ES407038A1 - Procedure of polymerization of a monomer in the presence of an organolitio initiator. (Machine-translation by Google Translate, not legally binding) - Google Patents
Procedure of polymerization of a monomer in the presence of an organolitio initiator. (Machine-translation by Google Translate, not legally binding)Info
- Publication number
- ES407038A1 ES407038A1 ES407038A ES407038A ES407038A1 ES 407038 A1 ES407038 A1 ES 407038A1 ES 407038 A ES407038 A ES 407038A ES 407038 A ES407038 A ES 407038A ES 407038 A1 ES407038 A1 ES 407038A1
- Authority
- ES
- Spain
- Prior art keywords
- monomer
- initiator
- translation
- polymerization
- machine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003999 initiator Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 239000000178 monomer Substances 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000007822 coupling agent Substances 0.000 abstract 2
- 125000001979 organolithium group Chemical group 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Abstract
Process for polymerizing a monomer in the presence of an organolithium initiator, the monomer being chosen from conjugated dienes containing 4 to 12 carbon atoms per molecule and monovinyl aromatic hydrocarbons having 8 to 20 carbon atoms per molecule, in the presence of an initiator of organolithium, adding a non-polymerizable coupling agent which reacts with the resulting lithium polymer to couple the corresponding polymer chains, a process characterized in that the coupling agent is added continuously or intermittently during the polymerization. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US19581071A | 1971-11-04 | 1971-11-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES407038A1 true ES407038A1 (en) | 1976-02-01 |
Family
ID=22722903
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES407038A Expired ES407038A1 (en) | 1971-11-04 | 1972-09-27 | Procedure of polymerization of a monomer in the presence of an organolitio initiator. (Machine-translation by Google Translate, not legally binding) |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS525071B2 (en) |
| BE (1) | BE790972A (en) |
| CA (1) | CA994495A (en) |
| ES (1) | ES407038A1 (en) |
| IT (1) | IT970097B (en) |
| ZA (1) | ZA726179B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4091198A (en) * | 1976-09-10 | 1978-05-23 | Phillips Petroleum Company | Suppressing gel in the continuous solution polymerization of a conjugated diene with a monovinyl aromatic compound |
| US4137391A (en) * | 1976-09-10 | 1979-01-30 | Phillips Petroleum Company | Continuous solution polymerization of a conjugated diene with a monovinylaromatic compound using alkoxysilicon treating agents in the first reactor means of a reactor series |
| JPS5540734A (en) * | 1978-09-18 | 1980-03-22 | Nippon Zeon Co Ltd | Controlling of mooney viscosity of polybutadiene |
| CN1105125C (en) * | 1997-11-27 | 2003-04-09 | 台橡股份有限公司 | Rubber for tire treads |
| TWI385182B (en) | 2004-03-15 | 2013-02-11 | Jsr Corp | Conjugated diene (co) poly rubber and method for producing the same |
| EP1783165B1 (en) | 2004-08-10 | 2011-10-19 | JSR Corporation | Rubber composition and tire |
| EP2003146B1 (en) * | 2006-03-31 | 2012-12-26 | Zeon Corporation | Use of a conjugated diene rubber for a tire |
| US8022129B2 (en) | 2007-03-15 | 2011-09-20 | Jsr Corporation | Conjugated diolefin copolymer rubber, method for producing the same, rubber composition and tire |
-
0
- BE BE790972D patent/BE790972A/en not_active IP Right Cessation
-
1972
- 1972-08-01 CA CA148,422A patent/CA994495A/en not_active Expired
- 1972-09-11 ZA ZA726179A patent/ZA726179B/en unknown
- 1972-09-27 ES ES407038A patent/ES407038A1/en not_active Expired
- 1972-10-18 JP JP47104346A patent/JPS525071B2/ja not_active Expired
- 1972-10-31 IT IT31148/72A patent/IT970097B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| CA994495A (en) | 1976-08-03 |
| ZA726179B (en) | 1973-06-27 |
| IT970097B (en) | 1974-04-10 |
| AU4671872A (en) | 1973-08-02 |
| BE790972A (en) | 1973-05-07 |
| JPS525071B2 (en) | 1977-02-09 |
| JPS4854188A (en) | 1973-07-30 |
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