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ES2182544T3 - Oxidacion catalitica parcial por medio de dos metales de actividad catalitica. - Google Patents

Oxidacion catalitica parcial por medio de dos metales de actividad catalitica.

Info

Publication number
ES2182544T3
ES2182544T3 ES99931148T ES99931148T ES2182544T3 ES 2182544 T3 ES2182544 T3 ES 2182544T3 ES 99931148 T ES99931148 T ES 99931148T ES 99931148 T ES99931148 T ES 99931148T ES 2182544 T3 ES2182544 T3 ES 2182544T3
Authority
ES
Spain
Prior art keywords
layer
partial
metal
precursor
catalytic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99931148T
Other languages
English (en)
Inventor
Gerrit Jan Barend Assink
Hans Michiel Huisman
Gert Jan Kramer
Ronald Jan Schoonebeek
Wim Wieldraaijer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Application granted granted Critical
Publication of ES2182544T3 publication Critical patent/ES2182544T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/468—Iridium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1023—Catalysts in the form of a monolith or honeycomb
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C01B2203/107—Platinum catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un catalizador o precursor del mismo en forma de un arreglo fijo, en el que el arreglo fijo comprende: una primera capa que está situada, durante la operación normal, en un extremo corriente arriba del arreglo fijo y que comprende como metal catalíticamente activo o precursor del mismo rodio o un compuesto de rodio, y una segunda capa adyacente a la primera capa sin espacio intermedio alguno entre la primera y la segunda capa, que está situada, durante la operación normal, corriente abajo de la primera capa, comprendiendo la segunda capa como metal catalíticamente activo o precursor del mismo iridio, osmio o platino o un compuesto del mismo.
ES99931148T 1998-06-30 1999-06-23 Oxidacion catalitica parcial por medio de dos metales de actividad catalitica. Expired - Lifetime ES2182544T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP98305179 1998-06-30

Publications (1)

Publication Number Publication Date
ES2182544T3 true ES2182544T3 (es) 2003-03-01

Family

ID=8234902

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99931148T Expired - Lifetime ES2182544T3 (es) 1998-06-30 1999-06-23 Oxidacion catalitica parcial por medio de dos metales de actividad catalitica.

Country Status (19)

Country Link
US (1) US6702960B1 (es)
EP (2) EP1098840B1 (es)
JP (2) JP2002519181A (es)
KR (2) KR20010053268A (es)
CN (2) CN1307539A (es)
AT (2) ATE222214T1 (es)
AU (2) AU746783B2 (es)
BR (2) BR9911654A (es)
CA (2) CA2335970C (es)
CZ (1) CZ20004900A3 (es)
DE (2) DE69902547T2 (es)
DK (1) DK1098840T3 (es)
ES (1) ES2182544T3 (es)
ID (2) ID28037A (es)
NO (2) NO20006579L (es)
PL (2) PL345190A1 (es)
PT (1) PT1098840E (es)
WO (2) WO2000000425A1 (es)
ZA (2) ZA200100317B (es)

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EP1274650A1 (en) 2000-04-17 2003-01-15 Shell Internationale Researchmaatschappij B.V. Fuel processor
US6436363B1 (en) 2000-08-31 2002-08-20 Engelhard Corporation Process for generating hydrogen-rich gas
AU2002360576A1 (en) * 2001-12-18 2003-06-30 Conocophillips Company Catalyst for SPOC-enhanced synthesis gas production
JP3870783B2 (ja) 2001-12-27 2007-01-24 日産自動車株式会社 燃料電池自動車用排ガス浄化システムおよび燃料電池自動車の排ガスの浄化方法
AU2003291498A1 (en) * 2002-11-11 2005-06-08 Conocophillips Company Improved supports for high surface area catalysts
EP1569869A4 (en) 2002-11-11 2008-11-19 Conocophillips Co STABILIZED ALUMINUM OXIDE SUPPLEMENTS, Catalysts Produced Therefrom, and Their Use in Partial Oxidation
ITMI20031739A1 (it) * 2003-09-11 2005-03-12 Enitecnologie Spa Procedimento di ossidazione parziale catalitica per
DE102004024026A1 (de) * 2004-03-11 2005-09-29 W.C. Heraeus Gmbh Katalysator zur N2O-Zersetzung beim Ostwaldprozess
US20050202966A1 (en) * 2004-03-11 2005-09-15 W.C. Heraeus Gmbh Catalyst for the decomposition of N2O in the Ostwald process
JP4589682B2 (ja) * 2004-08-25 2010-12-01 千代田化工建設株式会社 合成ガス製造用触媒の調製方法
US7569512B2 (en) * 2004-11-10 2009-08-04 Umicore Ag & Co. Kg Zirconia support and zirconia supported catalyst
US20070111884A1 (en) * 2005-11-14 2007-05-17 Laiyuan Chen Catalyst support, supported catalyst, and methods of making and using the same
US20070238610A1 (en) * 2006-04-05 2007-10-11 Laiyuan Chen Fuel reformer catalyst
WO2008053006A1 (en) 2006-10-31 2008-05-08 Shell Internationale Research Maatschappij B.V. Process for the production of hydrogen and the use thereof and a process for the operation of a internal combustion engine
US20080260631A1 (en) * 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
BRPI0912167A2 (pt) * 2008-05-15 2019-09-24 Shell Int Research método para recuperar um gás natural
WO2012177137A1 (en) 2011-06-23 2012-12-27 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Process for producing ammonia and urea
WO2012177136A1 (en) 2011-06-23 2012-12-27 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Process for producing a syngas intermediate suitable for the production of hydrogen
EP2771275B1 (en) 2011-10-26 2019-07-24 Stamicarbon B.V. acting under the name of MT Innovation Center Method for producing synthesis gas for methanol production
EP2771274B1 (en) 2011-10-26 2018-01-31 Stamicarbon B.V. acting under the name of MT Innovation Center Method for producing synthesis gas for methanol production
WO2013095130A1 (en) 2011-12-19 2013-06-27 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Process for producing ammonia and urea
KR20150028329A (ko) * 2012-06-29 2015-03-13 바스프 에스이 이리듐-함유 활성 물질의 존재 하에서 탄화수소의 이산화탄소 개질을 위한 고압 공정
KR101865032B1 (ko) 2013-11-06 2018-06-07 와트 퓨얼 셀 코퍼레이션 액체 연료 cpox 개질장치-연료 전지 시스템, 및 전기 생산 방법
US9627701B2 (en) 2013-11-06 2017-04-18 Watt Fuel Cell Corp. Integrated gaseous fuel CPOX reformer and fuel cell systems, and methods of producing electricity
AU2014346961B2 (en) 2013-11-06 2017-09-28 Watt Fuel Cell Corp. Reformer with perovskite as structural component thereof
KR101832864B1 (ko) 2013-11-06 2018-02-27 와트 퓨얼 셀 코퍼레이션 기체 반응 매질 플로우 관리용 매니폴드를 가지는 화학 반응기
MX352220B (es) 2013-11-06 2017-11-15 WATT Fuel Cell Corp Reformadores de cpox de combustible gaseoso y métodos de reformación de cpox.
MX352227B (es) 2013-11-06 2017-11-15 WATT Fuel Cell Corp Reformadores cpox de combustible liquido y metodo de reformacion cpox.
EP2886514A1 (de) * 2013-12-20 2015-06-24 Basf Se Verfahren zur Reformierung von Gemischen aus Kohlenwasserstoffen und Kohlendioxid
JP5994808B2 (ja) 2014-03-05 2016-09-21 トヨタ自動車株式会社 排ガス浄化用触媒及びその製造方法
WO2016010416A1 (en) 2014-07-15 2016-01-21 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Method for revamping a urea production complex
EP3362405B1 (en) 2015-10-15 2022-11-02 Stamicarbon B.V. acting under the name of MT Innovation Center Process and production unit for the production of methanol
AU2019463001B2 (en) 2019-08-29 2023-08-17 Watt Fuel Cell Corp. Multi-tubular chemical reactor with igniter for initiation of gas phase exothermic reactions

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IT1238676B (it) * 1990-01-26 1993-09-01 Snam Progetti Sistema catalitico e procedimento per la produzione di gas di sintesi mediante reazione di reforming di idrocarubri leggeri con co2
JP3061399B2 (ja) * 1990-06-20 2000-07-10 株式会社日本触媒 ディーゼルエンジン排ガス浄化用触媒および浄化方法
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IT1272532B (it) * 1993-08-27 1997-06-23 Snam Progetti Processo di ossidazione parziale catalitica del gas naturale per ottenere gas di sintesi e formaldeide
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US5883138A (en) * 1997-04-25 1999-03-16 Exxon Research And Engineering Company Rapid injection catalytic partial oxidation process and apparatus for producing synthesis gas (law 562)

Also Published As

Publication number Publication date
EP1098840B1 (en) 2002-08-14
DK1098840T3 (da) 2002-12-09
CN1307539A (zh) 2001-08-08
EP1098840A1 (en) 2001-05-16
EP1093439A1 (en) 2001-04-25
CZ20004900A3 (cs) 2001-08-15
PL345181A1 (en) 2001-12-03
NO20006580L (no) 2000-12-21
PL345190A1 (en) 2001-12-03
DE69905467T2 (de) 2003-09-11
JP2002519182A (ja) 2002-07-02
KR20010053267A (ko) 2001-06-25
NO20006579D0 (no) 2000-12-21
DE69902547D1 (de) 2002-09-19
CA2335970A1 (en) 2000-01-06
EP1093439B1 (en) 2003-02-19
NO20006580D0 (no) 2000-12-21
AU746783B2 (en) 2002-05-02
ZA200100316B (en) 2001-08-29
AU4776299A (en) 2000-01-17
ATE232836T1 (de) 2003-03-15
AU743727B2 (en) 2002-01-31
NO20006579L (no) 2000-12-21
PT1098840E (pt) 2002-11-29
DE69905467D1 (de) 2003-03-27
ID27777A (id) 2001-04-26
US6702960B1 (en) 2004-03-09
JP2002519181A (ja) 2002-07-02
BR9911739A (pt) 2001-04-03
CA2335983A1 (en) 2000-01-06
WO2000000425A1 (en) 2000-01-06
CN1307538A (zh) 2001-08-08
KR20010053268A (ko) 2001-06-25
ZA200100317B (en) 2001-07-23
ATE222214T1 (de) 2002-08-15
WO2000000426A1 (en) 2000-01-06
BR9911654A (pt) 2001-03-20
CA2335970C (en) 2009-01-06
DE69902547T2 (de) 2003-05-22
ID28037A (id) 2001-05-03
AU4777699A (en) 2000-01-17

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