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EP2980110A1 - Dispersions Aqueuses Hybrides de Polyuréthane et Polymère Vinylique - Google Patents

Dispersions Aqueuses Hybrides de Polyuréthane et Polymère Vinylique Download PDF

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Publication number
EP2980110A1
EP2980110A1 EP14179407.3A EP14179407A EP2980110A1 EP 2980110 A1 EP2980110 A1 EP 2980110A1 EP 14179407 A EP14179407 A EP 14179407A EP 2980110 A1 EP2980110 A1 EP 2980110A1
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EP
European Patent Office
Prior art keywords
groups
compounds
acid
mixture
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP14179407.3A
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German (de)
English (en)
Inventor
Anton Arzt
Ulrike Kuttler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Allnex Austria GmbH
Original Assignee
Allnex Austria GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Allnex Austria GmbH filed Critical Allnex Austria GmbH
Priority to EP14179407.3A priority Critical patent/EP2980110A1/fr
Priority to KR1020177002527A priority patent/KR102349873B1/ko
Priority to RU2017104515A priority patent/RU2704812C2/ru
Priority to JP2017505138A priority patent/JP6774936B2/ja
Priority to EP15738715.0A priority patent/EP3174909B1/fr
Priority to PCT/EP2015/066986 priority patent/WO2016016117A1/fr
Priority to CN201580035797.1A priority patent/CN106661186B/zh
Priority to US15/326,115 priority patent/US10239987B2/en
Priority to ES15738715.0T priority patent/ES2688741T3/es
Priority to BR112016030533-7A priority patent/BR112016030533B1/pt
Publication of EP2980110A1 publication Critical patent/EP2980110A1/fr
Priority to US16/269,763 priority patent/US11384190B2/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/007—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C08G18/2835—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds having less than 5 ether groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3228—Polyamines acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C08G18/3275—Hydroxyamines containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4288—Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4291—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from polyester forming components containing monoepoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/625—Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids
    • C08G18/6254—Polymers of alpha-beta ethylenically unsaturated carboxylic acids and of esters of these acids containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C08G18/724—Combination of aromatic polyisocyanates with (cyclo)aliphatic polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
    • C08G18/765—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group alpha, alpha, alpha', alpha', -tetraalkylxylylene diisocyanate or homologues substituted on the aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
    • C08G18/831—Chemically modified polymers by oxygen-containing compounds inclusive of carbonic acid halogenides, carboxylic acid halogenides and epoxy halides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/002—Priming paints

Definitions

  • the present invention relates to aqueous polyurethane - vinyl polymer hybrid dispersions which are prepared by polymerisation, initiated by free radicals, of ethylenically unsaturated monomers and polyurethane prepolymers containing acid groups and hydroxyl groups, to a method for their preparation, and to their use particularly as coating binder in multilayer coatings.
  • Dispersions of polyurethane - vinyl polymer hybrids made by radically initiated copolymerisation of ethylenically unsaturated monomers and polyurethane macromonomers have been known, i. a. from EP 0 522 420 A2 . These dispersions have been used in a variety of applications, including preparation of basecoats in multilayer coatings used for the painting of cars. In such multilayer applications, a key property of the coating layers is their intercoat adhesion, in this case, between the primer-surfacer layer, and the basecoat, and the basecoat layer and the clearcoat which is the topmost coating layer. Another property that is important for the basecoat is its water and humidity resistance, which needs constant improvement.
  • the invention therefore relates to aqueous polyurethane - vinyl polymer hybrid dispersions comprising a polyurethane - vinyl polymer hybrid UV, and water, wherein the polyurethane - vinyl polymer hybrid UV is dispersed.
  • the building blocks of the aqueously dispersed polyurethane - vinyl polymer hybrid comprise
  • the hydrophobically modified polyesters A have side chains with chain length of preferably from four to twenty carbon atoms, and are preferably obtained by reaction of a polyester A' having residual hydroxyl and acid groups, by reaction of the acid groups with a monofunctional compound A4 having an epoxide or aziridine functionality, and a linear or branched alkyl residue of at least four carbon atoms, in which reaction at least 90 % of the remaining acid groups are converted to ester or amide groups which groups link the side chains to the polyester main chain.
  • polyurethane - vinyl polymer hybrid dispersions having such hydrophobically modified polyesters A as building blocks yield coating films with improved interlayer adhesion, and increased water and humidity resistance.
  • Hydrophobically modified polyesters A are preferably made from polyesters A' based on aliphatic diols A1 and aliphatic and/or aromatic diacids A2, or on monohydroxymonoacids A3, having one hydroxyl group and one acid group per molecule, or mixtures of these starting materials. Small amounts, such as up to 10 % of the amount of substance of dihydroxy compounds, or up to 10 % of the amount of substance of diacids, or up to 10 % of the amount of substance of the monohydroxymonoacids, maybe replaced by higher functional compounds of the same kind, i. e. by triols A11, triacids A21, or hydroxy acids A31 having more than one functional hydroxyl or acid group.
  • the mixture of hydroxy-functional and acid-functional compounds A1, A2, A3, and optionally, A11, A21, and A31 is esterified at elevated temperature of up to 250 °C, under removal of the water formed in the polycondensation reaction, and optionally, in the presence of an esterification catalyst.
  • the stoichiometry is preferably chosen such that the hydroxyl value of the resulting polyester A' is at least 20 mg/g, and up to 100 mg/g.
  • a low acid number of preferably not more than 5 mg/g is obtained.
  • the polyester A' formed in this reaction is then treated at a temperature of preferably from 150 °C to 220 °C with a compound A4 which may be a monoepoxide compound or a monoaziridine compound which reacts with the acid groups of the polyester A' under addition and formation of an ester or an amide group, and of a hydroxyl or amino group by ring opening of the oxirane or aziridine ring.
  • the polyesters A which are formed by reaction of the polyesters A' with the compound A4 preferably have a remaining acid number of 0.1 mg/g or less. Their hydroxyl number is preferably at least 22 mg/g, and also preferably, not more than 105 mg/g.
  • the acid value or acid number w Ac is defined, according to DIN EN ISO 2114 (DIN 53 402), as the ratio of that mass m KOH of potassium hydroxide which is needed to neutralise the sample under examination, and the mass m B of this sample, or the mass of the solids in the sample in the case of a solution or dispersion; its customary unit is "mg/g". This value is determined in the examples according to this standard.
  • the hydroxyl value or hydroxyl number w OH is defined according to DIN EN ISO 4629 (DIN 53 240) as the ratio of the mass of potassium hydroxide m KOH having the same number of hydroxyl groups as the sample, and the mass m B of that sample (mass of solids in the sample for solutions or dispersions); the customary unit is "mg/g". This value is determined in the examples according to this standard.
  • Preferred compounds A1 are linear, branched, and cyclic aliphatic dihydroxy compounds preferably having from two to twelve carbon atoms.
  • Preferred are 1,2-ethanediol, 1,2- and 1,3-propanediol, 1,2- and 1,4-butanediol, 2,2-dimethyl-1,3-propanediol (neopentylglycol), 2-methyl-2,4-pentanediol, 1,4-bis-hydroxymethylcyclohexane, and the so-called bifunctional fatty alcohols which are alpha-, omega-dihydroxyalkanes with from six to twenty-five carbon atoms, particularly 1,6-hexanediol, 1,8-octanediol, 1,10-decanediol, 1,12-dodecanediol, 1,13-tridecanediol, 1,18-octadecanediol, 1,21-hene
  • Preferred compounds A2 are aliphatic dicarboxylic acids having from three to twelve carbon atoms, such as malonic acid, succinic acid, glutaric acid, adipic acid, octanedioic acid, and also dimeric fatty acids having up to forty carbon atoms, and also aromatic dicarboxylic acids such as isophthalic acid, terephthalic acid, and naphthalene dicarboxylic acids.
  • Preferred compounds A3 are hydroxybenzoic acid, lactic acid, gamma-hydroxybutyric acid, delta-hydroxyvaleric acid, and epsilon-hydroxycaproic acid.
  • Preferred compounds A11 are glycerol, trimethylolethane, trimethylolpropane, pentaerythritol, ditrimethylolethane, ditrimethylolpropane, dipentaerythritol, erythritol, threitol, and mannitol.
  • Preferred compounds A21 are trimellithic acid, trimesic acid, carballylic acid, and aconitic acid.
  • Preferred compounds A31 are citric acid, tartaric acid, alpha-, beta- and gamma-resorcylic acid, (3,5-dihydroxybenzoic acid, 2,4-dihydroxybenzoic acid, and 2,6-dihydroxybenzoic acid), and gentisic acid (2,5-dihydroxybenzoic acid).
  • Preferred compounds A4 are glycidol (2,3-epoxy-1-propanol), and ethers and esters thereof such as glycidyl acetate, glycidyl propionate, glycidyl butyrate, glycidyl pivalate, glycidyl 2-ethylhexanoate, glycidyl 2,2-dimethyloctanoate, commercial mixtures of the ester of glycidol with a mixture of isomeric alpha-branched decanoic acids, lauryl glycidyl ether, and stearyl glycidyl ether.
  • ethers and esters thereof such as glycidyl acetate, glycidyl propionate, glycidyl butyrate, glycidyl pivalate, glycidyl 2-ethylhexanoate, glycidyl 2,2-dimethyloctano
  • alkenes such as 1,2-epoxhexane, 1,2-epoxydecane, 1,2-epoxydodecane, and 1,2-epoxyoctadecane
  • alkylaziridines preferably having from six to twelve carbon atoms such as hexylaziridine, heptylaziridine, nonylaziridine, and dodecylaziridine.
  • the acids B that have further groups which react with isocyanates under formation of urethanes, ureas, or thiourethanes have at least one hydroxyl, amino or thiol group, and an acid group which is preferably a carboxylic acid group or a sulfonic acid group, preferably selected from the group consisting of 2,2-(bis-hydroxymethyl)acetic acid, 2,2-(bishydroxymethyl)-propionic acid, 2,2-(bishydroxymethyl)butyric acid, and 2-aminoethanesulfonic acid.
  • the hydroxy-functional oligomeric or polymeric compounds C which are optionally used may be polyesters, poly-carbonates, polyethers, polyamides, polydienes and polyenes, and which have at least two hydroxyl groups per molecule include polyhydroxy-polyethers of the formula H -[- O - (CHR) n -] m OH in which
  • poly(oxytetramethylene) glycols examples are poly(oxytetramethylene) glycols, poly(oxyethylene) glycols and poly(oxypropylene) glycols.
  • the preferred polyhydroxy-polyethers are poly(oxypropylene) glycols having a molar mass in the range from 400 g/mol to 5000 g/mol.
  • the polyhydroxy-polyesters are prepared by esterification of organic polycarboxylic acids or their anhydrides with organic polyols.
  • the polycarboxylic acids and the polyols can be aliphatic or aromatic polycarboxylic acids and polyols.
  • the polyols used for the preparation include those mentioned under A1 , and also, in a mass fraction of not more than 10 %, based on the mass of the polyols used in the polyhydroxy-polyesters, trishydroxyalkylalkanes, such as, for example, trimethylolpropane, and tetrakishydroxyalkylalkanes, such as, for example, pentaerythritol.
  • the acid component of the polyesters primarily consists of low molar mass polycarboxylic acids or their anhydrides having from two to eighteen carbon atoms in the molecule.
  • Suitable acids are, for example, phthalic acid, isophthalic acid, terephthalic acid, tetrahydrophthalic acid, hexahydrophthalic acid, succinic acid, adipic acid, azelaic acid, sebacic acid, maleic acid, glutaric acid, hexachloroheptanedicarboxylic acid, alkyl- and alkenylsuccinic acid, for example n-octenylsuccinic acid and n-and iso-dodecenylsuccinic acid, tetrachlorophthalic acid, trimellithic acid and pyromellithic acid.
  • these acids their anhydrides, where these exist, can also be used.
  • Dimeric and trimeric fatty acids can also be employed as the polycarbox
  • polyhydroxy-polyether and polyhydroxy-polyester are also to be understood as meaning those products of this type which contain monomers having carboxyl, phosphonic acid or sulfonic acid groups.
  • Polyhydroxy-polyesters which are derived from lactones can furthermore be used in the invention.
  • the polylactone-polyols which are obtained by this reaction are distinguished by the presence of a terminal hydroxyl group and by recurring polyester contents which are derived from the lactone.
  • the lactone used as the starting material can be any desired lactone or any desired combination of lactones, and this lactone should contain at least four carbon atoms in the ring, for example from five to eight carbon atoms, and two hydrogen atoms should be directly bonded to the carbon atom bonded to the oxygen group of the ring.
  • Preferred lactones are the caprolactones.
  • the most preferred lactone is unsubstituted epsilon-caprolactone. This lactone is particularly preferred, since it is available in large amounts and produces coatings which have excellent properties.
  • Various other lactones can furthermore be used individually or in combination.
  • aliphatic polyols which are suitable for the reaction with the lactone are ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, dimethylolcyclohexane, trimethylolpropane and pentaerythritol.
  • Possible starting compounds are furthermore polycarbonate-polyols and polycarbonate-diols
  • OH-functional polycarbonates can be prepared by reaction of polyols, such as 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, diethylene glycol, triethylene glycol, 1,4-bishydroxymethylcyclohexane, 2,2-bis(4-hydroxycyclohexyl)propane, neopentylglycol, trimethylolpropane or pentaerythritol, with di-carbonates, such as dimethyl, diethyl or diphenyl carbonate, or phosgene.
  • di-carbonates such as dimethyl, diethyl or diphenyl carbonate, or phosgene.
  • Mixtures of such polyols can likewise be employed.
  • Mixtures of polyhydroxy-polyethers, polyhydroxy-polyesters and polyhydroxy-polycarbonates
  • oligomeric or polymeric hydroxy-functional compounds are polyamides, polydienes and polyenes where the oligomer or polymer chain is a polyamide, a polyene or a polydiene, and there are at least two, preferably terminal, hydroxyl groups per molecule.
  • Particularly preferred are dihydroxy compounds based on polybutadiene, or on hydrogenated polybutadiene. These compounds also contribute to hydrophobicity and toughness of the coating layer made from a polyurethane - vinyl polymer hybrid comprising these building blocks.
  • the monomeric hydroxy compounds D having at least two hydroxyl groups per molecule, which are optionally used, are aliphatic diols which maybe linear, branched or cyclic, and have from two to forty carbon atoms.
  • Preferred compounds D are 1,2-ethanediol, 1,2- and 1,3-propanediol, 1,2- and 1,4-butanediol, 2,2-dimethyl-1,3-propanediol (neopentylglycol), 2-methyl-2,4-pentanediol, 1,4-bis-hydroxymethylcyclohexane, and the so-called bifunctional fatty alcohols which are alpha-, omega-dihydroxyalkanes with from six to twenty-five carbon atoms, particularly 1,6-hexanediol, 1,8-octanediol, 1,10-decanediol, 1,12-dodecanediol, 1,13-tridecaned
  • the compounds E which are optionally used, have one primary or secondary amino group, and at least one hydroxyl group per molecule, such as 2-aminoethanol, and may have preferably secondary amino groups, and two hydroxyl groups.
  • Preferred compounds are selected from the group consisting of the monohydroxymonoamines 2-aminoethanol, 2-methylaminoethanol, and 3-aminopropanol, the dihydroxymonoamines 2-amino-1,3-propanediol, diethanolamine, and 1,1'-iminodi-2-propanol (diisopropanolamine).
  • These compounds are optionally used, and react with an isocyanate group preferably to form a urea, and they can introduce additional hydroxyl groups into the polymer formed.
  • the compounds F having two or more amino groups per molecule, and no hydroxyl groups are aliphatic linear or branched diamines having from two to ten carbon atoms and at least two primary amino groups, such as 1,4-diaminobutane, 1,6-diaminohexane, and 2-methyl-1,5-diaminopentane. These compounds are optionally used, and provide chain extension under formation of urea groups by reacting with isocyanate-functional compounds formed during the synthesis.
  • the compounds G having not more than one hydroxyl group, and at least one tertiary amino group, are aliphatic, linear, branched or cyclic, and have from four to twelve carbon atoms; preferred compounds are N-N-dimethylaminoethanol, 1-dimethylamino-2-propanol, 1-dimethylamino-3-propanol, and also N-(2-hydroxyethyl)piperazine. These compounds are used as neutralising agents.
  • the olefinically unsaturated compounds H comprise hydroxy-functional monomers H2 having an olefinic unsaturation which are radically polymerisable, and also, olefinically unsaturated monomers H1 that are radically copolymerisable and do not have hydroxy functional groups in their molecules.
  • the monomers H2 have at least one hydroxyl group, preferably one or two hydroxyl groups, and are partial esters of polyhydric alcohols having at least two hydroxyl groups, and olefinically unsaturated carboxylic acids selected from the group consisting of acrylic acid, methacrylic acid, and their homologues such as vinylacetic acid, crotonic acid and isocrotonic acid.
  • Preferred monomers H2 are hydroxyethyl(meth)acrylate, hydroxypropyl-(meth)acrylate, glycerol mono(meth)acrylate, trimethylolpropane mono(meth)acrylate, where "(meth)acrylate” stands for "acrylate or methacrylate”.
  • Preferred monomers H1 are esters of (meth)acrylic acid with aliphatic linear, branched or cyclic monoalcohols having from one to twelve carbon atoms in the alkyl group, particularly methyl (meth)acrylate, ethyl (meth)acrylate, butyl (meth)-acrylate, hexyl(meth)acrylate, 2-ethylhexyl(meth)acrylate, and isobornyl (meth)acrylate, and also, copolymerisable vinyl monomers such as styrene, vinyltoluene, acrylonitrile, and methacrylonitrile.
  • the multifunctional isocyanates I having at least two isocyanate groups per molecule are aromatic or aliphatic or mixed aliphatic-aromatic isocyanates, and preferably selected from the group consisting of trimethylene diisocyanate, tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate (HDI), propylene diisocyanate, ethylethylene diisocyanate, 2,3-dimethylethylenediisocyanate, 1-methyltrimethylene diisocyanate, cyclopentylene 1,3-diisocyanate, cyclohexylene 1,4-diisocyanate, cyclohexylene 1,2-diisocyanate, phenylene 1,3-diisocyanate, phenylene 1,4-diisocyanate, toluylene 2,4-diisocyanate, toluylene 2,6-diisocyanate, biphenylene 4,
  • the amounts of these educts, or starting materials for the polyurethane-vinyl polymer hybrid UV are chosen such that the following conditions are preferably met:
  • At least two of these conditions are fulfilled, viz, a) and b); a) and c); a) and d); a) and e); b) and c); b) and d); b) and e); c) and d); c) and e); and d) and e). More preferably, at last three of these conditions are fulfilled, viz.
  • hydroxy-functional educts are always referred to in their hydroxyl form, having -OH end groups, and the aminofunctional educts are always referred to in their amine form having >NH or -NH 2 end groups, etc.
  • the polyesters A' are made in a polyesterification process wherein a mixture of aliphatic diols A1 and aliphatic and/or aromatic diacids A2, optionally in the presence of hydroxyacids A3, and further optionally, in the presence of one or more of hydroxy compounds A11 having more than two hydroxyl groups, acid compounds A21 having more than two acid groups, preferably carboxyl groups, and hydroxyacids A31 having more that one hydroxyl group or more than one acid group, or at least two hydroxyl groups and at least two acid groups, is esterified at elevated temperature of up to 250 °C, under removal of the water formed in the poly condensation reaction.
  • the polyester A' formed in the first step having residual hydroxyl and acid groups is treated at a temperature of preferably from 150 °C to 220 °C with a monofunctional compound A4 selected from the group consisting of a monoepoxide compound and a monoaziridine compound whereby preferably at least 90 % of the acid groups of the polyester A' are consumed under addition and formation of an ester or an amide group, and of a hydroxyl or amino group by ring opening of the oxirane or aziridine ring.
  • Hydrophobically modified polyesters A are obtained having an acid number of 0.1 mg/g or less.
  • hydrophobically modified polyesters A are then mixed with acids B that have further groups which react with isocyanates under formation of urethanes, ureas, or thiourethanes, optionally, hydroxy-functional oligomeric or polymeric compounds C which may be polyesters, poly-carbonates, polyethers, polyamides, polydienes and polyenes, and which have at least two hydroxyl groups per molecule, and further optionally, monomeric hydroxy compounds D having at least two hydroxyl groups per molecule.
  • the use of compounds C is optional, as well as the use of compounds D, where it is possible to use only C, only D, both C and D, or none of both.
  • the mixture of A, B, C (if used), and D (is used) is then heated under stirring preferably to at least 60 °C, to form a homogeneous solution, and then reacted by addition of a substoichiometric quantity of the multifunctional isocyanate I preferably over a time of from twenty minutes to one hundred and twenty minutes, depending on the size of the lot, and keeping the reaction temperature in a range of from 60 °C to 150 °C.
  • An intermediate also referred to as "prepolymer” is formed which has hydroxyl functional groups.
  • substoichiometric it is meant that the amount of substance of isocyanate groups in the quantity of multifunctional isocyanate I added is less than the sum of the amounts of substance of isocyanate-reactive groups, in this case, hydroxyl groups, of the compounds A, B, C, and D present in this reaction. At the end of this stage of he reaction, no more unreacted isocyanate groups are present in the reaction mixture.
  • a solution which comprises at least one olefinically unsaturated monomer H1 having no further functional group other than one or more vinyl or polymerisable olefinically unsaturated groups, and at least one olefinically unsaturated monomer H2 having at least one hydroxyl group and a vinyl or polymerisable olefinically unsaturated group, optionally, an antioxydant or radical scavenger is also added which is preferably a sterically hindered phenol, such as a phenol having bulky substituents, preferably tert-butyl groups, in the 2- and 6-positions, and an alkyl substituent in the 4-position, further optionally, a solvent S which is inert in the reaction, and the solution and the prepolymer are homogenised.
  • an antioxydant or radical scavenger is also added which is preferably a sterically hindered phenol, such as a phenol having bulky substituents, preferably tert-buty
  • a mixture is then added which comprises the compounds E (if used), F (if used), and G, as well as water, and the resulting mixture is homogenised well for preferably from thirty to ninety minutes before adding an aqueous solution of a radical initiator, preferably an alkyl hydroperoxide, homogenised again, and then, preferably, an aqueous solution of a reducing agent, preferably ascorbic acid, is added.
  • a radical initiator preferably an alkyl hydroperoxide
  • a reducing agent preferably ascorbic acid
  • the dispersions of the polyurethane-vinyl polymer hybrid UV according to the invention are suitable for diverse uses, for example for the preparation of coating systems, inter alia for coating wood, as binders for water-dilutable adhesives or as resins for printing inks.
  • plastics for example acrylic and/or methacrylic polymers, polyurethane, polyurea resins, polyester resins and epoxy resins, thermoplastics based on polyvinyl acetate, -vinyl chloride, -vinyl ether, -chloroprene and -acrylonitrile and ethylene/butadiene/styrene copolymers.
  • substances which have a thickening action can also be combined with substances which have a thickening action and are based on polyacrylates or polyurethanes containing carboxyl groups, hydroxyethylcellulose, polyvinyl alcohols and inorganic thixotropic agents, such as bentonite, sodium-magnesium silicates and sodium-magnesium-fluorine-lithium silicates.
  • the polyurethane - vinyl polymer hybrid dispersions according to the invention can be applied to the most diverse substrates, for example ceramic, wood, glass, concrete and preferably plastics, such as polycarbonate, polystyrene, polyvinyl chloride, polyester, poly(meth)acrylates, acrylonitrile/ butadiene/styrene polymers and the like, and preferably to metal, such as iron, copper, aluminum, steel, brass, bronze, tin, zinc, titanium, magnesium and the like. They adhere to the various substrates without adhesion-promoting primers or intermediate layers.
  • plastics such as polycarbonate, polystyrene, polyvinyl chloride, polyester, poly(meth)acrylates, acrylonitrile/ butadiene/styrene polymers and the like, and preferably to metal, such as iron, copper, aluminum, steel, brass, bronze, tin, zinc, titanium, magnesium and the like. They adhere to the various substrates without adhesion-promoting primers or intermediate layers
  • the polyurethane - vinyl polymer hybrid dispersions according to the invention are suitable, for example, for the production of corrosion-preventing coatings and/or intermediate coatings for the most diverse fields of use, in particular for the production of metallic and solid base paints in multi-coat build-ups of paint for the fields of painting of automobiles and plastics, and for producing primer paints for the field of painting of plastics.
  • the pigmented coat of base paint can be over-varnished with a clear varnish without a stoving step (wet-in-wet process) and the coatings can then be stoved together or subjected to forced drying.
  • Base paints prepared with the polyurethane - vinyl polymer hybrid dispersions according to the invention give paint films of the same quality largely independently of the stoving or drying temperature, so that they can be employed both as a repair paint for motor vehicles and as a stoving paint for series painting of motor vehicles. In both cases, paint films result having a good adhesion to the original coating and a good resistance to condensation water.
  • crosslinking agents customary in the paint industry such as, for example, water-soluble or -emulsifiable aminoplast crosslinkers such as urea, cyclic urea, melamine or benzoguanamine resins, polyisocyanates or prepolymers having terminal isocyanate groups, water-soluble or water-dispersible polyaziridines and blocked polyisocyanates, can be added during formulation of water-dilutable paints using the polyurethane - vinyl polymer hybrid dispersions according to the invention.
  • water-soluble or -emulsifiable aminoplast crosslinkers such as urea, cyclic urea, melamine or benzoguanamine resins, polyisocyanates or prepolymers having terminal isocyanate groups, water-soluble or water-dispersible polyaziridines and blocked polyisocyanates
  • the aqueous coating systems can contain all the inorganic or organic pigments and dyestuffs which are known and are customary in paint technology, as well as wetting agents, foam suppressants, flow control agents, stabilisers, catalysts, fillers, plasticisers and solvents.
  • the coating composition is completed to a paint by adding the usual additives, such as thickeners, flow modifiers, wetting agents, light stabilisers, and pigments, particularly metal flake pigments.
  • the paint obtained is the applied to a substrate, and hardened by crosslinking the paint to form a coating film on the substrate, by heating the coated substrate to a temperature of preferably from 50 °C to 180 °C.
  • the polyurethane - vinyl polymer hybrid dispersions according to the invention can also be used directly for gluing any desired substrates.
  • the polyurethane - vinyl polymer hybrid dispersions according to the invention can be mixed with other dispersions or solutions of plastics (see above).
  • Crosslinking agents such as, for example, polyisocyanates or prepolymers having terminal isocyanate groups or water-soluble or -emulsifiable melamine or benzoguanamine resins, can furthermore be added to improve the resistance to heat and peeling.
  • the adhesives based on the polyurethane - vinyl polymer hybrid dispersions according to the invention can contain the additives customary in adhesives technology, such as plasticizers, solvents, film-binding auxiliaries, fillers and synthetic and naturally occurring resins. They are specifically suitable for the production of gluings of substrates in the motor vehicle industry, for example gluing of interior finishings, and in the shoe industry, for example for gluing the shoe sole and shoe shaft.
  • the adhesives based on the polyurethane - vinyl polymer hybrid dispersions according to the invention are prepared and processed by the customary methods of adhesives technology used for aqueous dispersion and solution adhesives.
  • polyester A' 89.4 g were reacted with 1.4 g of the glycidyl ester of neodecanoic acid (®Cardura E 10P, sold by Momentive Specialty Chemicals Inc.) at a temperature between 180 °C and 200 °C for about one hour until the acid value as determined on a sample was below 0.1 mg/g. hydroxyl value: 45 mg/g acid number: 0.08 mg/g
  • polyester A' 863 g of polyester A' were heated to 130 °C together with 79 g of dimethylolpropionic acid (DMPA) and the mixture was kept at this temperature until a homogeneous solution was formed.
  • DMPA dimethylolpropionic acid
  • 150 g of tetramethylxylylene diisocyanate (TMXDI) were then metered in over a period of from thirty to forty-five minutes, while stirring was continued at 130 °C until no more free isocyanate groups could be detected.
  • polyester A' 950 g were heated to 130 °C together with 111 g of dimethylolpropionic acid (DMPA), and the mixture was kept at this temperature under stirring until a homogeneous solution was obtained.
  • DMPA dimethylolpropionic acid
  • TMXDI tetramethylxylylene diisocyanate
  • polyester A 950 g were heated to 130 °C together with 98 g of dimethylolpropionic acid (DMPA) and the mixture was kept at this temperature until a homogeneous solution was obtained.
  • DMPA dimethylolpropionic acid
  • TMXDI tetramethylxylylene diisocyanate
  • a mixture of 124 g TMXDI and 143 g 5-isocyanato-1- (isocyanatomethyl)-1,3,3-trimethyl-cyclohexane (IPDI) were then added over a period of fifteen minutes, and the mixture was subjected to reaction at 75 °C until the mass fraction of free isocyanate groups in the current reaction mixture was 0.88 %.
  • a mixture having a temperature of from 70 °C to 75 °C, composed of 23.8 g of 2-methyl-1,5-pentanediamine, 58.6 g of N,N-dimethylethanolamine and 4335 g of water were added and stirred intensively at 75 °C for sixty minutes.
  • polyester A 950 g were heated to 130°C together with 98 g of dimethylolpropionic acid (DMPA) and the mixture was kept at this temperature until a homogeneous solution was obtained. 190 g of tetramethylxylylene diisocyanate (TMXDI) were then metered in over a period of from thirty to forty-five minutes, while stirring was continued at 130 °C until no free isocyanate groups were detected.
  • DMPA dimethylolpropionic acid
  • polyester A 950 g were heated to 130 °C together with 98 g of dimethylolpropionic acid (DMPA) and the mixture was kept at this temperature until a homogeneous solution was formed. 190 g of tetramethylxylylene diisoxyanate (TMXDI) were then metered in over a period of from thirty to forty-five minutes, while stirring was continued at 130 °C until no more free isocyanate groups could be detected.
  • DMPA dimethylolpropionic acid
  • TXDI tetramethylxylylene diisoxyanate
  • Polyester A 950 g of Polyester A were heated to 130 °C together with 98 g of dimethylolpropionic acid (DMPA) and the mixture was kept at this temperature until a homogeneous solution was formed. 190 g of tetramethylxylylene diisoxyanate (TMXDI) were then metered in over a period of from thirty to forty-five minutes, while stirring was continued at 130 °C until no more free isocyanate groups could be detected.
  • DMPA dimethylolpropionic acid
  • TXDI tetramethylxylylene diisoxyanate
  • 2572 g of an epoxy resin based on bisphenol A, having a number average molar mass of 380 g/mol, 440 g of a polycaprolactone diol having a number average molar mass of 550 g/mol, 661 g of bisphenol A, and 1734 g of methoxypropanol were sequentially filled into a resin kettle, and heated under stirring to 43 °C. The mixture was stirred for further thirty minutes, and then cooled to 41°C. At this temperature, 221 g of diethanolamine and then, 194 g of dimethylaminopropylamine, were added, whereupon the temperature rose to a maximum of 125 °C under cooling.
  • an acidic catalyst solution was prepared by dissolving 107 g of bismuth trioxide in 298.3 g of an aqueous solution of methanesulfonic acid with a mass fraction of solute of 70 %, and diluting after complete dissolution by adding 7913 g of deionized water.
  • the homogenised mixture of resin and curing agent was then added to this catalyst solution within thirty minutes under thorough stirring, whereby the mixture assumed a temperature of 40 C.
  • the mixture was stirred for two more hours at this temperature, and then diluted by addition of 2058 g of deionised water to a mass fraction of solids of 37 %.
  • This intermediate was brought to a temperature of 100 °C, and 204 g of 3-(N,N-dimethyl)-aminopropylamine-1 were added, and the mixture was reacted at 100 °C for one hour. 314 g of 2-butoxyethanol were then added, together with 66 g of paraformaldehyde having a mass fraction of formaldehyde of 91 %. The temperature was raised to 140 °C, and 36 g of water formed in the reaction were distilled off azeotropically using methyl isobutylketone as carrier. When the water was separated, the ketone was removed by distillation under reduced pressure, and the remainder was diluted to a mass fraction of solids of 55 % by adding 774 g of 2-butoxyethanol.
  • CED coating compositions were prepared from the emulsion of example 9, the pigment paste of example 11 and water, according to the following recipe:
  • the primer/surfacer coating composition 13b used was prepared from a grey pigment paste 13ba that was completed by addition of a blend 13bb consisting of the condensation product of example 13ac which had been adjusted to a mass fraction of solids of 42 % by addition of deionised water, the aqueous dispersion of example 13ad and a highly methoxymethylated melamine crosslinker.
  • an acid functional polyurethane 13aa was prepared by charging, in a resin kettle, a mixture of 810 g of dimethylolpropionic acid in a mixture of 946 g of diethylene glycol dimethyl ether and 526 g of methyl isobutyl ketone and heating this mixture to 100 °C until complete dissolution. At this temperature, a mixture of 870 g of toluylene diisocyanate ("TDI”) and 528 g of a semicapped TDI which is a reaction product of one mol of TDI with one mol of ethyleneglycol monoethylether was added over four hours while keeping the temperature constant at 100 °C.
  • TDI toluylene diisocyanate
  • This acid functional polyurethane 13aa had an acid number of 140 mg/g and a Staudinger-Index of 9.3 cm 3 /g, measured on solutions in N,N-dimethylformamide (DMF) at 20 °C.
  • the semi-capped TDI was prepared separately by addition of 300 g of ethylene glycol monoethylether to 580 g of TDI within two hours at 30 °C and subsequent reaction for two more hours after which time a final mass fraction of isocyanate groups in the adduct of 16.5 % was found.
  • a hydroxy-functional polyester 13ab was prepared by mixing in a resin kettle, 190 g of tripropylene glycol, 625 g of neopentyl glycol, 140 g of isomerised linoleic acid, 415 g of isophthalic acid, and 290 g of trimellitic acid anhydride, and esterification at 230 °C until the acid number of the reaction mixture had decreased to 4 mg/g.
  • the efflux time of a 50 % strength solution in 2-n-butoxyethanol of the resin formed measured according to DIN 53211 at 20 °C, was 165 s.
  • a resin kettle equipped with stirrer and reflux condenser was charged with 192 g of tripropylene glycol and 104 g of neopentyl glycol, the charge was heated under stirring to 110 °C. 192 g of trimellithic anhydride were then added, and the mixture was heated within two hours to 170 °C. The reaction mixture was held at that temperature until the acid number was 87 mg/g. After cooling to 150 °C, 40 g of a commercial mixture of glycidyl esters of alpha-branched decanoic acids (®Cardura E 10, Momentive Specialty Chemicals, Inc.) and 14 g of linseed oil fatty acid were added.
  • a commercial mixture of glycidyl esters of alpha-branched decanoic acids ®Cardura E 10, Momentive Specialty Chemicals, Inc.
  • This mixture was then heated to 180 °C within one hour, and held at that temperature until an acid number of 55 mg/g was reached.
  • the reaction mixture was then cooled and diluted by addition of methoxypropanol to a mass fraction of solids of 70 %.
  • 7 g of dimethyl ethanolamine, and 68 g of deionised water were added and homogenised with a mechanical stirrer for fifteen minutes at 600 min -1 . An aqueous dispersion with a mass fraction of solids of 40 % was obtained.
  • a pigmented primer/surfacer coating composition was prepared according to the following recipe: To 21.10 g of the condensation product of example 13ac which had been adjusted to a mass fraction of solids of 42 % by addition of deionised water was charged, in the sequence stated, 3.35 g of deionised water, 12.65 g of a rutil-type titanium dioxide pigment (surface treated with Al and Zr compounds, ®Kronos 2190, Kronos Titan GmbH),12.65 g of precipitated barium sulfate pigment (Blanc fixe F, Sachtleben GmbH), and 0.05 g of carbon black (®Printex U, Evonik Carbon Black GmbH), and then homogenised with a mechanical stirrer at 1200 min -1 for fifteen minutes.
  • This pre-blend was transferred to a bead mill and ground at a temperature not exceeding 50 °C. After a milling time of forty-five minutes, the required particle size of 10 ⁇ m was achieved, grinding was stopped and the paste referred to as 13ba thus formed was separated from the beads.
  • a mixture 13bb was prepared by charging 9.00 g of the condensation product of example 13ac which had been adjusted to a mass fraction of solids of 42 % by addition of deionised water, and adding in this sequence, 27.20 g of the aqueous dispersion of example 13ad, 1.75 g of a highly methoxymethylated melamine crosslinker having a molar ratio of methoxy groups to methylene groups to melamine derived moieties of from 5.0 mol: 5.8 mol: 1 mol (Cymel® 303, Allnex USA Inc.), and 12 g of deionised water.
  • This mixture 13bb was added to the paste 13ba at ambient temperature (23 °C) and homogenised with a mechanical stirrer at 1200 min -1 for fifteen minutes to obtain the pigmented primer-surfacer coating composition 13b.
  • Dynamic viscosity of this coating composition 13b was 300 mPa ⁇ s (measured at a shear rate of 25 s -1 ), and its p H value was 8.0.
  • Basecoat coating compositions were prepared from the polyurethane - vinyl polymer hybrid dispersions of examples 1 to 6, according to the following recipe in Table 1: Table 1 Basecoat compositions (mass of constituents in g) polyurethane - vinyl polymer hybrid dispersion 351.2 Part A Cymel® 327 15.6 Part A DMEA 10 % in water 14.4 Part A H 2 O deionised 115.2 Part A Rheovis® AS 1130 (10 % strength in water) 87.4 Part B H 2 O deionised 227.9 Part B Aluminum flakes (Hydrolan® 2154) 93.6 Part C Additol® XL 250 6 Part C Butylglycol 69.2 Part C Isobutanol 19.5 Part D
  • a basecoat composition was prepared according to the following recipe: the polyurethane - vinyl polymer hybrid dispersion (Example 1 to Example 6) was charged, in the sequence stated a methylated high imino melamine crosslinker (Cymel® 327, Allnex USA Inc.), dimethyl ethanolamine (a 10 % strength solution in deionised water) and deionised water (Part A) were added to this charge and then homogenised with a mechanical stirrer at 900 min -1 .
  • a methylated high imino melamine crosslinker Cymel® 327, Allnex USA Inc.
  • dimethyl ethanolamine a 10 % strength solution in deionised water
  • Part A deionised water
  • Part C The aluminum flake slurry (Part C) was prepared in a separate step by charging the aluminum flakes (silica encapsulated aluminium flakes, Hydrolan ®2154, Eckart GmbH), adding the anionic wetting agent (Additol XL® 250, Allnex Austria GmbH) and butylglycol (ethylene glycol monobutyl ether) and homogenising with a mechanical stirrer at 600 min -1 for thirty minutes.
  • Part C was then added with stirring at 900 min -1 to the preblended Part A and B, and homogenised for another twenty minutes.
  • isobutanol Part D was added and the mixture was homogenised for another five minutes at 900 min -1 .
  • the basecoat coating compositions prepared as described were allowed to rest for twelve hours at ambient temperature (23 °C). After this time the p H value was adjusted to 8.3 by means of a 10 % strength solution of dimethylethanolamine in deionised water, and the viscosity of the paints was adjusted to 300 mPa ⁇ s (measured at a shear rate of 25 s -1 ), by adding deionised water. Their composition is detailed in Table 2.
  • a recator equipped with a stirrer, in inert gas inlet, a heating and cooling system, and an addition funnel, the glycidylester of neodecanoic acid was charged and heated to 175 °C.
  • a monomer and initiator mixture was continuously added that consisted of 74.8 g of acrylic acid, 229.3 g of hydroxyethylmethacrylate, 178.3 g of tert.-butylmethacrylate, 62.7 g of methylmethacrylate, and 222.4 g of styrene, together with 19.8 g of di-tert-amyl peroxide, and a polymer was formed.
  • the reaction mixture was stirred for two further hours, by when more than 95 % of conversion was noted.
  • the copolymer was diluted by addition of butyl acetate to a mass fraction of solids of 75 %, the solution was filtered after cooling to room temperature to remove suspended solids, and the mass fraction of solids was then adjusted to 70 % by addition of further butyl acetate.
  • the solution of trimeric HDI, and solvents were blended and added with stirring at 900 min -1 to the preblended Part A.
  • the viscosity of the clearcoat was adjusted to 130 mPa ⁇ s (measured at a shear rate of 25 s -1 ), by adding a mixture in a mass ratio of 60/40 of butyl acetate and solvent naphtha having a boiling temperature in the range of from 150 °C to 180 °C.
  • This ready to use clearcoat coating composition must be applied within ninety minutes.
  • a multilayer coating was prepared from the CED coating composition of example 12, the primer-surfacer coating composition of example 13b, the basecoat compositions of example 14 (paints L1 to L6), and the clearcoat coating composition of example 15 according to the following procedure:
  • Zinc-phosphated steel panels (®Gardobond 26S 6800 OC from Chemetall) were coated with the CED paint according to example 12 under following conditions:
  • the primer surfacer coating composition of example 13b was applied to all 12 panels (dry film thickness 30 ⁇ m), and after a flash off step (ten minutes at 23 °C) stoved for twenty minutes at 165 °C.
  • the 12 panels were overcoated with the basecoat compositions of example 14 (paints L1 through L6, with 2 panels each for all paints L1 through L6). The basecoat layers (10 ⁇ m dry film thickness) were allowed to flash off for ten minutes at 23 °C and were then stoved for ten minutes at 80 °C.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Dispersion Chemistry (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
EP14179407.3A 2014-07-31 2014-07-31 Dispersions Aqueuses Hybrides de Polyuréthane et Polymère Vinylique Withdrawn EP2980110A1 (fr)

Priority Applications (11)

Application Number Priority Date Filing Date Title
EP14179407.3A EP2980110A1 (fr) 2014-07-31 2014-07-31 Dispersions Aqueuses Hybrides de Polyuréthane et Polymère Vinylique
PCT/EP2015/066986 WO2016016117A1 (fr) 2014-07-31 2015-07-24 Dispersions aqueuses hybrides de polyuréthane-polymère vinylique
RU2017104515A RU2704812C2 (ru) 2014-07-31 2015-07-24 Водные полиуретан-виниловые полимерные гибридные дисперсии
JP2017505138A JP6774936B2 (ja) 2014-07-31 2015-07-24 水性ポリウレタン−ビニルポリマーハイブリッド分散液
EP15738715.0A EP3174909B1 (fr) 2014-07-31 2015-07-24 Dispersions aqueuses hybrides de polyuréthane et polymère vinylique
KR1020177002527A KR102349873B1 (ko) 2014-07-31 2015-07-24 수성의 폴리우레탄 - 비닐 중합체 하이브리드 분산물
CN201580035797.1A CN106661186B (zh) 2014-07-31 2015-07-24 水性聚氨酯-乙烯基聚合物混合物分散体
US15/326,115 US10239987B2 (en) 2014-07-31 2015-07-24 Aqueous polyurethane—vinyl polymer hybrid dispersions
ES15738715.0T ES2688741T3 (es) 2014-07-31 2015-07-24 Dispersiones híbridas acuosas de poliuretano - polímero de vinilo
BR112016030533-7A BR112016030533B1 (pt) 2014-07-31 2015-07-24 Dispersões híbridas aquosas de polímero de poliuretano de vinila, processo para preparação das dispersões híbridas aquosas de polímero de poliuretano de vinila, e, método de uso das dispersões híbridas aquosas de polímero de poliuretano de vinila
US16/269,763 US11384190B2 (en) 2014-07-31 2019-02-07 Aqueous polyurethane—vinyl polymer hybrid dispersions

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CN (1) CN106661186B (fr)
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US11066574B2 (en) * 2018-05-29 2021-07-20 Nano And Advanced Materials Institute Limited Self-healing coating compositions
US12398098B2 (en) 2020-01-22 2025-08-26 Covestro (Netherlands) B.V. Waterborne crosslinker composition
CA3220999A1 (fr) 2021-07-06 2023-01-12 Allnex Austria Gmbh Dispersion aqueuse d'hybride de polyurethane-polymere vinylique
KR102638208B1 (ko) * 2023-01-25 2024-02-19 추강길 스프레이용 준불연성 폴리우레탄 폼 조성물

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JP2017528559A (ja) 2017-09-28
KR20170039156A (ko) 2017-04-10
JP6774936B2 (ja) 2020-10-28
KR102349873B1 (ko) 2022-01-10
US20170218110A1 (en) 2017-08-03
EP3174909A1 (fr) 2017-06-07
WO2016016117A1 (fr) 2016-02-04
CN106661186B (zh) 2020-05-15
BR112016030533A8 (pt) 2021-05-04
EP3174909B1 (fr) 2018-07-04
US10239987B2 (en) 2019-03-26
US11384190B2 (en) 2022-07-12
ES2688741T3 (es) 2018-11-06
US20190169353A1 (en) 2019-06-06
RU2704812C2 (ru) 2019-10-31
BR112016030533A2 (pt) 2017-08-22
RU2017104515A3 (fr) 2018-12-27
BR112016030533B1 (pt) 2021-08-17
CN106661186A (zh) 2017-05-10
RU2017104515A (ru) 2018-08-28

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