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ES2153291B1 - Procedimiento para la obtencion de esteres. - Google Patents

Procedimiento para la obtencion de esteres.

Info

Publication number
ES2153291B1
ES2153291B1 ES009801411A ES9801411A ES2153291B1 ES 2153291 B1 ES2153291 B1 ES 2153291B1 ES 009801411 A ES009801411 A ES 009801411A ES 9801411 A ES9801411 A ES 9801411A ES 2153291 B1 ES2153291 B1 ES 2153291B1
Authority
ES
Spain
Prior art keywords
ester
alcohol
mixture
reactive
inlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES009801411A
Other languages
English (en)
Other versions
ES2153291A1 (es
Inventor
Bernd Bessling
Jean Werner Knab
Rudiger Welker
Walter Disteldorf
Bern Lohe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of ES2153291A1 publication Critical patent/ES2153291A1/es
Application granted granted Critical
Publication of ES2153291B1 publication Critical patent/ES2153291B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/32—Packing elements in the form of grids or built-up elements for forming a unit or module inside the apparatus for mass or heat transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
    • B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00805—Details of the particulate material
    • B01J2208/00814—Details of the particulate material the particulate material being provides in prefilled containers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

Procedimiento para la obtención de ésteres a partir de alcohol y de ácido carboxílico mediante a) la alimentación de una mezcla, que comprende al menos alcohol y/o ácido carboxílico en forma de educto, en una columna de destilación que presenta secciones separadas, que comprenden inserciones reactivas y convencionales, estando dispuestas las inserciones reactivas por debajo de la entrada de la mezcla y las inserciones convencionales por encima de la entrada de la mezcla, b) la reacción del alcohol y del ácido carboxílico en las inserciones reactivas en presencia de un catalizador, c) la separación por destilación de las mezcla de la reacción en éster de elevado punto de ebullición y azeótropo de bajo punto de ebullición, que contiene alcohol, agua y éster, acumulándose el éster en la cola y el azeótropo es separado por la cabeza, d) la separación del azeótropo en un separador de fases en una fase acuosa y en una fase orgánica y la fase orgánica se envía de nuevo hasta la cabeza de la columna, utilizándose en la etapa b) un catalizador heterogéneo y en la etapa c) el éster es retirado por encima de la cola en forma de producto puro entre otras inserciones convencionales que difieren en su disposición de la de la etapa a) y que están dispuestas por encima de la entrada de un evaporador con circulación.
ES009801411A 1997-07-04 1998-07-03 Procedimiento para la obtencion de esteres. Expired - Fee Related ES2153291B1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19728683 1997-07-04

Publications (2)

Publication Number Publication Date
ES2153291A1 ES2153291A1 (es) 2001-02-16
ES2153291B1 true ES2153291B1 (es) 2001-07-01

Family

ID=7834698

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009801411A Expired - Fee Related ES2153291B1 (es) 1997-07-04 1998-07-03 Procedimiento para la obtencion de esteres.

Country Status (7)

Country Link
US (1) US6028215A (es)
JP (1) JP4390298B2 (es)
CN (1) CN1130329C (es)
BE (1) BE1014031A3 (es)
DE (1) DE19829809B4 (es)
ES (1) ES2153291B1 (es)
MY (1) MY124268A (es)

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WO1999048855A1 (en) * 1998-03-25 1999-09-30 Sulzer Chemtech Ag Process and apparatus for the production of butylacetate and isobutylacetate
DE19938980A1 (de) * 1999-08-19 2001-02-22 Basf Ag Verfahren zur Herstellung von 2-Keto-L-gulonsäureestern
CZ292620B6 (cs) 1999-10-14 2003-11-12 Sulzer Chemtech Ltd. Způsob výroby etylacetátu a zařízení k provádění tohoto způsobu
US6900360B2 (en) * 2000-02-04 2005-05-31 Daicel Chemical Industries, Ltd. High-purity 1,3-butylen glycol, process for producing 1,3-butylene glycol, and process for producing by-product butanol and butyl acetate
EP1300387A1 (de) * 2001-10-05 2003-04-09 Haltermann GmbH Verfahren zum Herstellen von Estern einer Hydroxysäure
DE10155241C1 (de) * 2001-11-09 2003-07-03 Gmk Ges Fuer Motoren Und Kraft Verfahren zur Herstellung von Kraftstoffen aus sauren Fetten und Anlage zu dessen Durchführung
ATE322499T1 (de) 2002-11-11 2006-04-15 Verfahren zur herstellung von 2-keto-l-gulonsäure-c-4 c-10 /sb -alkylestern
TWI324592B (en) 2002-11-28 2010-05-11 Sulzer Chemtech Ag A method for the esterification of a fatty acid
EP1424115B1 (de) * 2002-11-28 2016-01-13 Sulzer Chemtech AG Verfahren zum Verestern einer Fettsäure
US7199263B2 (en) * 2004-08-18 2007-04-03 Celanese International Corporation Acetic anhydride and acetate ester co-production
TW200635892A (en) 2005-02-10 2006-10-16 Sulzer Chemtech Ag A method for the manufacture of carboxylic acid ester by means of a reactive distillation
EP1690849B1 (de) * 2005-02-10 2009-08-26 Sulzer Chemtech AG Verfahren zur Herstellung von Carbonsäureester mittels einer Reaktivdestillation
CA2643721A1 (en) * 2006-02-28 2007-09-07 Shell Internationale Research Maatschappij B.V. A process for reactive distillation of a carboxylic acid
CN100395226C (zh) * 2006-03-20 2008-06-18 无锡百川化工股份有限公司 以硫酸为催化剂反应精馏法规模化生产乙酸丁酯的方法
EP1842843A1 (de) 2006-04-04 2007-10-10 Basf Aktiengesellschaft Verfahren zur Herstellung eines Carbonsäurealkylesters
US7857944B2 (en) * 2007-04-25 2010-12-28 National Taiwan University Method and apparatus for esterification
JP4593638B2 (ja) * 2008-02-18 2010-12-08 ダイセル化学工業株式会社 エステル系溶剤の製造方法
CN101519349B (zh) * 2008-02-27 2015-02-25 中国石油化学工业开发股份有限公司 利用酸和醇制造酯类的方法和系统
CN101781200B (zh) * 2009-01-20 2013-04-03 中国石油化学工业开发股份有限公司 有机羧酸酯的制造方法
US8268131B2 (en) * 2009-03-24 2012-09-18 Amt International, Inc. Apparatus and method for recovery of acetic acid from an aqueous solution thereof
FR2949229B1 (fr) 2009-08-24 2011-08-26 Rhodia Operations Procede d'esterification d'acide carboxylique
US20110076207A1 (en) * 2009-09-29 2011-03-31 Lanxess Sybron Chemicals Inc. Method and apparatus for protecting and monitoring the kinetic performance of an esterification catalyst material
CN101948384B (zh) * 2010-10-14 2013-11-06 谢仁华 连续式酯化法制备中高碳脂肪酸酯的设备和方法
CN102249913B (zh) * 2011-05-17 2013-11-06 上海华谊丙烯酸有限公司 一种制备丙烯酸丁酯的方法
PT2012164573W (pt) 2011-05-27 2014-10-08 Reliance Ind Ltd Procedimento para a preparação de um ácido carboxílico orgânico por hidrólise de um ester de ácido carboxílico orgânico
US8785697B2 (en) 2011-06-24 2014-07-22 Eastman Chemical Company Nickel modified catalyst for the production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US8829207B2 (en) 2011-06-24 2014-09-09 Eastman Chemical Company Production of cyclic acetals by reactive distillation
US9388105B2 (en) 2011-06-24 2016-07-12 Eastman Chemical Company Production of hydroxy ether hydrocarbons by liquid phase hydrogenolysis of cyclic acetals or cyclic ketals
US9000229B2 (en) 2011-06-24 2015-04-07 Eastman Chemical Company Production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US8829206B2 (en) 2011-06-24 2014-09-09 Eastman Chemical Company Production of cyclic acetals or ketals using solid acid catalysts
US9056313B2 (en) 2011-06-24 2015-06-16 Eastman Chemical Company Catalysts for the production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US8969598B2 (en) 2011-06-24 2015-03-03 Eastman Chemical Company Production of cyclic acetals or ketals using liquid-phase acid catalysts
JP2015030700A (ja) * 2013-08-02 2015-02-16 株式会社ダイセル エステル系溶剤の製造方法
US9328054B1 (en) 2013-09-27 2016-05-03 Travis Danner Method of alcoholisis of fatty acids and fatty acid gyicerides
KR102019037B1 (ko) * 2017-05-26 2019-09-06 지에스칼텍스 주식회사 알킬 카르복실산 에스테르의 제조 방법
CN116272675B (zh) * 2023-02-20 2023-10-17 安徽瑞柏新材料有限公司 基于催化蒸馏法的乙酸丙酯制备装置
CN116271906B (zh) * 2023-03-14 2023-09-22 安徽瑞柏新材料有限公司 一种环保低能耗连续式乙酸丁酯制备设备

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DE1768104C3 (de) * 1968-04-01 1974-07-18 Wacker-Chemie Gmbh, 8000 Muenchen Verfahren zur kontinuierlichen Herstellung von praktisch carbonsäurefreien Estern aus wasserunlöslichen C tief 4 -C tief 6 -Alkoholen und gesättigten aliphatischen Carbonsäuren mit 2- 4 C-Atomen
DE2756748A1 (de) * 1977-12-20 1979-06-28 Basf Ag Verfahren zur vervollstaendigung der veresterung von carbonsaeuren mit alkoholen
US4314947A (en) * 1978-12-21 1982-02-09 Basf Aktiengesellschaft Process for completing the esterification of carboxylic acids with alcohols
DE3121383C2 (de) * 1981-05-29 1983-04-14 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Veresterung von Essigsäure mit C↓2↓- bis C↓5↓-Alkoholen
DE3809417A1 (de) * 1988-03-21 1989-10-12 Henkel Kgaa Verfahren zur kontinuierlichen veresterung von fettsaeuren
ATE138904T1 (de) * 1989-01-17 1996-06-15 Davy Process Techn Ltd Kontinuierliches verfahren zur herstellung von carbonsäureestern
US4939294A (en) * 1989-05-22 1990-07-03 Eastman Kodak Company Preparation of ultra high purity methyl acetate
DE69313068T2 (de) * 1992-10-22 1998-03-05 Sumitomo Chemical Co Verfahren zur Herstellung von Methylmethacrylat

Also Published As

Publication number Publication date
JP4390298B2 (ja) 2009-12-24
MY124268A (en) 2006-06-30
BE1014031A3 (fr) 2003-03-04
CN1130329C (zh) 2003-12-10
DE19829809A1 (de) 1999-01-07
JPH1192417A (ja) 1999-04-06
ES2153291A1 (es) 2001-02-16
DE19829809B4 (de) 2015-09-10
CN1204640A (zh) 1999-01-13
US6028215A (en) 2000-02-22

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