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EP3074495B1 - Composition de blanchisserie - Google Patents

Composition de blanchisserie Download PDF

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Publication number
EP3074495B1
EP3074495B1 EP14799722.5A EP14799722A EP3074495B1 EP 3074495 B1 EP3074495 B1 EP 3074495B1 EP 14799722 A EP14799722 A EP 14799722A EP 3074495 B1 EP3074495 B1 EP 3074495B1
Authority
EP
European Patent Office
Prior art keywords
cationic
silicone
polymer
anionic
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP14799722.5A
Other languages
German (de)
English (en)
Other versions
EP3074495A1 (fr
Inventor
Martin Charles Crossman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
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Unilever PLC
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Filing date
Publication date
Application filed by Unilever PLC filed Critical Unilever PLC
Priority to EP14799722.5A priority Critical patent/EP3074495B1/fr
Publication of EP3074495A1 publication Critical patent/EP3074495A1/fr
Application granted granted Critical
Publication of EP3074495B1 publication Critical patent/EP3074495B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions

Definitions

  • the silicone is added to the formulation in the form of an emulsion, more preferably in the form of a nonionic emulsion, most preferably using a branched nonionic emulsifier.
  • suitable synthetic anionic detergent compounds are sodium and potassium alkyl sulphates, especially those obtained by sulphating higher C 8 to C 18 alcohols, produced for example from tallow or coconut oil, sodium and potassium alkyl C 9 to C 20 benzene sulphonates, particularly sodium linear secondary alkyl C 10 to C 15 benzene sulphonates; and sodium alkyl glyceryl ether sulphates, especially those ethers of the higher alcohols derived from tallow or coconut oil and synthetic alcohols derived from petroleum.
  • the preferred anionic detergent compounds are sodium C 11 to C 15 alkyl benzene sulphonates and sodium C 12 to C 18 alkyl sulphates.
  • the total amount of surfactant present in the composition is from 5 to 40 wt.%.
  • the surfactant level is preferably at least 6 wt.%, more preferably at least 10 wt.%, More preferably the total amount of surfactant is from 12.5 to 40 wt.%, preferably from 15 to 35 wt.%.
  • the nonionic detergent is preferably present in amounts of from 2 to 40 wt.%, preferably from 5 to 35 wt.%, more preferably from 6 to 20 wt.%.
  • the anionic surfactant is preferably present in amounts of from 4 to 40 wt.%, preferably from 5 to 35 wt.%, more preferably from 6 to 20 wt.%.
  • Preferred anionic surfactants are: linear alkyl benezene sulphonates, sodium lauryl ether sulphonates with 1 to 3 moles (average) of ethoxylation, primary alkyl sulphonates, methyl ether sulphates and secondary alkyl sulphonates or mixtures thereof.
  • surfactants such as amphoteric, zwitterionic and cationic surfactants may also be present in addition to the aforementioned nonionic and anionic surfactants.
  • fabric softening anionic silicone examples include silicones that incorporate carboxylic, sulphate, sulphonic, phosphate and/or phosphonate functionality.
  • the fabric softening anionic silicone used herein contains anionic groups that not located on a terminal position on the silicone.
  • Some silicones are branched in nature. When this is the case, the terms 'terminal position' and 'at the end of the silicone chain' are used to indicate that the anionic functionality is not found on the terminus of the longest linear silicone chain.
  • Anionic silicones are those that comprise the anionic group at a mid-chain position on the silicone. So the anionic group(s) on the fabric softening anionic silicone are located at least 5 Si atoms from a terminal position on the longest linear silicone chain.
  • the silicone is added to the formulation in the form of an emulsion, more preferably in the form of a nonionic emulsion. More preferably the emulsion is prepared from nonionic emulsifiers, more preferably branched nonionic emulsifiers for examples Ecosurf EH-3 (Dow Chemical) or Berol 840 (Akzo Nobel).
  • the composition comprises a cationic polymer at a level of from 0.05 to 2.5 wt.%, preferably from 0.1 to 2 wt.%, more preferably from 0.1 to 1 wt.% most preferably from 0.1 to 0.75 wt.%.
  • the cationic polymer is selected from the group consisting of: cationic polysaccharide polymers, and cationic non-saccharide polymers having cationic protonated amine or quaternary ammonium functionalities that are homo or copolymers derived from monomers containing an amino or quaternary nitrogen functional group polymerised from at least one of the following monomer classes: acrylate, methacrylate, acrylamide, methacrylamide; allyls (including diallyl and methallyl); ethylene imine; and/or vinyl monomer classes, and mixtures thereof.
  • the cationic polymer is a cationic polysaccharide polymer.
  • the cationic polysaccharide polymer is a cationic guar or cationic cellulose polymer.
  • the cationic polymer is a cationic cellulose polymer, for example, quaternised hydroxy ethyl cellulose.
  • the composition may include a single cationic polymer or a mixture of cationic polymers from the same or different classes, i.e. the composition may contain a cationic polysaccharide polymer and a cationic non-polysaccharide polymer.
  • Suitable commercial cationic non-polysaccharide polymers are ones preferably but not exclusively taken from the Polyquarternium series for example Polyquat 5, 6, 7, 11, 15, 16, 28, 32, 37 and 46 which are sold commercially under the Flocare, Merquat, Salcare, Mirapol, Gafquat and Luviquat tradenames.
  • Cationic non-polysaccharides can be used without conforming to the Polyquaterium nomenclature.
  • a preferred class of cationic polysaccharide polymers suitable for this invention are those that have a polysaccharide backbone modified to incorporate a quaternary ammonium salt.
  • the quaternary ammonium salt is linked to the polysaccharide backbone by a hydroxyethyl or hydroxypropyl group.
  • the charged nitrogen of the quaternary ammonium salt has one or more alkyl group substituents.
  • Suitable cationic guar gum derivatives such as guar hydroxypropyltrimonium chloride, specific examples of which include the Jaguar series commercially available from Rhone-Poulenc Incorporated and the N-Hance series commercially available from Aqualon Division of Hercules, Inc.
  • guar 2-hydroxy-3-(trimethylammonium) propyl ether salt is guar 2-hydroxy-3-(trimethylammonium) propyl ether salt.
  • Cellulose is a polysaccharide with glucose as its monomer, specifically it is a straight chain polymer of D-glucopyranose units linked via ⁇ -1,4 glycosidic bonds and is a linear, non-branched polymer.
  • Example cationic cellulose polymers are salts of hydroxyethyl cellulose reacted with trimethyl ammonium substituted epoxide, referred to in the field under the International Nomenclature for Cosmetic Ingredients as Polyquatemium 10 and is commercially available from the Amerchol Corporation, a subsidiary of The Dow Chemical Company, marketed as the Polymer LR and JR series of polymers. Other polymers are marketed under the SoftCAT tradename from The Dow Chemical Company.
  • cationic celluloses include the polymeric quaternary ammonium salts of hydroxyethyl cellulose reacted with lauryl dimethyl ammonium-substituted epoxide referred to in the field under the International Nomenclature for Cosmetic Ingredients as Polyquatemium 24.
  • Typical examples of preferred cationic cellulosic polymers include cocodimethylammonium hydroxypropyl oxyethyl cellulose, lauryldimethylammonium hydroxypropyl oxyethyl cellulose, stearyldimethylammonium hydroxypropyl oxyethyl cellulose, and stearyldimethylammonium hydroxyethyl cellulose; cellulose 2-hydroxyethyl 2-hydroxy 3-(trimethyl ammonio) propyl ether salt, polyquaternium-4, polyquaternium-10, polyquaternium-24 and polyquaternium-67 or mixtures thereof.
  • the cationic cellulosic polymer is a quaternised hydroxy ether cellulose cationic polymer. These are commonly known as polyquaternium-10. Suitable commercial cationic cellulosic polymer products for use according to the present invention are marketed by The Dow Chemical Corporation under the trade name UCARE.
  • Preferred cationic non-saccharide polymers include cationic diallyl quaternary ammonium-containing polymers and homo or copolymers of dimethylaminoethyl (meth)acrylate, diethylaminoethyl (meth)acrylate or tert-butylaminoethyl (meth)acrylate in their quaternary or protonated amine form, and mixtures thereof.
  • the detergent composition may optionally comprise one or more of the following optional ingredients, fatty acids or salts thereof, shading dye, enzyme, antiredeposition polymer, dye transfer inhibiting polymer, builder, sequestrant, sunscreen, fluorescer, perfume, and/or soil release polymer.
  • Fatty acid is present at a level of from 0.25 to 12 wt.%, preferably from 0.5 to 10 wt.%.
  • the detergent compositions may also optionally contain relatively low levels of organic detergent builder or sequestrant material.
  • organic detergent builder or sequestrant material examples include the alkali metal, citrates, succinates, malonates, carboxymethyl succinates, carboxylates, polycarboxylates and polyacetyl carboxylates.
  • Specific examples include sodium, potassium and lithium salts of oxydisuccinic acid, mellitic acid, benzene polycarboxylic acids, ethylene diamine tetra-acetic acid, diethylenetriaminepentaacetic acid, alkyl- or alkenylsuccinic acid, nitrilotriacetic acid, and citric acid.
  • DEQUEST TM organic phosphonate type sequestering agents sold by Thermophos and alkanehydroxy phosphonates.
  • suitable organic builders include the higher molecular weight polymers and copolymers known to have builder properties.
  • such materials include appropriate polyacrylic acid, polymaleic acid, and polyacrylic/polymaleic acid copolymers and their salts, such as those sold by BASF under the name SOKALAN TM .
  • SOKALAN TM Another suitable builder is sodium carbonate.
  • the laundry detergent formulation is a non-phosphate built laundry detergent formulation, i.e., contains less than 1 wt.% of phosphate.
  • Shading dyes deposit to fabric during the wash or rinse step of the washing process providing a visible hue to the fabric. Shading of white garments may be done with any colour depending on consumer preference. Blue and Violet are particularly preferred shades and consequently preferred dyes or mixtures of dyes are ones that give a blue or violet shade on white fabrics. The shading dyes used are preferably blue or violet.
  • the shading dye chromophore is preferably selected from the group comprising: mono-azo, bis-azo, triphenylmethane, triphenodioxazine, phthalocyanin, naptholactam, azine and anthraquinone. Most preferably mono-azo, bis-azo, azine and anthraquinone.
  • Preferred shading dyes are selected from direct dyes, acid dyes, hydrophobic dyes, cationic dyes and reactive dyes.
  • the composition preferably comprises a fluorescent agent (optical brightener).
  • fluorescent agents are well known and many such fluorescent agents are available commercially. Usually, these fluorescent agents are supplied and used in the form of their alkali metal salts, for example, the sodium salts.
  • the total amount of the fluorescent agent or agents used in the composition is generally from 0.005 to 2 wt.%, more preferably 0.01 to 0.1 wt.%.
  • Preferred classes of fluorescer are: Di-styryl biphenyl compounds, e.g. Tinopal (Trade Mark) CBS-X, Di-amine stilbene di-sulphonic acid compounds, e.g.
  • Preferred fluorescers are: sodium 2-(4-styryl-3-sulfophenyl)-2H-napthol[1,2-d]trazole, disodium 4,4'-bis ⁇ [(4-anilino-6-(N methyl-N-2 hydroxyethyl) amino 1,3,5-triazin-2-yl)]amino ⁇ stilbene-2-2' disulfonate, disodium 4,4'-bis ⁇ [(4-anilino-6-morpholino-1,3,5-triazin-2-yl)]amino ⁇ stilbene-2-2' disulfonate, and disodium 4,4'-bis(2-sulfoslyryl)biphenyl.
  • the composition comprises a perfume.
  • the perfume is preferably in the range from 0.001 to 3 wt.%, most preferably 0.1 to 1 wt.%.
  • CTFA Cosmetic, Toiletry and Fragrance Association
  • Many suitable examples of perfumes are provided in the CTFA (Cosmetic, Toiletry and Fragrance Association) 1992 International Buyers Guide, published by CFTA Publications and OPD 1993 Chemicals Buyers Directory 80th Annual Edition, published by Schnell Publishing Co.
  • compositions of the present invention it is envisaged that there will be four or more, preferably five or more, more preferably six or more or even seven or more different perfume components.
  • top notes are defined by Poucher (Journal of the Society of Cosmetic Chemists 6(2):80 [1955 ]).
  • Preferred top-notes are selected from citrus oils, linalool, linalyl acetate, lavender, dihydromyrcenol, rose oxide and cis-3-hexanol.
  • the laundry treatment composition does not contain a peroxygen bleach, e.g., sodium percarbonate, sodium perborate, and peracid.
  • a peroxygen bleach e.g., sodium percarbonate, sodium perborate, and peracid.
  • the composition may comprise one or more polymers.
  • polymers are carboxymethylcellulose, hydroxyethyl cellulose, hydroxpropyl cellulose, poly(ethylene glycol), poly(vinyl alcohol), ethoxylated polyamines, polycarboxylates such as polyacrylates, maleic/acrylic acid copolymers and lauryl methacrylate/acrylic acid copolymers.
  • Modern detergent compositions typically employ polymers as so-called 'dye-transfer inhibitors'. These prevent migration of dyes, especially during long soak times.
  • dye-transfer inhibiting agents include polyvinyl pyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, manganese pthalocyanine, peroxidases, and mixtures thereof, and are usually present at a level of from 0.01 to 10 wt.% based on total amount in the laundry composition.
  • Anti-redeposition polymers are designed to suspend or disperse soil.
  • antiredeposition polymers are ethoxylated and or propoxylated polyethylene imine or polycarboxylate materials, for example, Acrylic acid based homo or copolymers available under the trade mark ACUSOL from Dow Chemical, Alcosperse from Akzonobel or Sokolan from BASF.
  • suitable soil release polymers include graft copolymers of poly(vinyl ester), e.g., C 1 -C 6 vinyl esters, preferably poly(vinyl acetate) grafted onto polyalkylene oxide backbones.
  • Commercially available soil release agents of this kind include the SOKALAN type of material, e.g., SOKALAN HP-22, available from BASF (Germany).
  • Further suitable soil release polymers of a different type include the commercially available material ZELCON 5126 (from DuPont) and MILEASE T (from ICI). If present, the soil release polymer may be included at a level of from from 0.01 to 10 wt.% based on total amount in the laundry composition.
  • Further examples of soil release polymers are terephthalic acid / glycol copolymers sold under the tradenames Texcare, Repel-o-tex, Gerol, Marloquest, Cirrasol.
  • the hydrotrope is selected from the group consisting of propylene glycol, xylene sulfonate, ethanol, and urea to provide optimum performance.
  • the amount of the hydrotrope is generally in the range of from 0 to 30%, preferably from 0.5 to 30%, more preferably from 0.5 to 30%, most preferably from 1 to 15%.
  • Enzymes can also be present in the formulation.
  • Preferred enzymes include protease, lipase, pectate lyase, amylase, cutinase, cellulase, mannanase. If present the enzymes may be stabilized with a known enzyme stabilizer for example boric acid.
  • Silicone 1 is according to the invention, while silicones X, Y and Z are comparative
  • anionic silicone (silicone 1) that is functionalised by mid chain anionic substituents, and moreover doesn't contain a terminal anionic silicone group shows the best stability in terms of reduced haze, in comparison to a non-anionic silicone (silicone X) and anionic silicones that have a terminal anionic group (silicones Y and Z).

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Claims (10)

  1. Composition détergente de lessive liquide comprenant :
    (a) de 5 à 40 % en masse de tensioactif ;
    (b) de 0,05 à 5 % en masse de silicone anionique assouplissant de textile ; et
    (c) de 0,05 à 2,5 % en masse de polymère cationique,
    dans laquelle le(les) groupe(s) anionique(s) sur le silicone anionique assouplissant de textile sont disposés à au moins 5 atomes de Si à partir d'une position terminale sur la chaîne de silicone linéaire la plus longue ; et,
    dans laquelle la composition détergente liquide présente un pH de 6 à 10.
  2. Composition selon la revendication 1, dans laquelle le silicone anionique présente une masse moléculaire de 1 000 à 100 000, de préférence de 2 000 à 50 000, encore mieux de 5 000 à 50 000, bien mieux encore de 10 000 à 50 000 ; et/ou le silicone anionique présente une teneur en groupe anionique d'au moins 1 % en mole, de préférence de 2 % en mole.
  3. Composition selon l'une quelconque des revendications précédentes, dans laquelle le silicone anionique comprend un carboxysilicone.
  4. Composition selon l'une quelconque des revendications précédentes, dans laquelle le silicone est ajouté à la formulation dans la forme d'une émulsion, de préférence une émulsion non ionique, encore mieux en utilisant un émulsionnant non ionique ramifié.
  5. Composition selon l'une quelconque des revendications précédentes, dans laquelle la composition détergente liquide présente un pH de pH 6,5 à 9,5, encore mieux de pH 7 à 9, par exemple de pH 7,5 à 8,5.
  6. Composition selon l'une quelconque des revendications précédentes, dans laquelle le polymère cationique est présent à une teneur de 0,1 à 2 % en masse, de préférence de 0,1 à 1 % en masse, encore mieux de 0,1 à 0,75 % en masse ; et le silicone anionique est présent à une teneur de 0,1 à 2,5 % en masse, de préférence de 0,1 à 2 % en masse.
  7. Composition selon l'une quelconque des revendications précédentes, dans laquelle le polymère cationique est un polymère de polysaccharide cationique, de préférence un polymère de guar cationique et/ou de cellulose cationique.
  8. Composition selon la revendication 7, dans laquelle le polymère de polysaccharide cationique est un polymère de cellulose cationique, de préférence l'hydroxyéthylcellulose quaternisée.
  9. Composition selon l'une quelconque des revendications précédentes, dans laquelle la composition comprend de plus un ingrédient choisi parmi, des acides gras ou des sels de ceux-ci, un colorant nuanceur, une enzyme, un polymère anti-redéposition, un polymère inhibant le transfert de colorant, un adjuvant, un séquestrant, un écran solaire, un fluorescent, un parfum, et/ou un polymère antisalissure.
  10. Utilisation d'une composition selon l'une quelconque des revendications 1 à 9 pour assouplir des textiles.
EP14799722.5A 2013-11-27 2014-11-12 Composition de blanchisserie Active EP3074495B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP14799722.5A EP3074495B1 (fr) 2013-11-27 2014-11-12 Composition de blanchisserie

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13194579 2013-11-27
PCT/EP2014/074345 WO2015078692A1 (fr) 2013-11-27 2014-11-12 Composition de blanchisserie
EP14799722.5A EP3074495B1 (fr) 2013-11-27 2014-11-12 Composition de blanchisserie

Publications (2)

Publication Number Publication Date
EP3074495A1 EP3074495A1 (fr) 2016-10-05
EP3074495B1 true EP3074495B1 (fr) 2017-07-05

Family

ID=49641668

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14799722.5A Active EP3074495B1 (fr) 2013-11-27 2014-11-12 Composition de blanchisserie

Country Status (6)

Country Link
EP (1) EP3074495B1 (fr)
CN (1) CN105745314B (fr)
BR (1) BR112016011675B1 (fr)
CL (1) CL2016001186A1 (fr)
ES (1) ES2642141T3 (fr)
WO (1) WO2015078692A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3722498A4 (fr) * 2017-12-06 2021-09-08 Kao Corporation Agent détachant
US11220657B2 (en) 2019-12-31 2022-01-11 Henkel IP & Holding GmbH Solid perfume composition delivering softening
US11447722B2 (en) 2020-01-30 2022-09-20 Henkel Ag & Co. Kgaa Detergent composition for textile softening and anti-redeposition

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CN109563444A (zh) 2016-08-10 2019-04-02 荷兰联合利华有限公司 洗衣组合物
WO2018028927A1 (fr) 2016-08-10 2018-02-15 Unilever Plc Composition de blanchisserie
WO2018060056A1 (fr) * 2016-09-29 2018-04-05 Unilever Plc Composition de blanchisserie
WO2018059892A1 (fr) * 2016-09-29 2018-04-05 Unilever Plc Composition de blanchisserie
EP3580315B1 (fr) 2017-02-13 2020-12-09 Unilever PLC Adjuvant pour composition de lavage
EP3580317B1 (fr) 2017-02-13 2021-10-13 Unilever IP Holdings B.V. Adjuvant pour composition de lavage
US11053463B2 (en) 2017-02-13 2021-07-06 Conopco, Inc. Method of delivering a laundry composition
WO2018146256A1 (fr) * 2017-02-13 2018-08-16 Unilever Plc Utilisation d'une silicone dans une composition de lessive
WO2019166477A1 (fr) * 2018-03-02 2019-09-06 Unilever Plc Compositions de blanchisserie
CN111971377B (zh) 2018-03-02 2022-06-21 联合利华知识产权控股有限公司 洗衣方法
EP3759206B1 (fr) * 2018-03-02 2024-04-03 Unilever IP Holdings B.V. Procédé d'adoucissement d'une composition de lessive
WO2019166476A1 (fr) * 2018-03-02 2019-09-06 Unilever Plc Compositions de lessive
CN112534032B (zh) * 2018-09-06 2023-02-21 陶氏环球技术有限责任公司 织物护理组合物
EP3874019B1 (fr) 2018-10-29 2022-07-27 Dow Global Technologies LLC Composition d'entretien des tissus comportant de la silicone
WO2021118774A1 (fr) * 2019-12-13 2021-06-17 Rohm And Haas Company Composition d'entretien pour tissus

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3722498A4 (fr) * 2017-12-06 2021-09-08 Kao Corporation Agent détachant
US11220657B2 (en) 2019-12-31 2022-01-11 Henkel IP & Holding GmbH Solid perfume composition delivering softening
US11447722B2 (en) 2020-01-30 2022-09-20 Henkel Ag & Co. Kgaa Detergent composition for textile softening and anti-redeposition

Also Published As

Publication number Publication date
BR112016011675A2 (pt) 2017-08-08
ES2642141T3 (es) 2017-11-15
BR112016011675B1 (pt) 2021-11-30
EP3074495A1 (fr) 2016-10-05
CL2016001186A1 (es) 2016-10-14
CN105745314A (zh) 2016-07-06
WO2015078692A1 (fr) 2015-06-04
CN105745314B (zh) 2018-09-14

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