EP3953051B1 - Two-piece nozzle for aerosol dispensers - Google Patents
Two-piece nozzle for aerosol dispensers Download PDFInfo
- Publication number
- EP3953051B1 EP3953051B1 EP19718293.4A EP19718293A EP3953051B1 EP 3953051 B1 EP3953051 B1 EP 3953051B1 EP 19718293 A EP19718293 A EP 19718293A EP 3953051 B1 EP3953051 B1 EP 3953051B1
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- EP
- European Patent Office
- Prior art keywords
- channels
- nozzle
- face
- piece
- lateral
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B1/00—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
- B05B1/34—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl
- B05B1/3405—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl
- B05B1/341—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet
- B05B1/3421—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber
- B05B1/3431—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber the channels being formed at the interface of cooperating elements, e.g. by means of grooves
- B05B1/3447—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber the channels being formed at the interface of cooperating elements, e.g. by means of grooves the interface being a cylinder having the same axis as the outlet
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B1/00—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
- B05B1/34—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl
- B05B1/3405—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl
- B05B1/341—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet
- B05B1/3421—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber
- B05B1/3426—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber the channels emerging in the swirl chamber perpendicularly to the outlet axis
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B1/00—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
- B05B1/34—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl
- B05B1/3405—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl
- B05B1/341—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet
- B05B1/3421—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber
- B05B1/3431—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber the channels being formed at the interface of cooperating elements, e.g. by means of grooves
- B05B1/3436—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber the channels being formed at the interface of cooperating elements, e.g. by means of grooves the interface being a plane perpendicular to the outlet axis
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant
- B65D83/75—Aerosol containers not provided for in groups B65D83/16 - B65D83/74
- B65D83/753—Aerosol containers not provided for in groups B65D83/16 - B65D83/74 characterised by details or accessories associated with outlets
Definitions
- the invention relates to a two-piece nozzle for an aerosol dispenser.
- a diffuser is placed at the valve outlet, which serves on the one hand to actuate the valve and on the other hand to direct the jet in a predefined direction.
- the diffuser is equipped with a conduit leading from the valve stem to an outlet orifice.
- a nozzle is generally placed at the outlet of the conduit. This nozzle traditionally consists of a cup-shaped insert with a small central orifice in its base and fitted onto a stud made in the diffuser, at the end of the conduit.
- the diffuser conduit ends with one or more longitudinal channels distributed around the circumference of the stud.
- Another solution is to place a two-piece nozzle in a cavity made at the end of the diffuser duct, namely an inner part fulfilling the function of the diffuser tenon and an outer part similar to the insert.
- the longitudinal channels are then placed either on the inner part or on the outer part.
- Such a two-piece nozzle is known, for example, from US 9,527,092 B2 or the document WO 03/061839 A1 .
- converging channels are placed in the bottom of the insert or on the front face of the tenon or inner part, opening tangentially into a circular or annular turbulence chamber surrounding the outlet orifice. This is called a swirl nozzle (mechanical break-up or MBU).
- the determining factors for spray quality include the geometry and distribution of the channels, the diameter of the outlet orifice and the conical shape of the outlet orifice.
- current injection techniques for inserts do not reliably produce outlet orifices with diameters less than 0.2 mm.
- the objective of the invention is therefore to improve the two-piece nozzles of the state of the art.
- the channels are divided into lateral channels made in the lateral face of the inner part and/or in the inner face of the tubular wall of the outer part, and into converging channels made in the front wall of the outer part or in the front face of the inner part.
- the cross-section of the lateral channels decreases between the upstream end of the channels, located opposite the front face or the front wall, and the downstream end of the channels, located on the side of the front face or the front wall.
- the lateral channels may have a bottom wall surrounded by two side walls, the side walls approaching each other in the direction of the front face of the inner part or the front wall of the outer part. It is also possible for the bottom wall to approach the inner face of the tubular wall of the outer part, when the lateral channels are placed on the outer part, or the lateral face of the inner part, when the lateral channels are placed on the inner part.
- the side channels have a bottom wall surrounded by two side walls, the intersection between each side wall and the bottom wall forming a non-right angle, the two walls sloping relative to the bottom wall preferably in the same direction, the two walls preferably being inclined at the same angle and/or the two walls preferably extending parallel to each other.
- the front face of the inner part is free of projection, or the front face of the inner part has a projection, the end of which does not penetrate into the outlet opening.
- the cavity of the outer part and the inner part preferably have the shape of a cylinder of revolution or a cone of revolution around the axis of symmetry. It goes without saying that it would also be possible to provide other shapes, in particular a cylinder or a cone with a polygonal base. Similarly, it would be possible for the front face of the inner part and/or that of the front wall of the outer part to be curved, for example hemispherical.
- the side channels may be substantially straight and parallel to an axial plane passing through them defined by a main axis passing through the center of the nozzle.
- the length of the channels is the shortest. It is also possible for the channels not to be straight and to diverge from an axial plane defined by the main axis passing through the center of the nozzle.
- the side channels may be helical in shape. This latter shape is particularly simple to achieve on the inner part. In such a case, the channels are longer. Changing the length of the side channels allows the flow rate of the material stream to be adapted.
- the converging channels may extend from the envelope defining the side face of the inner part or the internal face of the tubular wall of the outer part towards the turbulence chamber into which they preferably open tangentially.
- the inner part has a rear face, preferably substantially flat, provided with a peripheral edge projecting in the direction opposite to the front face, one or more passages being made in the peripheral edge to bring the inner face and the outer face of said peripheral edge into contact.
- the passages passing through the projecting edge preferably open into said lateral channels.
- the nozzle may be immobilized in the cavity, in particular to ensure exact alignment of the lateral channels and the converging channels.
- the nozzle may be provided with fixing means for fixing the inner part in the cavity of the outer part so that it is immobilized in the cavity.
- Another solution is to dimension the inner part so that it is retained by clamping in the cavity of the outer part so that it is immobilized there.
- the inner part and/or the outer part may be provided with first orientation means for orienting the inner part relative to the outer part in order to align the channels with each other.
- Another solution is to orient the inner part before transferring it into the cavity of the outer part.
- the inner part may be able to rotate in the outer part.
- the nozzle may be provided with retaining means for retaining the inner part in the cavity of the outer part so that it is rotatable in the cavity around the axis of symmetry.
- the diffuser duct When the nozzle is to be used with two-way valves, provision may be made for the diffuser duct to extend the separation of the two ways to its outlet end and for part of the nozzle channels to be intended for one of the ways and the rest of the channels for the other way. In this case, it is preferable to provide the nozzle with second orientation means to orient the nozzle relative to the diffuser for which it is intended.
- Another solution consists of separating the channels sufficiently from each other, or giving them a sufficiently small angular deployment, so that the same duct cannot be in contact simultaneously with both ways.
- the nozzle of the invention may be sold alone or be mounted in a housing of an aerosol diffuser, the housing being able to have a bottom face provided with diverging channels.
- the invention relates to a nozzle (1, 2) for an aerosol dispenser to be placed on a valve of a pressurized container.
- the nozzle can also be used with an aerosol dispenser cooperating with a container that is not pressurized.
- the nozzle consists of an inner part (11, 21) and an outer part (12, 22). Two examples of nozzles are shown in the figures. The constituent elements of variants are indicated by a "'" sign.
- the nozzle and its components have a certain rotational symmetry around a principal axis (A) passing through the nozzle parallel to the general direction of diffusion of the product. It will be seen that this rotational symmetry is not absolute, certain parts of the nozzle deviating from it.
- the adjectives "axial” or “radial” relate to this principal axis and define an element parallel to the axis or perpendicular to this axis respectively.
- spatial references such as “upper” and “lower”, “above” or “below” refer to the nozzle and its components as represented for example on the Fig. 6 or the Fig. 18 for example. This is not an absolute position, but only a reference position for the description, the nozzle integrated in a diffuser can be used in any position suitable for the product to be delivered.
- the outer part (12, 22) has the general shape of a bucket formed by a tubular wall (121, 221) open on one side and closed on the other by a front wall (122, 222).
- the cavity defined by the tubular wall and the front wall has the general shape of a cylinder of revolution or a cone of revolution.
- An outlet opening (123, 223) is made in the center of the front wall to bring the cavity into contact with the external face of the front wall.
- the inner part (11, 21) has the general shape of a cylinder of revolution or a cone of revolution essentially complementary to that of the cavity of the outer part. It has a front face (111, 211) which, in the mounted state of the nozzle, is opposite the wall front (122, 222) of the outer part, generally being partially in contact with it.
- the front face (111, 211) is free of projection. It is preferably smooth or substantially smooth. A projection could be provided, but this does not penetrate into the outlet orifice (123, 223).
- the inner part has a substantially flat rear face (115, 215). It is provided with a peripheral edge (115a) projecting in the opposite direction to the front face (111). One or more passages (115b) are provided in the peripheral edge to bring the inner face and the outer face of said peripheral edge into contact. These passages (115b) open into the lateral channels (112) when said lateral channels are made in the side wall of the inner part. This is the case of the 1st nozzle, as is clearly visible in the Fig. 2 notably.
- Channels are provided in the inner part and/or in the outer part to bring the product to be diffused coming from the valve to the outlet opening (123, 223) of the nozzle.
- These channels are divided into two parts: lateral channels (112, 112', 224) leading from the nozzle inlet to the front wall and converging channels (125, 225) leading from the end of the lateral channels (112, 224) to a turbulence chamber (127, 227) from which the outlet opening (123, 223) starts.
- the lateral channels can be provided on the cylindrical or frustoconical wall of the inner part (11) as in the first nozzle or on the internal face of the tubular wall (221) of the outer part as in the second nozzle.
- the converging channels (125, 225) are made in the bottom of the bucket, on the internal face of the front wall (122, 222) of the outer part. It would however be possible to make them on the front face (111, 211) of the inner part (11, 21).
- the converging channels are used to form the spray. These channels start from the peripheral edge of the front wall (122, 222) of the cavity of the outer part or from the front face (111, 211) of the inner part, and open tangentially, or at least non-radially, into a circular cavity so that when the two parts are assembled, a turbulence chamber (127, 227) is formed, promoting the formation of the spray. This is the process known as "mechanical break-up".
- the outlet opening (223, 223') is always located downstream of the central swirl chamber (227, 227') and, when placed on the axis of symmetry (A), behind the swirl chamber in the direction of flow of the product, but it does not start necessarily closer to the external face of the front wall (222) than certain parts of the converging channels.
- the outlet opening can be surrounded in its lower part by at least part of the converging channels without them however opening into this outlet opening. This is clearly visible for example on the section of the Fig. 18 .
- the side channels (112, 224) may be vertical, as in the exemplary embodiments presented in Fig. 1 And Fig. 8 .
- the channels are straight and extend parallel to an axial plane passing through them defined by the axis of symmetry (A). They define the shortest path between the nozzle inlet and the converging channels. It is also possible to make them with a geometry that deviates from the vertical. For example, they can be helical in shape as in the Fig. 20 , or even zigzag.
- the lateral channels (112') do not extend parallel to an axial plane defined by the axis of symmetry (A), but diverge from this axial plane. This makes it possible to lengthen the channels while maintaining the same height for the nozzle.
- the shorter the channel the greater the flow rate.
- By moving the lateral channels away from the vertical their length is increased, which makes it possible to adapt the flow rate to specific needs while maintaining the same size for the nozzle.
- the side channels are placed on the inner part (11).
- the cross-section of these side channels decreases slightly between the inlet located at the lower face (115) and the outlet located at the front face (111).
- the side channels (112, 112', 224) may have a bottom wall (112a) surrounded by two side walls (112b).
- To reduce the cross-section of the side channels it is possible, for example, to bring the side walls (112b) closer to each other in the direction of the front wall (122, 222) or the front face (111, 211).
- the two side walls (112b) of the side channels can be inclined relative to the bottom wall (112a), preferably in the same direction, generally at the same angle. This is clearly visible on the Fig. 3 in particular. It would also be possible that the two side walls (112b) extend parallel to each other.
- the side channels (224) of the 2nd nozzle are placed on the inner face of the tubular wall (221) of the outer part. They also have a cross section which decreases due to a slight inclination of the side walls and the bottom wall of the channels. In other words, the closer the side channels get to the front wall (122, 222), the closer the side walls get to each other.
- Another alternative or complementary solution may provide that the closer the side channels get to the front wall (122, 222), the closer the bottom wall (112a) gets to the inner face of the tubular wall (121, 221) of the outer part.
- each side wall and the bottom wall of the side channels may form a non-right angle, the two walls sloping relative to the bottom wall preferably in the same direction, the two walls preferably being sloping at the same angle. It would also be possible for the two walls to extend parallel to each other.
- One of the side walls of the lateral channels is rounded and is an extension of the side wall of the converging channels. This rounded shape of the side wall helps guide the flow into the corresponding converging channel.
- the second side wall of the lateral channels is straight and substantially radial.
- the converging channels can be placed in the front wall of the cavity of the outer part or on the front face of the inner part.
- the converging channels of the first set start from the lateral channels and open radially into a first annular cavity from which the channels of the second set start, which open radially into a second circular or annular cavity forming the turbulence chamber (227) and from which the outlet opening (223) starts.
- the inner part (11) is well oriented with respect to the outer part (12) and that it maintains this orientation throughout the use of the diffuser carrying the nozzle in order to ensure proper operation of the nozzle and to limit the cross-section of the lateral channels (112) at their junction with converging channels.
- first orientation means such as foolproofers or orientation markers.
- Another solution consists of correctly orienting the inner part before introducing it into the outer part.
- the inner part (11) can be slightly oversized compared to the cavity of the outer part (12) so that it is forced in and held in the correct position by clamping. Thanks to this correct orientation of the two parts, it is possible to limit the cross-section of the lateral channels (112) since it is certain that they will open exactly into the inlet of the converging channels (125). It goes without saying that in the second nozzle too, the inner part (21) can be locked in the cavity of the outer part (22) either by orientation means or by clamping or force-fitting, although the question of the alignment of the side channels and the converging channels does not arise.
- the nozzle is used in a diffuser for a two-way valve.
- the diffuser duct is designed to maintain the separation of the paths between the outlet of the valve stem and the nozzle.
- the first path of the valve is brought into contact with a portion of the side channels and the second path with the remainder of the side channels.
- the mixing of the products then takes place in the turbulence chamber. It is therefore necessary for the nozzle to be correctly oriented in the diffuser. This can be done either by maintaining the initial orientation of the nozzle, for example by keeping it in its molding cavity until it is placed in the diffuser, or by providing orientation means such as polarizing devices.
- Another solution consists of distributing the inlets of the side channels and/or their angular extent in such a way that, whatever whatever the position of the nozzle, the same side channel cannot be in contact simultaneously with the first channel and with the second channel.
- the outer part (12, 22) is preferably made of polyacetal such as POM. It can also be made of polyamide or semi-crystalline polyester such as PBT.
- the inner part (11, 21) is preferably made of polyacetal such as POM. It can also be made of polyamide or semi-crystalline polyester such as PBT. These materials offer the advantage of being fluid and allow the molding of precision parts with good geometric and dimensional stability. In addition, they are rigid, which allows good anchoring of the nozzle in the diffuser via the anchoring means (126, 226) which grip in the softer PP-type material of the diffuser. In addition, in the case where sterilization by ionizing radiation is required for the diffuser equipped with its nozzle, the PBT will have better behavior than the POM or certain PAs.
- the nozzle of the invention is placed in a housing provided directly at the outlet of the duct.
- Anchoring means (126, 226) ensure secure attachment of the nozzle to the outlet of the diffuser duct. The nozzle thus retained cannot be ejected, even when the pressure inside the duct is high and the valve is open. If necessary, the bottom of the housing can have diverging channels opening into the lateral channels of the nozzle.
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Nozzles (AREA)
Description
L'invention concerne une buse en deux pièces pour un diffuseur d'aérosol.The invention relates to a two-piece nozzle for an aerosol dispenser.
De nombreux produits sont appliqués sous forme d'aérosol. Pour pulvériser un produit contenu dans un générateur d'aérosol sous pression, on place à la sortie de la valve un diffuseur servant d'une part à actionner la valve et d'autre part à diriger le jet dans une direction prédéfinie. À cette fin, le diffuseur est muni d'un conduit menant du stem de la valve à un orifice de sortie. Afin d'obtenir un spray avec des gouttelettes finement divisées et non un jet de liquide ou des gouttes, on place généralement une buse à la sortie du conduit. Cette buse est traditionnellement constituée d'un insert en forme de godet muni dans son fond d'un petit orifice central et emmanché sur un tenon réalisé dans le diffuseur, à l'extrémité du conduit. Le conduit du diffuseur se termine par un ou plusieurs canaux longitudinaux répartis sur la circonférence du tenon. Une autre solution consiste à placer dans une cavité réalisée à l'extrémité du conduit du diffuseur une buse en deux pièces, à savoir une pièce intérieure remplissant la fonction du tenon du diffuseur et une pièce extérieure semblable à l'insert. Les canaux longitudinaux sont alors placés soit sur la pièce intérieure, soit sur la pièce extérieure. On connait une telle buse en deux pièces par exemple de
Par ailleurs, la maitrise du montage de l'insert dans le diffuseur ou l'assemblage de la buse en deux pièces est complexe et la qualité du spray dépend fortement du positionnement angulaire de l'insert sur le tenon du diffuseur ou de la pièce intérieure par rapport à la pièce extérieure. Pour garantir que les canaux longitudinaux coïncident avec les canaux convergents lorsqu'ils ne sont pas réalisés sur la même pièce, il est courant de concevoir les canaux longitudinaux avec des secteurs angulaires bien plus importants que ceux des canaux convergents. Même si l'insert ou la pièce extérieure n'est pas exactement orienté par rapport au tenon ou à la pièce intérieure, les canaux convergents se trouvent forcément dans la continuité des canaux longitudinaux.Furthermore, mastering the mounting of the insert in the diffuser or the assembly of the two-piece nozzle is complex and the quality of the spray depends heavily on the angular positioning of the insert on the tenon of the diffuser or the inner part relative to the outer part. To ensure that the longitudinal channels coincide with the converging channels when they are not made on the same part, it is common to design the longitudinal channels with angular sectors much larger than those of the converging channels. Even if the insert or the outer part is not exactly oriented relative to the tenon or the interior part, the converging channels are necessarily in the continuity of the longitudinal channels.
L'objectif de l'invention est donc d'améliorer les buses en deux pièces de l'état de la technique.The objective of the invention is therefore to improve the two-piece nozzles of the state of the art.
Cet objectif est atteint par une buse pour diffuseur d'aérosol, notamment pour un diffuseur d'aérosol sous pression, comprenant
- une pièce extérieure munie d'une paroi tubulaire ouverte d'un côté et fermée de l'autre par une paroi frontale en formant une cavité, la paroi frontale étant munie en son centre d'une ouverture de sortie, la pièce extérieure présentant une certaine symétrie autour d'un axe de symétrie,
- une pièce intérieure indépendante du diffuseur auquel la buse est destinée, laquelle pièce intérieure est dimensionnée pour pénétrer dans la cavité de la pièce extérieure en y étant retenue, la pièce intérieure présentant une face frontale en regard de la paroi frontale de la pièce extérieure et une face latérale à la suite de la face frontale,
- des canaux étant réalisés dans la cavité de la pièce extérieure et/ou sur la surface de la pièce intérieure, lesquels canaux débouchent dans une chambre de turbulence centrale en communication avec l'ouverture de sortie, l'ouverture de sortie étant placée dans le chemin d'écoulement du flux de produit en aval de la chambre de turbulence.
- an outer part provided with a tubular wall open on one side and closed on the other by a front wall forming a cavity, the front wall being provided in its center with an outlet opening, the outer part having a certain symmetry around an axis of symmetry,
- an inner part independent of the diffuser for which the nozzle is intended, which inner part is sized to penetrate into the cavity of the outer part and be retained therein, the inner part having a front face opposite the front wall of the outer part and a side face following the front face,
- channels being provided in the cavity of the outer part and/or on the surface of the inner part, which channels open into a central swirl chamber in communication with the outlet opening, the outlet opening being placed in the flow path of the product stream downstream of the swirl chamber.
Conformément à l'invention, les canaux se divisent en des canaux latéraux réalisés dans la face latérale de la pièce intérieure et/ou dans la face interne de la paroi tubulaire de la pièce extérieure, et en des canaux convergents réalisés dans la paroi frontale de la pièce extérieure ou dans la face frontale de la pièce intérieure. Pour un meilleur effet, la section transversale des canaux latéraux diminue entre l'extrémité amont des canaux, située à l'opposé de la face frontale ou de la paroi frontale, et l'extrémité aval des canaux, située du côté de la face frontale ou de la paroi frontale. Notamment, les canaux latéraux peuvent présenter une paroi de fond entourée de deux parois latérales, les parois latérales se rapprochant l'une de l'autre en direction de la face frontale de la pièce intérieure ou de la paroi frontale de la pièce extérieure. Il est également possible que la paroi de fond se rapproche de la face interne de la paroi tubulaire de la pièce externe, quand les canaux latéraux sont placés sur la pièce extérieure, ou de la face latérale de la pièce intérieure, quand les canaux latéraux sont placés sur la pièce intérieure.According to the invention, the channels are divided into lateral channels made in the lateral face of the inner part and/or in the inner face of the tubular wall of the outer part, and into converging channels made in the front wall of the outer part or in the front face of the inner part. For a better effect, the cross-section of the lateral channels decreases between the upstream end of the channels, located opposite the front face or the front wall, and the downstream end of the channels, located on the side of the front face or the front wall. In particular, the lateral channels may have a bottom wall surrounded by two side walls, the side walls approaching each other in the direction of the front face of the inner part or the front wall of the outer part. It is also possible for the bottom wall to approach the inner face of the tubular wall of the outer part, when the lateral channels are placed on the outer part, or the lateral face of the inner part, when the lateral channels are placed on the inner part.
Dans une variante de réalisation de l'invention, les canaux latéraux présentent une paroi de fond entourée de deux parois latérales, l'intersection entre chaque paroi latérale et la paroi de fond formant un angle non droit, les deux parois s'inclinant par rapport à la paroi de fond de préférence dans la même direction, les deux parois étant de préférence inclinées selon un même angle et/ou les deux parois s'étendant de préférence parallèlement l'une à l'autre.In an alternative embodiment of the invention, the side channels have a bottom wall surrounded by two side walls, the intersection between each side wall and the bottom wall forming a non-right angle, the two walls sloping relative to the bottom wall preferably in the same direction, the two walls preferably being inclined at the same angle and/or the two walls preferably extending parallel to each other.
Dans une variante de réalisation privilégiée, la face frontale de la pièce intérieure est exempte de saillie, ou la face frontale de la pièce intérieure présente une saillie dont l'extrémité ne pénètre pas dans l'ouverture de sortie.In a preferred embodiment, the front face of the inner part is free of projection, or the front face of the inner part has a projection, the end of which does not penetrate into the outlet opening.
La cavité de la pièce extérieure et la pièce intérieure ont de préférence la forme d'un cylindre de révolution ou d'un cône de révolution autour de l'axe de symétrie. Il va de soi qu'il serait également possible de prévoir d'autres formes, notamment un cylindre ou un cône de base polygonale. De même, il serait possible que la face frontale de la pièce intérieure et/ou celle de la paroi frontale de la pièce extérieure soient bombées, par exemple hémisphériques.The cavity of the outer part and the inner part preferably have the shape of a cylinder of revolution or a cone of revolution around the axis of symmetry. It goes without saying that it would also be possible to provide other shapes, in particular a cylinder or a cone with a polygonal base. Similarly, it would be possible for the front face of the inner part and/or that of the front wall of the outer part to be curved, for example hemispherical.
Selon les besoins, les canaux latéraux peuvent être sensiblement droits et parallèles à un plan axial les traversant défini par un axe principal passant par le centre de la buse. Dans un tel cas, la longueur des canaux est la plus courte. Il est également possible que les canaux ne soient pas droits et divergent d'un plan axial défini par l'axe principal passant par le centre de la buse. Notamment, les canaux latéraux peuvent être de forme hélicoïdale. Cette dernière forme est particulièrement simple à réaliser sur la pièce intérieure. Dans un tel cas, les canaux sont plus longs. La modification de la longueur des canaux latéraux permet d'adapter le débit du flux de matière. Il est également possible en inclinant les canaux latéraux, au moins au niveau de leur jonction avec les canaux convergents, d'orienter de façon prédéterminée et optimisée le flux lors de son entrée dans les canaux convergents, ce qui contribue à parfaire la qualité du spray. Ainsi, on peut éviter des angles, ou tout du moins des angles trop importants, à la jonction entre les canaux latéraux et les canaux convergents qui généralement sont eux-mêmes inclinés par rapport au plan radiant.Depending on requirements, the side channels may be substantially straight and parallel to an axial plane passing through them defined by a main axis passing through the center of the nozzle. In such a case, the length of the channels is the shortest. It is also possible for the channels not to be straight and to diverge from an axial plane defined by the main axis passing through the center of the nozzle. In particular, the side channels may be helical in shape. This latter shape is particularly simple to achieve on the inner part. In such a case, the channels are longer. Changing the length of the side channels allows the flow rate of the material stream to be adapted. It is also possible by tilting the side channels, at least at their junction with the converging channels, to orient the flow in a predetermined and optimized manner as it enters the converging channels, which contributes to perfecting the quality of the spray. This way, angles, or at least excessively large angles, can be avoided at the junction between the lateral channels and the converging channels, which are generally themselves inclined relative to the radiant plane.
Les canaux convergents peuvent s'étendre depuis l'enveloppe définissant la face latérale de la pièce intérieure ou la face interne de la paroi tubulaire de la pièce extérieure vers la chambre de turbulence dans laquelle ils débouchent de préférence de façon tangentielle.The converging channels may extend from the envelope defining the side face of the inner part or the internal face of the tubular wall of the outer part towards the turbulence chamber into which they preferably open tangentially.
La pièce intérieure présente une face arrière, de préférence sensiblement plane, munie d'un bord périphérique saillant en direction opposée à la face frontale, un ou plusieurs passages étant réalisés dans le bord périphérique pour mettre en contact la face interne et la face externe dudit bord périphérique. Quand les canaux latéraux sont réalisés dans la paroi latérale de la pièce intérieure, les passages traversant le bord saillant débouchent de préférence dans lesdits canaux latéraux. Ainsi, le produit sortant du canal de sortie du diffuseur peut pénétrer dans l'évidement situé à l'intérieur du bord périphérique, traverser le ou les passages pour atteindre les canaux latéraux de la pièce intérieure ou de la pièce extérieure.The inner part has a rear face, preferably substantially flat, provided with a peripheral edge projecting in the direction opposite to the front face, one or more passages being made in the peripheral edge to bring the inner face and the outer face of said peripheral edge into contact. When the lateral channels are made in the side wall of the inner part, the passages passing through the projecting edge preferably open into said lateral channels. Thus, the product leaving the outlet channel of the diffuser can enter the recess located inside the peripheral edge, pass through the passage(s) to reach the lateral channels of the inner part or the outer part.
Il peut être intéressant que la buse soit immobilisée dans la cavité, notamment pour garantir un alignement exact des canaux latéraux et des canaux convergents. Dans ce cas, la buse peut être munie de moyens de fixation pour fixer la pièce intérieure dans la cavité de la pièce extérieure de sorte qu'elle soit immobilisée dans la cavité. Une autre solution consiste à dimensionner la pièce intérieure pour qu'elle soit retenue par serrage dans la cavité de la pièce extérieure de sorte à y être immobilisée. Pour faciliter le montage de la pièce intérieure dans la pièce extérieure, la pièce intérieure et/ou la pièce extérieure peuvent être munies de premiers moyens d'orientation pour orienter la pièce intérieure par rapport à la pièce extérieure en vue d'aligner les canaux entre eux. Une autre solution consiste à orienter la pièce intérieure avant de la transférer dans la cavité de la pièce extérieure.It may be advantageous for the nozzle to be immobilized in the cavity, in particular to ensure exact alignment of the lateral channels and the converging channels. In this case, the nozzle may be provided with fixing means for fixing the inner part in the cavity of the outer part so that it is immobilized in the cavity. Another solution is to dimension the inner part so that it is retained by clamping in the cavity of the outer part so that it is immobilized there. To facilitate the assembly of the inner part in the outer part, the inner part and/or the outer part may be provided with first orientation means for orienting the inner part relative to the outer part in order to align the channels with each other. Another solution is to orient the inner part before transferring it into the cavity of the outer part.
Dans d'autres cas au contraire, il peut être intéressant que la pièce intérieure puisse tourner dans la pièce extérieure. Dans ce cas, la buse peut être munie de moyens de retenue pour retenir la pièce intérieure dans la cavité de la pièce extérieure de sorte qu'elle soit mobile en rotation dans la cavité autour de l'axe de symétrie.In other cases, on the contrary, it may be advantageous for the inner part to be able to rotate in the outer part. In this case, the nozzle may be provided with retaining means for retaining the inner part in the cavity of the outer part so that it is rotatable in the cavity around the axis of symmetry.
Dans un exemple de réalisation privilégié de l'invention,
- les canaux latéraux sont placés sur face latérale de la pièce intérieure, la section transversale des canaux latéraux diminuant depuis l'extrémité amont, située à l'opposé de la face frontale, et l'extrémité aval, située du côté de la face frontale, les canaux latéraux étant munis d'une paroi de fond entourée de deux parois latérales qui chacune forme un angle non droit avec la paroi de fond, les deux parois latérales s'étendant de préférence parallèlement l'une à l'autre ;
- les canaux convergents sont placés sur la paroi frontale de la pièce extérieure ;
- la face frontale de la pièce intérieure est exempte de saillie ou présente une saillie dont l'extrémité opposée à la face frontale ne pénètre pas dans l'ouverture de sortie de la paroi frontale de la partie extérieure ;
- la pièce intérieure étant de préférence dimensionnée pour être retenue par serrage dans la cavité de la pièce extérieure de sorte à y être immobilisée.
- the side channels are placed on the side face of the inner part, the cross-section of the side channels decreasing from the upstream end, located opposite the front face, and the downstream end, located on the side of the front face, the side channels being provided with a bottom wall surrounded by two side walls which each form a non-right angle with the bottom wall, the two side walls preferably extending parallel to each other;
- the converging channels are placed on the front wall of the outer room;
- the front face of the inner part is free from projection or has a projection whose end opposite the front face does not penetrate into the outlet opening of the front wall of the outer part;
- the inner part preferably being sized to be clamped into the cavity of the outer part so as to be immobilized therein.
Lorsque la buse doit être utilisée avec des valves à deux voies, on peut prévoir que le conduit du diffuseur prolonge la séparation des deux voies jusqu'à son extrémité de sortie et qu'une partie des canaux de la buse soit destinée à l'une des voies et le reste des canaux à l'autre voie. Dans ce cas, il est préférable de munir la buse de seconds moyens d'orientation pour orienter la buse par rapport au diffuseur auquel elle est destinée. Une autre solution consiste à écarter suffisamment les canaux les uns des autres, ou à leur donner un déploiement angulaire suffisamment petit, pour qu'un même conduit ne puisse pas être en contact simultanément avec les deux voies.When the nozzle is to be used with two-way valves, provision may be made for the diffuser duct to extend the separation of the two ways to its outlet end and for part of the nozzle channels to be intended for one of the ways and the rest of the channels for the other way. In this case, it is preferable to provide the nozzle with second orientation means to orient the nozzle relative to the diffuser for which it is intended. Another solution consists of separating the channels sufficiently from each other, or giving them a sufficiently small angular deployment, so that the same duct cannot be in contact simultaneously with both ways.
Il est possible de munir une paroi arrière de la pièce intérieure de canaux divergents, de préférence débouchant dans les canaux latéraux.It is possible to provide a rear wall of the interior room with diverging channels, preferably opening into the side channels.
La buse de l'invention peut être vendue seule ou être montée dans un logement d'un diffuseur d'aérosol, le logement pouvant présenter une face de fond munie de canaux divergents.The nozzle of the invention may be sold alone or be mounted in a housing of an aerosol diffuser, the housing being able to have a bottom face provided with diverging channels.
L'invention est décrite plus en détail ci-dessous à l'aide de deux exemples de réalisation présentés dans les figures suivantes qui montrent :
- Fig. 1
- une vue en perspective de dessus de la pièce intérieure d'une première buse selon l'invention ;
- Fig. 2
- une vue en perspective de dessous de la pièce intérieure de la
Fig. 1 ; - Fig. 3
- une vue de dessous de la pièce intérieure de la
Fig. 1 ; - Fig. 4
- une vue de côté de la pièce intérieure de la
Fig. 1 ; - Fig. 5
- une vue en perspective de dessous de la pièce extérieure de la 1ère buse ;
- Fig. 6
- une vue en coupe axiale de la 1ère buse ;
- Fig. 7
- une vue en coupe radiale de la 1ère buse ;
- Fig. 8
- une vue éclatée d'une deuxième buse selon l'invention ;
- Fig. 9
- une vue en perspective de la pièce intérieure de la 2ème buse ;
- Fig. 10
- une vue en perspective du dessous de la pièce extérieure de la 2ème buse ;
- Fig. 11
- une vue de dessous de la pièce extérieure de la 2ème buse ;
- Fig. 12
- une coupe axiale de la pièce extérieure de la 2ème buse ;
- Fig. 13
- une coupe horizontale en perspective de la pièce extérieure selon le plan A-A de la
figure 18 ; - Fig. 14
- une vue en perspective de dessous de la 2ème buse ;
- Fig. 15
- une vue en perspective de dessus de la 2ème buse ;
- Fig. 16
- une coupe horizontale de la 2ème buse selon le plan A-A de la
Fig. 18 ; - Fig. 17
- une coupe horizontale de la 2ème buse selon le plan B-B de la
Fig. 18 ; - Fig. 18
- une coupe verticale de la 2ème buse selon le plan C-C de la
Fig. 17 ; - Fig. 19
- une coupe en perspective de la 2ème buse selon le plan D-D de la
Fig. 18 - Fig. 20
- une vue en perspective d'une variante de la pièce intérieure de la première buse.
- Fig. 1
- a perspective view from above of the inner part of a first nozzle according to the invention;
- Fig. 2
- a perspective view from below of the interior room of the
Fig. 1 ; - Fig. 3
- a bottom view of the interior room of the
Fig. 1 ; - Fig. 4
- a side view of the interior room of the
Fig. 1 ; - Fig. 5
- a perspective view from below of the outer part of the 1st nozzle;
- Fig. 6
- an axial sectional view of the 1st nozzle;
- Fig. 7
- a radial sectional view of the 1st nozzle;
- Fig. 8
- an exploded view of a second nozzle according to the invention;
- Fig. 9
- a perspective view of the inner part of the 2nd nozzle;
- Fig. 10
- a perspective view of the bottom of the outer part of the 2nd nozzle;
- Fig. 11
- a bottom view of the outer part of the 2nd nozzle;
- Fig. 12
- an axial section of the outer part of the 2nd nozzle;
- Fig. 13
- a horizontal perspective section of the exterior room according to plan AA of the
figure 18 ; - Fig. 14
- a perspective view from below of the 2nd nozzle;
- Fig. 15
- a perspective view from above of the 2nd nozzle;
- Fig. 16
- a horizontal section of the 2nd nozzle according to plane AA of the
Fig. 18 ; - Fig. 17
- a horizontal section of the 2nd nozzle according to plane BB of the
Fig. 18 ; - Fig. 18
- a vertical section of the 2nd nozzle according to the CC plane of the
Fig. 17 ; - Fig. 19
- a perspective section of the 2nd nozzle according to plan DD of the
Fig. 18 - Fig. 20
- a perspective view of a variant of the inner part of the first nozzle.
L'invention concerne une buse (1, 2) pour un diffuseur d'aérosol à placer sur une valve d'un récipient sous pression. La buse peut également être utilisée avec un diffuseur d'aérosol coopérant avec un récipient qui n'est pas sous pression. La buse est constituée d'une pièce intérieure (11, 21) et d'une pièce extérieure (12, 22). Deux exemples de buses sont présentés dans les figures. Les éléments constitutifs de variantes sont indiqués par un signe « ' ».The invention relates to a nozzle (1, 2) for an aerosol dispenser to be placed on a valve of a pressurized container. The nozzle can also be used with an aerosol dispenser cooperating with a container that is not pressurized. The nozzle consists of an inner part (11, 21) and an outer part (12, 22). Two examples of nozzles are shown in the figures. The constituent elements of variants are indicated by a "'" sign.
La buse et ses composants présentent une certaine symétrie de rotation autour d'un axe principal (A) passant à travers la buse parallèlement à la direction générale de diffusion du produit. On verra que cette symétrie de rotation n'est pas absolue, certaines parties de la buse s'en écartant. Les adjectifs « axial » ou « radial » se rapportent à cet axe principal et définissent un élément parallèle à l'axe ou perpendiculaire à cet axe respectivement. Pour simplifier la description, les références spatiales telles que « supérieur » et « inférieur », « dessus » ou « dessous » se réfèrent à la buse et ses composants tels que représentés par exemple sur la
La pièce extérieure (12, 22) a la forme générale d'un godet formé d'une paroi tubulaire (121, 221) ouverte d'un côté et fermée de l'autre par une paroi frontale (122, 222). La cavité définie par la paroi tubulaire et la paroi frontale a une forme générale de cylindre de révolution ou de cône de révolution. Une ouverture de sortie (123, 223) est réalisée au centre de la paroi frontale pour mettre en contact la cavité avec la face externe de la paroi frontale.The outer part (12, 22) has the general shape of a bucket formed by a tubular wall (121, 221) open on one side and closed on the other by a front wall (122, 222). The cavity defined by the tubular wall and the front wall has the general shape of a cylinder of revolution or a cone of revolution. An outlet opening (123, 223) is made in the center of the front wall to bring the cavity into contact with the external face of the front wall.
La pièce intérieure (11, 21) a la forme générale d'un cylindre de révolution ou d'un cône de révolution essentiellement complémentaire à celle de la cavité de la pièce extérieure. Elle présente une face frontale (111, 211) qui, à l'état monté de la buse, est en regard de la paroi frontale (122, 222) de la pièce extérieure, généralement en étant partiellement en contact avec elle. La face frontale (111, 211) est exempte de saillie. Elle est de préférence lisse ou sensiblement lisse. On pourrait prévoir une saillie, mais celle-ci ne pénètre pas dans l'orifice de sortie (123, 223).The inner part (11, 21) has the general shape of a cylinder of revolution or a cone of revolution essentially complementary to that of the cavity of the outer part. It has a front face (111, 211) which, in the mounted state of the nozzle, is opposite the wall front (122, 222) of the outer part, generally being partially in contact with it. The front face (111, 211) is free of projection. It is preferably smooth or substantially smooth. A projection could be provided, but this does not penetrate into the outlet orifice (123, 223).
La pièce intérieure présente une face arrière (115, 215) sensiblement plane. Elle est munie d'un bord périphérique (115a) saillant en direction opposée à la face frontale (111). Un ou plusieurs passages (115b) sont prévus dans le bord périphérique pour mettre en contact la face interne et la face externe dudit bord périphérique. Ces passages (115b) débouchent dans les canaux latéraux (112) quand lesdits canaux latéraux sont réalisés dans la paroi latérale de la pièce intérieure. C'est le cas de la 1ère buse, comme cela est bien visible sur la
Des canaux sont réalisés dans la pièce intérieure et/ou dans la pièce extérieure pour amener le produit à diffuser provenant de la valve jusqu'à l'ouverture de sortie (123, 223) de la buse. Ces canaux se divisent en deux parties : des canaux latéraux (112, 112', 224) menant de l'entrée de la buse jusqu'à la paroi frontale et des canaux convergents (125, 225) menant de l'extrémité des canaux latéraux (112, 224) jusqu'à une chambre de turbulence (127, 227) d'où part l'ouverture de sortie (123, 223). Les canaux latéraux peuvent être réalisés sur la paroi cylindrique ou tronconique de la pièce intérieure (11) comme dans la première buse ou sur la face interne de la paroi tubulaire (221) de la pièce extérieure comme dans la deuxième buse. Dans les exemples présentés ici, les canaux convergents (125, 225) sont réalisés dans le fond du godet, sur la face interne de la paroi frontale (122, 222) de la pièce extérieure. Il serait cependant possible de les réaliser sur la face frontale (111, 211) de la pièce intérieure (11, 21).Channels are provided in the inner part and/or in the outer part to bring the product to be diffused coming from the valve to the outlet opening (123, 223) of the nozzle. These channels are divided into two parts: lateral channels (112, 112', 224) leading from the nozzle inlet to the front wall and converging channels (125, 225) leading from the end of the lateral channels (112, 224) to a turbulence chamber (127, 227) from which the outlet opening (123, 223) starts. The lateral channels can be provided on the cylindrical or frustoconical wall of the inner part (11) as in the first nozzle or on the internal face of the tubular wall (221) of the outer part as in the second nozzle. In the examples presented here, the converging channels (125, 225) are made in the bottom of the bucket, on the internal face of the front wall (122, 222) of the outer part. It would however be possible to make them on the front face (111, 211) of the inner part (11, 21).
Les canaux convergents servent à former le spray. Ces canaux partent du bord périphérique de la paroi frontale (122, 222) de la cavité de la pièce extérieure ou de la face frontale (111, 211) de la pièce intérieure, et débouchent de façon tangentielle, ou tout du moins non radiale, dans une cavité circulaire de sorte que lorsque les deux pièces sont assemblées, il se forme une chambre de turbulence (127, 227) favorisant la formation du spray. Il s'agit du procédé connu sous le nom de « mechanical break-up ».The converging channels are used to form the spray. These channels start from the peripheral edge of the front wall (122, 222) of the cavity of the outer part or from the front face (111, 211) of the inner part, and open tangentially, or at least non-radially, into a circular cavity so that when the two parts are assembled, a turbulence chamber (127, 227) is formed, promoting the formation of the spray. This is the process known as "mechanical break-up".
L'ouverture de sortie (223, 223') se trouve toujours en aval de la chambre de turbulence centrale (227, 227') et, en se plaçant sur l'axe de symétrie (A), derrière la chambre de turbulence dans le sens d'écoulement du produit, mais elle ne commence pas nécessairement plus près de la face externe de la paroi frontale (222) que certaines parties des canaux convergents. Autrement dit, l'ouverture de sortie peut être entourée dans sa partie inférieure par une partie au moins des canaux convergents sans qu'ils ne débouchent cependant dans cette ouverture de sortie. Cela est bien visible par exemple sur la coupe de la
Les canaux latéraux (112, 224) peuvent être verticaux, comme dans les exemples de réalisation présentés aux
Dans l'exemple de la 1ère buse, les canaux latéraux sont placés sur la pièce intérieure (11). La section transversale de ces canaux latéraux diminue légèrement entre l'entrée située au niveau de la face inférieure (115) et la sortie située au niveau de la face frontale (111).In the example of the 1st nozzle, the side channels are placed on the inner part (11). The cross-section of these side channels decreases slightly between the inlet located at the lower face (115) and the outlet located at the front face (111).
Les canaux latéraux (112, 112', 224) peuvent présenter une paroi de fond (112a) entourée de deux parois latérales (112b). Pour diminuer la section transversale des canaux latéraux, il est possible par exemple de rapprocher les parois latérales (112b) l'une de l'autre en direction de la paroi frontale (122, 222) ou de la face frontale (111, 211). Autrement dit, plus on est proche de la face inférieure (115) plus les parois latérales sont écartées l'une de l'autre, tandis que plus on est proche de la face frontale (111) plus elles sont rapprochées. Ceci est bien visible sur les
Les deux parois latérales (112b) des canaux latéraux peuvent s'incliner par rapport à la paroi de fond (112a), de préférence dans la même direction, généralement selon un même angle. Ceci est bien visible sur la
Les canaux latéraux (224) de la 2ème buse sont quant à eux placés sur la face interne de la paroi tubulaire (221) de la pièce extérieure. Ils ont également une section transversale qui diminue en raison d'une légère inclinaison des parois latérales et de la paroi du fond des canaux. Autrement dit, plus les canaux latéraux s'approchent de la paroi frontale (122, 222), plus les parois latérales se rapprochent l'une de l'autre. Une autre solution, alternative ou complémentaire, peut prévoir que plus les canaux latéraux s'approchent de la paroi frontale (122, 222), plus la paroi de fond (112a) se rapproche de la face interne de la paroi tubulaire (121, 221) de la pièce extérieure.The side channels (224) of the 2nd nozzle are placed on the inner face of the tubular wall (221) of the outer part. They also have a cross section which decreases due to a slight inclination of the side walls and the bottom wall of the channels. In other words, the closer the side channels get to the front wall (122, 222), the closer the side walls get to each other. Another alternative or complementary solution may provide that the closer the side channels get to the front wall (122, 222), the closer the bottom wall (112a) gets to the inner face of the tubular wall (121, 221) of the outer part.
L'intersection entre chaque paroi latérale et la paroi de fond des canaux latéraux peuvent former un angle non droit, les deux parois s'inclinant par rapport à la paroi de fond de préférence dans la même direction, les deux parois étant de préférence inclinées selon un même angle. Il serait également possible que les deux parois s'étendant parallèlement l'une à l'autre.The intersection between each side wall and the bottom wall of the side channels may form a non-right angle, the two walls sloping relative to the bottom wall preferably in the same direction, the two walls preferably being sloping at the same angle. It would also be possible for the two walls to extend parallel to each other.
Une des parois latérales des canaux latéraux est arrondie et se trouve dans le prolongement de la paroi latérale des canaux convergents. Cette forme arrondie de la paroi latérale contribue à guider le flux dans le canal convergent correspondant. La deuxième paroi latérale des canaux latéraux est droite et sensiblement radiale.One of the side walls of the lateral channels is rounded and is an extension of the side wall of the converging channels. This rounded shape of the side wall helps guide the flow into the corresponding converging channel. The second side wall of the lateral channels is straight and substantially radial.
Les canaux convergents peuvent être placés dans la paroi frontale de la cavité de la pièce extérieure ou sur la face frontale de la pièce intérieure.The converging channels can be placed in the front wall of the cavity of the outer part or on the front face of the inner part.
Dans l'exemple de la 2ème buse, il y a deux jeux de canaux convergents. Les canaux convergents du premier jeu partent des canaux latéraux et débouchent radialement dans une première cavité annulaire d'où partent les canaux du deuxième jeu qui débouchent radialement dans une deuxième cavité circulaire ou annulaire formant la chambre de turbulence (227) et d'où part l'ouverture de sortie (223).In the example of the 2nd nozzle, there are two sets of converging channels. The converging channels of the first set start from the lateral channels and open radially into a first annular cavity from which the channels of the second set start, which open radially into a second circular or annular cavity forming the turbulence chamber (227) and from which the outlet opening (223) starts.
Quand les canaux latéraux et les canaux convergents ne sont pas réalisés dans la même pièce, il est préférable que la pièce intérieure (11) soit bien orientée par rapport à la pièce extérieure (12) et qu'elle conserve cette orientation durant toute l'utilisation du diffuseur portant la buse afin d'assurer un bon fonctionnement de la buse et de permettre de limiter la section transversale des canaux latéraux (112) au niveau de leur jonction avec des canaux convergents. Pour cela, on peut prévoir des premiers moyens d'orientation, tels que des détrompeurs ou des repères d'orientation. Une autre solution consiste à orienter correctement la pièce intérieure avant de l'introduire dans la pièce extérieure. Par ailleurs, pour maintenir la bonne orientation de la pièce intérieure dans la pièce extérieure durant toute la durée de vie du diffuseur, la pièce intérieure (11) peut être légèrement surdimensionnée par rapport à la cavité de la pièce extérieure (12) de sorte qu'elle est entrée en force et maintenue dans la bonne position par serrage. Grâce à cette bonne orientation des deux pièces, on peut limiter la section transversale des canaux latéraux (112) puisqu'il est sûr qu'ils déboucheront exactement dans l'entrée des canaux convergents (125). Il va de soi que dans la deuxième buse aussi, la pièce intérieure (21) peut être bloquée dans la cavité de la pièce extérieure (22) soit par des moyens d'orientation soit par montage serrant ou montage à force, bien que la question de l'alignement des canaux latéraux et des canaux convergents ne se pose pas.When the side channels and the converging channels are not made in the same part, it is preferable that the inner part (11) is well oriented with respect to the outer part (12) and that it maintains this orientation throughout the use of the diffuser carrying the nozzle in order to ensure proper operation of the nozzle and to limit the cross-section of the lateral channels (112) at their junction with converging channels. For this, it is possible to provide first orientation means, such as foolproofers or orientation markers. Another solution consists of correctly orienting the inner part before introducing it into the outer part. Furthermore, to maintain the correct orientation of the inner part in the outer part throughout the lifetime of the diffuser, the inner part (11) can be slightly oversized compared to the cavity of the outer part (12) so that it is forced in and held in the correct position by clamping. Thanks to this correct orientation of the two parts, it is possible to limit the cross-section of the lateral channels (112) since it is certain that they will open exactly into the inlet of the converging channels (125). It goes without saying that in the second nozzle too, the inner part (21) can be locked in the cavity of the outer part (22) either by orientation means or by clamping or force-fitting, although the question of the alignment of the side channels and the converging channels does not arise.
Quand les canaux latéraux et les canaux convergents sont placés sur la même pièce, dans le cas de la deuxième buse sur la pièce extérieure (22), la question de l'orientation ne se pose pas. Il est alors possible de prévoir que la pièce intérieure (21) soit maintenue dans la cavité de la pièce extérieure (22) tout en pouvant tourner autour de l'axe principal (A). Dans ce cas, on peut prévoir des moyens de retenue, par exemple un système d'encliquetage, qui empêche la pièce intérieure de ressortir de la cavité sans pour autant l'empêcher de tourner. Cette solution peut favoriser la vibration de la buse et créer un phénomène de résonance dans le flux, améliorant encore la qualité du spray.When the side channels and the converging channels are placed on the same part, in the case of the second nozzle on the outer part (22), the question of orientation does not arise. It is then possible to provide that the inner part (21) is held in the cavity of the outer part (22) while being able to rotate around the main axis (A). In this case, it is possible to provide retaining means, for example a snap-in system, which prevents the inner part from coming out of the cavity without preventing it from rotating. This solution can promote the vibration of the nozzle and create a resonance phenomenon in the flow, further improving the quality of the spray.
Dans une variante de réalisation de l'invention, la buse est utilisée dans un diffuseur pour valve à deux voies. Dans ce cas, le conduit du diffuseur est conçu pour maintenir la séparation des voies entre la sortie du stem de la valve et la buse. La première voie de la valve est mise en contact avec une partie des canaux latéraux et la deuxième voie avec le reste des canaux latéraux. Le mélange des produits se fait alors dans la chambre de turbulence. Il faut donc que la buse soit correctement orientée dans le diffuseur. Cela peut se faire soit en conservant l'orientation initiale de la buse, par exemple en la maintenant dans son empreinte de moulage jusqu'au moment de sa mise en place dans le diffuseur, soit en prévoyant des moyens d'orientation tels que des détrompeurs. Une autre solution consiste à répartir les entrées des canaux latéraux et/ou leur étendue angulaire de telle sorte que, quelle que soit la position de la buse, un même canal latéral ne puisse pas être en contact simultanément avec la première voie et avec la deuxième voie.In an alternative embodiment of the invention, the nozzle is used in a diffuser for a two-way valve. In this case, the diffuser duct is designed to maintain the separation of the paths between the outlet of the valve stem and the nozzle. The first path of the valve is brought into contact with a portion of the side channels and the second path with the remainder of the side channels. The mixing of the products then takes place in the turbulence chamber. It is therefore necessary for the nozzle to be correctly oriented in the diffuser. This can be done either by maintaining the initial orientation of the nozzle, for example by keeping it in its molding cavity until it is placed in the diffuser, or by providing orientation means such as polarizing devices. Another solution consists of distributing the inlets of the side channels and/or their angular extent in such a way that, whatever whatever the position of the nozzle, the same side channel cannot be in contact simultaneously with the first channel and with the second channel.
Il est de plus possible de prévoir sur la face arrière (115, 215) de la pièce intérieure (11, 21), face opposée à la face frontale (111, 211), un ou plusieurs canaux divergents, identiques ou différents des canaux convergents.It is further possible to provide on the rear face (115, 215) of the inner part (11, 21), the face opposite the front face (111, 211), one or more diverging channels, identical or different from the converging channels.
La pièce extérieure (12, 22) est réalisée de préférence en polyacétal tel que du POM. Elle peut aussi être réalisée en polyamide ou en polyester semi-cristallin tel que du PBT. La pièce intérieure (11, 21) est quant à elle de préférence réalisée en polyacétal tel que du POM. Elle peut aussi être réalisée en polyamide ou en polyester semi-cristallin tel que du PBT. Ces matériaux offrent l'avantage d'être fluides et permettent le moulage de pièces de précisions avec une bonne stabilité géométrique et dimensionnelle. De plus ils sont rigides, ce qui permet un bon ancrage de la buse dans le diffuseur via les moyens d'ancrage (126, 226) qui s'agrippent dans le matériau plus mou de type PP du diffuseur. De plus, dans le cas où une stérilisation par rayonnements ionisants serait requise pour le diffuseur muni de sa buse, le PBT aura un meilleur comportement que le POM ou certains PA.The outer part (12, 22) is preferably made of polyacetal such as POM. It can also be made of polyamide or semi-crystalline polyester such as PBT. The inner part (11, 21) is preferably made of polyacetal such as POM. It can also be made of polyamide or semi-crystalline polyester such as PBT. These materials offer the advantage of being fluid and allow the molding of precision parts with good geometric and dimensional stability. In addition, they are rigid, which allows good anchoring of the nozzle in the diffuser via the anchoring means (126, 226) which grip in the softer PP-type material of the diffuser. In addition, in the case where sterilization by ionizing radiation is required for the diffuser equipped with its nozzle, the PBT will have better behavior than the POM or certain PAs.
La buse de l'invention est placée dans un logement prévu directement à la sortie du conduit. Des moyens d'ancrage (126, 226) garantissent une fixation sûre de la buse à la sortie du conduit du diffuseur. La buse ainsi retenue ne peut pas être éjectée, même quand la pression régnant à l'intérieur du conduit est importante et que la valve est ouverte. Si nécessaire, le fond du logement peut présenter des canaux divergents débouchant dans les canaux latéraux de la buse.The nozzle of the invention is placed in a housing provided directly at the outlet of the duct. Anchoring means (126, 226) ensure secure attachment of the nozzle to the outlet of the diffuser duct. The nozzle thus retained cannot be ejected, even when the pressure inside the duct is high and the valve is open. If necessary, the bottom of the housing can have diverging channels opening into the lateral channels of the nozzle.
Les exemples présentés ici n'ont pas de caractères limitatifs. Notamment, les variantes suivantes peuvent être envisagées selon les besoins :
- La cavité de la pièce extérieure (12, 22) et la pièce intérieure (11, 21) peuvent avoir la forme d'un cylindre ou d'un cône, non pas de révolution, mais à base polygonale. Notamment, on peut prévoir une base polygonale ayant le même nombre de côtés qu'il y a de canaux latéraux.
- La paroi frontale (12, 22) de la pièce extérieure et la face frontale (111, 211) de la pièce intérieure sont sensiblement radiales dans les exemples présentés ici. On pourrait leur donner une autre forme, par exemple conique ou bombée, par exemple hémisphérique.
- Le nombre de canaux latéraux et de canaux convergents est généralement de deux ou de quatre. D'autres configurations peuvent être cependant envisagées.
- The cavity of the outer part (12, 22) and the inner part (11, 21) may have the shape of a cylinder or a cone, not of revolution, but with a polygonal base. In particular, a polygonal base may be provided having the same number of sides as there are lateral channels.
- The front wall (12, 22) of the outer part and the front face (111, 211) of the inner part are substantially radial in the examples presented here. They could be given another shape, for example conical or curved, for example hemispherical.
- The number of side channels and converging channels is usually two or four. However, other configurations can be considered.
Il va de soi que les caractéristiques suivantes peuvent être utilisées indépendamment les unes des autres et qu'il serait possible de prévoir des buses présentant une ou plusieurs de ces caractéristiques :
- canaux latéraux non verticaux, c.-à-d. divergents du plan axial, par exemple des canaux hélicoïdaux ;
- pièce intérieure libre en rotation dans la pièce extérieure.
- non-vertical lateral channels, i.e. diverging from the axial plane, e.g. helical channels;
- free rotating inner part in the outer part.
En choisissant une structure en deux pièces, il est possible de donner toute sorte de formes aux canaux, notamment aux canaux latéraux, et des longueurs ajustables pour un encombrement donné constant de la pièce interne.By choosing a two-piece structure, it is possible to give all kinds of shapes to the channels, especially the side channels, and adjustable lengths for a constant given size of the internal part.
Claims (14)
- Two-piece nozzle for an aerosol dispenser, comprising,- an outer piece (12, 22) provided with a tubular wall (121, 221) open on one side and closed on another side by a front wall (122, 222) forming a cavity, the front wall being provided at a center thereof with an outlet opening (123, 223), the outer piece having a certain symmetry about an axis of symmetry (A),- an inner piece (11, 21) separate from the dispenser for which the nozzle is intended, which inner piece (11, 21) is dimensioned to penetrate into the cavity of the outer piece while being retained therein, the inner piece having a front face (111, 211) facing the front wall (122, 222) of the outer piece and a lateral face following the front face,channels (112, 125, 224, 225) being made in the cavity of the outer piece (12, 22) and/or on the surface of the inner piece (11, 21), which channels open into a turbulence chamber (127, 227) in communication with the outlet opening (123, 223), the outlet opening (123, 223) being placed in the flow path of the product flow downstream of the turbulence chamber (127, 227),wherein the channels are divided into lateral channels (112, 224) made in the lateral face of the inner piece (11, 21) and/or in the inner face of the tubular wall of the outer piece (12, 22), and into converging channels (125, 225) made in the front wall (122, 222) of the outer piece or in the front face (111, 211) of the inner piece.characterized in that- the transverse cross-section of the lateral channels (112, 112', 224) decreases between the upstream end of the channels, located opposite to the front face (111, 211) or the front wall (122, 222), and the downstream end of the channels, located on the side of the front face (111, 211) or the front wall (122, 222), and in that- the inner piece has a rear face (115, 215) provided with a peripheral edge projecting in the direction opposite to the front face (111, 211), one or more passages being made in the peripheral edge to bring in contact the inner face and the outer face of said peripheral edge, which passages open into the lateral channels when said lateral channels are made in the lateral wall of the inner piece.
- Nozzle (1, 2) according to one of the preceding claims, characterized in that the lateral channels (112, 112', 224) have a bottom wall (112a) surrounded by two side walls (112b), and in that the closer the side channels come to the front wall (122, 222) or the front face (111, 211), the closer the side walls (112b) come to each other and/or the closer the bottom wall (112a) comes to the inner face of the tubular wall (121, 221) of the outer piece, when the channels are placed on the outer piece, or to the lateral face of the inner piece, when the channels are placed on the inner piece.
- Nozzle (1, 2) according to one of the preceding claims, characterized in that the lateral channels have a bottom wall surrounded by two side walls, the intersection between each side wall and the bottom wall forming a non-right angle, the two walls being preferably inclined relative to the bottom wall in the same direction, the two walls preferably being inclined at the same angle and/or the two walls preferably extending parallel to each other.
- Nozzle (1, 2) according to one of the preceding claims, characterized in that the front face (111, 211) of the inner piece is free of protrusion, or in that the front face (111, 211) of the inner piece has a protrusion, the end of which does not penetrate into the outlet opening (123, 223').
- Nozzle (1, 2) according to one of the preceding claims, characterized in that the cavity of the outer piece (12, 22) and the inner piece (11, 21) have the shape of a cylinder of revolution or of a cone of revolution about the axis of symmetry (A).
- Nozzle (1, 2) according to one of the preceding claims, characterized in that the lateral channels (112, 224) are substantially rectilinear and parallel to an axial plane passing through them and defined by a main axis (A) passing through the center of the nozzle.
- Nozzle (1, 2) according to one of claims 1 to 5, characterized in that the lateral channels are not rectilinear and diverge from an axial plane defined by a main axis (A) passing through the center of the nozzle, the lateral channels preferably having a helical shape.
- Nozzle (1, 2) according to one of the preceding claims, characterized in that the converging channels extend from the envelope that defines the lateral face of the inner piece or the inner face of the tubular wall of the outer piece toward the turbulence chamber (127, 227) into which they open preferably tangentially.
- Nozzle (1, 2) according to one of the preceding claims, characterized in that the rear face (115, 215) of the inner piece is substantially planar.
- Nozzle (1, 2) according to one of the preceding claims, characterized in that- the nozzle is provided with fixing means for fixing the inner piece (11, 21) in the cavity of the outer piece (12, 22) so that it is immobilized in the cavity, or in that- the inner piece (11, 21) is dimensioned to be retained by a tight fit in the cavity of the outer piece (12, 22) so as to be immobilized therein.
- Nozzle (1, 2) according to one of the preceding claims, characterized in that- the inner piece and/or the outer piece are provided with first orientation means for orienting the inner piece relative to the outer piece in order to align the channels with one another, and/or in that- the nozzle (1, 2) is provided with second orientation means for orienting the nozzle relative to the dispenser for which it is intended.
- Nozzle (1, 2) according to one of the preceding claims, characterized in that- the lateral channels are placed on the lateral face of the inner piece, the transverse cross-section of the lateral channels decreasing from the upstream end, located opposite to the front face, and the downstream end, located on the side of the front face, the lateral channels being provided with a bottom wall surrounded by two side walls which each form a non-right angle with the bottom wall, the two side walls preferably extending parallel to each other;- the converging channels are placed on the front wall of the outer piece;- the front face of the inner piece is free of protrusion, or has a protrusion whose end opposite to the front face does not penetrate into the outlet opening of the front wall of the outer piece;- the inner piece preferably being dimensioned to be retained by a tight fit in the cavity of the outer piece so as to be immobilized therein.
- Nozzle (1, 2) according to one of the preceding claims, characterized in that the inner piece (11, 21) has a rear face (115, 215) provided with divergent channels, preferably opening into the lateral channels.
- Nozzle (1, 2) according to one of the preceding claims, characterized in that the nozzle is mounted in a housing of an aerosol dispenser, the housing possibly having a bottom face provided with divergent channels.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2019/059173 WO2020207584A1 (en) | 2019-04-10 | 2019-04-10 | Two-piece nozzle for aerosol dispensers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP3953051A1 EP3953051A1 (en) | 2022-02-16 |
| EP3953051B1 true EP3953051B1 (en) | 2025-04-23 |
| EP3953051C0 EP3953051C0 (en) | 2025-04-23 |
Family
ID=66223691
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19718293.4A Active EP3953051B1 (en) | 2019-04-10 | 2019-04-10 | Two-piece nozzle for aerosol dispensers |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20220184645A1 (en) |
| EP (1) | EP3953051B1 (en) |
| AR (1) | AR118646A1 (en) |
| CA (1) | CA3133778C (en) |
| MX (1) | MX2021012379A (en) |
| WO (1) | WO2020207584A1 (en) |
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|---|---|---|---|---|
| CN114622386B (en) * | 2020-12-14 | 2025-11-28 | 青岛海尔洗涤电器有限公司 | Nozzle structure, additive throwing device and washing machine |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3129893A (en) * | 1962-05-31 | 1964-04-21 | Edward Howard Green | Spray head for swirling spray |
| US4260110A (en) * | 1977-02-18 | 1981-04-07 | Winfried Werding | Spray nozzle, devices containing the same and apparatus for making such devices |
| US4187985A (en) * | 1978-12-08 | 1980-02-12 | The Continental Group, Inc. | Aerosol valve for barrier type packages |
| CH650469A5 (en) * | 1982-11-10 | 1985-07-31 | Werding Winfried J | DEVICE FOR CONTROLLING THE THRUST OF A FLUID USING TURBULENCE. |
| DE4134885C2 (en) * | 1991-10-23 | 1994-04-07 | Praezisions Ventil Gmbh | Actuator attachment for a spray container |
| ES2130943B1 (en) * | 1996-06-18 | 2000-02-16 | Fico Transpar Sa | SPRAY DEVICE FOR WINDSHIELD WASHERS OF AUTOMOBILE VEHICLES. |
| FR2772645B1 (en) * | 1997-12-24 | 2000-01-28 | D Investissement Ind Et Commer | SPRAY NOZZLE WITH INSERTED PLATE |
| FR2792552B1 (en) * | 1999-04-20 | 2002-04-19 | Valois Sa | FLUID PRODUCT SPRAY HEAD COMPRISING AN IMPROVED SHUTTER |
| FR2835203B1 (en) * | 2002-01-25 | 2004-04-09 | Verbena Corp N V | SPRAY NOZZLE WITH REDUCED DIAMETER |
| FR2860771B1 (en) * | 2003-10-09 | 2006-03-03 | Valois Sas | FLUID PRODUCT DISPENSING HEAD AND METHOD OF MANUFACTURING SUCH A HEAD |
| WO2007004314A1 (en) * | 2005-07-06 | 2007-01-11 | Mitani Valve Co., Ltd. | Content discharge mechanism, and aerosol-type product and pump-type product with the same |
| US9527092B2 (en) | 2010-06-15 | 2016-12-27 | Daizo Corporation | Nozzle hole mechanism |
| KR101022601B1 (en) * | 2010-08-19 | 2011-03-16 | 정해룡 | Dispenser Nozzle |
| EP2570190A1 (en) * | 2011-09-15 | 2013-03-20 | Braun GmbH | Spray nozzle for dispensing a fluid and sprayer comprising such a spray nozzle |
| KR101233080B1 (en) * | 2011-09-20 | 2013-02-14 | (주)연우 | Spray pump |
| WO2015138241A1 (en) * | 2014-03-10 | 2015-09-17 | Plastek Industries, Inc. | Modular spray cap |
| KR101661575B1 (en) * | 2014-10-22 | 2016-10-04 | (주)연우 | Spray orifice structure |
| KR101826634B1 (en) * | 2016-03-28 | 2018-02-08 | 임종수 | Mist pump of cosmetic containers |
| KR102077606B1 (en) * | 2018-03-15 | 2020-02-17 | (주)연우 | orifice and spray vessel having the same |
-
2019
- 2019-04-10 MX MX2021012379A patent/MX2021012379A/en unknown
- 2019-04-10 US US17/602,315 patent/US20220184645A1/en active Pending
- 2019-04-10 CA CA3133778A patent/CA3133778C/en active Active
- 2019-04-10 WO PCT/EP2019/059173 patent/WO2020207584A1/en not_active Ceased
- 2019-04-10 EP EP19718293.4A patent/EP3953051B1/en active Active
-
2020
- 2020-04-09 AR ARP200101019A patent/AR118646A1/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| US20220184645A1 (en) | 2022-06-16 |
| MX2021012379A (en) | 2021-11-04 |
| WO2020207584A1 (en) | 2020-10-15 |
| BR112021020233A2 (en) | 2021-12-07 |
| AR118646A1 (en) | 2021-10-20 |
| EP3953051C0 (en) | 2025-04-23 |
| CA3133778C (en) | 2023-09-26 |
| CA3133778A1 (en) | 2020-10-15 |
| EP3953051A1 (en) | 2022-02-16 |
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