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ES396404A1 - Terpene aryl ethers - Google Patents

Terpene aryl ethers

Info

Publication number
ES396404A1
ES396404A1 ES396404A ES396404A ES396404A1 ES 396404 A1 ES396404 A1 ES 396404A1 ES 396404 A ES396404 A ES 396404A ES 396404 A ES396404 A ES 396404A ES 396404 A1 ES396404 A1 ES 396404A1
Authority
ES
Spain
Prior art keywords
signify
alkaline
hydrogen
formula
propargiloxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES396404A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH1543670A external-priority patent/CH552943A/en
Priority claimed from CH1232171A external-priority patent/CH578834A5/en
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of ES396404A1 publication Critical patent/ES396404A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/84—Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/28—Ethers with hydroxy compounds containing oxirane rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Epoxy Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Procedure for the preparation of terpenaryl ethers of the formula ** (See formula) ** in which Z1 and Z2 signify a carbon-carbon bond or an oxygen bridge; R1 and R2 each signify methyl or ethyl; Z3 and Z4 together, signify a carbon-carbon bond; R3 signifies allyloxy, beta-chloroalyloxy, gammar-chloroalyloxy, propargyloxy, acetylamino, benzoyl, benzyl, phenoxy or (methylthio) -carbonyl and R4 represents hydrogen; O well R3 means hydrogen and R4 signifies propargiloxy; O well Z3 and Z4 each signify hydrogen, R3 means propargiloxy and R4 represents hydrogen; O well Z1, Z2, Z3 and Z4 each signify hydrogen, R3 means propargiloxy and R4 stands for hydrogen, characterized by reacting a halide of the formula ** (See formula) ** in which X stands for halogen (preferably chlorine or bromine), while R1 R2 and Z1 through Z4 have the same meaning as attributed to them earlier in this claim, with a phenol of the formula ** (See formula) ** in which R3 and R4 have the same meaning that has been attributed to them before, in a solvent (such as 1,2-dimethoxyethane, tetrahydrofuran, dioxane, dimethylformamide, dimethyl sulfoxide, sulfolane, or a dialkyl ether), in the presence of an acid acceptor (such as alkaline or alkaline-earth hydroxides, alkaline or alkaline earth carbonates, alkali alkoxides, or alkaline hydrides), stirring, at room temperature and optionally with consecutive heating, and reacting the product obtained, optionally, with an epoxidation agent (such as a peracid), in an indifferent solvent (such as a chlorinated hydrocarbon), at temperature between -10ºC and + 10ºC. (Machine-translation by Google Translate, not legally binding)
ES396404A 1970-10-20 1971-10-19 Terpene aryl ethers Expired ES396404A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH1543670A CH552943A (en) 1970-10-20 1970-10-20 SCHAEDLING INHIBITOR.
CH1232171A CH578834A5 (en) 1971-08-23 1971-08-23 Aryl ethers of terpene alcohols - insecticides acaricides, anthelmintics

Publications (1)

Publication Number Publication Date
ES396404A1 true ES396404A1 (en) 1975-05-16

Family

ID=25710058

Family Applications (1)

Application Number Title Priority Date Filing Date
ES396404A Expired ES396404A1 (en) 1970-10-20 1971-10-19 Terpene aryl ethers

Country Status (18)

Country Link
AR (1) AR195061A1 (en)
AT (2) AT316201B (en)
AU (2) AU3467471A (en)
BE (1) BE774132A (en)
BG (1) BG18572A3 (en)
BR (1) BR7106967D0 (en)
CA (1) CA982564A (en)
DE (1) DE2166152C3 (en)
EG (1) EG10661A (en)
ES (1) ES396404A1 (en)
FR (1) FR2111543A5 (en)
GB (2) GB1355575A (en)
HU (1) HU163849B (en)
IL (1) IL37921A (en)
IT (1) IT954177B (en)
NL (1) NL7114366A (en)
OA (1) OA03819A (en)
SE (1) SE384018B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL41744A0 (en) * 1972-03-16 1973-05-31 Ciba Geigy Ag New aryl ether derivatives,their production and their use as pesticides
DE3410543A1 (en) * 1984-03-22 1985-10-03 Basf Ag, 6700 Ludwigshafen NEW ESTERS, METHODS FOR THEIR PRODUCTION AND THEIR USE FOR CONTROLLING Pests

Also Published As

Publication number Publication date
NL7114366A (en) 1972-04-24
EG10661A (en) 1976-03-31
SE384018B (en) 1976-04-12
DE2144954B2 (en) 1977-03-24
BE774132A (en) 1972-04-12
AR195061A1 (en) 1973-09-10
CA982564A (en) 1976-01-27
DE2166152A1 (en) 1973-03-08
AT316201B (en) 1974-06-25
HU163849B (en) 1973-11-28
AU3467371A (en) 1973-04-19
AT316202B (en) 1974-05-15
DE2166152C3 (en) 1980-09-18
FR2111543A5 (en) 1972-06-02
GB1355575A (en) 1974-06-05
IL37921A (en) 1974-11-29
DE2144954A1 (en) 1972-04-27
AU465931B2 (en) 1975-10-09
BR7106967D0 (en) 1973-05-08
GB1356560A (en) 1974-06-12
OA03819A (en) 1971-12-24
IT954177B (en) 1973-08-30
AU3467471A (en) 1973-04-19
IL37921A0 (en) 1971-12-29
DE2166152B2 (en) 1980-02-07
BG18572A3 (en) 1975-02-25

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