
| WO2014053984A1 (en) | 2012-10-01 | 2014-04-10 | Geco Technology B.V. | Solid marine seismic streamers |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3016369A (en) * | 1958-07-16 | 1962-01-09 | Juan C Montermoso | Organotin acrylic polymers |
| NL127801C (es) * | 1960-06-06 | 1900-01-01 | ||
| BE637090A (es) * | 1963-01-03 | 1900-01-01 | ||
| GB1124297A (en) * | 1964-10-29 | 1968-08-21 | Internat Paints Ltd | Improved anti-fouling composition |
| US3555148A (en) * | 1965-10-20 | 1971-01-12 | Nitto Kasei Co Ltd | Fungicides |
-
1976
- 1976-09-07 US US05/720,950 patent/US4064338A/en not_active Expired - Lifetime
-
1977
- 1977-01-24 BE BE174340A patent/BE850702A/xx not_active IP Right Cessation
- 1977-01-25 FR FR7702001A patent/FR2363589A1/fr active Granted
- 1977-02-03 ZA ZA770617A patent/ZA77617B/xx unknown
- 1977-02-03 PT PT66148A patent/PT66148A/pt unknown
- 1977-02-04 MX MX775410U patent/MX4261E/es unknown
- 1977-02-09 DE DE2705440A patent/DE2705440C2/de not_active Expired
- 1977-02-10 DK DK056477A patent/DK151344C/da not_active IP Right Cessation
- 1977-02-11 IT IT09334/77A patent/IT1072376B/it active
- 1977-02-14 GB GB6014/77A patent/GB1516965A/en not_active Expired
- 1977-02-15 PL PL1977196008A patent/PL102361B1/pl unknown
- 1977-02-15 AU AU22283/77A patent/AU504779B2/en not_active Expired
- 1977-02-15 NZ NZ183340A patent/NZ183340A/xx unknown
- 1977-02-17 NL NLAANVRAGE7701694,A patent/NL185285C/xx not_active IP Right Cessation
- 1977-02-17 ES ES456011A patent/ES456011A1/es not_active Expired
- 1977-02-21 SE SE7701894A patent/SE425499B/xx not_active IP Right Cessation
- 1977-02-21 CA CA272,151A patent/CA1085548A/en not_active Expired
- 1977-02-24 YU YU00516/77A patent/YU51677A/xx unknown
- 1977-02-25 BR BR7701168A patent/BR7701168A/pt unknown
- 1977-02-25 NO NO770643A patent/NO146204C/no unknown
- 1977-02-28 JP JP2040277A patent/JPS5331789A/ja active Granted
- 1977-05-27 GR GR53569A patent/GR63132B/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA77617B (en) | 1977-12-28 |
| FR2363589A1 (fr) | 1978-03-31 |
| NO770643L (no) | 1978-03-08 |
| IT1072376B (it) | 1985-04-10 |
| FR2363589B1 (es) | 1980-09-26 |
| DE2705440A1 (de) | 1978-03-09 |
| CA1085548A (en) | 1980-09-09 |
| PT66148A (en) | 1977-03-01 |
| JPS5739250B2 (es) | 1982-08-20 |
| BE850702A (fr) | 1977-05-16 |
| GR63132B (en) | 1979-09-17 |
| JPS5331789A (en) | 1978-03-25 |
| NL185285B (nl) | 1989-10-02 |
| DE2705440C2 (de) | 1986-10-30 |
| YU51677A (en) | 1982-05-31 |
| MX4261E (es) | 1982-03-08 |
| NO146204B (no) | 1982-05-10 |
| SE425499B (sv) | 1982-10-04 |
| PL102361B1 (pl) | 1979-03-31 |
| BR7701168A (pt) | 1978-03-28 |
| PL196008A1 (pl) | 1978-03-13 |
| AU504779B2 (en) | 1979-10-25 |
| DK151344C (da) | 1988-06-27 |
| GB1516965A (en) | 1978-07-05 |
| NO146204C (no) | 1982-08-18 |
| NL7701694A (nl) | 1978-03-09 |
| AU2228377A (en) | 1978-08-24 |
| SE7701894L (sv) | 1978-03-08 |
| NZ183340A (en) | 1978-04-03 |
| US4064338A (en) | 1977-12-20 |
| DK56477A (da) | 1978-03-08 |
| NL185285C (nl) | 1990-03-01 |
| DK151344B (da) | 1987-11-23 |
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