ES2003780A6 - Process for producing 4-phenoxyphenoxyalkanecarboxylic acid derivatives - Google Patents
Process for producing 4-phenoxyphenoxyalkanecarboxylic acid derivativesInfo
- Publication number
- ES2003780A6 ES2003780A6 ES8700281A ES8700281A ES2003780A6 ES 2003780 A6 ES2003780 A6 ES 2003780A6 ES 8700281 A ES8700281 A ES 8700281A ES 8700281 A ES8700281 A ES 8700281A ES 2003780 A6 ES2003780 A6 ES 2003780A6
- Authority
- ES
- Spain
- Prior art keywords
- formula
- image
- producing
- acid derivatives
- residue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- HFZWRUODUSTPEG-UHFFFAOYSA-N 2,4-dichlorophenol Chemical compound OC1=CC=C(Cl)C=C1Cl HFZWRUODUSTPEG-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000003158 alcohol group Chemical group 0.000 abstract 1
- -1 alkali metal phenoxide Chemical class 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229940125890 compound Ia Drugs 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/367—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in singly bound form
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a process for producing 4-phenoxyphenoxyalkanecarboxylic acid derivatives of formula Ia < IMAGE > in which R1 is an alkyl residue and R2 is a hydroxyl, alcohol, amino or -OM residue (M being an alkali metal). According to the invention, 2,4-dichlorophenol or its alkali metal phenoxide is reacted, under basic conditions, with a halogenated derivative of formula II < IMAGE > in the presence of a catalyst and optionally in an inert organic solvent to give a compound of formula Ib < IMAGE > where R1 has the same meaning as in the case of the compound Ia and R2 is a hydroxyl or alcohol residue, which can be easily converted to derivatives of formula Ia. The invention applies especially to the preparation of herbicidal products.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES8700281A ES2003780A6 (en) | 1987-02-05 | 1987-02-05 | Process for producing 4-phenoxyphenoxyalkanecarboxylic acid derivatives |
| FR8801247A FR2616147B1 (en) | 1987-02-05 | 1988-02-03 | PROCESS FOR OBTAINING 4-PHENOXYPHENOXY-ALKANECARBOXYLIC ACID DERIVATIVES |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES8700281A ES2003780A6 (en) | 1987-02-05 | 1987-02-05 | Process for producing 4-phenoxyphenoxyalkanecarboxylic acid derivatives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2003780A6 true ES2003780A6 (en) | 1988-11-16 |
Family
ID=8249385
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES8700281A Expired ES2003780A6 (en) | 1987-02-05 | 1987-02-05 | Process for producing 4-phenoxyphenoxyalkanecarboxylic acid derivatives |
Country Status (2)
| Country | Link |
|---|---|
| ES (1) | ES2003780A6 (en) |
| FR (1) | FR2616147B1 (en) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CS185694B2 (en) * | 1974-07-17 | 1978-10-31 | Ishihara Sangyo Kaisha | Herbicidal agent |
| GB2093021B (en) * | 1981-01-24 | 1985-10-02 | Reckitt & Colman Product Ltd | 2-(2,4-dichlorophenoxy) phenylacetic acid |
| US4430510A (en) * | 1981-06-18 | 1984-02-07 | Schering Corporation | Process for the preparation of 2-(2,4-dichlorophenoxy)-phenylacetic acid |
-
1987
- 1987-02-05 ES ES8700281A patent/ES2003780A6/en not_active Expired
-
1988
- 1988-02-03 FR FR8801247A patent/FR2616147B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FR2616147B1 (en) | 1990-09-28 |
| FR2616147A1 (en) | 1988-12-09 |
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