ES2005492A6 - N-hydroxyphenyl formamide deriv. prepn. - Google Patents
N-hydroxyphenyl formamide deriv. prepn.Info
- Publication number
- ES2005492A6 ES2005492A6 ES8703715A ES8703715A ES2005492A6 ES 2005492 A6 ES2005492 A6 ES 2005492A6 ES 8703715 A ES8703715 A ES 8703715A ES 8703715 A ES8703715 A ES 8703715A ES 2005492 A6 ES2005492 A6 ES 2005492A6
- Authority
- ES
- Spain
- Prior art keywords
- hydroxy
- formamide
- deriv
- prepn
- hydroxyphenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 title 1
- -1 4-hydroxy 3-(N-formylamino) phenyl oxirane Chemical compound 0.000 abstract 1
- 230000003266 anti-allergic effect Effects 0.000 abstract 1
- 239000000043 antiallergic agent Substances 0.000 abstract 1
- 239000000924 antiasthmatic agent Substances 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 229940124630 bronchodilator Drugs 0.000 abstract 1
- 239000000168 bronchodilator agent Substances 0.000 abstract 1
- BPZSYCZIITTYBL-UHFFFAOYSA-N formoterol Chemical compound C1=CC(OC)=CC=C1CC(C)NCC(O)C1=CC=C(O)C(NC=O)=C1 BPZSYCZIITTYBL-UHFFFAOYSA-N 0.000 abstract 1
- NEGYEDYHPHMHGK-UHFFFAOYSA-N para-methoxyamphetamine Chemical compound COC1=CC=C(CC(C)N)C=C1 NEGYEDYHPHMHGK-UHFFFAOYSA-N 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 230000004936 stimulating effect Effects 0.000 abstract 1
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
N-(2-hydroxy 5- (1-hydroxy 2-((2-(4- methoxyphenyl) 1-methyl ethyl) amino)ethyl)phenyl) formamide of formula (I), with beta adrenergic- stimulating activity, for use as a broncho-dilator, anti-allergy and anti-asthma agent, etc., is made by reacting 4-hydroxy 3-(N-formylamino) phenyl oxirane, with the 4-hydroxy gps. protected, pref. by a benzyl gp., with 1-(4-methoxy phenyl) 2-propanamine and subsequent removal of the protective gp. by treatment with liq. HF.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES8703715A ES2005492A6 (en) | 1987-12-23 | 1987-12-23 | N-hydroxyphenyl formamide deriv. prepn. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES8703715A ES2005492A6 (en) | 1987-12-23 | 1987-12-23 | N-hydroxyphenyl formamide deriv. prepn. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2005492A6 true ES2005492A6 (en) | 1989-03-01 |
Family
ID=8253876
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES8703715A Expired ES2005492A6 (en) | 1987-12-23 | 1987-12-23 | N-hydroxyphenyl formamide deriv. prepn. |
Country Status (1)
| Country | Link |
|---|---|
| ES (1) | ES2005492A6 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LT3813B (en) | 1990-09-26 | 1996-03-25 | Astra Ab | Process for preparing 3-formamido-4-hydroxy-alpha£n£1-methyl-2(p-methoxyphenyl)ethylaminomethyl|benzyl alkohol fumarate (formoterol) and related compounds and derivatives thereof |
| US6040344A (en) * | 1996-11-11 | 2000-03-21 | Sepracor Inc. | Formoterol process |
| WO2005092840A1 (en) * | 2004-03-23 | 2005-10-06 | Pfizer Limited | Formamide derivatives useful as adrenoceptor |
| US7342132B2 (en) | 2001-11-09 | 2008-03-11 | Sepracor Inc. | Formoterol tartrate process and polymorph |
| EA010133B1 (en) * | 2004-03-23 | 2008-06-30 | Пфайзер Инк. | Formamide derivatives useful as adrenoceptor |
| US7718822B2 (en) | 2007-08-28 | 2010-05-18 | Sepracor Inc. | Carbamate Stereoisomer |
| US8501994B2 (en) | 2007-08-28 | 2013-08-06 | Sunovion Pharmaceuticals Inc. | Acetamide stereoisomer |
| CN113999134A (en) * | 2018-11-28 | 2022-02-01 | 广州健康元呼吸药物工程技术有限公司 | Preparation method of formoterol, medicinal salt and intermediate thereof |
-
1987
- 1987-12-23 ES ES8703715A patent/ES2005492A6/en not_active Expired
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LT3813B (en) | 1990-09-26 | 1996-03-25 | Astra Ab | Process for preparing 3-formamido-4-hydroxy-alpha£n£1-methyl-2(p-methoxyphenyl)ethylaminomethyl|benzyl alkohol fumarate (formoterol) and related compounds and derivatives thereof |
| US6040344A (en) * | 1996-11-11 | 2000-03-21 | Sepracor Inc. | Formoterol process |
| US7732641B2 (en) | 2001-11-09 | 2010-06-08 | Sepracor Inc. | Formoterol tartrate process and polymorph |
| US8110706B2 (en) | 2001-11-09 | 2012-02-07 | Sunovion Pharmaceuticals Inc. | Formoterol tartrate process and polymorph |
| US7342132B2 (en) | 2001-11-09 | 2008-03-11 | Sepracor Inc. | Formoterol tartrate process and polymorph |
| US7479572B2 (en) | 2001-11-09 | 2009-01-20 | Sepracor Inc. | Formoterol tartrate process and polymorph |
| US7964753B2 (en) | 2001-11-09 | 2011-06-21 | Sunovion Pharmaceuticals Inc. | Formoterol tartrate process and polymorph |
| EA010133B1 (en) * | 2004-03-23 | 2008-06-30 | Пфайзер Инк. | Formamide derivatives useful as adrenoceptor |
| AU2005225632B2 (en) * | 2004-03-23 | 2011-08-04 | Pfizer Inc. | Formamide derivatives useful as adrenoceptor |
| WO2005092840A1 (en) * | 2004-03-23 | 2005-10-06 | Pfizer Limited | Formamide derivatives useful as adrenoceptor |
| US7718822B2 (en) | 2007-08-28 | 2010-05-18 | Sepracor Inc. | Carbamate Stereoisomer |
| US8173829B2 (en) | 2007-08-28 | 2012-05-08 | Sunovion Pharmaceuticals Inc. | Carbamate stereoisomer |
| US8501994B2 (en) | 2007-08-28 | 2013-08-06 | Sunovion Pharmaceuticals Inc. | Acetamide stereoisomer |
| US8664441B2 (en) | 2007-08-28 | 2014-03-04 | Sunovion Pharmaceuticals Inc. | Acetamide stereoisomer |
| US9040588B2 (en) | 2007-08-28 | 2015-05-26 | Sunovion Pharmaceuticals Inc. | Acetamide stereoisomer |
| US9499476B2 (en) | 2007-08-28 | 2016-11-22 | Sunovion Pharmaceuticals Inc. | Acetamide stereoisomer |
| CN113999134A (en) * | 2018-11-28 | 2022-02-01 | 广州健康元呼吸药物工程技术有限公司 | Preparation method of formoterol, medicinal salt and intermediate thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| SA6 | Expiration date (snapshot 920101) |
Free format text: 2007-12-23 |