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EP2447033A1 - Procédé de fabrication de récipients en plastique et/ou de moules en plastique - Google Patents

Procédé de fabrication de récipients en plastique et/ou de moules en plastique Download PDF

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Publication number
EP2447033A1
EP2447033A1 EP20110174139 EP11174139A EP2447033A1 EP 2447033 A1 EP2447033 A1 EP 2447033A1 EP 20110174139 EP20110174139 EP 20110174139 EP 11174139 A EP11174139 A EP 11174139A EP 2447033 A1 EP2447033 A1 EP 2447033A1
Authority
EP
European Patent Office
Prior art keywords
plastic
heated
recyclate
heat
plastic material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP20110174139
Other languages
German (de)
English (en)
Other versions
EP2447033B1 (fr
Inventor
Jochen FORSTHÖVEL
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Krones AG
Original Assignee
Krones AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Krones AG filed Critical Krones AG
Priority to SI201131192A priority Critical patent/SI2447033T1/sl
Publication of EP2447033A1 publication Critical patent/EP2447033A1/fr
Application granted granted Critical
Publication of EP2447033B1 publication Critical patent/EP2447033B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B13/00—Conditioning or physical treatment of the material to be shaped
    • B29B13/02—Conditioning or physical treatment of the material to be shaped by heating
    • B29B13/021—Heat treatment of powders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B13/00—Conditioning or physical treatment of the material to be shaped
    • B29B13/06—Conditioning or physical treatment of the material to be shaped by drying
    • B29B13/065—Conditioning or physical treatment of the material to be shaped by drying of powder or pellets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/18—Feeding the material into the injection moulding apparatus, i.e. feeding the non-plastified material into the injection unit
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/72—Heating or cooling
    • B29C2045/7292—Recovering waste heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0084—General arrangement or lay-out of plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/065—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts containing impurities
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/25—Solid
    • B29K2105/251—Particles, powder or granules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/25—Solid
    • B29K2105/253—Preform
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/26—Scrap or recycled material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Definitions

  • the invention relates to a method for producing plastic containers and / or plastic preforms with an injection molding machine.
  • Plastic containers such as plastic bottles, are often used as containers for liquid products, such as drinks.
  • the production of plastic containers can be done directly in an injection molding machine using thermoplastic material.
  • Another known method for producing the plastic containers comprises first producing plastic preforms in an injection molding machine. These plastic preforms are then formed in a blow molding machine to the desired plastic containers. For this, the plastic preforms are thermally conditioned and then shaped in so-called blow molding under compressed air to containers.
  • plastic recyclate For the production of the containers and / or the preforms in the injection molding machine not only new plastic granulate is often used, but also recycled (recycled) plastic material, so-called plastic recyclate.
  • the plastic recyclate can be obtained, for example, from already used plastic containers that have been recycled by the consumer. It is necessary to crush the old container and to free the resulting plastic flakes of impurities and decontaminate.
  • a disadvantage of the known methods is that both in the recycling process as well as in the manufacturing process many process steps must be carried out at high temperatures and therefore require an energy-consuming heating of the plastic material.
  • the object of the present invention is to provide a more energy-efficient method for producing plastic containers and / or plastic preforms. This object is achieved by a method according to claim 1.
  • At least part of the heat of the heated plastic recyclate can be dissipated and supplied to the plastic material.
  • the plastic containers to be produced may in particular comprise a thermoplastic, for example PET (polyethylene terephthalate).
  • PET polyethylene terephthalate
  • the plastic container may in particular be a plastic bottle, for example a PET bottle.
  • a plastic preform or Kunststoffpreform can be designed such that it can be formed in a blow molding process by applying compressed air in a blow mold to a plastic container, such as a plastic bottle.
  • a stretching of the preform can also be carried out in the blow mold by means of a stretching rod.
  • a plastic recyclate can be understood here in particular to be a recycled plastic material.
  • the recycled plastic material can in particular be produced from recycled plastic containers that have been recycled by consumers. For this purpose, the recycled plastic bottles can be first crushed. In this case, so-called. Plastic flakes, ie 5 to 20 mm large pieces of plastic can be formed. These plastic flakes can subsequently be freed of foreign bodies and cleaned.
  • providing the plastic recyclate may include shredding recycled plastic containers into plastic flakes.
  • Kunststoffneumaterials herein can be understood in particular plastic material that was not obtained in a recycling process of recycled plastic containers.
  • the Kunststoffneumaterial may be present for example in the form of plastic granules.
  • the heating of the plastic recyclate may in particular be part of the recycling process.
  • the plastic recyclate may be heated to a temperature above that required for introduction and / or processing in the injection molding machine, wherein at least a portion of the amount of heat above the temperature required for introduction and / or processing in the injection molding machine is used to heat the plastic material becomes.
  • the temperature required for introduction and / or processing in the injection molding machine can be between 140 ° C and 180 ° C, in particular 160 ° C.
  • the plastic recyclate can be heated in such a way that the plastic recyclate is at least partially decontaminated by the heating.
  • the plastic recyclate can be heated in particular to temperatures above the temperature required for introduction into and / or processing in the injection molding machine, in particular above 180 ° C.
  • heating the plastic recyclate may correspond to decontaminating the plastic recyclate, especially at a temperature above 180 ° C.
  • the heating of the plastic recyclate may also comprise a solid-phase condensation (SSP) at temperatures above 180 ° C., whereby a solid phase condensation may also be understood to mean the increase in the IV value (intrinsic viscosity).
  • SSP solid-phase condensation
  • decontamination can be understood to mean, in particular, removal of impurities and / or undesired substances from the plastic recyclate. In other words, contaminants should be removed from the plastic recyclate.
  • the Kunststoffneumaterial can be heated to a temperature between 140 ° C and 180 ° C, in particular to 160 ° C.
  • a drying of the plastic material can be achieved, on the other hand so that the plastic material can be brought to the temperature required for introduction into and / or processing in the injection molding machine.
  • the heat transport medium may in particular comprise dry air and / or an inert gas or be dry air and / or an inert gas.
  • the inert gas may be, for example, nitrogen and / or a noble gas, for example helium.
  • the heat transport medium can be passed directly and / or indirectly past the heated plastic recyclate and / or the plastic material.
  • the heat transport medium can come into direct contact with the heated plastic recyclate and / or the plastic material.
  • a direct heat exchange between the heated plastic recyclate and / or the plastic material and the heat transfer medium can be achieved.
  • the heat transport medium can be guided indirectly past the heated plastic recyclate and / or the plastic material.
  • the heat transport medium can be guided past the heated plastic recyclate and / or from the plastic material, for example in a conduit.
  • the region in which the heat transport medium is conducted past the heated plastic recyclate and / or plastic material can be separated from the region in which the heated plastic recyclate and / or the plastic material are arranged by a heat-conducting or heat-permeable wall.
  • the heat-permeable wall may comprise a heat-conducting material, for example a metal, in particular stainless steel.
  • the heat-permeable wall may be formed such that the heat-transporting means can be heated by the heated plastic recyclate or that the plastic material can be heated by the heated heat-transporting means.
  • the heat transfer medium can be passed in countercurrent to the heated plastic recyclate and / or the plastic material.
  • the relative speed of the heat transport medium to the heated plastic recyclate and / or the plastic material can be increased and the heat exchange can be improved.
  • heating the plastic material may include placing the heated plastic recyclate and the plastic material in two at least partially joined by a heat-permeable wall Containers.
  • the heated plastic recyclate may be disposed in a first container and the plastic material in a second container, wherein the first container and the second container are at least partially connected by a heat-permeable wall.
  • a heat-permeable or heat-conducting wall may be understood herein to mean, in particular, a container wall which comprises or consists of a heat-conducting material.
  • the thermal conductivity of the heat-permeable wall, in particular of the heat-conducting material may be at least 15 W / (K ⁇ m), in particular at least 40 W / (K ⁇ m). According to a preferred embodiment, the thermal conductivity may be at least 300 W / (K m).
  • the container or reservoir for the plastic material may be at least partially disposed inside the container or reservoir for the heated plastic recyclate.
  • the container for the heated plastic recyclate and / or the container for the plastic material may each be designed as a downpipe, in particular as concentric downpipes.
  • arranging the heated plastic recyclate and the plastic material in two containers connected by a heat-permeable wall may include or correspond to introducing the plastic recyclate and / or the plastic material into the respective drop tube.
  • the method according to the invention can also comprise producing, in particular injection molding, at least one plastic container and / or at least one plastic preform in the injection molding machine using the heated plastic recyclate and the heated plastic material.
  • at least one plastic container and / or at least one plastic preform can be injection-molded from the heated plastic recyclate and the heated plastic material.
  • the device can be designed in particular for carrying out a method mentioned above.
  • the plastic recyclate, the plastic material, the plastic containers and / or the plastic preforms may in particular have one or more of the above-mentioned features.
  • the apparatus may in particular comprise a device for transporting a heat transport means, which is designed in such a way that the heat transfer medium is conducted past the heated plastic recyclate for heating the heat transfer medium, and the heated heat transfer medium is conducted past the plastic material.
  • a heat transfer from the heated plastic recyclate to the plastic material can be achieved.
  • the apparatus may further comprise a container or reservoir for the heated plastic recyclate and a reservoir or reservoir for the plastic material, the containers being at least partially connected by a heat-permeable wall.
  • the container for the heated plastic recyclate, the container for the plastic material and / or the heat-permeable wall can in particular have one or more of the above-mentioned features.
  • the container for the plastic material can be arranged at least partially inside the container for the heated plastic recyclate.
  • the device may in particular correspond to a block machine comprising a recycling plant and an injection molding machine.
  • plastics recycling process it is necessary to decontaminate plastic recyclate obtained from used plastic containers at high temperatures, in particular at more than 180 ° C., or to lengthen the molecular chains (solid-phase condensation, SSP). These temperatures are usually above the level required for introduction into the injection molding machine or for processing in the injection molding machine.
  • FIG. 1 illustrates an exemplary method of manufacturing plastic containers and / or plastic preforms with an injection molding machine.
  • the injection molding machine itself is in the FIG. 1 not shown.
  • plastic recyclate and, on the other hand, plastic material are used.
  • recycled plastic material is first crushed into flakes. These are then cleaned and heated to a temperature above 180 ° C for decontamination / SSP.
  • the Kunststoffneumaterial is initially usually at room temperature, ie at about 20 ° C. For drying and for introduction into the injection molding machine this Kunststoffneumaterial must be heated.
  • the heating of the plastic material is performed using at least a portion of the amount of heat contained in the heated plastic recyclate.
  • the excess temperature of the plastic recyclate achieved by decontaminating the plastic recyclate may be used to heat the plastic material. This also has the advantage that the plastic recyclate is thereby cooled and thus the risk of thermal and hydrolytic damage to the plastic recyclate is reduced.
  • the heated plastic recyclate is first provided in a first container 1.
  • the plastic material is provided in a second container 2, which further comprises a drying hopper 3.
  • the first container 1 and the second container 1 are formed in this example as downpipes.
  • the heated plastic recyclate is introduced into the top of the container 1.
  • the heated plastic recyclate can be removed and fed to an injection molding machine.
  • plastic material can be introduced into the container 2 from above. In the area of the drying hopper 3, it can be removed and forwarded to the injection molding machine.
  • FIG. 1 also shows a dry air dryer 4, which first introduces dry air as a heat transport medium in the first container 1, where it is passed in countercurrent directly to the plastic recyclate. This heats the dry air. The heated dry air is then introduced into the drying hopper 3 and passed up to the Kunststoffneumaterial. The heated dry air can heat the plastic material. The heat transfer medium is then returned to the dry air dryer 4, whereby a dry air cycle is formed.
  • a dry air dryer 4 which first introduces dry air as a heat transport medium in the first container 1, where it is passed in countercurrent directly to the plastic recyclate. This heats the dry air. The heated dry air is then introduced into the drying hopper 3 and passed up to the Kunststoffneumaterial. The heated dry air can heat the plastic material. The heat transfer medium is then returned to the dry air dryer 4, whereby a dry air cycle is formed.
  • the dry air dryer can be designed in this case such that it controls the inlet temperature of the drying hopper 3, in particular additionally supplies the heat that can not be obtained from the plastic recyclate.
  • the heat transport medium may alternatively or in addition to the dry air also include an inert gas, for example helium.
  • the streams of plastic recyclate and plastic material may be separately formed.
  • the plastic recyclate and the plastic material could be fed separately to the injection molding machine.
  • the Kunststoffneumaterial can be heated to a temperature between 140 and 180 ° C. As a result, drying of the plastic material can be achieved and the temperature adjusted for introduction into the injection molding machine.
  • FIG. 1 By a in FIG. 1 As shown, heat from the recycling process can be used. By blocking the recycling plant with the injection molding machine and a lesser logistical effort can be achieved.
  • FIG. 2 illustrates another exemplary process for making plastic containers and / or plastic preforms.
  • a first container 1 for the plastic recyclate and a second container 2 for the plastic material are provided.
  • the second container 2 comprises a drying hopper 3.
  • the first container 1 and the second container 2 are arranged concentrically with each other, wherein the first container 1 at least partially surrounds the second container 2.
  • the partition wall between the first container 1 and the second container 2 is in this case a heat-permeable wall, thus comprising a heat-conducting material, such as stainless steel.
  • the wall can be about 2 to 3 mm thick.
  • the thermal conductivity of the material of the heat-permeable wall may be in particular between 15 and 60 W / (Km). However, it is also conceivable to make the heat-permeable wall of copper, so that the thermal conductivity of about 350 W / (m K) can also be much higher.
  • FIG. 2 also shows a dry air dryer 4. This passes dry air into the drying hopper 3, which is passed on the plastic material and recycled to the dry air dryer 4. The dry air is used in this case to ensure good heat transfer to the heat-permeable wall.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
EP11174139.3A 2010-10-26 2011-07-15 Procédé et dispositiv de fabrication de récipients en plastique et/ou de préformes en plastique Active EP2447033B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SI201131192A SI2447033T1 (sl) 2010-10-26 2011-07-15 Postopek in naprava za izdelavo vsebnikov iz umetne snovi in/ali predoblikovancev iz umetne snovi

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE201010042965 DE102010042965A1 (de) 2010-10-26 2010-10-26 Verfahren zum Herstellen von Kunststoffbehältern und/oder Kunststoffvorformlingen

Publications (2)

Publication Number Publication Date
EP2447033A1 true EP2447033A1 (fr) 2012-05-02
EP2447033B1 EP2447033B1 (fr) 2017-04-19

Family

ID=44512655

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11174139.3A Active EP2447033B1 (fr) 2010-10-26 2011-07-15 Procédé et dispositiv de fabrication de récipients en plastique et/ou de préformes en plastique

Country Status (8)

Country Link
US (1) US8795575B2 (fr)
EP (1) EP2447033B1 (fr)
CN (1) CN102452156B (fr)
BR (1) BRPI1104273B1 (fr)
CA (1) CA2755638A1 (fr)
DE (1) DE102010042965A1 (fr)
MX (1) MX2011011279A (fr)
SI (1) SI2447033T1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017183048A1 (fr) * 2016-04-20 2017-10-26 Suntory Holdings Limited Dispositif de fabrication de préforme
US12257749B2 (en) 2020-09-17 2025-03-25 Husky Injection Molding Systems Ltd. Injection unit with telescopic melt coupling

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Publication number Priority date Publication date Assignee Title
NL2009234C2 (en) * 2012-07-26 2014-02-06 Heineken Supply Chain Bv Tapping assembly and connecting device, as well as a container and method for beverage dispensing.
NL2009235C2 (en) 2012-07-26 2014-01-28 Heineken Supply Chain Bv Container and set of preforms for forming a container.
US9708463B2 (en) 2015-01-14 2017-07-18 International Business Machines Corporation Recyclate verification
JP7478356B2 (ja) * 2020-05-26 2024-05-07 大日本印刷株式会社 樹脂製品製造システムおよび樹脂製品の製造方法

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CN2659663Y (zh) * 2003-12-21 2004-12-01 李希云 注塑机保温取热回收净化装置
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AT506489B1 (de) * 2008-02-14 2010-12-15 Erema Verfahren und vorrichtung zum spritzgiessen von kunststoffmaterial

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US5440005A (en) * 1994-07-08 1995-08-08 Hosokawa Bepex Corporation Process and apparatus for solid phase polymerization of polymers
JP2000280288A (ja) * 1999-03-31 2000-10-10 Kobe Steel Ltd 多層樹脂成形体の製造方法とその製造装置、及び、再生ペットボトルとその製造方法
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BRPI1104273B1 (pt) 2020-05-19
EP2447033B1 (fr) 2017-04-19
SI2447033T1 (sl) 2017-06-30
US20120098159A1 (en) 2012-04-26
MX2011011279A (es) 2012-04-25
BRPI1104273A2 (pt) 2013-02-26
CA2755638A1 (fr) 2012-04-26
DE102010042965A1 (de) 2012-05-10
US8795575B2 (en) 2014-08-05
CN102452156A (zh) 2012-05-16
CN102452156B (zh) 2014-06-18

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