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ES2002418A6 - Procedimiento de obtencion de monomeros acriliocos fluorados utiles en forma polimerizada para el tratamiento hidrofugo y oleofugo de diversos substratos. - Google Patents

Procedimiento de obtencion de monomeros acriliocos fluorados utiles en forma polimerizada para el tratamiento hidrofugo y oleofugo de diversos substratos.

Info

Publication number
ES2002418A6
ES2002418A6 ES8602605A ES8602605A ES2002418A6 ES 2002418 A6 ES2002418 A6 ES 2002418A6 ES 8602605 A ES8602605 A ES 8602605A ES 8602605 A ES8602605 A ES 8602605A ES 2002418 A6 ES2002418 A6 ES 2002418A6
Authority
ES
Spain
Prior art keywords
proofing
radical
polymers
oil
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES8602605A
Other languages
English (en)
Inventor
Marie-Jose Lina
Andre Dessaint
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Atochem SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atochem SA filed Critical Atochem SA
Publication of ES2002418A6 publication Critical patent/ES2002418A6/es
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • C14C11/003Surface finishing of leather using macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1809Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety
    • C07C273/1818Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety from -N=C=O and XNR'R"
    • C07C273/1827X being H
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/34Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F20/36Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/3154Of fluorinated addition polymer from unsaturated monomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PROCEDIMIENTO DE OBTENCION DE MONOMEROS ACRILICOS FLUORADOS UTILES EN FORMA POLIMERIZADA PARA EL TRATAMIENTO HIDROFUGO Y OLEOFUGO DE DIVERSOS SUSTRATOS. LOS MONOMEROS RESPONDEN A LA FORMULA: EN DONDE LOS DIVERSOS RADICALES TIENEN LOS SIGNIFICADOS INDICADOS EN LA DESCRIPCION Y EL PROCEDIMIENTO COMPRENDE REACCIONAR SOBRE UN DIISOCIANATO DE FORMULA OFCFC-Z-NFCFO, CANTIDADES EQUIMOLARES DE UN COMPUESTO POLIFLUORADO DE FORMULA RF-W-Q-H Y DE UN ESTER DE FORMULA RKNH-A-OCO-C(R)FCH2, EFECTUANDOSE LA REACCION EN EL SENO DE UN DISOLVENTE ORGANICO, A UNA TEMPERATURA DE 30 A 90J Y BAJO ATMOSFERA INERTE.
ES8602605A 1985-10-16 1986-10-15 Procedimiento de obtencion de monomeros acriliocos fluorados utiles en forma polimerizada para el tratamiento hidrofugo y oleofugo de diversos substratos. Expired ES2002418A6 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8515347A FR2588555B1 (fr) 1985-10-16 1985-10-16 Monomeres acryliques fluores, polymeres en derivant et leur application au traitement hydrofuge et oleofuge de substrats divers

Publications (1)

Publication Number Publication Date
ES2002418A6 true ES2002418A6 (es) 1988-08-01

Family

ID=9323882

Family Applications (1)

Application Number Title Priority Date Filing Date
ES8602605A Expired ES2002418A6 (es) 1985-10-16 1986-10-15 Procedimiento de obtencion de monomeros acriliocos fluorados utiles en forma polimerizada para el tratamiento hidrofugo y oleofugo de diversos substratos.

Country Status (9)

Country Link
US (1) US4778915A (es)
EP (1) EP0223648B1 (es)
JP (1) JPS6293267A (es)
KR (1) KR900000157B1 (es)
CN (1) CN86106575A (es)
AU (1) AU594981B2 (es)
DE (1) DE3667658D1 (es)
ES (1) ES2002418A6 (es)
FR (1) FR2588555B1 (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2207420A1 (es) * 2002-11-07 2004-05-16 Pymag S.A. Procedimiento de preparacion de nuevos monomeros acrilicos fluorados.

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ES2143125T3 (es) 1996-11-07 2000-05-01 Minnesota Mining & Mfg Uso de copolimeros anfifilicos que contienen un monomero fluorado para impartir impermeabilidad al cuero.
US6485789B1 (en) 1997-04-14 2002-11-26 3M Innovative Properties Company Fluorochemical composition containing a condensation product of a fluorochemical polyether and a poly-isocyanate to impart stain release properties to a substrate
US6239247B1 (en) 1997-05-14 2001-05-29 3M Innovative Properties Company Fluorochemical composition comprising a urethane having a fluorochemical oligomer and a hydrophilic segment to impart stain release properties to a substrate
US6224782B1 (en) 1997-05-14 2001-05-01 3M Innovative Properties Company Fluorochemical composition comprising a polyurethane having a fluorochemical oligomer and a hydrophilic segment to impart stain release properties to a substrate
US6162369A (en) * 1997-05-14 2000-12-19 3M Innovative Properties Company Fluorochemical composition comprising a polyurethane having a fluorochemical oligomer and a hydrophilic segment to impart stain release properties to a substrate
US6383633B1 (en) 1997-05-14 2002-05-07 3M Innovative Properties Company Fluorochemical composition comprising a polymer derived from a fluorochemical urethane (meth)acrylate monomer for imparting stain release properties to a substrate
US6380336B1 (en) 1998-03-24 2002-04-30 Nano-Tex, Llc Copolymers and oil-and water-repellent compositions containing them
WO1999049124A2 (en) 1998-03-24 1999-09-30 Avantgarb, Llc Modified textile and other materials and methods for their preparation
US6168866B1 (en) 1998-08-19 2001-01-02 3M Innovative Properties Company Abrasion and stain resistant curable fluorinated coating
US6098349A (en) * 1998-09-22 2000-08-08 Patent Category Corp. Collapsible structures
US6525127B1 (en) 1999-05-11 2003-02-25 3M Innovative Properties Company Alkylated fluorochemical oligomers and use thereof in the treatment of fibrous substrates
US7049379B2 (en) * 1999-05-11 2006-05-23 3M Innovative Properties Company Alkylated fluorochemical oligomers and use thereof in the treatment of fibrous substrates
US6479612B1 (en) 1999-08-10 2002-11-12 E. I. Du Pont De Nemours And Company Fluorochemical water and oil repellents
US6449147B2 (en) * 2000-05-01 2002-09-10 Patent Category Corp. Collapsible structures having enhancements
JP3778168B2 (ja) * 2002-12-24 2006-05-24 ダイキン工業株式会社 皮革用塗料組成物、塗装方法および塗装皮革
WO2005066224A1 (en) * 2003-12-31 2005-07-21 3M Innovative Properties Company Water-and oil-repellent fluoroacrylates
US7081545B2 (en) * 2003-12-31 2006-07-25 3M Innovative Properties Company Process for preparing fluorochemical monoisocyanates
US7345123B2 (en) * 2004-12-28 2008-03-18 3M Innovative Properties Company Fluoroacrylate-multifunctional acrylate copolymer compositions
US7291688B2 (en) * 2004-12-28 2007-11-06 3M Innovative Properties Company Fluoroacrylate-mercaptofunctional copolymers
US20060142530A1 (en) * 2004-12-28 2006-06-29 Moore George G Water- and oil-repellent fluorourethanes and fluoroureas
US20060188729A1 (en) * 2005-02-22 2006-08-24 Kai-Volker Schubert Washable leather with repellency
US7160480B2 (en) * 2005-02-22 2007-01-09 E. I. Du Pont De Nemours And Company Leather treated with fluorochemicals
US7750093B2 (en) * 2005-06-29 2010-07-06 3M Innovative Properties Company Polyurethanes derived from oligomeric fluoroacrylates
US7722955B2 (en) * 2006-04-13 2010-05-25 3M Innovative Properties Company Flooring substrate having a coating of a curable composition
US20070244289A1 (en) * 2006-04-13 2007-10-18 3M Innovative Properties Company Method of making urethane based fluorinated monomers
US7728098B2 (en) * 2006-07-27 2010-06-01 3M Innovative Properties Company Fluorochemical composition comprising fluorinated oligomeric silane
US8071489B2 (en) * 2007-07-10 2011-12-06 E. I. Du Pont De Nemours And Company Amphoteric fluorochemicals for paper
EP2045276A1 (en) * 2007-10-05 2009-04-08 E.I. Du Pont De Nemours And Company Fluoropolymer
MX2011006535A (es) * 2008-12-23 2011-07-13 Basf Se Proceso y formacion acuosa para impregnar materiales inertes y conferirles actividad de proteccion contra plagas.
CN102471237A (zh) * 2009-06-30 2012-05-23 旭硝子株式会社 表面处理剂、物品及含氟醚化合物
GB0919014D0 (en) 2009-10-30 2009-12-16 3M Innovative Properties Co Soll and stain resistant coating composition for finished leather substrates
CN107043466B (zh) * 2017-05-16 2019-03-15 苏州棠华纳米科技有限公司 一种改性壳聚糖-二氧化硅复合气凝胶材料及其制备方法和应用

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2207420A1 (es) * 2002-11-07 2004-05-16 Pymag S.A. Procedimiento de preparacion de nuevos monomeros acrilicos fluorados.
WO2004041757A1 (es) * 2002-11-07 2004-05-21 Pymag, S.A. Procedimiento de preparacion de nuevos monomeros acrilicos fluorados

Also Published As

Publication number Publication date
FR2588555A1 (fr) 1987-04-17
JPS6293267A (ja) 1987-04-28
AU6412386A (en) 1987-04-30
CN86106575A (zh) 1987-04-22
EP0223648A2 (fr) 1987-05-27
FR2588555B1 (fr) 1987-12-11
DE3667658D1 (de) 1990-01-25
KR900000157B1 (ko) 1990-01-23
EP0223648A3 (en) 1988-03-23
EP0223648B1 (fr) 1989-12-20
KR870004066A (ko) 1987-05-07
US4778915A (en) 1988-10-18
AU594981B2 (en) 1990-03-22

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Legal Events

Date Code Title Description
SA6 Expiration date (snapshot 920101)

Free format text: 2006-10-15

FD1A Patent lapsed

Effective date: 20001204