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EP3186351B1 - Lingette à détergent tous lavages munie d'un substrat détergent - Google Patents

Lingette à détergent tous lavages munie d'un substrat détergent Download PDF

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Publication number
EP3186351B1
EP3186351B1 EP15771501.2A EP15771501A EP3186351B1 EP 3186351 B1 EP3186351 B1 EP 3186351B1 EP 15771501 A EP15771501 A EP 15771501A EP 3186351 B1 EP3186351 B1 EP 3186351B1
Authority
EP
European Patent Office
Prior art keywords
phase
substrate
laundry detergent
washing
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP15771501.2A
Other languages
German (de)
English (en)
Other versions
EP3186351C0 (fr
EP3186351A1 (fr
Inventor
Marcus Mausberg
Michael Pulina
Jost Adler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Coin Consulting GmbH
Original Assignee
Coin Consulting GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Coin Consulting GmbH filed Critical Coin Consulting GmbH
Publication of EP3186351A1 publication Critical patent/EP3186351A1/fr
Application granted granted Critical
Publication of EP3186351C0 publication Critical patent/EP3186351C0/fr
Publication of EP3186351B1 publication Critical patent/EP3186351B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile

Definitions

  • the present invention relates to heavy-duty detergent wipes for cleaning textiles and in particular heavy-duty detergent wipes in which the substrate contains homogeneously distributed washing-active components, and to a process for their production.
  • Hygiene has been a priority since the dawn of civilization. After all, hygiene is an important component in people's everyday lives. Human hygiene is primarily about maintaining health. With the further development of the possibilities, in addition to the basic cleaning effects, the scent and the improvement of the cleaning performance through the raw material mixtures used came into focus. The optimization of the cleaning performance is characterized in particular by the possibility of extending a hygienically clean state and improving the degree of cleaning.
  • a detergent powder is still a mixture of different washing-active substances.
  • liquid detergents which can be dosed without leaving any residue and represent a physical alternative to the solid mixture of detergents.
  • the cleaning properties of liquid detergents have not yet reached the cleaning level of heavy-duty detergents (i.e. a mixture of solids).
  • the reason for this lies in the fact that a liquid detergent is limited to liquid components or components that are readily soluble in water.
  • the decisive missing substance in a liquid detergent is the group of zeolites. These support the dirt adsorption as well as the gloss formation/color fastness during use.
  • a current product trend is the way the detergent is portioned. On the one hand, this can be done by packaging a liquid detergent in small polymer bags. Another physical modification of the detergent is blending a detergent with a fatty alcohol so that desired shapes can be achieved.
  • the DE 10 2010 060 126 A1 discloses a two-phase product in the form of a laundry detergent wipe characterized by the combination of a hydrophilic carrier substrate and a liquid impregnating solution.
  • the DE 10 2013 014 015 in contrast, discloses a three-phase product in which a dispersion was applied to a carrier substrate that is solid at room temperature.
  • a dispersion for the first time, it was possible to achieve a cleaning performance with the characteristics of a detergent powder (eg zeolites, phyllosilicates, etc.).
  • Hydrophobic carrier substrates were primarily used here, since the detergent dispersion also has hydrophobic properties due to the higher proportion of washing-active substances in relation to the two-phase system.
  • the DE 10 2014 004 915 discloses a further improved Three-phase product with a more homogeneous distribution of the washing-active substances and a process for its production.
  • the EP 0 957 158 A1 discloses a detergent article in the form of a rigid sheet product comprising two water-soluble substrates sandwiched on either side of a thin layer of dry detergent putty, powder or granules, respectively, such that the product comprises three solid phases and is therefore completely dry.
  • This dry detergent item completely dissolves with its use.
  • the U.S. 2003/207630 A1 discloses a detergent product in which a homogeneous detergent slurry is applied to a substrate, after which the water portion of the slurry is evaporated so that the final product - like the detergent article, the EP 0 957 158 A1 - comprises two solid phases and is therefore completely dry.
  • the object of the present invention was to provide a detergent cloth with homogeneous distribution of the washing-active substances or solid components of the dispersion on the substrate and a process for its production in order to achieve a further improved distribution of the active substances and thus better performance of the detergent cloth.
  • the distribution of the washing-active substances or solid components of a dispersion on a substrate is generally not homogeneous.
  • the three-phase detergent sheet according to the invention with a homogeneous distribution of the washing-active substances or solid components on a substrate could be realized by the secondary builders (zeolite and/or phyllosilicates and/or optical brighteners) which are solid and water-insoluble at room temperature and previously contained on the substrate applied dispersion, are now incorporated into the substrate, which is solid at room temperature, during its manufacturing process - i.e. before the application of a liquid impregnation medium.
  • the solid, water-insoluble additives can be added in a water bath before the substrate solidifies.
  • the zeolite and/or the phyllosilicates can be sprayed on by means of a slurried dispersion (additive/water or the like) during production of the substrate.
  • the incorporation of solid, water-insoluble and washing-active substances leads to activation of the substrate with components that give the three-phase end product the properties of a heavy-duty detergent.
  • the substrate functionalized in this way is impregnated with a liquid impregnation medium, which is a liquid detergent.
  • the functionalized substrate can be impregnated with the liquid detergent formulation by soaking in an immersion bath, spraying the liquid detergent onto the active substrate or moistening the substrate with the liquid detergent using one or more moistening sticks.
  • the substrate raw materials listed can be fiber mixtures (one or more filament fibers), as well as mixed fibers (sheath-core, or side by side).
  • the components described are hydrophobic and therefore have the further advantageous property of absorbing hydrophobic textile dyes in the hydrophilic wash water.
  • This invention can be used across all categories of detergents.
  • the following impregnation media were used in their construction: Heavy duty detergent cloth (universal): anionic surfactants nonionic surfactants Phosphonates/Complexing Agents C10-C18 fatty acid salts Optical brighteners enzymes Stabilizers (propylene glycol, glycerin, borax, inulin) fragrances preservatives Soil release polymer pH regulators Color detergent cloth (Color): anionic surfactants nonionic surfactants Phosphonates/Complexing Agents C10-C18 fatty acid salts dyes Color transfer protection Hydrotropes (Sodium Cumene Sulfonate) enzymes Stabilizers (propylene glycol, glycerin, borax, inulin) fragrances preservatives Soil release polymer pH regulators Black detergent cloth (black): anionic surfactants nonionic surfactants Phosphonates/Complexing Agents C10-C18 fatty acid salts dyes Color
  • the liquid detergent of the impregnation medium can have a viscosity of more than 500 mPas. Furthermore, all known components of a liquid detergent can be included.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)

Claims (10)

  1. Procédé de fabrication d'une lingette à détergent triphasique homogène caractérisé par les étapes suivantes :
    (a) incorporation de substances détergentes, insolubles dans l'eau et solides à température ambiante dans un substrat solide à température ambiante, de sorte que les substances sont dispersées de manière homogène dans le substrat après l'incorporation,
    (b) trempage du substrat ainsi fonctionnalisé dans un milieu de trempage liquide de sorte que la lingette à détergent triphasique comprenne une phase liquide.
  2. Procédé de fabrication d'une lingette à détergent triphasique homogène selon la revendication 1, caractérisé en ce que les substances détergentes insolubles dans l'eau contiennent des zéolithes, et/ou des phyllosilicates, et/ou des azurants optiques.
  3. Procédé de fabrication d'une lingette à détergent triphasique homogène selon la revendication 1 ou la revendication 2, caractérisé en ce que le substrat est constitué d'au moins une fibre sans fin ou d'une fibre mixte.
  4. Procédé de fabrication d'une lingette à détergent triphasique homogène selon l'une des revendications 1 à 3, caractérisé en ce que le substrat est constitué d'au moins une fibre synthétique hydrophobe de sorte qu'il présente une propriété de capture de la couleur.
  5. Procédé de fabrication d'une lingette à détergent triphasique homogène selon l'une des revendications 1 à 4, caractérisé en ce que le milieu de trempage est un détergent liquide.
  6. Lingette à détergent triphasique comprenant un substrat solide à température ambiante et trempé dans un milieu de trempage liquide, caractérisée en ce que des substances détergentes, insolubles dans l'eau et solides à température ambiante sont incorporées dans le substrat de sorte que les substances sont dispersées de manière homogène dans le substrat et la lingette à détergent triphasique comprend une phase liquide.
  7. Lingette à détergent triphasique selon la revendication 6, caractérisée en ce que les substances détergentes insolubles dans l'eau contiennent des zéolithes, et/ou des phyllosilicates, et/ou des azurants optiques.
  8. Lingette à détergent triphasique selon la revendication 6 ou la revendication 7, caractérisée en ce que le substrat est constitué d'au moins une fibre sans fin ou d'une fibre mixte.
  9. Lingette à détergent triphasique selon l'une des revendications 6 à 8, caractérisée en ce que le substrat est constitué d'au moins une fibre synthétique hydrophobe de sorte qu'il présente une propriété de capture de la couleur.
  10. Lingette à détergent triphasique selon l'une des revendications 6 à 9, caractérisée en ce que le milieu de trempage est un détergent liquide.
EP15771501.2A 2014-08-25 2015-08-20 Lingette à détergent tous lavages munie d'un substrat détergent Active EP3186351B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102014012380.4A DE102014012380A1 (de) 2014-08-25 2014-08-25 Vollwaschmitteltuch mit waschaktivem Substrat
PCT/DE2015/000416 WO2016029894A1 (fr) 2014-08-25 2015-08-20 Lingette à détergent tous lavages munie d'un substrat détergent

Publications (3)

Publication Number Publication Date
EP3186351A1 EP3186351A1 (fr) 2017-07-05
EP3186351C0 EP3186351C0 (fr) 2023-06-07
EP3186351B1 true EP3186351B1 (fr) 2023-06-07

Family

ID=54207269

Family Applications (1)

Application Number Title Priority Date Filing Date
EP15771501.2A Active EP3186351B1 (fr) 2014-08-25 2015-08-20 Lingette à détergent tous lavages munie d'un substrat détergent

Country Status (9)

Country Link
US (1) US10781409B2 (fr)
EP (1) EP3186351B1 (fr)
CN (1) CN107075430A (fr)
CA (1) CA2986159A1 (fr)
DE (1) DE102014012380A1 (fr)
ES (1) ES2950613T3 (fr)
PL (1) PL3186351T3 (fr)
RU (1) RU2726845C2 (fr)
WO (1) WO2016029894A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015014015A1 (de) * 2015-10-30 2017-05-04 Coin Consulting GmbH Hochaktives Dreiphasen-Vollwaschmitteltuch und Verfahren zu dessen Herstellung
DE102017200139A1 (de) * 2017-01-08 2018-07-12 Coin Consulting GmbH Waschmitteltuch mit kontrollierter Aktivierung der waschaktiven Substanzen
DE102021212785A1 (de) 2021-11-13 2023-05-17 Coin Consulting GmbH Feuchttuch mit biologisch abbaubarem verbundträger

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030207630A1 (en) * 1995-12-19 2003-11-06 Newlund Laboratories, Inc. Method of making a laundry detergent article containing detergent formulations

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4740326A (en) * 1987-02-19 1988-04-26 The Procter & Gamble Company Soil release polymer coated substrate containing a laundry detergent for improved cleaning performance
US4938888A (en) * 1989-01-05 1990-07-03 Lever Brothers Company Detergent sheet with alkyl polyglycoside composition
JP3126675B2 (ja) * 1997-01-23 2001-01-22 花王株式会社 シート状洗剤
ES2193405T3 (es) * 1996-12-09 2003-11-01 Kao Corp Articulo impregnado de detergente.
AU2006233523B2 (en) * 2005-04-13 2010-06-03 Unilever Plc Liquid hard surface cleaning composition
US8066956B2 (en) * 2006-12-15 2011-11-29 Kimberly-Clark Worldwide, Inc. Delivery of an odor control agent through the use of a presaturated wipe
WO2008100842A1 (fr) * 2007-02-12 2008-08-21 Dow Global Technologies Inc. Composite
WO2011131585A1 (fr) * 2010-04-20 2011-10-27 Henkel Ag & Co. Kgaa Article de blanchissage ayant des propriétés nettoyantes
DE202010018072U1 (de) * 2010-10-22 2013-12-02 Albaad Deutschland Gmbh Feuchtes Waschmitteltuch
US20120255129A1 (en) * 2011-04-05 2012-10-11 Akos Jankura Method, apparatus and system for laundry cleaning
DE102013014015A1 (de) 2013-08-26 2015-02-26 Coin Consulting Ug (Haftungsbeschränkt) Dreiphasen-Vollwaschmitteltuch
DE102014004915A1 (de) 2014-04-07 2015-10-08 Coin Consulting Ug (Haftungsbeschränkt) Homogenes Dreiphasen-Waschmitteltuch und Verfahren zu dessen Herstellung
EP3039108A1 (fr) * 2013-08-26 2016-07-06 Coin Consulting UG (Haftungsbeschränkt) Lingette triple phase contenant un détergent et son procédé de fabrication

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030207630A1 (en) * 1995-12-19 2003-11-06 Newlund Laboratories, Inc. Method of making a laundry detergent article containing detergent formulations

Also Published As

Publication number Publication date
EP3186351C0 (fr) 2023-06-07
RU2726845C2 (ru) 2020-07-16
WO2016029894A4 (fr) 2016-05-12
RU2017105624A (ru) 2018-10-01
WO2016029894A1 (fr) 2016-03-03
US10781409B2 (en) 2020-09-22
EP3186351A1 (fr) 2017-07-05
RU2017105624A3 (fr) 2018-10-01
CN107075430A (zh) 2017-08-18
DE102014012380A1 (de) 2016-02-25
CA2986159A1 (fr) 2016-03-03
PL3186351T3 (pl) 2023-11-20
ES2950613T3 (es) 2023-10-11
US20180216042A1 (en) 2018-08-02

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