ES2245585B1 - MICROENCAPSULATED INSECTICIATED FORMULATE ON A RESIN BASE, FOR APPLICATION IN PREPARATIONS AND EMULGENTS FOR THE CONTROL AND PREVENTION OF ARTROPODES, DIPTERS, REPLANTS, ACARIDS, ARACNIDS AND OTHER SPECIES. - Google Patents

Abstract

It is a microencapsulated formulation on a resin base for incorporation into paints, varnishes, gels and / or the like, for the control and prevention of arthropods comprising the formula: ** (Figure) ** This refers to the composition of a formulation microencapsulated resin-based insecticide (acrylic, vinyl or similar), controlled release in biodegradable polymers, used to attach to vehicles such as plastic paints, varnishes, gels and water or the like, after application (skin, contact, absorption and / or non-toxic flipping) arthropods (insects and mites) are controlled for a long time in all their states and biological cycles (egg, larva, nymph, and adult), interfering with their central nervous systems, and inhibiting the action of acetylcholinesterase enzymes.

Description

Formulated microencapsulated insecticide on a resin base, for application in preparations and emulsifiers, for the control and prevention of arthropods, dipterans, crawlers, accharides, arachnids and other species.

Formulated microencapsulated insecticide prepared in a resin base (Acrylic, Vinyl or similar), forming this microcapsules and microcrystals, for dilution and mixing in both water as in plastic paints, varnishes, gels or the like, which they form polymeric biodegradable microspheres that act in the control and prevention of arthropods and allergens in general (Insects, Mites and Arachnids).

Our formula responds to the formula:

Since Until Water 10% fifty% Insecticide-Acaricide 0.001% 18% Insecticide Organophosphorus 0.001% 18% Attractants protein 0.001% 18% Resin (Vinyl, Acrylic) 5% fifty% Stabilizers one% twenty% Preservatives one% twenty%

Where all percentages are by weight with respect to the total weight of the composition, being able to combine in any possible variation between them with the different percentages established.

On the other hand the existing compounds in Our formulation can be formulated at high concentrations which vary from 20% - 70% of the active substance. His presentation more frequent it will be in emulsifiable liquid with different types of solvents, (water and acrylic or vinyl resins). These presentations will be called concentrates emulsifiable

From where:

Insecticides Cherished can belong to: (N-methylbis (2,4Xyliminomethyl) amine), (1H 1,2,4-triazole), Isopropyl 4,4-dibromobenzylate), (Cihexatin, Tricyclohexyltin hydroxide), 3,6-bis (2-chlorophenyl) 1,2,4,5-tetrazine), (2,2,2-trichloro 1,1-bis 4-chlorophenylethanol), (2-sec butyl carbonate 4,6-dinitrophenyl and isopropyl), (4- (2- (4- (1,1-dimethylethyl) phenyl) ethoxy) quinazoline), (Terbutyl (E) -x- (1,3 dimethyl-5-phenoxypyridazol-4-yl methylenaminoxy) -p-toluate), (2-terbutyl 5- (4-ter butylbenzyl uncle) 4-chlorpyrididacin 3 (2h) -one), (Sulfite of 2- (4-tert-butylphenoxy) cyclohexyl and 2-inyl bow), (N- (4-terbutylbenzyl) 4-chloro 3-ethyl 1-methylpyrazole 5-carboximide), (4'-chlorophenyl 2,4,5-tetrachlorophenylsulfone).

Organophosphorus insecticides may belong to: (Mixture containing 80% of avermectin B-1a and 20% of avermectin B-1b), (0, S-dimethyl acetyl thiophosphoramidate, ((1RS) cis 3- (2,2- dichlorovinyl) 2,2-dimethyl cyclopropane α-cyano 3-phenoxybenzyl carboxylate), (((Dibutylamino) thio) 2,3-dihydro 2,2-dimethyl 7-benzofuranyl), (Cyromacina, N-cyclopropyl 1 , 3,5-Triazine 2,4,6-triamine), (Diethyl and 2-chloro 1- (2,4-dichlorophenyl) vinyl phosphate), (N-n4- (3-chloro 5-trifluoromethyl 2- pyridimyl oxy) 3,5-dichlorophenyl aminocarbonyl-2,6-difluorobenzamide), ((1R, 3R) 3- (2,2-dibromovinyl) 2,2-dimethyl cyclopropane carboxylate of (S) α-cyano 2-phenoxybenzyl), (0.0-diethyl and 0- (2-isopropyl 6-methyl 4-pyrimidinyl) thiophosphate), (0.0-dimethyl and S- (N-methylcarbamoyl) methyl dithiophosphate), (O, O thiophosphate -dimethyl and 0- (3-methyl 4-mitrophenyl), ((RS) 2,2,3,3-tetramethyl cyclopropane carboxylate of α-cyano 3-phenoxybenzyl), (0.0-dimethyl dithiophosphate and S- ( α-ethoxycarbonylbenzyl), (í- (6-chloro-3-pyridinyl) methyl-4,5-dihydro-N-nitro-1H-imidazol-2amine), (N - ((2,5-dichloro-4- (1,1) 2,3,3,3-hexafluoro-propoxyl) - (phenyl) amino) carbonyl) -2,6-difluoro-benzamide), (0.0-dimethyl diethyl phosphate and S- (3, 4-dihydro 4 oxo 1,2,4-benzotriazin 3-yl) methyl), (0.0-dimethyl and 0- (3,5,6-trichloro 2-pyruidyl) thiophosphate), (N- (methyl carbamoyloxy) ) S-methyl thioacetimidate), (Zn ** ion complex with manganese 1,2-ethylenebis (dithiocarbamate) or zinc and manganese ethylenebis dithiocarbamate), ((1R, 3S, 1'RS) -2,2- dimethyl-3- (1 ', 2', 2 ', 2'-tetrabromoethyl) cyclopropane-carboxylate of (S) -α-cyano- (3-phenoxybenzyl)) ...

Attractants Proteins may belong to: Methyl Eugenol, Cue-lure, Siglure, Medlure, Trimedlure, Gyplure, Disparlure, Butyl sórbalo, Methyl linolenato, PEP. Eugenol (7: 3), Lactone, Grandlure, Gossyplure, Hexalure, Z-9-DQA, Virdure, Qrfamone.

Resin they can be vinyl and acrylic emulsions or similar, with a maximum wealth of 12% purity.

The stabilizers will be used as usual in these cases as they are sodium benzoates, hexametaphosphates, sodium nitrites, among others.

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Solvents framed in the following families: Ethyl acetate, Dichloromethane, Chloroform, Acetonotril, Methanol, Ethanol opropylene glycol or the like.

The emulsifiers framed in the following families: Colloids hydrophilic polymers, ammonium or non-phonic surfactants, polyvinyl alcohol, polyvinylpyrrolidone, alginates, gelatin, methyl cellulose, hiroxyalkyl cellulose, polysorbate, the sapn, the licetina or similar.

Preservatives the usual ones will be used in these cases.

With respect to the other elements of the formulation such as dehodorizers and color polymeters those commonly known within a delusion will be used and water emulsion

This insecticidal formulation prepared in a resin base (Acrylic, Vinyl or similar) that form some microspheres with insecticidal compounds (active ingredients), these microspheres in synthesis are analogous spherical particles of the microcapsules but without clear distinction between core and wall, It has a monolithic structure prepared from materials biodegradable, has a great expert of transfer speed and degradative properties, where the active ingredients of their components and / or dildos agents are distributed through the matrix as a molecular or particle dispersion.

In their application they cause a release controlled of the active components in biodegradable polymers, which enables the release of its insecticidal components (pesticides) cutaneously, by contact and also by absorption and turn around Playing this a very important, effective function, durable, biodegradability, non-toxicity, biocompatibility and Respect for the environment, people and their environment.

So far, different methods of microspheres of different biodegradable polymers, but with drugs for consumption and medical or veterinary treatments via oral. Some micro type formulations are also known encapsulated, with generic and individual active materials in each case, Organophosphorus in each other with a specific IGR, but none that contain in its formulation various types of principles assets with different actions of action and control as is the case that concerns us and that this can be incorporated as a vehicle for control and protector in paints, varnishes or gels or similar.

Some products are also known as Paints and Varnishes with insecticidal powers whose patents are: EPO 871011308-2, 30-1-1987, Europe; USES: 2-21987, No. 0010300; and in other countries.

This insecticidal formulation prepared in a Resin base is an innovative product, designed to control and prevent, effective, multiple, non-toxic, durable and residual, without irritating or toxic effects to humans, or consumer and / or companion animals and specially designed as parasite controllers and vectors in general (arthropods), by the action of the stomach (by absorption) by cutaneous (contact) by inhalation (Snok choc) and by Inhibition (Channels of sodium) thereof.

It is a formulation to be attached, for use and application in plastic paint bases (acrylic, vinyl or similar), varnishes, gels, water and / or Similar vehicles against arthropod control and protection both indoors and outdoors.

It can also be attached as a product curative and preventive against wood pests and materials related to both constructive, mechanized and decorative types.

In particular it is an active product that acts against insects (arthropods in general) by: attraction, inhalation, contact and ingestion, amateur, systemic and absorption and inhibition of the sodium chain (ecetilcolinesterasa) of arthropod species (insects and mites).

It can act unilaterally as multiplied in the same way not only as a disinfectant, insecticide, acaricide, bactericide, fungicide, inhibitors, attractive sexual and protein pheromones made us facilitates a single application, getting a greater effectiveness, control and security of success.

This formulation to be attached has a excellent weather resistance and atmospheric agents in normal circumstances, in vehicles and recommended doses.

The active components of our formulated are framed within the latest generation insecticides, belonging to the families of the Pyrethroids, Organophosphates, Carbamates, Metomilos, (synthetic) referred to as systemic, petted, nematicides and as cholinesterase inhibitors and of non-systemic others acting as growth inhibitors of insects and protein and hormonal attractants.

The multiple action of the components incorporated into our formulation produce in insects alterations and deformations, due to its inhibition in the central nervous system of the Insect (Sodium channels), and of the Acetylcholinesterase enzyme, causing paralysis and subsequent death.

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For being a part of the active principles of formulated fat soluble, have the ability to penetrate the areas insect fats, which gives them death by effect immediate shock

This formulation to be annexed affects the eggs of infectious species or pests, and especially when these insects deposit said eggs in the parts treated with the same.

All the components of the formulation and / or invention are existing products in the market and can be acquired both as technical products (PAT) and formulated (%), They are commercially known and are available worldwide they are easily acquired by known commercial methods and established in each country.

All relevant tests have been performed of toxicity and effectiveness of the product with resounding successes in the different fields of research both in laboratories specialized and approved as in the many field works made with it.

Claims (6)

1. Formulated Micro encapsulated resin-based insecticide (Acrylic, Vinyl or similar) for application in preparations and emulsifiers, for the application of control and prevention of arthropods in general (Diptera, craters, acridids, and other species), characterized by the formula that includes the following: Since Until Water 10% fifty% Insecticide Acaricide (U.G) 0.001% 18% Insecticide Organophosphorus 0.001% 18% Attractants protein 0.001% 18% Resin (Vinyl, Acrylic) 5% fifty% Stabilizers one% twenty% Preservatives one% twenty% Where Acaricides can belong to: (N-methylbis (2,4Xyliminomethyl) amine), (1H 1,2,4-triazole), Isopropyl 4,4-dibromobenzylate), (Cihexatin, Tricyclohexyltin hydroxide), 3,6-bis (2-chlorophenyl) 1,2,4,5-tetrazine), (2,2,2-trichloro 1,1-bis 4-chlorophenylethanol), (2-sec butyl carbonate 4,6-dinitrophenyl and isopropyl), (4- (2- (4- (1,1-dimethylethyl) phenyl) ethoxy) quinazoline), (Terbutyl (E) -x- (1,3 dimethyl-5-phenoxypyridazol-4-yl methylenaminoxy) -p-toluate), (2-terbutyl 5- (4-ter butylbenzyl uncle) 4-chlorpyrididacin 3 (2h) -one), (Sulfate 2- (4-tert-butylphenoxy) cyclohexyl and bow 2-inflo), (N- (4-terbutylbenzyl) 4-chloro 3-ethyl 1-methylpyrazole 5-carboximide), (4'-chlorophenyl 2,4,5- and tetrachlorophenylsulfone). Where attractants can belong to: Methyl eugenol, Cue-lure, Siglure, Medlure, Trimedlure, Gyplure, Disparlure, Butyl sórbalo, Methyl linolenato, PEP Eugenol (7: 3), Lactone, Grandlure, Gossyplure, Hexalure, Z-9-DQA, Virdure, Qrfamone. Where the percentages are by weight with respect to total weight of the composition, being able to combine in any possible variation between them with the different percentages. 2. Formulated microencapsulated insecticide based Resin (Acrylic, Vinyl or similar) for application in preparations and emulsifiers, for the application of control and prevention of Arthropods in general (Diptera, crawlers, acarids, and others species) according to claim 1, wherein the Insecticides Organophosphates may belong to: (Mixture containing 80% avermectin B-1a and 20% avermectin B-1b), (acetyl thiophosphoramidate of O, S-dimethyl, ((1RS) cis 3- (2,2-dichlorovinyl) 2,2-dimethyl α-cyano cyclopropane carboxylate 3-pheoxybenzyl), (((Dibutylamino) thio) methylcarbamate of 2,3-dihydro 2,2-dimethyl 7-benzofuranyl), (Cyromacina, N-cyclopropyl 1,3,5-triazine 2,4,6-triamine), (Diethyl Phosphate and 2-chlorine 1- (2,4-dichlorophenyl) vinyl), (N-n4- (3-Chlorine 5-trifluoromethyl 2-pyridimyl oxy) 3,5-dichlorophenyl aminocarbonyl-2,6-difluorobenzamide), ((1R, 3R) 3- (2,2-dibromovinyl) 2,2-dimethyl  (S) α-cyano cyclopropane carboxylate 2-phenoxybenzyl), (Thiophosphate 0,0-diethyl and 0- (2-isopropyl 6-methyl 4-pyrimidinyl), (0.0-dimethyl dithiophosphate and S- (N-methylcarbamoyl) methyl), (Thiophosphate 0,0-dimethyl and O- (3-methyl 4-mitrophenyl), ((RS) 2,2,3,3-tetramethyl cyclopropane carboxylate α-cyano 3-phenoxybenzyl), (0.0-dimethyl dithiophosphate and S- (a-ethoxycarbonylbenzyl), (1- (6-Chloro-3-pyridinyl) methyl-4,5-dihydro-N-nitro-lH-imidazol-2amine), (N - ((2,5-di chloro-4- (1, l) 2,3,3,3-hexafluoro-propoxyl) - (phenyl) Not me) carbonyl) -2,6-difluoro-benzamide), (0.0-dimethyl diethyl phosphate and S- (3,4-dihydro 4 oxo 1,2,4-benzotriazin 3-yl) methyl), (Thiophosphate OO-dimethyl and O- (3,5,6-trichloro 2-pyruidyl), (N- (methyl carbamoyloxy) S-methyl thioacetimidate), (Zn ion complex ** with manganese 1,2-ethylenebis (dithiocarbamate) or zinc ethylene bis dithiocarbamate), ((IR, 3S, 1'RS) -2,2-dimethyl-3- (1 ', 2', 2 ', 2'-tetrabromoethyl) cyclopropane carboxylate (S) -? -Cyan- (3-phenoxybenzyl)). 3. Formulated micro encapsulated insecticide a Resin base (Acrylic, Vinyl or similar) for application in preparations and emulsifiers, for the application of control and prevention of Arthropods in general (Diptera, crawlers, acarids, and others species) according to claim 1, wherein the resin may be Vinyl and acrylic emulsions or similar, with a wealth 12% maximum purity. 4. Formulated Micro encapsulated resin-based insecticide (Acrylic, Vinyl or similar) for application in preparations and emulsifiers, for the application of control and prevention of arthropods in general (Diptera, crawlers, accharides, and other species) according to claim 1 , characterized by the micro encapsulation technique based on the physical-chemical characteristics of the polymer and the active ingredient to be encapsulated, taking into account the performance of micro spheres (with the desired size range), encapsulation efficiency (of the active substance), the biological activity (of the active substance), the release profile (adjusted by means of composition control and process variables) and the microspheres (they will be as thin as possible to facilitate their fluid). The properties of the microspheres are optimized by: Size and distribution, surface properties, load of active substance, release rate of the active substance and degradation rate of the matrix. 5. Formulated Micro encapsulated resin-based insecticide (Acrylic, Vinyl or similar) for application in preparations and emulsifiers, for the application of control and prevention of arthropods in general (Diptera, crawlers, accharides, and other species) according to claim 1 , characterized by microencapsulation by using the solvents framed in the following families: Ethyl acetate, Diclomethane, Chloroform, Acetonotril, Methanol, Ethanol or Propylene Glycol or the like. 6. Formulated Micro encapsulated resin-based insecticide (Acrylic, Vinyl or similar) for application in preparations and emulsifiers, for the application of control and prevention of arthropods in general (Diptera, crawlers, acridids, and other species), according to claim 1, characterized by the use of emulsifiers framed in the following families: Hydrophilic polymeric colloids, surfactants ammonium or non-phonic, polyvinyl alcohol, polyvinyl pyrrolidone, alginates, gelatin, methylcellulose, hiroxyalkylcellulose, polysorbate, sapn, licetin or Similar.