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EP2699387B1 - Resin bonded grinding wheel - Google Patents

Resin bonded grinding wheel Download PDF

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Publication number
EP2699387B1
EP2699387B1 EP12774388.8A EP12774388A EP2699387B1 EP 2699387 B1 EP2699387 B1 EP 2699387B1 EP 12774388 A EP12774388 A EP 12774388A EP 2699387 B1 EP2699387 B1 EP 2699387B1
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EP
European Patent Office
Prior art keywords
filler particles
grinding wheel
diamond
high concentration
diamonds
Prior art date
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EP12774388.8A
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German (de)
French (fr)
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EP2699387A2 (en
EP2699387A4 (en
Inventor
Janusz HAJDUK
James L. Mcardle
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3M Innovative Properties Co
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3M Innovative Properties Co
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Publication of EP2699387A4 publication Critical patent/EP2699387A4/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/20Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
    • B24D3/28Resins or natural or synthetic macromolecular compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/20Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
    • B24D3/28Resins or natural or synthetic macromolecular compounds
    • B24D3/30Resins or natural or synthetic macromolecular compounds for close-grained structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B5/00Machines or devices designed for grinding surfaces of revolution on work, including those which also grind adjacent plane surfaces; Accessories therefor
    • B24B5/18Machines or devices designed for grinding surfaces of revolution on work, including those which also grind adjacent plane surfaces; Accessories therefor involving centreless means for supporting, guiding, floating or rotating work
    • B24B5/22Machines or devices designed for grinding surfaces of revolution on work, including those which also grind adjacent plane surfaces; Accessories therefor involving centreless means for supporting, guiding, floating or rotating work for grinding cylindrical surfaces, e.g. on bolts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/04Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
    • B24D3/06Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
    • B24D3/10Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements for porous or cellular structure, e.g. for use with diamonds as abrasives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/34Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
    • B24D3/342Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent
    • B24D3/344Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent the bonding agent being organic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/34Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
    • B24D3/346Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties utilised during polishing, or grinding operation

Definitions

  • Polycrystalline diamond compacts include a polycrystalline diamond layer bonded to a tungsten carbide substrate.
  • the polycrystalline diamond layer provides high hardness and abrasion resistance, while the tungsten carbide layer improves the toughness of the composite.
  • PDC's are often employed as the cutting tips for boring bits used to drill into the earth for natural resources.
  • Resin bond grinding wheels with diamond abrasive particles can be used to grind and finish PDC to its final specified dimensions.
  • PDC is extremely difficult to grind because of the interface of the two dissimilar hardness materials.
  • the diamond abrasive in the resin bonded grinding wheel dulls very quickly.
  • the tungsten carbide substrate loads the grinding wheel reducing the ability of the abrasive wheel to further grind the polycrystalline diamond layer.
  • the resin bonded grinding wheel must be constantly dressed with a carborundum stone to reduce or eliminate the tungsten carbide loading of the grinding wheel and to expose fresh diamond cutting points.
  • the invention resides in a method of grinding according to claim 1.
  • the invention resides in an abrasive article according to claim 6.
  • the centerless grinder includes a resin bonded grinding wheel 12, a regulating wheel 14, and a support 16 for holding a PDC 18 between the two wheels.
  • the PDC includes a polycrystalline diamond layer 20 bonded to a tungsten carbide substrate 22.
  • the speed at which the PDC will traverse through the grinding interface between the two wheels is controlled by the helix angle ⁇ between the axis of the resin bonded grinding wheel 12 and the axis of the regulating wheel 14 in combination with the rotational speed of the regulating wheel.
  • Prior art resin bonded grinding wheels require constant dressing of the outer surface 26 with a carborundum stone to maintain the ability of the resin bonded grinding wheel to grind the polycrystalline diamond layer.
  • the resin bonded grinding wheel behave similar to a vitrified bonded grinding wheel.
  • Such an effect can be achieved by using a very high diamond concentration while including both hard filler particles and soft filler particles to control the breakdown rate of the resin bonded abrasive wheel.
  • Such a resin bonded grinding wheel will ensure the exposure of fresh diamonds particles in the wheel while reducing or eliminating glazing of the outer surface during use.
  • the high concentration diamond portion can be an outer annulus of the grinding wheel, a segmented portion thereof, or the entire grinding wheel.
  • Suitable diamonds for use in the abrasive wheel include, for example, natural diamond, synthetic diamond, resin bond diamonds, metal bond diamonds, diamond abrasive powder, resin bonded or vitrified bonded diamond agglomerates of the foregoing, and combinations of all of the foregoing.
  • the diamond concentration is very high.
  • the diamond concentration based on the total volume of the high concentration diamond portion of the grinding wheel is from 175 to 225 or from 180 to 200. Diamond concentrations less than 175 do not reduce the need for dressing and concentrations greater than 225 become difficult to bond with sufficient integrity.
  • the diamonds may be coated or uncoated with a metal such as nickel or copper.
  • the coating weight percent should be less than 40%, or less than or equal to 30%. Excessive coating amounts reduces the diamond concentration to too low of a level and does not result in reduced dressing of the resin bonded grinding wheel during use.
  • the size of the diamonds, if not agglomerated, should be between 60/80 mesh size to 200/230 mesh size. Ranges above and below these limits do not provide the requisite packing density to achieve the desired diamond concentration.
  • Resin bond diamonds may be suitable, especially if agglomerated, the diamonds are preferred to be metal bond diamonds.
  • Resin bond diamonds are generally too weak and friable to be used in a resin bonded grinding wheel to grind PDC.
  • Metal bond diamonds are available in strengths from friable (weaker) to less friable (stronger). Such strength rating is qualified by various suppliers using different designations. In order to expose fresh diamonds more effectively, weaker metal bond diamonds are preferred. For example, if using diamonds from ABC Superabrasives, the strength is rated on a scale from ABS 2 (weak) to ABS 9 (strong). When using ABC Superabrasive diamonds, the diamonds are desirably ABS 2 or ABS 3.
  • Suitable strength diamonds can include WSG 200, WSG300, WSG400, and WSG500.
  • LANDS Superabrasives has strengths designated as LS200, LS230, LS250, LS260, LS270, and LS290.
  • Suitable strength diamonds can include LS200, LS230, and LS240. In general, the bottom 50% of the strength scale for a given supplier's metal bond diamonds are suitable.
  • Suitable resin binders for use with the diamond abrasive particles include formaldehyde-containing resins, such as phenol formaldehyde, novolac phenolics and especially those with added crosslinking agent (e.g., hexamethylenetetramine), phenoplasts, and aminoplasts; unsaturated polyester resins; vinyl ester resins; alkyd resins, allyl resins; furan resins; epoxies; polyurethanes; cyanate esters; and polyimides.
  • the amount of binder resin used in the resin bonded grinding wheel is from about 30% to about 40% by volume such as approximately 35% by volume of the high concentration diamond portion.
  • the amount of resin should be sufficient to fully wet the surfaces of all the individual particles during manufacturing such that a continuous resin structure, substantially devoid of porosity, is formed with the inorganic components discretely bonded throughout, which comprises the mechanical structure of the grinding wheel.
  • Suitable filler additives can include reinforcing particles, grinding aids, dessicants, colorants, and lubricants. As mentioned, both hard and soft filler particles are used in addition to the diamonds to reinforce and control the breakdown rate of the grinding wheel.
  • Hard filler particles (excluding diamonds) are those having a Mohs hardness of 7 or greater.
  • Suitable hard filler particles include aluminum oxide, silicon carbide, zirconia, ceramic alpha alumina particles typically derived from boehmite sol gels, or other abrasive particles having the requisite Mohs hardness.
  • Soft filler particles have a Mohs hardness of 5 or less.
  • Suitable soft fillers include petroleum coke, pyrophyllite, cryolite, lime, graphite, refractory grog, ball clay, copper, or talc.
  • the volume ratio of the hard to soft filler particles is from 15:85 to 85:15, or from 30:70 to 70:30, or from 40:60 to 60:40.
  • Suitable hard filler particle sizes include sizes equal to or less than about 30 microns, such as 600, 800, or 1000 ANSI mesh equivalents.
  • Suitable soft filler particles sizes include 100 mesh or finer.
  • the soft particles can have a fine fraction and coarse fraction if desired. The fine fraction can be finer than 280 mesh and the coarse fraction can be from 100 to 180 mesh.
  • volume fraction of the coarse to fine particles can be 50:50 to 70:30. Too large a volume fraction of hard filler particles impedes breakdown leading to heat buildup and glazing of the grinding wheel, and too large a volume fraction of soft filler particles undesirably increase the wear rate of the grinding wheel.
  • the volume percent of a mixture of hard filler particles and soft filler particles used in the resin bonded grinding wheel is from 8% to 20% of the high concentration diamond portion.
  • fillers can include fibrous and plate-like materials such as carbon or glass whiskers and mica.
  • Grinding aids such as cryolite, potassium tetrafluoroborate (KBF4), polyvinyl chloride, lignosulfonates, and blends thereof.
  • Colorants such as organic or inorganic pigments or dies may be incorporated into the grinding wheel.
  • the grinding wheels of Examples 1, 7, 9 to 14 and Comparative Examples 1A to 6A were prepared and tested to evaluate their grinding performance on PDC.
  • Examples 1 and Comparative Example 1A were evaluated under different grinding wheel dressing procedures.
  • the weight percentage compositions of the various grinding wheels are shown in Table 2.
  • composition listed in Table 2 was thoroughly mixed for 4 hours in a 1000 ml polyethylene mixing jar and a roller mill stand (2-Bar Tumbler Base, C&M Topline Inc., Goleta CA) set at approximately 18.85 rad/s (180 rpm).
  • the die cavity in the five-piece, ring-punch double-compaction steel mold was filled with the mixed abrasive composition by rotating the die assembly on a circular table while pouring the abrasive powder mixture into the annular cavity around the core. The powder was then smoothed and leveled with a plastic straightedge tool, and the filled mold was closed with the upper ring punch.
  • the filled mold was placed in a 200-ton heated-platen hydraulic press with the platen set point temperature set at 177 °C (350 degrees F).
  • the press platens were closed to bring the ring-punch surfaces flush against the mold shell.
  • a magnetic thermometer was attached to the side of the mold shell and the mold temperature was monitored. When the mold shell reached 177 °C ( 350 degree F), the mold was held closed under pressure for 20 minutes.
  • the mold assembly was removed from the heated-platen press and placed on a water-cooled steel table and allowed to cool to room temperature.
  • the mold shell was stripped from the formed wheel section using a 50-ton hydraulic press and steel spacers.
  • the formed wheel sections were cured in air according the following schedule. One hour ramp to 66 °C (150 degree F), one hour soak at 66 °C (150 degree F), 4 hour ramp to 177 °C (350 degree F), seven hour soak at 177 °C (350 degree F), followed by 3 hour cool to room temperature.
  • Example 1 Comp.
  • Example 2A Comp.
  • Example 3A Comp.
  • Example 4A Comp.
  • Example 6A Example 7 Example 9 Example 10
  • Example 12 Example 13
  • Example 14 NP1 0 19.5 NP2 8.4 0 19.4 18.4 16.5 18.2 8.4 8.3 16.2 16.3 NP3 8.4 0 8.4 8.3 SC 0 10.6 14.6 11.1 BC 0 1.7 5.0 Cu 0 18.5 MO 0 1.5 PC1 3.9 0 4.5 4.3 2.1 3.5 3.9 3.8 3.8 PC2 3.9 0 3.9 1.9 CO 0.7 0 0.6 1.1 0.9 0.7 0.6 0.5 0.7 0.7 0.7 321 12.2 0 14.0 13.3 7.7 11.3 12.2 8.0 321B 8.0 19.5 11.8 D1 0 34.5 38.8 16.5 21 D2 0 8.1 9.1 D3 0 2.8 3.2 D4 0 2.8 3.2 D5 23.6 0 25.2 23.5 20.4 20.0 D6 23.6 0 25.2 23.5 20.4 20.0 20.2 D7 15.3 0 23.5 D8 11.6 D9 48.7 NP4 14.1 1
  • Cylindrical diamond cutter inserts obtained from US Synthetic Corporation, Orem, Utah, were ground using a centerless grinder (Acme Model 47 Centerless Grinder, Acme Manufacturing Company, Auburn Hills, Michigan) using the 20.32 cm diameter x 6.35 cm wide (8" diameter x 2.5" wide ), resin bond diamond wheels of Example 1 and Comparative Example A.
  • the PDCs were mounted in a spring-loaded fixture to hold them during the grinding process.
  • the grinding wheel speed was about 4000 SFPM and the regulating wheel speed was about 55 SFPM and the helix angle of the regulating wheel was set to about 3 degrees. This provided a grinding contact time of about 5.5 seconds per load of PDC.
  • Comparative Example 1A is a prior art resin bonded grinding wheel sold by 3M having part number MMMRBDW26435-R. Comparative Examples 2A and 3A utilized non-agglomerated resin bond diamonds, which were too friable and sheared off on the outer surface of the grinding wheels when grinding PDC leading to excessive glazing and poor cut. Comparative Example 4A used the same diamond concentration of Comparative Example 1A of approximately 125 and a brittle soft filler particles instead of ductile soft filler particles. The need for dressing was reduced, but not significantly. Comparative Example 6A used the same 125 diamond concentration but the fine grade diamonds were replaced with courser grades. No significant performance difference was noted. Example 1 (185), Example 7 (225), Example 9 (200), and Example 10 (200) used significantly higher diamond concentrations with a mixture of hard and soft filler particles as described above. During test grinding on PDC, the need for dressing was significantly reduced.
  • the cut rate of the inventive grinding wheel was significantly greater than that of the comparative grinding wheel when dressing was employed every pass (0.0442 cm3 versus 0.0377 cm3 (0.0027 cubic inches versus 0.0023 cubic inches)), and the inventive wheel had a good level of cut rate when dressing was employed only every 10 th pass (0.021 cm3 versus 0.0131 cm3 (0.0013 cubic inches versus 0.0008 cubic inches).
  • the cut rate of the inventive wheel with only every 10 th path dressing was approximately 48% of the single pass cut rate versus approximately 35% for the comparative wheel 1A.
  • Example 1 was evaluated at a customer who produces PDC's using centerless grinding.
  • the centerless grinding application reduced the outside diameter of the PDC's to the final required diameter/tolerance and was conducted under a coolant flood.
  • the existing grinding wheel that was previously used by the customer required frequent or substantially continuous abrasive media dressing to maintain stock removal with the existing diamond abrasive grinding wheel.
  • the Example 1 grinding wheel was installed on the centerless grinder, the PDC's were processed using the same previous grinding conditions of the prior existing diamond abrasive grinding wheel. No external abrasive dressing media was used on the Example 1 grinding wheel during the centerless grinding of the PDC's.
  • the centerless grinding operations were able to continue to produce PDC's to the required finished size using the existing process parameters while achieving the same production rates without the use of abrasive wheel dressing or conditioning media on the surface of the Example 1 grinding wheel during the production of the PDC's.
  • the total absence of dressing media while grinding PDC's had not been previously possible under the existing process conditions for any prior grinding wheel used.
  • the Example 1 grinding wheels were fully consumed to the core while grinding the PDC's and did not become glazed over or inoperative at any point in the grinding process.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Description

    BACKGROUND
  • Polycrystalline diamond compacts (PDC) include a polycrystalline diamond layer bonded to a tungsten carbide substrate. The polycrystalline diamond layer provides high hardness and abrasion resistance, while the tungsten carbide layer improves the toughness of the composite. PDC's are often employed as the cutting tips for boring bits used to drill into the earth for natural resources.
  • Resin bond grinding wheels with diamond abrasive particles can be used to grind and finish PDC to its final specified dimensions. PDC is extremely difficult to grind because of the interface of the two dissimilar hardness materials. Because of the extreme hardness of the polycrystalline diamond layer, the diamond abrasive in the resin bonded grinding wheel dulls very quickly. In addition, the tungsten carbide substrate loads the grinding wheel reducing the ability of the abrasive wheel to further grind the polycrystalline diamond layer. As a result, the resin bonded grinding wheel must be constantly dressed with a carborundum stone to reduce or eliminate the tungsten carbide loading of the grinding wheel and to expose fresh diamond cutting points.
  • Document US 2011/056141 discloses a method for grinding a PCD compact according to the preamble of claim 1.
  • Document US 4 907 376 discloses an abrasive article according to the preamble of claim 6.
  • SUMMARY
  • To improve the grinding of PDC with resin bonded grinding wheels, it is desirable to reduce or eliminate the need to constantly dress the resin bonded grinding wheel with a carborundum stone. Reducing or eliminating the need to dress the resin bonded grinding wheel, while still achieving an acceptable cut rate on the polycrystalline diamond layer of PDC, improves the safety and efficiency of the grinding operation. A grinding wheel operator can run more than one grinding machine if the resin bonded grinding wheel does not require constant dressing while finish grinding a PDC.
  • Hence, in one aspect, the invention resides in a method of grinding according to claim 1.
  • In another aspect, the invention resides in an abrasive article according to claim 6.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • Repeated use of reference characters in the specification and drawings is intended to represent the same or analogous features or elements of the disclosure.
    • FIG. 1 shows a centerless grinding process with a resin bonded grinding wheel operating to grind a PDC to its final diameter.
    • FIG. 2 shows the grinding results for the inventive resin bonded grinding wheel versus the comparative resin bonded grinding wheel with different dressing frequency.
    DETAILED DESCRIPTION
  • Referring to FIG. 1 a centerless grinder 10 is illustrated. The centerless grinder includes a resin bonded grinding wheel 12, a regulating wheel 14, and a support 16 for holding a PDC 18 between the two wheels. The PDC includes a polycrystalline diamond layer 20 bonded to a tungsten carbide substrate 22. The speed at which the PDC will traverse through the grinding interface between the two wheels is controlled by the helix angle α between the axis of the resin bonded grinding wheel 12 and the axis of the regulating wheel 14 in combination with the rotational speed of the regulating wheel. Prior art resin bonded grinding wheels require constant dressing of the outer surface 26 with a carborundum stone to maintain the ability of the resin bonded grinding wheel to grind the polycrystalline diamond layer.
  • In order to reduce or eliminate dressing of the outer surface while grinding PDC, it is desirable to make the resin bonded grinding wheel behave similar to a vitrified bonded grinding wheel. Such an effect can be achieved by using a very high diamond concentration while including both hard filler particles and soft filler particles to control the breakdown rate of the resin bonded abrasive wheel. Such a resin bonded grinding wheel will ensure the exposure of fresh diamonds particles in the wheel while reducing or eliminating glazing of the outer surface during use. The high concentration diamond portion can be an outer annulus of the grinding wheel, a segmented portion thereof, or the entire grinding wheel.
  • Suitable diamonds for use in the abrasive wheel include, for example, natural diamond, synthetic diamond, resin bond diamonds, metal bond diamonds, diamond abrasive powder, resin bonded or vitrified bonded diamond agglomerates of the foregoing, and combinations of all of the foregoing. To achieve the necessary hardness of the resin bonded abrasive wheel, the diamond concentration is very high. In particular, the diamond concentration based on the total volume of the high concentration diamond portion of the grinding wheel is from 175 to 225 or from 180 to 200. Diamond concentrations less than 175 do not reduce the need for dressing and concentrations greater than 225 become difficult to bond with sufficient integrity. The diamonds may be coated or uncoated with a metal such as nickel or copper. If metal coated diamonds are used, the coating weight percent should be less than 40%, or less than or equal to 30%. Excessive coating amounts reduces the diamond concentration to too low of a level and does not result in reduced dressing of the resin bonded grinding wheel during use. The size of the diamonds, if not agglomerated, should be between 60/80 mesh size to 200/230 mesh size. Ranges above and below these limits do not provide the requisite packing density to achieve the desired diamond concentration.
  • While resin bond diamonds may be suitable, especially if agglomerated, the diamonds are preferred to be metal bond diamonds. Resin bond diamonds are generally too weak and friable to be used in a resin bonded grinding wheel to grind PDC. Metal bond diamonds are available in strengths from friable (weaker) to less friable (stronger). Such strength rating is qualified by various suppliers using different designations. In order to expose fresh diamonds more effectively, weaker metal bond diamonds are preferred. For example, if using diamonds from ABC Superabrasives, the strength is rated on a scale from ABS 2 (weak) to ABS 9 (strong). When using ABC Superabrasive diamonds, the diamonds are desirably ABS 2 or ABS 3. From Worldwide Superabrasives strength ratings from WSG 200 to WSG 900 are available. Suitable strength diamonds can include WSG 200, WSG300, WSG400, and WSG500. LANDS Superabrasives has strengths designated as LS200, LS230, LS250, LS260, LS270, and LS290. Suitable strength diamonds can include LS200, LS230, and LS240. In general, the bottom 50% of the strength scale for a given supplier's metal bond diamonds are suitable.
  • Suitable resin binders for use with the diamond abrasive particles include formaldehyde-containing resins, such as phenol formaldehyde, novolac phenolics and especially those with added crosslinking agent (e.g., hexamethylenetetramine), phenoplasts, and aminoplasts; unsaturated polyester resins; vinyl ester resins; alkyd resins, allyl resins; furan resins; epoxies; polyurethanes; cyanate esters; and polyimides. The amount of binder resin used in the resin bonded grinding wheel is from about 30% to about 40% by volume such as approximately 35% by volume of the high concentration diamond portion. In general, the amount of resin should be sufficient to fully wet the surfaces of all the individual particles during manufacturing such that a continuous resin structure, substantially devoid of porosity, is formed with the inorganic components discretely bonded throughout, which comprises the mechanical structure of the grinding wheel.
  • Suitable filler additives can include reinforcing particles, grinding aids, dessicants, colorants, and lubricants. As mentioned, both hard and soft filler particles are used in addition to the diamonds to reinforce and control the breakdown rate of the grinding wheel. Hard filler particles (excluding diamonds) are those having a Mohs hardness of 7 or greater. Suitable hard filler particles include aluminum oxide, silicon carbide, zirconia, ceramic alpha alumina particles typically derived from boehmite sol gels, or other abrasive particles having the requisite Mohs hardness. Soft filler particles have a Mohs hardness of 5 or less. Suitable soft fillers include petroleum coke, pyrophyllite, cryolite, lime, graphite, refractory grog, ball clay, copper, or talc. The volume ratio of the hard to soft filler particles is from 15:85 to 85:15, or from 30:70 to 70:30, or from 40:60 to 60:40. Suitable hard filler particle sizes include sizes equal to or less than about 30 microns, such as 600, 800, or 1000 ANSI mesh equivalents. Suitable soft filler particles sizes include 100 mesh or finer. The soft particles can have a fine fraction and coarse fraction if desired. The fine fraction can be finer than 280 mesh and the coarse fraction can be from 100 to 180 mesh. If two sizes of soft filler particles are used the volume fraction of the coarse to fine particles can be 50:50 to 70:30. Too large a volume fraction of hard filler particles impedes breakdown leading to heat buildup and glazing of the grinding wheel, and too large a volume fraction of soft filler particles undesirably increase the wear rate of the grinding wheel. The volume percent of a mixture of hard filler particles and soft filler particles used in the resin bonded grinding wheel is from 8% to 20% of the high concentration diamond portion.
  • Other fillers can include fibrous and plate-like materials such as carbon or glass whiskers and mica. Grinding aids such as cryolite, potassium tetrafluoroborate (KBF4), polyvinyl chloride, lignosulfonates, and blends thereof. Colorants such as organic or inorganic pigments or dies may be incorporated into the grinding wheel.
  • EXAMPLES
  • Objects and advantages of this disclosure are further illustrated by the following non-limiting examples. The particular materials and amounts thereof recited in these examples as well as other conditions and details, should not be construed to unduly limit this disclosure. Unless otherwise noted, all parts, percentages, ratios, etc. in the Examples are by weight.
  • The following materials were used to prepare the inventive and comparative grinding wheels. Table 1: Components
    Symbol Description
    NP1 Phenolic Resin Powder from Hexion Speciality Chemicals Inc., Augusta, GA as Durite® AD-3237
    NP2 Phenolic Resin Powder from Hexion Speciality Chemicals Inc., Augusta, GA as Durite® AD-5575
    NP3 Phenolic Resin Powder from Hexion Speciality Chemicals Inc., Augusta, GA as Durite® AD-3235
    SC 1000 grit Green Silicon Carbide from Washington Mills Electro Minerals Corp., Niagara Falls, NY as "CGW-3" Green Silicon Carbide, Wheel Grade, Grade 1000
    BC Boron Carbide, Grade 1000 from Electro Abrasives Corporation, Buffalo, NY as Electrobor B4C grade 1000
    CU Untreated Copper Powder from ACuPowder International LCC, Union, NJ as Copper Powder EL-100 untreated
    MO Magnesium Oxide from Atlantic Equipment Engineers, Bergenfield, NJ as Magnesium Oxide MG-601
    PC 1 Calcined Petroleum Coke from Asbury Graphite Mills Inc., Asbury, NJ as Calcined Petroleum Coke (4082)
    PC2 Calcined Petroleum Coke from Asbury Graphite Mills Inc., Asbury, NJ as Calcined Petroleum Coke (4372)
    CO Calcium Oxide from Mississippi Lime, Alton, IL as Polycal OF325 Calcium Oxide
    321 Ceramic abrasive from 3M Company, St. Paul, MN as 321 Cubitron JIS800
    321B Ceramic abrasive from 3M Company, St. Paul, MN as 321 Cubitron JB800
    D1 Metal Bond Synthetic Diamond Powder, 30% Nickel Coated, 100/120 mesh from WorldWide Superabrasives, Ft. Lauderdale, FL as MB-100 N30 100/120
    D2 Metal Bond Synthetic Diamond Powder, 30% Nickel Coated, 140/170 mesh from WorldWide Superabrasives, Ft. Lauderdale, FL as MB-100 N30 140/170
    D3 LSMB0 Synthetic Metal Bond Diamond Powder, Uncoated, 200/230 mesh from LANDS Superabrasives Co., New York, NY
    D4 LSMB0 Synthetic Metal Bond Diamond Powder, Uncoated, 325/400 mesh from LANDS Superabrasives Co., New York, NY
    D5 LS-MA0 Synthetic Metal Bond Diamond Powder, Uncoated, 100/120 mesh from LANDS Superabrasives Co., New York, NY
    D6 LS-MA0 Synthetic Metal Bond Diamond Powder, Uncoated, 120/140 mesh from LANDS Superabrasives Co., New York, NY
    D7 LS-MA0 Synthetic Metal Bond Diamond Powder, Uncoated, 140/170 mesh from LANDS Superabrasives Co., New York, NY
    D8 Resin Bond Synthetic Diamond Powder, Uncoated, 140/170 mesh from WorldWide Superabrasives, Ft. Lauderdale, FL as RB-150 140/170
    D9 Resin Bond Synthetic Diamond Powder, 50% Copper Coated, 120/140 mesh from WorldWide Superabrasives, Ft. Lauderdale, FL as RB-150 C50 120/140
    NP4 Resin Powder from Bitrez Ltd., Standish Wigan, Lancashire, United Kingdom as Dialok AR939P Resin Powder
    CK Synthetic Cryolite from Washington Mills, Tonawanda, NY as SODIUM HEXAFLUOROALUMINATE, CRYOLITE K
    D10 Resin Bond Synthetic Diamond Powder, 30% Nickel Coated, 140/170 mesh from WorldWide Superabrasives, Ft. Lauderdale, FL as RB-150 N30 140/170
    D11 Resin Bond Synthetic Diamond Powder, 56% Nickel Coated, 100/120 mesh from WorldWide Superabrasives, Ft. Lauderdale, FL as RB-150 N56 100/120
    G Graphite/Carbon 4539 Powder from Asbury Graphite Mills Inc., Asbury, NJ
    D12 Metal Bond Synthetic Diamond Powder, 30% Nickel Coated, 60/80 mesh from WorldWide Superabrasives, Ft. Lauderdale, FL as MB-100 N30 60/80
    D13 Metal Bond Synthetic Diamond Powder, 30% Nickel Coated, 80/100 mesh from WorldWide Superabrasives, Ft. Lauderdale, FL as MB-100 N30 80/100
    D14 LSMB0 Synthetic Metal Bond Diamond Powder, Uncoated, 60/80 mesh from LANDS Superabrasives Co., New York, NY
    D15 LSMB0 Synthetic Metal Bond Diamond Powder, Uncoated, 80/100 mesh from LANDS Superabrasives Co., New York, NY
    D16 LSMB0 Synthetic Metal Bond Diamond Powder, Uncoated, 100/120 mesh from LANDS Superabrasives Co., New York, NY
    D17 LS-MA0 Synthetic Metal Bond Diamond Powder, Uncoated, 80/100 mesh from LANDS Superabrasives Co., New York, NY
    D18 LS00 Synthetic Metal Bond Diamond Powder, Uncoated, 200/230 mesh from LANDS Superabrasive Co., New York, NY
  • The grinding wheels of Examples 1, 7, 9 to 14 and Comparative Examples 1A to 6A were prepared and tested to evaluate their grinding performance on PDC. Examples 1 and Comparative Example 1A were evaluated under different grinding wheel dressing procedures. The weight percentage compositions of the various grinding wheels are shown in Table 2.
  • General Procedure for Forming Grinding Wheel Section
  • Each composition listed in Table 2 was thoroughly mixed for 4 hours in a 1000 ml polyethylene mixing jar and a roller mill stand (2-Bar Tumbler Base, C&M Topline Inc., Goleta CA) set at approximately 18.85 rad/s (180 rpm). The abrasive wheels were direct-pressed onto preformed phenolic cores to yield type 1A1 abrasive wheel sections 20.32 cm OD x 3.18 cm TK x 3.18 cm ID (8" OD x 1.25" TK x 1.25" ID), with diamond depth x = 0.375. The die cavity in the five-piece, ring-punch double-compaction steel mold was filled with the mixed abrasive composition by rotating the die assembly on a circular table while pouring the abrasive powder mixture into the annular cavity around the core. The powder was then smoothed and leveled with a plastic straightedge tool, and the filled mold was closed with the upper ring punch.
  • The filled mold was placed in a 200-ton heated-platen hydraulic press with the platen set point temperature set at 177 °C (350 degrees F).
  • The press platens were closed to bring the ring-punch surfaces flush against the mold shell. A magnetic thermometer was attached to the side of the mold shell and the mold temperature was monitored. When the mold shell reached 177 °C ( 350 degree F), the mold was held closed under pressure for 20 minutes.
  • After 20 minutes at 177 °C(350 degree F), the mold assembly was removed from the heated-platen press and placed on a water-cooled steel table and allowed to cool to room temperature. The mold shell was stripped from the formed wheel section using a 50-ton hydraulic press and steel spacers. The formed wheel sections were cured in air according the following schedule. One hour ramp to 66 °C (150 degree F), one hour soak at 66 °C (150 degree F), 4 hour ramp to 177 °C (350 degree F), seven hour soak at 177 °C (350 degree F), followed by 3 hour cool to room temperature.
  • The wheel sections were surface ground to thickness and then two sections were bonded together using epoxy adhesive. The bonded structure was then trued and dressed using a 40/60 grit SiC grinding wheel on a 3M E228 truing and dressing machine to make the final test grinding wheels Table 2: Grinding Wheel Compositions
    Percent by Weight
    Component Example 1 Comp. Example 1A Comp. Example 2A Comp. Example 3A Comp. Example 4A Comp. Example 6A Example 7 Example 9 Example 10 Example 11 Example 12 Example 13 Example 14
    NP1 0 19.5
    NP2 8.4 0 19.4 18.4 16.5 18.2 8.4 8.3 16.2 16.3
    NP3 8.4 0 8.4 8.3
    SC 0 10.6 14.6 11.1
    BC 0 1.7 5.0
    Cu 0 18.5
    MO 0 1.5
    PC1 3.9 0 4.5 4.3 2.1 3.5 3.9 3.8 3.8
    PC2 3.9 0 3.9 1.9
    CO 0.7 0 0.6 1.1 0.9 0.7 0.6 0.5 0.7 0.7 0.7 0.7
    321 12.2 0 14.0 13.3 7.7 11.3 12.2 8.0
    321B 8.0 19.5 11.8
    D1 0 34.5 38.8 16.5 21
    D2 0 8.1 9.1
    D3 0 2.8 3.2
    D4 0 2.8 3.2
    D5 23.6 0 25.2 23.5 20.4 20.0
    D6 23.6 0 25.2 23.5 20.4 20.0 20.2
    D7 15.3 0 23.5
    D8 11.6
    D9 48.7
    NP4 14.1 12.1 16.1
    CK 10.4 6.9 6.5 5.8
    D10 13.5
    D11 55.3
    G 6.9
    D12 16.5 21
    D13 23.8 41.4
    D14 18.8
    D15 33.9
    D16 20.4
    D17 16.6
    D18 20.2 19.8 20.0
  • Cylindrical diamond cutter inserts (PDCs), obtained from US Synthetic Corporation, Orem, Utah, were ground using a centerless grinder (Acme Model 47 Centerless Grinder, Acme Manufacturing Company, Auburn Hills, Michigan) using the 20.32 cm diameter x 6.35 cm wide (8" diameter x 2.5" wide ), resin bond diamond wheels of Example 1 and Comparative Example A. The PDCs were mounted in a spring-loaded fixture to hold them during the grinding process. The grinding wheel speed was about 4000 SFPM and the regulating wheel speed was about 55 SFPM and the helix angle of the regulating wheel was set to about 3 degrees. This provided a grinding contact time of about 5.5 seconds per load of PDC. A coolant flood of 5% "Shell Metalina Y-850" (Shell Lubricants, Houston, Texas) in water was used. Depending on the size of the PDCs, testing was performed using either 2 PDCs per load or 3 PDCs per load as noted below:
    Test Format PDC Diameter Diamond Depth per PDC Carbide Depth per PDC
    2 PDCs Nominal 0.63" 0.085" 0.4365"
    3 PDCs Nominal 0.63" 0.062" 0.257"
  • Testing was performed with Comparative Example 1A that verified the 2 PDC format gave a similar polycrystalline diamond volume removal rate as the 3 PDC format. The motor load during grinding was controlled to about 2.5 - 3.1 amps over the idle load via in feed control of the regulating wheel. Test grinding wheels were dressed after every pass for the high frequency dressing test. For the low frequency dressing test, each grinding wheel was dressed after every 10th pass. Dressing was accomplished by manually contacting a 220 grit, 2.54 cm x 2.54 cm x 15.24 cm (1" x 1" x 6" ) white dressing stick ("3M Dressing Stick 200TH", 3M Company, St. Paul, Minnesota) with the wheel and traversing it across the wheel a total of 6 passes.
  • Comparative Example 1A is a prior art resin bonded grinding wheel sold by 3M having part number MMMRBDW26435-R. Comparative Examples 2A and 3A utilized non-agglomerated resin bond diamonds, which were too friable and sheared off on the outer surface of the grinding wheels when grinding PDC leading to excessive glazing and poor cut. Comparative Example 4A used the same diamond concentration of Comparative Example 1A of approximately 125 and a brittle soft filler particles instead of ductile soft filler particles. The need for dressing was reduced, but not significantly. Comparative Example 6A used the same 125 diamond concentration but the fine grade diamonds were replaced with courser grades. No significant performance difference was noted. Example 1 (185), Example 7 (225), Example 9 (200), and Example 10 (200) used significantly higher diamond concentrations with a mixture of hard and soft filler particles as described above. During test grinding on PDC, the need for dressing was significantly reduced.
  • Referring now to FIG. 2, the cut rate of the inventive grinding wheel was significantly greater than that of the comparative grinding wheel when dressing was employed every pass (0.0442 cm3 versus 0.0377 cm3 (0.0027 cubic inches versus 0.0023 cubic inches)), and the inventive wheel had a good level of cut rate when dressing was employed only every 10th pass (0.021 cm3 versus 0.0131 cm3 (0.0013 cubic inches versus 0.0008 cubic inches).
  • The cut rate of the inventive wheel with only every 10th path dressing was approximately 48% of the single pass cut rate versus approximately 35% for the comparative wheel 1A.
  • Example 1 was evaluated at a customer who produces PDC's using centerless grinding. The centerless grinding application reduced the outside diameter of the PDC's to the final required diameter/tolerance and was conducted under a coolant flood. The existing grinding wheel that was previously used by the customer required frequent or substantially continuous abrasive media dressing to maintain stock removal with the existing diamond abrasive grinding wheel. When the Example 1 grinding wheel was installed on the centerless grinder, the PDC's were processed using the same previous grinding conditions of the prior existing diamond abrasive grinding wheel. No external abrasive dressing media was used on the Example 1 grinding wheel during the centerless grinding of the PDC's. The centerless grinding operations were able to continue to produce PDC's to the required finished size using the existing process parameters while achieving the same production rates without the use of abrasive wheel dressing or conditioning media on the surface of the Example 1 grinding wheel during the production of the PDC's. The total absence of dressing media while grinding PDC's had not been previously possible under the existing process conditions for any prior grinding wheel used. Furthermore, the Example 1 grinding wheels were fully consumed to the core while grinding the PDC's and did not become glazed over or inoperative at any point in the grinding process.
  • Other modifications and variations to the present disclosure may be practiced by those of ordinary skill in the art, without departing from the scope of the present disclosure, which is defined in the appended claims.

Claims (10)

  1. A method of grinding comprising:
    contacting a polycrystalline diamond compact with a grinding wheel; the method being characterised in that
    the grinding wheel comprising a high concentration diamond portion having diamonds, a resin binder, and a mixture of hard filler particles and soft filler particles;
    wherein the high concentration diamond portion has a diamond concentration from 175 to 225 based on the volume of the high concentration diamond portion, the resin binder comprises 30 percent to 40 percent based on the volume of the high concentration diamond portion, a ratio of hard filler particles to soft filler particles in the mixture is from 85:15 to 15:85, and the mixture of hard filler particles and soft filler particles comprises 8 percent to 20 percent based on the volume of the high concentration diamond portion.
  2. The method of claim 1 wherein the ratio of hard filler particles to soft filler particles in the mixture is from 70:30 to 30:70.
  3. The method of claim 1 wherein the diamonds comprise metal bond diamonds.
  4. The method of claim 2 wherein the hard filler particles comprise ceramic alpha alumina and the soft filler particles comprise petroleum coke.
  5. The method of any of claims 1 to 4, wherein the high concentration diamond portion is an outer annulus of the grinding wheel, a segmented portion thereof or the entire grinding wheel.
  6. An abrasive article comprising:
    a grinding wheel, the grinding wheel comprising a high concentration diamond portion having diamonds, a resin binder, and a mixture of hard filler particles and soft filler particles;
    being characterised in that
    the high concentration diamond portion has a diamond concentration from 175 to 225 based on the volume of the high concentration diamond portion, the resin binder comprises 30 percent to 40 percent based on the volume of the high concentration diamond portion, a ratio of hard filler particles to soft filler particles in the mixture is from 85:15 to 15:85, and the mixture of hard filler particles and soft filler particles comprises 8 percent to 20 percent based on the volume of the high concentration diamond portion.
  7. The abrasive article of claim 6 wherein the ratio of hard filler particles to soft filler particles in the mixture is from 70:30 to 30:70.
  8. The abrasive article of claim 6 wherein the diamonds comprise metal bond diamonds.
  9. The abrasive article of claim 6 wherein the hard filler particles comprise ceramic alpha alumina and the soft filler particles comprise petroleum coke.
  10. The abrasive article of any of claims 6 to 9, wherein the high concentration diamond portion is an outer annulus of the grinding wheel, a segmented portion thereof or the entire grinding wheel.
EP12774388.8A 2011-04-18 2012-04-17 Resin bonded grinding wheel Active EP2699387B1 (en)

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RU2567165C2 (en) 2015-11-10
BR112013026817A2 (en) 2017-01-10
CA2833342A1 (en) 2012-10-26
WO2012145284A3 (en) 2012-12-27
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US20140057534A1 (en) 2014-02-27
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RU2013146357A (en) 2015-05-27
CA2833342C (en) 2020-05-12

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