ES363106A1 - Method of Recovering Fluorine from Carbonaceous Waste Material - Google Patents
Method of Recovering Fluorine from Carbonaceous Waste MaterialInfo
- Publication number
- ES363106A1 ES363106A1 ES363106A ES363106A ES363106A1 ES 363106 A1 ES363106 A1 ES 363106A1 ES 363106 A ES363106 A ES 363106A ES 363106 A ES363106 A ES 363106A ES 363106 A1 ES363106 A1 ES 363106A1
- Authority
- ES
- Spain
- Prior art keywords
- fluorine
- recovered
- carbonaceous material
- steam
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052731 fluorine Inorganic materials 0.000 title abstract 5
- 239000011737 fluorine Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 2
- 239000002699 waste material Substances 0.000 title abstract 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 title 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract 4
- 239000003575 carbonaceous material Substances 0.000 abstract 3
- 239000007789 gas Substances 0.000 abstract 3
- 239000003513 alkali Substances 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 229910001610 cryolite Inorganic materials 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/19—Fluorine; Hydrogen fluoride
- C01B7/20—Fluorine
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/19—Fluorine; Hydrogen fluoride
- C01B7/191—Hydrogen fluoride
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Treating Waste Gases (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
Fluorine is recovered from waste carbonaceous material, in the form of gaseous HF, by pyrohydrolysis in the presence of steam and air, the process being carried out continuously in a fluidized bed reactor to which solid carbonaceous material crushed to granular form is continuously added, the fluidizing gases being a mixture of air and steam. The preferred temperature is above 1100 C., and the fluidizing gases may be preheated in a heat exchanger. The heat demand comes either entirely from the combustion of the carbonaceous material or partly also from added fuel. The grain size is preferably below 10 mm. and the fluorine may be recovered from the off gas by washing with water or aqueous alkali. Disclosed is the recovery of fluorine from pot linings and pot rakings, scum and cyclone dust derived from the melt electrolytic production of aluminium. The fluorine recovered may be converted into cryolite and returned to the electrolysis.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO40668 | 1968-02-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES363106A1 true ES363106A1 (en) | 1970-11-16 |
Family
ID=19877580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES363106A Expired ES363106A1 (en) | 1968-02-01 | 1969-01-30 | Method of Recovering Fluorine from Carbonaceous Waste Material |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS4916719B1 (en) |
| AT (1) | AT290463B (en) |
| BE (1) | BE727690A (en) |
| BR (1) | BR6906065D0 (en) |
| CA (1) | CA922486A (en) |
| CH (1) | CH515849A (en) |
| DE (1) | DE1904391B2 (en) |
| ES (1) | ES363106A1 (en) |
| FR (1) | FR2001087A1 (en) |
| GB (1) | GB1183308A (en) |
| NL (1) | NL6901515A (en) |
| OA (1) | OA02987A (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2127910C3 (en) * | 1971-06-04 | 1984-08-02 | Vereinigte Aluminium-Werke AG, 1000 Berlin und 5300 Bonn | Process for the thermal remuneration of solids that are discharged from systems for the dry cleaning of exhaust gases from aluminum electrolysis furnaces and used as an insert for aluminum electrolysis |
| DD117428A1 (en) * | 1974-09-06 | 1976-01-12 | ||
| DE2928368A1 (en) * | 1979-07-13 | 1981-02-05 | Metallgesellschaft Ag | METHOD FOR PRODUCING HYDROFLUORINE |
| DE2942439C2 (en) * | 1979-10-20 | 1981-10-15 | Vereinigte Aluminium-Werke Ag, 5300 Bonn | Process and device for the production of hydrogen fluoride from fluorine-containing materials by pyrohydrolysis |
| RU2221739C1 (en) * | 2002-12-20 | 2004-01-20 | Закрытое акционерное общество "АСТОР ЭЛЕКТРОНИКС" | Fluorine production process |
| KR102165662B1 (en) | 2015-03-31 | 2020-10-14 | 가부시키가이샤 엔프라스 | Sockets for electrical contacts and electrical components |
| CN110173696B (en) * | 2019-06-10 | 2024-07-26 | 龙科天成(厦门)科技有限公司 | Electrolytic aluminum solid waste coupling type incineration treatment system and method |
| CN115591890A (en) * | 2021-07-10 | 2023-01-13 | 上海钰宣节能技术有限公司(Cn) | A method for harmless treatment of carbonaceous hazardous waste from aluminum electrolytic cells |
-
1968
- 1968-12-30 AT AT1268768A patent/AT290463B/en not_active IP Right Cessation
-
1969
- 1969-01-22 FR FR6901127A patent/FR2001087A1/fr not_active Withdrawn
- 1969-01-23 GB GB3888/69A patent/GB1183308A/en not_active Expired
- 1969-01-28 OA OA53494A patent/OA02987A/en unknown
- 1969-01-30 CH CH143969A patent/CH515849A/en not_active IP Right Cessation
- 1969-01-30 ES ES363106A patent/ES363106A1/en not_active Expired
- 1969-01-30 DE DE19691904391 patent/DE1904391B2/en active Pending
- 1969-01-30 NL NL6901515A patent/NL6901515A/xx unknown
- 1969-01-30 JP JP44006386A patent/JPS4916719B1/ja active Pending
- 1969-01-30 BE BE727690D patent/BE727690A/en not_active IP Right Cessation
- 1969-01-31 CA CA041700A patent/CA922486A/en not_active Expired
- 1969-01-31 BR BR206065/69A patent/BR6906065D0/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1183308A (en) | 1970-03-04 |
| AT290463B (en) | 1971-06-11 |
| BR6906065D0 (en) | 1973-01-02 |
| JPS4916719B1 (en) | 1974-04-24 |
| DE1904391B2 (en) | 1970-09-10 |
| CA922486A (en) | 1973-03-13 |
| OA02987A (en) | 1970-12-15 |
| BE727690A (en) | 1969-07-01 |
| CH515849A (en) | 1971-11-30 |
| DE1904391A1 (en) | 1969-09-18 |
| FR2001087A1 (en) | 1969-09-26 |
| NL6901515A (en) | 1969-08-05 |
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