EP2761241B1 - Monitoring method - Google Patents
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- EP2761241B1 EP2761241B1 EP11771056.6A EP11771056A EP2761241B1 EP 2761241 B1 EP2761241 B1 EP 2761241B1 EP 11771056 A EP11771056 A EP 11771056A EP 2761241 B1 EP2761241 B1 EP 2761241B1
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- heating
- zone
- pressure
- furnace
- suction
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B13/00—Furnaces with both stationary charge and progression of heating, e.g. of ring type or of the type in which a segmental kiln moves over a stationary charge
- F27B13/06—Details, accessories or equipment specially adapted for furnaces of this type
- F27B13/14—Arrangement of controlling, monitoring, alarm or like devices
Definitions
- the invention relates to a method for monitoring an operating state of an anode furnace, wherein the anode furnace is formed of a plurality of heating channels and furnace chambers, wherein the furnace chambers for receiving anodes and the heating channels for controlling the temperature of the furnace chambers, wherein the anode furnace at least one furnace unit with a heating zone , a fire zone and a cooling zone, wherein in the heating zone, a suction device and in the fire zone, a burner device is arranged, wherein by means of the burner combustion air is heated in the heating channels of the fire zone, and wherein by means of the suction hot air is sucked out of the heating channels of the heating zone.
- the present process finds application in the production of anodes needed for fused-salt electrolysis to produce primary aluminum.
- These anodes are prepared from petroleum coke with the addition of pitch as a binder in a molding process as so-called “green anodes” or “raw aodes”, which are subsequently sintered in an anode furnace in the molding process.
- This sintering process takes place in a defined heat treatment process in which the anodes pass through three phases, namely a heating phase, a sintering phase and a cooling phase.
- a heating phase namely a heating phase, a sintering phase and a cooling phase.
- the Rohanoden in a heating zone of an assembled from the heating zone, a fire zone and a cooling zone, anode furnace formed "fire” and are preheated by the originating from the fire zone waste heat of already finished sintered anodes before the preheated anodes in the fire zone on the Sintering temperature of about 1200 ° Celsius are heated.
- the prior art as he, for example, from the EP 1 785 685 A1 or the article " Process Control in an anode bake furnace fired with heavy oil ", by Dr. U. Mannweiler, S.
- an anode furnace comprises a plurality of furnace units, the aggregates of each other Subsequently, above the furnace chambers or heating channels for subsequent heat treatments of the raw anode or anodes are moved.
- Anodenbrennöfen which may be designed in different types as an open anode furnace or anode ring furnace, there is the problem that a volume flow of the guided through the anode furnace air can be measured only with unreasonable effort.
- a determination of the volume flow is needed in particular for the regular monitoring of an operating state of the anode furnace. This is to ensure that sufficient oxygen is available for combustion of a fuel of the burner device in the heating channels of the anode furnace. Since a direct volume flow measurement is not possible due to the meandering, rectangular geometry of the heating channels, an attempt is made to determine the volume flow by an indirect measurement, for example a pressure measurement.
- volumetric flow rate evaluation is carried out by trained oven personnel as part of a kiln tour at regular intervals. If a malfunction of the anode furnace is detected, it is then turned off manually by the furnace personnel. However, this can lead to hazardous operating conditions of the anode furnace, which can lead to deflagration, fires or explosions, may not be detected in time.
- Object of the present invention is therefore to propose a method for monitoring an operating condition of an anode furnace, which allows continuous monitoring of the operating condition.
- the anode furnace is formed from a plurality of heating channels and furnace chambers, wherein the furnace chambers for receiving anodes and the heating channels for controlling the temperature of the furnace chambers, wherein the anode furnace at least one furnace unit with a heating zone, a fire zone and a cooling zone, wherein in the heating zone, a suction device and in the fire zone, a burner means is arranged, wherein by means of the burner means combustion air is heated in the heating channels of the fire zone, being sucked by the suction hot air from the heating channels of the heating zone, wherein a suction of the Suction is determined, and wherein a pressure in the heating channel is measured, wherein from a ratio of suction and pressure, a volume flow in the heating channel is determined.
- the suction power of the suction device can be determined relatively reliably, since the suction device indeed causes a volume flow in the heating channels, but is not regulated in direct dependence of the volume flow. Therefore, a suction power of the suction device is set on the assumption that the desired volume flow results therefrom. So it is also possible to determine the suction of the suction easily and accurately. Furthermore, a pressure or a vacuum caused by the suction device is measured in the heating channel. From the ratio of suction power to pressure comparatively accurately the volume flow in the heating channel can be determined. For example, if a Schukanalabdeckung open or improperly closed or the heating channel is clogged, there is a change in pressure in the heating channel relative to the suction of the suction.
- the measured pressure in the heating channel thus deviates from a presumed pressure at the same suction power from. From this, a reduced or increased volume flow in the heating channel can be derived.
- the respectively corresponding size of the volume flow results from a deviation from the presumed volume flow at known suction power and measured pressure. Since the determination of the suction power and the measurement of the pressure in the heating channel can be carried out continuously, via transducers and thus without furnace personnel, it is thus possible to perform a similar monitoring of the operating state of the anode furnace by the continuous determination of the volume flow.
- a pressure or negative pressure in the heating channel in the heating zone and / or the fire zone can be measured.
- a pressure or negative pressure in, for example, a collecting duct of the suction device it is also possible for a more detailed determination of an operating state, to measure a pressure or negative pressure in, for example, a collecting duct of the suction device. If the suction device is designed such that it spans and is connected to a plurality of heating channels in the transverse direction, the pressure measured in this collecting channel of the suction device can also be used to determine the volume flow. Furthermore, it can also be ensured that there is no malfunction when the suction power and the measured pressure in the suction device is in an expected relationship to each other.
- the volume flow can be determined even more accurately if this is determined from a ratio of suction power and pressure in the suction device and the ratio of suction power and pressure in the heating duct.
- the respective conditions can each be formed separately from each other and the volume flow can be derived therefrom.
- a volume flow can be determined individually for individual heating channels, for example, by setting a respective pressure in a plurality of heating channels in relation to the pressure in the suction device.
- a particularly high or low pressure in a heating channel compared to the other heating channels can already indicate a possible malfunction in the relevant heating channel.
- a pressure deviation in a heating channel has an effect on the pressures in the other heating channels, so that a correspondingly changed volume flow can also be determined or calculated here with relative reference to the pressure measured in the suction device.
- a determination of the suction power of the suction device can be made by determining a flap position of a throttle valve of the suction device.
- a cross-section of a suction channel can be varied by adjusting the throttle, so that the suction power of the suction device depends inter alia on the set cross-section of the suction channel. Therefore, when using a butterfly valve or similar such device, an exhaust performance may be deduced from a flap position, for example given in degrees of angularity relative to the suction channel.
- a flap position can be determined particularly simply and accurately, for example by means of a rotary potentiometer.
- the volume flow in the heating channel of the heating zone and / or the fire zone is determined. Since this may result from the combustion process caused flow differences, they can be considered so. Thus, a volume flow in the heating channel of the aforementioned zones can be determined separately from each other. Thus, a more differentiated consideration of the operating state in the respective zones of the anode furnace is possible.
- an operating state can be derived from the ratio of suction power and pressure and / or the specific volume flow.
- the determination of the operating state can be used to determine a point in time for a conversion of the suction device and the burner device and a blower device in more detail.
- a temperature in the heating channel can be measured.
- An evaluation of an operating condition is thereby further simplified, since such a required firing temperature can be monitored.
- a temperature gradient in the heating channel can also be measured. Accordingly, a temperature profile can be monitored over a period of time, with a falling or rising temperature or a negative or positive temperature gradient allowing conclusions to be drawn on an operating state change.
- the temperature gradient and / or the temperature can or can be measured in a collecting channel of the suction device and / or the heating zone and / or the fire zone.
- the collecting channel or the aforementioned zones each require a specific temperature gradient or temperature range for proper operation of the furnace unit, so that a more precise determination of an operating state becomes possible with metrological monitoring of these plant sections.
- the volumetric flow can be determined even more accurately if a change in density of air in the heating channel is calculated from the temperature gradient and the temperature, and this density change is taken into account in the determination of the volumetric flow. Which is through an increase or decrease in a temperature in the heating channel resulting volume change of the air located in the heating channel can significantly affect a flow in the heating channel. A calculation of the volumetric flow can therefore be corrected by a correction factor that can be derived from a calculation of the density change on the basis of temperature gradient and temperature.
- the operating state is evaluated, wherein in case of deviation from a presumed operating state, a shutdown of the burner device takes place.
- a malfunction of the furnace unit has a possible damage to the same result.
- the shutdown of the burner device or the entire furnace unit can also be done automatically without furnace personnel must be on site.
- the operating state can also be influenced or corrected automatically by an influencing control of the respective units of the furnace unit.
- an evaluation of the current operating state can be carried out by comparing the stored with the current operating state parameters.
- a continuous comparison of the current operating state parameters with the stored operating state parameters can be performed.
- a plausibility check of transducers can also be carried out before each start or startup or recommissioning of the furnace unit.
- the transducers of the furnace unit are connected to each other in the intended manner.
- it can thus be ensured that, in the event of a malfunction of a measuring transducer, there is no undesirable operating state influencing.
- FIG. 1 and 2 shows a schematic representation of an anode furnace 10 with a furnace unit 11.
- the anode furnace 10 has a plurality of heating channels 12 which extend parallel along intermediate furnace chambers 13.
- the oven chambers 13 serve to receive anodes not shown here.
- the heating channels 12 are meandering in the longitudinal direction of the anode furnace 10 and have at regular intervals Schukanalö Anlagenen 14, which are each covered with a Schukanalabdeckung not shown here.
- the oven unit 11 further comprises a suction device 15, a burner device 16 and a blower device 17. Their position on the anode baking oven 10 defines functionally a heating zone 18, a fire zone 19 and a cooling zone 20.
- the oven unit 11 is relative to the Furnace chambers 13 and the anodes shifted by moving the devices 15 to 17 in the longitudinal direction of the anode furnace 10, so that all located in the anode furnace 10 anodes pass through the zones 18 to 20.
- the suction device 15 is essentially formed from a collecting channel 21, which is connected via an annular channel 22 to an exhaust gas cleaning system, not shown here.
- the collecting channel 21 is in turn connected in each case via a connecting channel 23 to a heating channel opening 14, in which case a throttle valve 24 is arranged on the connecting channel 23.
- a measuring ramp 27 with measuring sensors 28 for each heating channel 12 is arranged in the heating zone 18. By means of the measuring ramp 27, a pressure and a temperature in the relevant section of the heating channel 12 can be determined.
- the burner device 16 comprises three burner ramps 29 with burners 30 and transducers 31 for each heating channel 12.
- the burners 30 each burn a flammable fuel in the heating channel 12, wherein a burner temperature is measured by means of the transducers 31. This makes it possible to set a desired burner temperature in the area of the fire zone 19.
- the cooling zone 20 comprises the blower device 17, which is formed from a feed channel 32 with respective connection channels 33 and throttle valves 34 for connection to the heating channels 12. Fresh air is blown into the heating channels 12 via the feed channel 32. The fresh air cools the heating channels 12 and the anodes located in the furnace chambers 13 in the region of the cooling zone 20, wherein the fresh air is continuously heated until it reaches the fire zone 19.
- a diagram of the temperature distribution based on the length of a heating channel 12 and the zones 18 to 20 can be seen.
- a measuring ramp 35 with transducers 36 is arranged in the cooling zone 20. The transducers 36 serve to detect a pressure in the respective heating channels 12.
- the pressure in the heating channel 12 essentially assumes the value zero, wherein between the transducers 36 and the fan 17 an overpressure and between the transducers 36 and the Absauginraum 15 a negative pressure in the heating channels 12 is formed. Consequently, the fresh air flows from the fan 17 through the heating channels 12 to the suction device 15th
- a measurement of a position of the respective throttle valves 24, a pressure measurement in the collecting channel 21 and a pressure measurement in the heating channels 12 by means of the transducer 28. From the measured values for the throttle position and the respective measured values for a negative pressure in the collecting channel 21 and in the heating channel 12 in each case formed ratios from which, together with the above-described density correction, a volume flow in the heating channel 12 can be derived. From a ratio of volume flow and temperature gradient in the heating channel 12, an operating state for the volume flow is again determined. Here it is intended to store the corresponding measured values or operating state parameters and thus to calibrate an operating state or to describe a proper operating state. During repetitive operating phases, it is then possible to make a comparison between the calibrated or presumed proper operating state and the current operating state.
- This comparison may, for example, as in Fig. 4 represented by comparing a current operating pressure to a throttle valve with a presumed operating pressure.
- a ratio of volume flow and temperature gradient as in Fig. 5 presented to evaluate.
- the ratio in a region 37 of the graph could be considered to be proper for the operating state, critical for a region 38, and unsatisfactory for a region 39.
- These operating states can be signaled, for example, as a graphic representation in the manner of a traffic light or acoustically to an operator.
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Description
Die Erfindung betrifft ein Verfahren zur Überwachung eines Betriebszustandes eines Anodenbrennofens, wobei der Anodenbrennofen aus einer Mehrzahl von Heizkanälen und Ofenkammern gebildet ist, wobei die Ofenkammern zur Aufnahme von Anoden und die Heizkanäle zur Temperierung der Ofenkammern dienen, wobei der Anodenbrennofen zumindest eine Ofeneinheit mit einer Aufheizzone, einer Feuerzone und einer Kühlzone umfasst, wobei in der Aufheizzone eine Absaugeinrichtung und in der Feuerzone eine Brennereinrichtung angeordnet ist, wobei mittels der Brennereinrichtung Verbrennungsluft in den Heizkanälen der Feuerzone erhitzt wird, und wobei mittels der Absaugeinrichtung Heißluft aus den Heizkanälen der Aufheizzone abgesaugt wird.The invention relates to a method for monitoring an operating state of an anode furnace, wherein the anode furnace is formed of a plurality of heating channels and furnace chambers, wherein the furnace chambers for receiving anodes and the heating channels for controlling the temperature of the furnace chambers, wherein the anode furnace at least one furnace unit with a heating zone , a fire zone and a cooling zone, wherein in the heating zone, a suction device and in the fire zone, a burner device is arranged, wherein by means of the burner combustion air is heated in the heating channels of the fire zone, and wherein by means of the suction hot air is sucked out of the heating channels of the heating zone.
Das vorliegende Verfahren findet Anwendung bei der Herstellung von Anoden, die für die Schmelzflusselektrolyse zur Herstellung von Primäraluminium benötigt werden. Diese Anoden werden aus Petrolkoks unter Zusatz von Pech als Bindemittel in einem Formungsverfahren als sogenannte "Grüne Anoden" oder "Rohanoden" hergestellt, die nachfolgend dem Formungsverfahren in einem Anodenbrennofen gesintert werden.The present process finds application in the production of anodes needed for fused-salt electrolysis to produce primary aluminum. These anodes are prepared from petroleum coke with the addition of pitch as a binder in a molding process as so-called "green anodes" or "raw aodes", which are subsequently sintered in an anode furnace in the molding process.
Dieser Sintervorgang findet in einem definiert ablaufenden Wärmebehandlungsprozess statt, bei dem die Anoden drei Phasen, nämlich eine Aufheizphase, eine Sinterphase und eine Abkühlphase, durchlaufen. Dabei befinden sich die Rohanoden in einer Aufheizzone eines aus der Aufheizzone, einer Feuerzone und einer Kühlzone zusammengesetzten, Anodenbrennofens ausgebildeten "Feuers" und werden durch die aus der Feuerzone stammende Abwärme von bereits fertig gesinterten Anoden vorgeheizt, bevor die vorgeheizten Anoden in der Feuerzone auf die Sintertemperatur von etwa 1200° Celsius aufgeheizt werden. Entsprechend dem Stand der Technik, wie er beispielsweise aus der
Durch eine Positionierung einer Brennereinrichtung oberhalb ausgewählter Ofenkammern bzw. Heizkanäle ist die Feuerzone definiert, die zwischen der Aufheizzone und der Kühlzone angeordnet ist. In der Kühlzone befinden sich unmittelbar zuvor gebrannte, also auf Sintertemperatur aufgeheizte, Anoden. Oberhalb der Kühlzone ist eine Gebläseeinrichtung angeordnet, mittels der Luft in die Heizkanäle der Kühlzone eingeblasen wird. Die Luft wird durch eine oberhalb der Aufheizzone angeordnete Absaugeinrichtung durch die Heizkanäle von der Kühlzone durch die Feuerzone hindurch in die Aufheizzone und von dieser als Rauchgas durch eine Rauchgasreinigungsanlage geleitet und in die Umgebung abgegeben. Die Absaugeinrichtung und die Brennereinrichtung bilden zusammen mit der Gebläseeinrichtung und den Heizkanälen eine Ofeneinheit.
Die vorgenannten Aggregate werden entlang der Heizkanäle in Richtung der im Anodenbrennofen angeordneten Rohanoden in regelmäßigen Zeitabständen verschoben. So kann es vorgesehen sein, dass ein Anodenbrennofen mehrere Ofeneinheiten umfasst, deren Aggregate einander nachfolgend oberhalb der Ofenkammern bzw. Heizkanäle zur nachfolgenden Wärmebehandlungen der Rohanoden bzw. Anoden verschoben werden. Bei derartigen Anodenbrennöfen, welche in unterschiedlichen Bauarten als offener Anodenbrennofen oder Anoden-Ringofen ausgebildet sein können, besteht das Problem, dass ein Volumenstrom der durch den Anodenbrennofen geführten Luft nur mit unvertretbar hohem Aufwand gemessen werden kann. Eine Bestimmung des Volumenstroms wird insbesondere zur regelmäßigen Überwachung eines Betriebszustandes des Anodenbrennofens benötigt. So soll sichergestellt werden, dass ausreichend Sauerstoff zur Verbrennung eines Brennstoffs der Brennereinrichtung in den Heizkanälen des Anodenbrennofens zur Verfügung steht. Da aufgrund der mäanderförmigen, rechteckigen Geometrie der Heizkanäle eine direkte Volumenstrommessung nicht möglich ist, wird versucht, den Volumenstrom durch eine indirekte Messung, beispielsweise eine Druckmessung, zu bestimmen. Eine derartige Abschätzung des Volumenstroms führt jedoch häufig zu unbrauchbaren Ergebnissen, wenn zum Beispiel eine Heizkanalabdeckung geöffnet oder unsachgemäß verschlossen ist, oder ein Heizkanal verstopft oder blockiert ist. Auch eine Messung des Volumenstroms mittels eines Venturirohrs führt zu unbefriedigenden Ergebnissen, da die für die Messung notwendigen Differenzdrücke nicht hergestellt werden können. In der Praxis wird daher eine Volumenstrombewertung durch geschultes Ofenpersonal im Rahmen eines Ofenrundgangs in regelmäßigen Zeitabständen durchgeführt. Wird eine Fehlfunktion des Anodenbrennofens erkannt, wird diese dann manuell durch das Ofenpersonal abgeschaltet. Dies kann jedoch dazu führen, dass gefährliche Betriebszustände des Anodenbrennofens, welche zu Verpuffungen, Bränden oder Explosionen führen können, möglicherweise nicht rechtzeitig erkannt werden.This sintering process takes place in a defined heat treatment process in which the anodes pass through three phases, namely a heating phase, a sintering phase and a cooling phase. Here are the Rohanoden in a heating zone of an assembled from the heating zone, a fire zone and a cooling zone, anode furnace formed "fire" and are preheated by the originating from the fire zone waste heat of already finished sintered anodes before the preheated anodes in the fire zone on the Sintering temperature of about 1200 ° Celsius are heated. According to the prior art, as he, for example, from the
By positioning a burner device above selected furnace chambers or heating channels, the fire zone is defined, which is arranged between the heating zone and the cooling zone. In the cooling zone are immediately before burned, ie heated to sintering temperature, anodes. Above the cooling zone, a blower device is arranged, is blown by means of the air in the heating channels of the cooling zone. The air is passed through an above the heating zone arranged suction through the heating channels from the cooling zone through the fire zone into the heating zone and from this as a flue gas through a flue gas cleaning system and discharged into the environment. The suction device and the burner device together with the blower device and the heating channels form a furnace unit.
The aforementioned aggregates are displaced along the heating channels in the direction of the anode arranged in the anode crucible at regular intervals. Thus, it may be provided that an anode furnace comprises a plurality of furnace units, the aggregates of each other Subsequently, above the furnace chambers or heating channels for subsequent heat treatments of the raw anode or anodes are moved. In such Anodenbrennöfen, which may be designed in different types as an open anode furnace or anode ring furnace, there is the problem that a volume flow of the guided through the anode furnace air can be measured only with unreasonable effort. A determination of the volume flow is needed in particular for the regular monitoring of an operating state of the anode furnace. This is to ensure that sufficient oxygen is available for combustion of a fuel of the burner device in the heating channels of the anode furnace. Since a direct volume flow measurement is not possible due to the meandering, rectangular geometry of the heating channels, an attempt is made to determine the volume flow by an indirect measurement, for example a pressure measurement. However, such an estimation of the volumetric flow often leads to unusable results, for example when a heating channel cover is opened or improperly closed, or a heating channel is blocked or blocked. Even a measurement of the volume flow by means of a Venturi tube leads to unsatisfactory results, since the differential pressures necessary for the measurement can not be established. In practice, therefore, a volumetric flow rate evaluation is carried out by trained oven personnel as part of a kiln tour at regular intervals. If a malfunction of the anode furnace is detected, it is then turned off manually by the furnace personnel. However, this can lead to hazardous operating conditions of the anode furnace, which can lead to deflagration, fires or explosions, may not be detected in time.
Aufgabe der vorliegenden Erfindung ist es daher, ein Verfahren zur Überwachung eines Betriebszustandes eines Anodenbrennofens vorzuschlagen, das eine kontinuierliche Überwachung des Betriebszustandes ermöglicht.Object of the present invention is therefore to propose a method for monitoring an operating condition of an anode furnace, which allows continuous monitoring of the operating condition.
Diese Aufgabe wird durch ein Verfahren mit den Merkmalen des Anspruchs 1 gelöst.This object is achieved by a method having the features of
Bei dem erfindungsgemäßen Verfahren zur Überwachung eines Betriebszustandes eines Anodenbrennofens ist der Anodenbrennofen aus einer Mehrzahl von Heizkanälen und Ofenkammern gebildet, wobei die Ofenkammern zur Aufnahme von Anoden und die Heizkanäle zur Temperierung der Ofenkammern dienen, wobei der Anodenbrennofen zumindest eine Ofeneinheit mit einer Aufheizzone, einer Feuerzone und einer Kühlzone umfasst, wobei in der Aufheizzone eine Absaugeinrichtung und in der Feuerzone eine Brennereinrichtung angeordnet ist, wobei mittels der Brennereinrichtung Verbrennungsluft in den Heizkanälen der Feuerzone erhitzt wird, wobei mittels der Absaugeinrichtung Heißluft aus den Heizkanälen der Aufheizzone abgesaugt wird, wobei eine Absaugleistung der Absaugeinrichtung bestimmt wird, und wobei ein Druck im Heizkanal gemessen wird, wobei aus einem Verhältnis von Absaugleistung und Druck ein Volumenstrom im Heizkanal bestimmt wird.In the method according to the invention for monitoring an operating state of an anode furnace, the anode furnace is formed from a plurality of heating channels and furnace chambers, wherein the furnace chambers for receiving anodes and the heating channels for controlling the temperature of the furnace chambers, wherein the anode furnace at least one furnace unit with a heating zone, a fire zone and a cooling zone, wherein in the heating zone, a suction device and in the fire zone, a burner means is arranged, wherein by means of the burner means combustion air is heated in the heating channels of the fire zone, being sucked by the suction hot air from the heating channels of the heating zone, wherein a suction of the Suction is determined, and wherein a pressure in the heating channel is measured, wherein from a ratio of suction and pressure, a volume flow in the heating channel is determined.
Die Absaugleistung der Absaugeinrichtung ist relativ zuverlässig bestimmbar, da die Absaugeinrichtung zwar einen Volumenstrom in den Heizkanälen bewirkt, jedoch nicht in unmittelbarer Abhängigkeit des Volumenstroms geregelt wird. Daher wird eine Absaugleistung der Absaugeinrichtung unter der Annahme eingestellt, dass sich daraus der erwünschte Volumenstrom ergibt. So ist es auch möglich, die Absaugleistung der Absaugeinrichtung einfach und genau zu bestimmen. Weiter wird ein Druck bzw. ein durch die Absaugeinrichtung bewirkter Unterdruck im Heizkanal gemessen. Aus dem Verhältnis von Absaugleistung zum Druck ist vergleichsweise genau der Volumenstrom im Heizkanal bestimmbar. Wenn beispielsweise eine Heizkanalabdeckung geöffnet oder unsachgemäß verschlossen oder auch der Heizkanal verstopft ist, kommt es zu einer Änderung des Drucks im Heizkanal relativ zur Absaugleistung der Absaugeinrichtung. Der gemessene Druck im Heizkanal weicht damit von einem vorausgesetzten Druck bei gleicher Absaugleistung ab. Daraus kann ein verminderter oder erhöhter Volumenstrom im Heizkanal abgeleitet werden. Die jeweils entsprechende Größe des Volumenstroms ergibt sich aus einer Abweichung von dem vorausgesetzten Volumenstrom bei bekannter Absaugleistung und gemessenem Druck. Da die Bestimmung der Absaugleistung und die Messung des Drucks im Heizkanal kontinuierlich, über Messwertaufnehmer und somit ohne Ofenpersonal erfolgen kann, wird es somit möglich, durch die fortlaufende Bestimmung des Volumenstroms eine ebensolche Überwachung des Betriebszustandes des Anodenbrennofens durchzuführen.The suction power of the suction device can be determined relatively reliably, since the suction device indeed causes a volume flow in the heating channels, but is not regulated in direct dependence of the volume flow. Therefore, a suction power of the suction device is set on the assumption that the desired volume flow results therefrom. So it is also possible to determine the suction of the suction easily and accurately. Furthermore, a pressure or a vacuum caused by the suction device is measured in the heating channel. From the ratio of suction power to pressure comparatively accurately the volume flow in the heating channel can be determined. For example, if a Heizkanalabdeckung open or improperly closed or the heating channel is clogged, there is a change in pressure in the heating channel relative to the suction of the suction. The measured pressure in the heating channel thus deviates from a presumed pressure at the same suction power from. From this, a reduced or increased volume flow in the heating channel can be derived. The respectively corresponding size of the volume flow results from a deviation from the presumed volume flow at known suction power and measured pressure. Since the determination of the suction power and the measurement of the pressure in the heating channel can be carried out continuously, via transducers and thus without furnace personnel, it is thus possible to perform a similar monitoring of the operating state of the anode furnace by the continuous determination of the volume flow.
Durch die verschiedenen Ausführungsformen des Verfahrens kann ein Druck bzw. Unterdruck im Heizkanal in der Aufheizzone und/oder der Feuerzone gemessen werden. So ist es denkbar, mehrere Druckmessungen in der betreffenden Zone bzw. den jeweiligen Zonen durchzuführen, um die Position einer Betriebsstörung schnell zu ermitteln.Due to the various embodiments of the method, a pressure or negative pressure in the heating channel in the heating zone and / or the fire zone can be measured. Thus, it is conceivable to carry out a plurality of pressure measurements in the relevant zone or the respective zones in order to quickly determine the position of a malfunction.
Weiter ist es zur näheren Bestimmung eines Betriebszustandes auch möglich, einen Druck bzw. Unterdruck in beispielsweise einem Sammelkanal der Absaugeinrichtung zu messen. Wenn die Absaugeinrichtung so ausgebildet ist, dass sie mehrere Heizkanäle in Querrichtung überspannt und an diese angeschlossen ist, kann der in diesem Sammelkanal der Absaugeinrichtung gemessene Druck ebenfalls zur Bestimmung des Volumenstroms herangezogen werden. Weiterhin kann damit auch sichergestellt werden, dass keine Fehlfunktion vorliegt, wenn die Absaugleistung und der gemessen Druck in der Absaugeinrichtung in einem zu erwartenden Verhältnis zueinander steht.It is also possible for a more detailed determination of an operating state, to measure a pressure or negative pressure in, for example, a collecting duct of the suction device. If the suction device is designed such that it spans and is connected to a plurality of heating channels in the transverse direction, the pressure measured in this collecting channel of the suction device can also be used to determine the volume flow. Furthermore, it can also be ensured that there is no malfunction when the suction power and the measured pressure in the suction device is in an expected relationship to each other.
Der Volumenstrom wird noch genauer bestimmbar, wenn dieser aus einem Verhältnis von Absaugleistung und Druck in der Absaugeinrichtung und dem Verhältnis von Absaugleistung und Druck im Heizkanal bestimmt wird. Die betreffenden Verhältnisse können jeweils getrennt voneinander gebildet und der Volumenstrom daraus abgeleitet werden.The volume flow can be determined even more accurately if this is determined from a ratio of suction power and pressure in the suction device and the ratio of suction power and pressure in the heating duct. The respective conditions can each be formed separately from each other and the volume flow can be derived therefrom.
Auch kann ein Volumenstrom individuell für einzelne Heizkanäle bestimmt werden, beispielsweise dadurch, dass ein jeweiliger Druck in einer Mehrzahl von Heizkanälen in Verhältnis zu dem Druck in der Absaugeinrichtung gesetzt wird. Ein im Vergleich zu den übrigen Heizkanälen besonders hoher oder niedriger Druck in einem Heizkanal kann schon auf eine mögliche Betriebsstörung im betreffenden Heizkanal hinweisen. Weiter hat eine Druckabweichung in einem Heizkanal Auswirkungen auf die Drücke in den übrigen Heizkanälen, sodass auch hier mit Relativbezug zu dem in der Absaugeinrichtung gemessenen Druck ein demnach veränderter Volumenstrom bestimmt bzw. berechnet werden kann.Also, a volume flow can be determined individually for individual heating channels, for example, by setting a respective pressure in a plurality of heating channels in relation to the pressure in the suction device. A particularly high or low pressure in a heating channel compared to the other heating channels can already indicate a possible malfunction in the relevant heating channel. Furthermore, a pressure deviation in a heating channel has an effect on the pressures in the other heating channels, so that a correspondingly changed volume flow can also be determined or calculated here with relative reference to the pressure measured in the suction device.
Eine Bestimmung der Absaugleistung der Absaugeinrichtung kann durch Bestimmung einer Klappenposition einer Drosselklappe der Absaugeinrichtung erfolgen. Ein Querschnitt eines Absaugkanals kann durch eine Verstellung der Drosselklappe variiert werden, sodass die Absaugleistung der Absaugeinrichtung unter anderem von dem eingestellten Querschnitt des Absaugkanals abhängt. Wenn eine Drosselklappe oder eine ähnliche derartige Einrichtung verwendet wird, kann daher aus einer Klappenposition, beispielsweise angegeben in Winkelgrad relativ zum Absaugkanal, auf eine Absaugleistung rückgeschlossen werden. Eine Klappenposition kann besonders einfach und genau, beispielsweise mittels eines Drehpotentiometers, bestimmt werden.A determination of the suction power of the suction device can be made by determining a flap position of a throttle valve of the suction device. A cross-section of a suction channel can be varied by adjusting the throttle, so that the suction power of the suction device depends inter alia on the set cross-section of the suction channel. Therefore, when using a butterfly valve or similar such device, an exhaust performance may be deduced from a flap position, for example given in degrees of angularity relative to the suction channel. A flap position can be determined particularly simply and accurately, for example by means of a rotary potentiometer.
Besonders vorteilhaft ist es, wenn der Volumenstrom im Heizkanal der Aufheizzone und/oder der Feuerzone bestimmt wird. Da sich hier gegebenenfalls durch das Brennverfahren bedingte Volumenstromunterschiede ergeben, können diese so berücksichtigt werden. So kann ein Volumenstrom im Heizkanal der vorgenannten Zonen jeweils getrennt voneinander bestimmt werden. Somit wird eine differenziertere Betrachtung des Betriebszustandes in den jeweiligen Zonen des Anodenbrennofens möglich.It is particularly advantageous if the volume flow in the heating channel of the heating zone and / or the fire zone is determined. Since this may result from the combustion process caused flow differences, they can be considered so. Thus, a volume flow in the heating channel of the aforementioned zones can be determined separately from each other. Thus, a more differentiated consideration of the operating state in the respective zones of the anode furnace is possible.
Insgesamt kann aus dem Verhältnis von Absaugleistung und Druck und/oder dem bestimmten Volumenstrom ein Betriebszustand abgeleitet werden. So wird es möglich, anhand der gemessenen Daten bzw. des Volumenstroms festzustellen, in welcher Phase der Anodenherstellung der Anodenbrennofen bzw. die betreffende Ofeneinheit sich gerade befindet. Zum Beispiel kann die Bestimmung des Betriebszustandes dazu herangezogen werden, einen Zeitpunkt für ein Umsetzen der Absaugeinrichtung und der Brennereinrichtung sowie einer Gebläseeinrichtung noch genauer zu bestimmen.Overall, an operating state can be derived from the ratio of suction power and pressure and / or the specific volume flow. Thus, it is possible to determine, based on the measured data or the volume flow, in which phase of the anode production of the anode furnace or the relevant furnace unit is currently located. For example, the determination of the operating state can be used to determine a point in time for a conversion of the suction device and the burner device and a blower device in more detail.
In einer weiteren Ausführungsform des Verfahrens kann eine Temperatur im Heizkanal gemessen werden. Eine Bewertung eines Betriebszustandes wird dadurch noch weiter vereinfacht, da so eine erforderliche Brenntemperatur überwacht werden kann.In a further embodiment of the method, a temperature in the heating channel can be measured. An evaluation of an operating condition is thereby further simplified, since such a required firing temperature can be monitored.
Weiter kann auch ein Temperaturgradient im Heizkanal gemessen werden. Demnach kann ein Temperaturverlauf über einen Zeitabschnitt überwacht werden, wobei eine fallende oder steigende Temperatur bzw. ein negativer oder positiver Temperaturgradient Rückschlüsse auf eine Betriebszustandsänderung zulässt.Furthermore, a temperature gradient in the heating channel can also be measured. Accordingly, a temperature profile can be monitored over a period of time, with a falling or rising temperature or a negative or positive temperature gradient allowing conclusions to be drawn on an operating state change.
Der Temperaturgradient und/oder die Temperatur können bzw. kann in einem Sammelkanal der Absaugeinrichtung und/oder der Aufheizzone und/oder der Feuerzone gemessen werden. Der Sammelkanal bzw. die vorgenannten Zonen erfordern für einen ordnungsgemäßen Betrieb der Ofeneinheit jeweils einen bestimmten Temperaturgradienten bzw. Temperaturbereich, sodass mit einer messtechnischen Überwachung dieser Anlagenabschnitte eine noch genauere Bestimmung eines Betriebszustandes möglich wird.The temperature gradient and / or the temperature can or can be measured in a collecting channel of the suction device and / or the heating zone and / or the fire zone. The collecting channel or the aforementioned zones each require a specific temperature gradient or temperature range for proper operation of the furnace unit, so that a more precise determination of an operating state becomes possible with metrological monitoring of these plant sections.
Auch kann der Volumenstrom noch genauer bestimmt werden, wenn aus dem Temperaturgradient und der Temperatur eine Dichteänderung von Luft in dem Heizkanal berechnet wird, und diese Dichteänderung bei der Bestimmung des Volumenstroms berücksichtigt wird. Die sich durch einen Anstieg oder ein Fallen einer Temperatur im Heizkanal ergebende Volumenänderung der sich im Heizkanal befindlichen Luft kann einen Volumenstrom im Heizkanal wesentlich beeinflussen. Eine Berechnung des Volumenstroms kann daher durch einen Korrekturfaktor, der aus einer Berechnung der Dichteänderung auf Basis von Temperaturgradient und Temperatur abgeleitet werden kann, korrigiert werden.Also, the volumetric flow can be determined even more accurately if a change in density of air in the heating channel is calculated from the temperature gradient and the temperature, and this density change is taken into account in the determination of the volumetric flow. Which is through an increase or decrease in a temperature in the heating channel resulting volume change of the air located in the heating channel can significantly affect a flow in the heating channel. A calculation of the volumetric flow can therefore be corrected by a correction factor that can be derived from a calculation of the density change on the basis of temperature gradient and temperature.
Aus einem Verhältnis von Temperaturgradient und Volumenstrom kann auch ein Betriebszustand abgeleitet werden. In Abhängigkeit des Volumenstroms im Heizkanal kommt es zu einer fortschreitenden Erwärmung in der Aufheizzone. Folglich kann so ein Zusammenhang zwischen Temperaturgradient und Volumenstrom hergestellt werden. Ein beispielsweise negativer oder sehr hoher Temperaturgradient in der Aufheizzone bei geringem Volumenstrom kann auf eine Verstopfung des betreffenden Heizkanals hinweisen. Durch die Verhältnisbildung von Temperaturgradient und Volumenstrom kann daher sogar eine mögliche Ursache für eine Betriebsstörung ermittelt werden.From a ratio of temperature gradient and flow rate can also be derived an operating condition. Depending on the volume flow in the heating channel, there is a progressive heating in the heating zone. Consequently, a relationship between temperature gradient and volume flow can be established. For example, a negative or very high temperature gradient in the heating zone at a low flow rate may indicate a blockage of the relevant heating channel. By the ratio formation of temperature gradient and flow rate, therefore, even a possible cause of a malfunction can be determined.
In diesem Zusammenhang ist es vorteilhaft, wenn der Betriebszustand bewertet wird, wobei bei Abweichung von einem vorausgesetzten Betriebszustand eine Abschaltung der Brennereinrichtung erfolgt. So kann vermieden werden, dass eine Fehlfunktion der Ofeneinheit eine eventuelle Beschädigung derselben zur Folge hat. Die Abschaltung der Brennereinrichtung oder der gesamten Ofeneinheit kann auch automatisch erfolgen, ohne dass Ofenpersonal vor Ort sein muss. Insofern kann es vorgesehen sein, dass eine Verarbeitung der im Rahmen des Überwachungsverfahrens erfassten Messwerte und Betriebszustandsgrößen mittels einer Einrichtung zur Datenverarbeitung oder einer entsprechenden Steuer- und Regelungseinrichtung erfolgt. So kann der Betriebszustand ebenfalls automatisch durch eine beeinflussende Regelung der betreffenden Aggregate der Ofeneinheit beeinflusst bzw. korrigiert werden.In this context, it is advantageous if the operating state is evaluated, wherein in case of deviation from a presumed operating state, a shutdown of the burner device takes place. Thus it can be avoided that a malfunction of the furnace unit has a possible damage to the same result. The shutdown of the burner device or the entire furnace unit can also be done automatically without furnace personnel must be on site. In this respect, provision may be made for processing of the measured values and operating state variables detected in the context of the monitoring method to take place by means of a data processing device or a corresponding control and regulating device. Thus, the operating state can also be influenced or corrected automatically by an influencing control of the respective units of the furnace unit.
Auch können den Betriebszustand beschreibende Betriebszustandsparameter gespeichert werden, wobei eine Bewertung des aktuellen Betriebszustands durch einen Vergleich der gespeicherten mit den aktuellen Betriebszustandsparametern durchgeführt werden kann. Insbesondere wenn eine Einrichtung zur Datenverarbeitung verwendet wird, kann ein fortlaufender Vergleich der aktuellen Betriebszustandsparameter mit den gespeicherten Betriebszustandsparametern durchgeführt werden. Dabei ist es möglich, für die verschiedenen Betriebszustandsparameter Schwellenwerte zu definieren, die eine Abschaltung bzw. korrigierende Regelung von Aggregaten auslösen.It is also possible to store operating state parameters describing the operating state, wherein an evaluation of the current operating state can be carried out by comparing the stored with the current operating state parameters. In particular, when a device for data processing is used, a continuous comparison of the current operating state parameters with the stored operating state parameters can be performed. In this case, it is possible to define threshold values for the various operating state parameters which trigger a shutdown or corrective control of units.
Vorteilhaft kann auch vor jedem Start bzw. Inbetriebnahme oder Wiederinbetriebnahme der Ofeneinheit eine Plausibilitätsprüfung von Messwertaufnehmern durchgeführt werden. So kann sichergestellt werden, dass nach einem Umsetzen der Aggregate der Ofeneinheit die Messwertaufnehmer der Ofeneinheit in der vorgesehenen Weise miteinander angeschlossen sind. Unter anderem kann so auch sichergestellt werden, dass bei einer Fehlfunktion eines Messwertaufnehmers keine unerwünschte Betriebszustandsbeeinflussung erfolgt.Advantageously, a plausibility check of transducers can also be carried out before each start or startup or recommissioning of the furnace unit. Thus it can be ensured that after a conversion of the units of the furnace unit, the transducers of the furnace unit are connected to each other in the intended manner. Among other things, it can thus be ensured that, in the event of a malfunction of a measuring transducer, there is no undesirable operating state influencing.
Nachfolgend wird eine bevorzugte Ausführungsform der Erfindung unter Bezugnahme auf die beigefügten Zeichnungen näher erläutert.Hereinafter, a preferred embodiment of the invention will be explained in more detail with reference to the accompanying drawings.
Es zeigen:
- Fig. 1:
- Eine schematische Darstellung eines Anodenbrennofens in einer perspektivischen Ansicht;
- Fig. 2:
- eine schematische Darstellung einer Ofeneinheit des Anodenbrennofens in einer Längsschnittansicht;
- Fig. 3:
- eine Temperaturverteilung in der Ofeneinheit;
- Fig. 4:
- eine grafische Darstellung des Verhältnisses von Volumenstrom zu Betriebszustandsparametern;
- Fig. 5:
- eine grafische Verhältnisdarstellung von Volumenstrom zu Temperaturgradient;
- Fig. 6:
- ein Ablaufdiagramm für eine Ausführungsform des Verfahrens zur Überwachung eines Betriebszustandes.
- Fig. 1:
- A schematic representation of an anode furnace in a perspective view;
- Fig. 2:
- a schematic representation of a furnace unit of the anode furnace in a longitudinal sectional view;
- 3:
- a temperature distribution in the furnace unit;
- 4:
- a graphical representation of the ratio of flow rate to operating state parameters;
- Fig. 5:
- a graphical representation of volume flow to temperature gradient;
- Fig. 6:
- a flowchart for an embodiment of the method for monitoring an operating condition.
Eine Zusammenschau der
Die Ofeneinheit 11 umfasst weiter eine Absaugeinrichtung 15, eine Brennereinrichtung 16 und eine Gebläseeinrichtung 17. Deren Position am Anodenbrennofen 10 definiert jeweils funktionsbedingt eine Aufheizzone 18, eine Feuerzone 19 und eine Kühlzone 20. Im Laufe des Produktionsprozesses der Anoden wird die Ofeneinheit 11 relativ zu den Ofenkammern 13 bzw. den Anoden durch Umsetzen der Einrichtungen 15 bis 17 in Längsrichtung des Anodenbrennofens 10 verschoben, sodass alle im Anodenbrennofen 10 befindlichen Anoden die Zonen 18 bis 20 durchlaufen.The oven unit 11 further comprises a
Die Absaugeinrichtung 15 ist im Wesentlichen aus einem Sammelkanal 21 gebildet, der über einen Ringkanal 22 an eine hier nicht dargestellte Abgasreinigungsanlage angeschlossen ist. Der Sammelkanal 21 ist seinerseits jeweils über einen Anschlusskanal 23 an einer Heizkanalöffnung 14 angeschlossen, wobei hier eine Drosselklappe 24 am Anschlusskanal 23 angeordnet ist. Weiter ist ein hier nicht dargestellter Messwertaufnehmer zur Druckmessung innerhalb des Sammelkanals 21 und ein weiterer Messwertaufnehmer 25 zur Temperaturmessung in jedem Heizkanal 12 unmittelbar vor dem Sammelkanal 21 angeordnet und über eine Datenleitung 26 mit diesem verbunden. In der Aufheizzone 18 ist darüber hinaus eine Messrampe 27 mit Messwertaufnehmern 28 für jeden Heizkanal 12 angeordnet. Mittels der Messrampe 27 können ein Druck und eine Temperatur im betreffenden Abschnitt des Heizkanals 12 ermittelt werden.The
Die Brennereinrichtung 16 umfasst drei Brennerrampen 29 mit Brennern 30 und Messwertaufnehmern 31 für jeden Heizkanal 12. Die Brenner 30 verbrennen jeweils im Heizkanal 12 einen entzündbaren Brennstoff, wobei mittels der Messwertaufnehmer 31 eine Brennertemperatur gemessen wird. So wird es möglich, im Bereich der Feuerzone 19 eine gewünschte Brennertemperatur einzustellen.The
Die Kühlzone 20 umfasst die Gebläseeinrichtung 17, welche aus einem Zuführkanal 32 mit jeweiligen Anschlusskanälen 33 und Drosselklappen 34 zum Anschluss an die Heizkanäle 12 ausgebildet ist. Über den Zuführkanal 32 wird Frischluft in die Heizkanäle 12 eingeblasen. Die Frischluft kühlt die Heizkanäle 12 bzw. die in den Ofenkammern 13 befindlichen Anoden im Bereich der Kühlzone 20, wobei die Frischluft sich bis zum Erreichen der Feuerzone 19 kontinuierlich erwärmt. Der
Mit dem beispielhaft in
Dieser Vergleich kann beispielsweise, wie in
Claims (16)
- A method for monitoring an operating status of an anode furnace (10), wherein the anode furnace is formed from a plurality of heating ducts (12) and furnace chambers (13), wherein the furnace chambers serve for receiving anodes and the heating ducts serve for controlling the temperature of the furnace chambers, wherein the anode furnace comprises at least one furnace unit (11) having a heating zone (18), a firing zone (19) and a cooling zone (20), wherein a suction device (15) is arranged in the heating zone and a burner device (16) is arranged in the firing zone, wherein, by means of the burner device, combustion air is heated up in the heating ducts of the firing zone, wherein, by means of the suction device, hot air is sucked out of the heating ducts of the heating zone, wherein a suction output of the suction device is determined, and wherein a pressure is measured in the heating duct,
characterized in that
a volumetric flow is determined in the heating duct from a ratio of suction output and pressure. - The method according to claim 1,
characterized in that
a pressure in the heating duct (12) of the heating zone (18) and/or of the firing zone (19) is measured. - The method according to claim 2,
characterized in that
a pressure in the suction device (15) is measured. - The method according to claim 3,
characterized in that
the volumetric flow in the heating duct is determined from a ratio of the suction output and pressure in the suction device (15) and from the ratio of the suction output and pressure in the heating duct (12). - The method according to claim 3 or 4,
characterized in that
a respective pressure in a plurality of heating ducts (12) is related to the pressure in the suction device (15). - The method according to any one of the preceding claims,
characterized in that
the suction output of the suction device (15) is determined by determining a throttle position of a throttle (24) of the suction device (15). - The method according to any one of the preceding claims,
characterized in that
the volumetric flow in the heating duct (12) of the heating zone (18) and/or of the firing zone (19) is determined. - The method according to any one of the preceding claims,
characterized in that
an operating status is derived from the ratio and/or from the volumetric flow. - The method according to any one of the preceding claims,
characterized in that
a temperature in the heating duct (12) is measured. - The method according to claim 9,
characterized in that
a temperature gradient in the heating duct (12) is measured. - The method according to claim 10,
characterized in that
the temperature gradient and/or the temperature in a collecting duct (21) of the suction device (15) and/or in the heating zone (18) and/or in the firing zone (19) is measured. - The method according to claim 10 or 11,
characterized in that
a density change of the air in the heating duct (12) is calculated from the temperature gradient and from the temperature, wherein the density change is used for determining the volumetric flow. - The method according to any one of the claims 10 to 12,
characterized in that
an operating status is derived from a ratio of temperature gradient and volumetric flow. - The method according to claim 8 or 13,
characterized in that
the operating status is evaluated, wherein, in case of a deviation from a presupposed operating status, the burner device (16) is switched off. - The method according to claim 14,
characterized in that
operating status parameters that describe the operating status are stored, wherein the current operating status is evaluated by comparing the stored operating status parameters to the current ones. - The method according to any one of the preceding claims,
characterized in that
before the initiation of operation of the furnace unit (11), a plausibility check of measuring sensors (25, 28, 31, 36) is performed.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2011/067034 WO2013044968A1 (en) | 2011-09-29 | 2011-09-29 | Monitoring method |
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| Publication Number | Publication Date |
|---|---|
| EP2761241A1 EP2761241A1 (en) | 2014-08-06 |
| EP2761241B1 true EP2761241B1 (en) | 2018-12-26 |
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|---|---|---|---|
| EP11771056.6A Active EP2761241B1 (en) | 2011-09-29 | 2011-09-29 | Monitoring method |
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| US (1) | US9927175B2 (en) |
| EP (1) | EP2761241B1 (en) |
| AU (1) | AU2011377913B2 (en) |
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| WO (1) | WO2013044968A1 (en) |
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| FR3012590B1 (en) * | 2013-10-31 | 2018-01-05 | Solios Carbone | METHOD FOR CONTROLLING A ROTATING FIRE CHAMBER (X) FOR THE COOKING OF CARBON BLOCKS |
| AU2020339655A1 (en) | 2019-08-28 | 2022-03-17 | Innovatherm Prof. Dr. Leisenberg Gmbh + Co. Kg | Furnace and method for operating a furnace |
| US12504232B2 (en) | 2020-09-03 | 2025-12-23 | Innovatherm Prof. Dr. Leisenberg Gmbh + Co. Kg | Furnace and method for operating a furnace |
| EP4237778A1 (en) | 2020-10-28 | 2023-09-06 | Innovatherm Prof. Dr. Leisenberg GmbH & Co. KG | Furnace and method for operating a furnace |
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| JPS5850772B2 (en) * | 1979-02-27 | 1983-11-12 | 工業技術院長 | Fluidized bed reactor and its operating method |
| EP1785685A1 (en) | 2005-11-10 | 2007-05-16 | Innovatherm Prof. Dr. Leisenberg GmbH & Co. KG | Apparatus and method for heating a starting material |
| CN101606036B (en) * | 2007-09-18 | 2011-12-28 | 德国伊诺瓦有限公司 | Method and device for heat recovery |
-
2011
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- 2011-09-29 EP EP11771056.6A patent/EP2761241B1/en active Active
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| US9927175B2 (en) | 2018-03-27 |
| US20140255860A1 (en) | 2014-09-11 |
| CA2850254A1 (en) | 2013-04-04 |
| AU2011377913B2 (en) | 2017-05-11 |
| WO2013044968A1 (en) | 2013-04-04 |
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| EP2761241A1 (en) | 2014-08-06 |
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