[go: up one dir, main page]

EP1690795A1 - Label with a fluid-sensitive adhesive coating, use of such a label, method for automatic application of a label with a fluid-sensitive adhesive coating and method of manufacturing a label paper - Google Patents

Label with a fluid-sensitive adhesive coating, use of such a label, method for automatic application of a label with a fluid-sensitive adhesive coating and method of manufacturing a label paper Download PDF

Info

Publication number
EP1690795A1
EP1690795A1 EP05002687A EP05002687A EP1690795A1 EP 1690795 A1 EP1690795 A1 EP 1690795A1 EP 05002687 A EP05002687 A EP 05002687A EP 05002687 A EP05002687 A EP 05002687A EP 1690795 A1 EP1690795 A1 EP 1690795A1
Authority
EP
European Patent Office
Prior art keywords
label
adhesive coating
container
liquid
sensitive adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP05002687A
Other languages
German (de)
French (fr)
Other versions
EP1690795B1 (en
Inventor
Willi Suhner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Papierfabriken Cham-Tenero AG
Papierfabriken Cham Tenero AG
Original Assignee
Papierfabriken Cham-Tenero AG
Papierfabriken Cham Tenero AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to SI200530182T priority Critical patent/SI1690795T1/en
Application filed by Papierfabriken Cham-Tenero AG, Papierfabriken Cham Tenero AG filed Critical Papierfabriken Cham-Tenero AG
Priority to ES05002687T priority patent/ES2298873T3/en
Priority to AT05002687T priority patent/ATE381489T1/en
Priority to DE502005002285T priority patent/DE502005002285D1/en
Priority to EP05002687A priority patent/EP1690795B1/en
Priority to PL05002687T priority patent/PL1690795T3/en
Priority to JP2007556511A priority patent/JP2008533511A/en
Priority to MX2007008915A priority patent/MX2007008915A/en
Priority to US11/883,655 priority patent/US20080226907A1/en
Priority to CNA200680004366XA priority patent/CN101128360A/en
Priority to PCT/EP2006/000572 priority patent/WO2006084567A1/en
Priority to BRPI0606777-8A priority patent/BRPI0606777B1/en
Priority to KR1020077018070A priority patent/KR20070101308A/en
Priority to RU2007133713/12A priority patent/RU2416826C2/en
Publication of EP1690795A1 publication Critical patent/EP1690795A1/en
Priority to ZA200706551A priority patent/ZA200706551B/en
Application granted granted Critical
Publication of EP1690795B1 publication Critical patent/EP1690795B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C9/00—Details of labelling machines or apparatus
    • B65C9/08—Label feeding
    • B65C9/12—Removing separate labels from stacks
    • B65C9/16—Removing separate labels from stacks by wetting devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C3/00—Labelling other than flat surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C9/00—Details of labelling machines or apparatus
    • B65C9/02—Devices for moving articles, e.g. containers, past labelling station
    • B65C9/04—Devices for moving articles, e.g. containers, past labelling station having means for rotating the articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C9/00—Details of labelling machines or apparatus
    • B65C9/20—Gluing the labels or articles
    • B65C9/22—Gluing the labels or articles by wetting, e.g. by applying liquid glue or a liquid to a dry glue coating
    • B65C9/2204—Gluing the labels or articles by wetting, e.g. by applying liquid glue or a liquid to a dry glue coating using spraying means
    • B65C9/2208—Applying the liquid on the article
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65C—LABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C9/00—Details of labelling machines or apparatus
    • B65C9/20—Gluing the labels or articles
    • B65C9/22—Gluing the labels or articles by wetting, e.g. by applying liquid glue or a liquid to a dry glue coating
    • B65C9/2204—Gluing the labels or articles by wetting, e.g. by applying liquid glue or a liquid to a dry glue coating using spraying means
    • B65C9/2213—Applying the liquid on the label
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852—Adhesive compositions
    • Y10T428/2865—Adhesive compositions including monomer or polymer of carbohydrate [e.g., starch, dextrin, etc.] Or protein [e.g., casein, animal protein, etc.] Or derivative thereof

Definitions

  • the invention relates to a label with liquid-sensitive adhesive coating, the use of such a label, a method for automatic application a label with liquid-sensitive adhesive coating and a method for producing a label paper.
  • the wet labeling technique is still the most cost-effective equipment option.
  • the materials used for label and adhesive are responsible for this, on the other hand, the machine technology is available for maximum possible efficiencies right down to the highest performance range. In practice, aggregates achieve a performance of 60,000 labels per hour in practice.
  • the glue is applied to a glue roller on which passes a pallet carousel with a large number of pallets.
  • the pallets are coated with glue.
  • the respective pallet rolls on the back of each issuing from the pallet magazine label paper and pulls the label paper from the magazine.
  • the adhering to the respective pallet label is fed to a gripper cylinder, the label, which now with his the glued page side of the label facing away from the gripper cylinder is further transported.
  • the gripper cylinder is arranged in the region of a bottle bottles receiving a lot of bottles. When turning the bottle table, the bottles are passed by the gripper cylinder and the bottles roll off the glued labels so that they adhere to the bottles.
  • the labeling described is structurally complex due to the various interacting components of the unit and difficult to control the process, especially against the background of the desired high production capacity of about 60,000 labels per hour.
  • the complexity of the process also results from the fact that glue must first be applied to the label in the labeling process.
  • the labels have a full-surface coating on the back of an adhesive, which is activated when moistened with water.
  • the adhesive is assembled to provide strong, durable label adhesion to the plastic surface of bottles.
  • the separation of the labels or the removal of the label stack is, however, using conventional cold glue by means of glue adhesion, so in a manner as practiced only with uncoated, adhesive-free labels. This partially leading to a double gluing measure is to be achieved that also activatable labels can be processed with the same high performance and accuracy, as is common in uncoated labels.
  • the advantages of the activatable adhesive coating should be fully retained.
  • the cold glue application is sufficient for a good initial adhesion between the label and the vessel, so that the activation of the adhesive coating can be carried out at any time before, during or after the application of the labels to the vessels.
  • the use of finding device is constructed in the above sense, thus has the pallet carousel with the pallets, the gripper cylinder and the rotating bottle table with of variety bottles on.
  • the labels are additionally provided in two opposite rows with two strips of cold glue.
  • a spraying device is arranged through which the area of the bottles to be labeled is wetted with water as it passes by.
  • a labeling device is known in which it is proposed to use labels that are already provided with a glue application, and to make this glue application by applying water sticky. It is proposed to design the supply system for the water without pressure, wherein the past of openings of an applicator label receives the necessary amount of water due to the effective adhesion forces.
  • a method and a device for attaching labels to vessels is also known from DE 41 05 524 C2.
  • the object of the invention is to provide a label with a special liquid-sensitive adhesive coating, which is suitable for use in the high-performance range of labeling, also a preferred use of such a label, further to provide a method for automatically attaching a label and a method for producing a label paper ,
  • the invention proposes a label with liquid-sensitive adhesive coating on its back, which is characterized in that the adhesive coating based on natural biopolymers and their derivatives and / or synthetic polymers which are activatable with liquid.
  • a label paper which has the liquid-sensitive adhesive coating. It is also conceivable, instead of a paper, to provide a porous film, in particular a plastic film, which is provided with the liquid-sensitive adhesive coating. This porous film has a certain vapor permeability, so that the moistened adhesive coating, after applying the label to the container, can dry.
  • caseins proteins, alginates, gelatin, galactomannans, starch, chitin and their derivatives, vinyl alcohol (VAL), vinyl acetate (VAC), acrylic acid and its derivatives, carboxymethyl cellulose (CMC) are used for the adhesive coating.
  • VAL vinyl alcohol
  • VAC vinyl acetate
  • acrylic acid and its derivatives carboxymethyl cellulose
  • the adhesive coating consists of 60-100, preferably 70-95, in particular 80-95% of a starch derivative and 0-40, preferably 5-30, in particular 5-20% of a polymer acting as thickener based on natural or synthetic base.
  • the adhesive coating has a solids content of 10 -70, preferably 10 to 40, in particular 20 to 30%.
  • the viscosity of the adhesive coating is 200-4000, preferably 400-3000, in particular 800-2500 mPas (Brookfield).
  • the adhesive coating is preferably activated with water or a water-alcohol mixture.
  • This liquid may additionally be provided with a wetting agent and / or a thickening agent.
  • the adhesive coating is not activated by humidity.
  • An inventive method for producing the labels with liquid-sensitive adhesive coating on the back provides that the adhesive coating is applied to the label in the papermaking or paper finishing or in painting or printing machines.
  • the label is used with liquid-sensitive adhesive coating on its back, in particular for labeling surfaces made of glass, tinplate, aluminum, polyethylene terephthalate (PET), polyvinyl chloride (PVC), polyolefins (polyethylene (PE), polypropylene (PP)), polystyrene (PS) or composite composites thereof.
  • PET polyethylene terephthalate
  • PVC polyvinyl chloride
  • PVC polyolefins
  • PE polyethylene
  • PP polypropylene
  • PS polystyrene
  • the invention thus proposes the replacement of the prior wet glue label process with a system of an activating agent and a label specially treated on the backside.
  • the label develops its adhesive power through the activating agent.
  • the bond does not dissolve due to condensation or ice water.
  • the adhesive coating can already be applied during papermaking or finishing, in varnishing machines or printing presses.
  • the adhesive coating is based on natural biopolymers and their derivatives and / or synthetic polymers which are activatable with liquid and lead to the above-mentioned adhesive behavior.
  • the invention further relates to a method for automatically applying a liquid-sensitive adhesive coating label to a surface of a container, in particular an outwardly curved surface of a bottle, wherein a plurality of stacked labels provided with the adhesive coating are arranged in a label magazine, the containers are conveyed relative to the label magazine, and a device for wetting the respective container or to be taken from the label magazine Label is provided with the liquid; wherein this method is characterized in that the container and the label magazine located in the label to be removed are brought directly into contact with each other and the container pulls the label out of the magazine.
  • the labels are applied directly to the container.
  • the containers are transported relative to the label magazine.
  • the label magazine is stationary and the containers, in particular bottles, are moved past the label magazine.
  • the movement presents itself in a particularly simple manner as a rolling movement of the container on the back of the label.
  • the container is preferably a cylindrical body, in particular a bottle, especially a beer bottle. This is rotated about its cylinder axis.
  • the adhesive layer can be activated if the container is previously sprayed with liquid, in particular in the region of the surface of the container which serves to receive the label, and then this region of the container in contact with the back of the label is brought.
  • the located in the label magazine to be removed label is removed from a removal member whose surface is wetted with liquid, the withdrawal member in the region of the adhesive layer on this adherent label to the labeling cylinder, such that the adhesive layer the opposite side of the label is applied to this, and the labeling cylinder is brought with the label in contact with the container and the container with the label equips.
  • the removal member is thus, in the sense of the above description of the prior art, the pallet, in the labeling cylinder to the gripper cylinder.
  • the liquid is not applied to the container or the back of the label in the label magazine with which a dry container preferably comes in contact, but it is liquid instead of the glue roller quasi transferred via a liquid applicator roll on the pallet containing the label wets and pulls out of the label magazine.
  • the label with already activated adhesive coating fed to the gripper cylinder and glued by means of this on the container, in particular the bottle.
  • the region of the withdrawal member which serves for wetting the label is formed as a sponge, rubber or the like or provided with a surface structure.
  • the liquid applicator roll is to be adapted to the requirements of the medium liquid instead of the medium glue when using a glue roller.
  • Bottles 1, especially beer bottles run on an endless belt 2, which is provided with turntables 3, past a label magazine 4.
  • This label magazine 4 receives the plurality of labels provided on the back side thereof with the liquid-sensitive adhesive coating.
  • the conveying direction of the endless belt is illustrated by the arrow A, the direction of rotation of the respective bottle 1 on the associated turntable 3 with the arrow B.
  • the respective bottle 1 is sprayed with wetting liquid 6 by means of a wetting unit 5 in the area where the label is to be positioned. Only in the area of the label magazine 4, the bottle 1 is rotated.
  • the directly wetted wet bottle 1 receives the specially treated label.
  • the Figure It can be seen that the bottles 1, which have passed the label magazine 4, are equipped with a label 7.

Landscapes

  • Labeling Devices (AREA)
  • Making Paper Articles (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Adhesive Tapes (AREA)

Abstract

The label (7) has a liquid-sensitive adhesive coating on a rear face. The coating is based on natural biopolymers and its derivatives and/or synthetic polymers that can be activated by a liquid. The label is formed by a paper or a porous foil such as plastic foil. The coating is activated with water or water-alcohol mixture. The mixture is provided with a wetting agent or a thickening agent. Independent claims are also included for the following: (1) a method for automatically applying a label comprising a liquid-sensitive adhesive coating (2) a method for production of a label paper.

Description

Die Erfindung betrifft ein Etikett mit flüssigkeitssensitiver Kleberbeschichtung, die Verwendung eines solchen Etiketts, ein Verfahren zum automatischen Aufbringen eines Etiketts mit flüssigkeitssensitiver Kleberbeschichtung sowie ein Verfahren zur Herstellung eines Etikettenpapiers.The invention relates to a label with liquid-sensitive adhesive coating, the use of such a label, a method for automatic application a label with liquid-sensitive adhesive coating and a method for producing a label paper.

Beim Ausstatten von Behältnissen, insbesondere Flaschen, mit Etiketten ist nach wie vor die Nassetikettiertechnik die kostengünstigste Ausstattungsmöglichkeit. Dafür verantwortlich sind zum einen die verwendeten Materialien für Etikett und Klebstoff, zum anderen steht die Maschinentechnik für maximal mögliche Wirkungsgrade bis in den Höchstleistungsbereich zur Verfügung. So erreichen Aggregate in der Praxis eine Leistung von 60.000 Etiketten pro Stunde.When furnishing containers, in particular bottles, with labels, the wet labeling technique is still the most cost-effective equipment option. On the one hand, the materials used for label and adhesive are responsible for this, on the other hand, the machine technology is available for maximum possible efficiencies right down to the highest performance range. In practice, aggregates achieve a performance of 60,000 labels per hour in practice.

Im "Handbuch der Etikettiertechnik - Grundlagen und Praxis erfolgreicher Produktausstattung", herausgegeben von Volker Kronseder, 6. Auflage 2001, Seiten 173 bis 189 ist unter "5.1 Erfahrener Leistungsträger - Die Nassetikettierung" die Nassetikettierung beschrieben.In the "Handbuch der Etikettiertechnik - Fundamentals and practice of successful product equipment", edited by Volker Kronseder, 6th edition 2001, pages 173 to 189, wet labeling is described under "5.1 Experienced service provider - wet labeling".

Bei dieser finden in aller Regel Etiketten Verwendung, die aus Papier bestehen und keine Kleberbeschichtung auf deren Rückseite aufweisen. Zum Befestigen der Etiketten an den Behältnissen wird statt dessen ein Leim auf wässriger Basis verwendet. Weil diese Leimsorten bei vergleichsweise niedrigen Temperaturen verarbeitet werden, spricht man auch von Kaltleim-Technik.In this usually find use labels that are made of paper and have no adhesive coating on the back. To attach the labels to the containers, an aqueous-based glue is used instead. Because these types of glue are processed at comparatively low temperatures, this is also referred to as cold glue technology.

Prinzipbedingt unterscheidet man bei der in der Literaturstelle beschriebenen Nassetikettierung zwischen Aggregaten mit feststehendem Etikettenmagazin und oszillierenden Paletten einerseits sowie mit schwenkbarem Etikettenmagazin andererseits. Bei Aggregaten mit feststehendem Etikettenbehälter und oszillierenden Paletten wird der Leim auf eine Leimwalze aufgetragen, an der ein Palettenkarussell mit einer Vielzahl Paletten vorbeiläuft. Die Paletten werden mit Leim bestrichen. Die jeweilige Palette rollt auf der Rückseite des jeweils aus dem Palettenmagazin auszugebenden Etikettenpapiers ab und zieht das Etikettenpapier aus dem Magazin. Das an der jeweiligen Palette haftende Etikett wird einem Greiferzylinder zugeführt, der das Etikett, das nunmehr mit seiner der beleimten Seite des Etiketts abgewandten Seite am Greiferzylinder anliegt, weiter transportiert wird. Der Greiferzylinder ist im Bereich eines viel Flaschen aufnehmenden Flaschentischs angeordnet. Beim Drehen des Flaschentischs werden die Flaschen am Greiferzylinder vorbeigeführt und es rollen die Flaschen an den beleimten Etiketten ab, so dass diese an den Flaschen haften.Due to the principle, a distinction is made in the wet labeling described in the literature between units with a fixed label magazine and oscillating pallets on the one hand and with hinged label magazine on the other. For units with a fixed label container and oscillating pallets, the glue is applied to a glue roller on which passes a pallet carousel with a large number of pallets. The pallets are coated with glue. The respective pallet rolls on the back of each issuing from the pallet magazine label paper and pulls the label paper from the magazine. The adhering to the respective pallet label is fed to a gripper cylinder, the label, which now with his the glued page side of the label facing away from the gripper cylinder is further transported. The gripper cylinder is arranged in the region of a bottle bottles receiving a lot of bottles. When turning the bottle table, the bottles are passed by the gripper cylinder and the bottles roll off the glued labels so that they adhere to the bottles.

Die beschriebene Etikettierung ist aufgrund der diversen miteinander zusammenwirkenden Bauteile des Aggregats baulich aufwendig und vom Prozess schwierig zu beherrschen, insbesondere vor dem Hintergrund der angestrebten hohen Produktionsleistung von ungefähr 60.000 Etiketten pro Stunde. Die Komplexität des Verfahrens resultiert auch dadurch, dass im Etikettierprozess zunächst Leim auf das Etikett aufgebracht werden muss.The labeling described is structurally complex due to the various interacting components of the unit and difficult to control the process, especially against the background of the desired high production capacity of about 60,000 labels per hour. The complexity of the process also results from the fact that glue must first be applied to the label in the labeling process.

In der DE 35 04 164 A1 ist ein Verfahren und eine Vorrichtung zum Ausstatten von Gefäßen oder dergleichen mit Etiketten beschrieben. Die Etiketten weisen auf ihrer Rückseite eine vollflächige Beschichtung aus einem Klebstoff auf, der beim Anfeuchten mit Wasser aktiviert wird. Der Klebstoff ist derart zusammengesetzt, dass er an der Kunststoffoberfläche von Flaschen eine starke, dauerhafte Haftung der Etiketten ermöglicht. Das Vereinzeln der Etiketten bzw. das Abnehmen vom Etikettenstapel erfolgt allerdings unter Verwendung von üblichem Kaltleim mittels Leimadhäsion, also auf einer Art und Weise, wie sie nur bei unbeschichteten, klebstofffreien Etiketten praktiziert wird. Durch diese teilweise zu einer Doppelbeleimung führende Maßnahme soll erreicht werden, dass auch aktivierbare Etiketten mit der gleichen hohen Leistung und Exaktheit verarbeitet werden können, wie dies bei unbeschichteten Etiketten üblich ist. Dabei sollen die Vorzüge der aktivierbaren Klebstoffbeschichtung voll erhalten bleiben. Der Kaltleimauftrag ist ausreichend für eine gute Anfangshaftung zwischen Etikett und Gefäß, so dass die Aktivierung der Klebstoffbeschichtung zu jedem beliebigen Zeitpunkt vor, während oder nach dem Anlegen der Etiketten an die Gefäße durchgeführt werden kann. Die Verwendung findende Vorrichtung ist in vorbeschriebenen Sinne aufgebaut, weist somit das Palettenkarussell mit den Paletten, den Greiferzylinder und den umlaufenden Flaschentisch mit der Vielzahl Flaschen auf. Mittels der Paletten werden die Etiketten in abgewandten Reihenbereichen mit zwei Kaltleimstreifen zusätzlich versehen. Im Umlaufbereich des Flaschentisches vor dem Greifzylinder ist eine Sprüheinrichtung angeordnet, durch welche der zu etikettierende Bereich der Flaschen bei deren Vorbeilauf mit Wasser benetzt wird.In DE 35 04 164 A1 a method and an apparatus for furnishing containers or the like with labels is described. The labels have a full-surface coating on the back of an adhesive, which is activated when moistened with water. The adhesive is assembled to provide strong, durable label adhesion to the plastic surface of bottles. The separation of the labels or the removal of the label stack is, however, using conventional cold glue by means of glue adhesion, so in a manner as practiced only with uncoated, adhesive-free labels. This partially leading to a double gluing measure is to be achieved that also activatable labels can be processed with the same high performance and accuracy, as is common in uncoated labels. The advantages of the activatable adhesive coating should be fully retained. The cold glue application is sufficient for a good initial adhesion between the label and the vessel, so that the activation of the adhesive coating can be carried out at any time before, during or after the application of the labels to the vessels. The use of finding device is constructed in the above sense, thus has the pallet carousel with the pallets, the gripper cylinder and the rotating bottle table with of variety bottles on. By means of the pallets, the labels are additionally provided in two opposite rows with two strips of cold glue. In the circulation area of the bottle table in front of the gripping cylinder, a spraying device is arranged through which the area of the bottles to be labeled is wetted with water as it passes by.

Das beschriebene Verfahren und die Vorrichtung zur Durchführung des Verfahrens gemäß dieser Schrift ist wegen der Doppelbeleimung und der in diesem Zusammenhang erforderlichen Gestaltung der Vorrichtung aufwendig.The method described and the device for carrying out the method according to this document are complicated because of the double gluing and the design of the device required in this connection.

Aus der DE-OS 1 586 400 ist eine Etikettiervorrichtung bekannt, bei der vorgeschlagen wird, Etiketten, die bereits mit einem Leimauftrag versehen sind, zu verwenden und diesen Leimauftrag durch Aufbringen von Wasser klebrig zu machen. Es wird vorgeschlagen, das Zuführungssystem für das Wasser drucklos zu gestalten, wobei das an Öffnungen eines Auftragskopfes vorbeistreichende Etikett die notwendige Wassermenge aufgrund der wirksam werdenden Adhäsionskräfte aufnimmt.From DE-OS 1 586 400 a labeling device is known in which it is proposed to use labels that are already provided with a glue application, and to make this glue application by applying water sticky. It is proposed to design the supply system for the water without pressure, wherein the past of openings of an applicator label receives the necessary amount of water due to the effective adhesion forces.

Ein Verfahren und eine Vorrichtung zum Anbringen von Etiketten an Gefäßen ist ferner aus der DE 41 05 524 C2 bekannt.A method and a device for attaching labels to vessels is also known from DE 41 05 524 C2.

Aufgabe der Erfindung ist es, ein Etikett mit besonderer flüssigkeitssensitiver Kleberbeschichtung anzugeben, das für den Einsatz im Höchstleistungsbereich der Etikettierung geeignet ist, ferner eine bevorzugte Verwendung eines solchen Etiketts, des weiteren ein Verfahren zum automatischen Anbringen eines Etiketts sowie ein Verfahren zur Herstellung eines Etikettenpapiers anzugeben.The object of the invention is to provide a label with a special liquid-sensitive adhesive coating, which is suitable for use in the high-performance range of labeling, also a preferred use of such a label, further to provide a method for automatically attaching a label and a method for producing a label paper ,

Die Erfindung schlägt ein Etikett mit flüssigkeitssensitiver Kleberbeschichtung auf dessen Rückseite vor, das dadurch gekennzeichnet ist, dass die Kleberbeschichtung auf natürlichen Biopolymeren sowie deren Derivaten und / oder synthetischen Polymeren, die mit Flüssigkeit aktivierbar sind, basiert.The invention proposes a label with liquid-sensitive adhesive coating on its back, which is characterized in that the adhesive coating based on natural biopolymers and their derivatives and / or synthetic polymers which are activatable with liquid.

Verwendung findet insbesondere ein Etikettenpapier das die flüssigkeitssensitive Kleberbeschichtung aufweist. Es ist gleichfalls denkbar, statt eines Papiers eine poröse Folie, insbesondere Kunststofffolie, vorzusehen, die mit der flüssigkeitssensitiven Kleberbeschichtung versehen ist. Diese poröse Folie besitzt eine gewisse Dampfdurchlässigkeit, so dass die angefeuchtete Kleberbeschichtung, nach dem Aufbringen des Etiketts auf das Behältnis, trocknen kann.In particular, use is made of a label paper which has the liquid-sensitive adhesive coating. It is also conceivable, instead of a paper, to provide a porous film, in particular a plastic film, which is provided with the liquid-sensitive adhesive coating. This porous film has a certain vapor permeability, so that the moistened adhesive coating, after applying the label to the container, can dry.

Für die Kleberbeschichtung finden insbesondere Caseine, Proteine, Alginate, Gelatine, Galactomannane, Stärke, Chitin und deren Derivate, Vinylalkohol (VAL), Vinylacetat (VAC), Acrylsäure und deren Derivate, Carboxymethylcellulose (CMC) Verwendung.In particular, caseins, proteins, alginates, gelatin, galactomannans, starch, chitin and their derivatives, vinyl alcohol (VAL), vinyl acetate (VAC), acrylic acid and its derivatives, carboxymethyl cellulose (CMC) are used for the adhesive coating.

Die Kleberbeschichtung besteht aus 60 - 100, vorzugsweise 70 - 95, insbesondere 80 - 95 % eines Stärkederivats und 0 - 40, vorzugsweise 5 - 30, insbesondere 5 - 20 % eines als Verdicker wirkenden, auf natürlicher oder synthetischer Basis beruhenden Polymer.The adhesive coating consists of 60-100, preferably 70-95, in particular 80-95% of a starch derivative and 0-40, preferably 5-30, in particular 5-20% of a polymer acting as thickener based on natural or synthetic base.

Die Kleberbeschichtung besitzt einen Feststoffgehalt von 10 -70, vorzugsweise 10 - 40, insbesondere 20 -30 %.The adhesive coating has a solids content of 10 -70, preferably 10 to 40, in particular 20 to 30%.

Die Viskosität der Kleberbeschichtung beträgt 200 - 4000, vorzugsweise 400 - 3000, insbesondere 800 - 2500 mPas (Brookfield).The viscosity of the adhesive coating is 200-4000, preferably 400-3000, in particular 800-2500 mPas (Brookfield).

Die Kleberbeschichtung wird vorzugsweise mit Wasser oder einem Wasser-Alkohol-Gemisch aktiviert. Diese Flüssigkeit kann zusätzlich mit einem Netzmittel und / oder einem Verdickungsmittel versehen sein. Die Kleberbeschichtung wird nicht über Luftfeuchtigkeit aktiviert.The adhesive coating is preferably activated with water or a water-alcohol mixture. This liquid may additionally be provided with a wetting agent and / or a thickening agent. The adhesive coating is not activated by humidity.

Ein erfindungsgemäßes Verfahren zur Herstellung der Etiketten mit flüssigkeitssensitiver Kleberbeschichtung auf der Rückseite sieht vor, dass die Kleberbeschichtung bei der Papierherstellung oder Papierveredelung oder in Lackiermaschinen oder in Druckmaschinen auf das Etikett aufgebracht wird.An inventive method for producing the labels with liquid-sensitive adhesive coating on the back provides that the adhesive coating is applied to the label in the papermaking or paper finishing or in painting or printing machines.

Verwendung findet das Etikett mit flüssigkeitssensitiver Kleberbeschichtung auf dessen Rückseite, insbesondere zum Etikettieren von Oberflächen aus Glas, Weißblech, Aluminium, Polyethylenterephthalat (PET), Polyvinylchlorid (PVC), Polyolefine (Polyethylen (PE), Polypropylen (PP)), Polystyrol (PS) oder daraus bestehenden Verbundstoffen.The label is used with liquid-sensitive adhesive coating on its back, in particular for labeling surfaces made of glass, tinplate, aluminum, polyethylene terephthalate (PET), polyvinyl chloride (PVC), polyolefins (polyethylene (PE), polypropylene (PP)), polystyrene (PS) or composite composites thereof.

Die Erfindung schlägt somit den Austausch des bisherigen Nassleimetikettenverfahrens mit einem System von einem Aktivierungsmittel und einem speziell auf der Rückseite behandelten Etikett vor. Das Etikett entwickelt seine Klebkraft durch das Aktivierungsmittel. Die Klebung löst sich durch Schwitz- oder Eiswasser nicht auf. Ist die Kleberbeschichtung aktiviert, entsteht beim Wiederbefeuchten ein klebriges Gel, der Klebstoff löst sich nicht auf, sondern es kann das Etikett nur mechanisch abgezogen werden. Die Kleberbeschichtung kann bereits bei der Papierherstellung oder -veredelung, in Lackiermaschinen oder Druckmaschinen aufgebracht werden. Die Kleberbeschichtung basiert auf natürlichen Biopolymeren sowie deren Derivaten und / oder synthetischen Polymeren, die mit Flüssigkeit aktivierbar sind und zu dem oben erwähnten Klebeverhalten führen.The invention thus proposes the replacement of the prior wet glue label process with a system of an activating agent and a label specially treated on the backside. The label develops its adhesive power through the activating agent. The bond does not dissolve due to condensation or ice water. If the adhesive coating is activated, a sticky gel is formed when remoistened, the adhesive does not dissolve, but the label can only be peeled off mechanically. The adhesive coating can already be applied during papermaking or finishing, in varnishing machines or printing presses. The adhesive coating is based on natural biopolymers and their derivatives and / or synthetic polymers which are activatable with liquid and lead to the above-mentioned adhesive behavior.

Mit der Kleberbeschichtung wird durch das Aktivierungsmittel eine Aktivierungszeit der Klebekraft von > / = 40 ms erreicht. Dies gewährleistet, dass Behältnisse im Hochleistungsbereich mit Etiketten ausgestattet werden können.With the adhesive coating, an activation time of the adhesive force of> / = 40 ms is achieved by the activating agent. This ensures that containers in the high-performance area can be equipped with labels.

Unter dem Aspekt des beschriebenen Standes der Technik betrifft die Erfindung ferner ein Verfahren zum automatischen Aufbringen eines Etiketts mit flüssigkeitssensitiver Kleberbeschichtung auf dessen Rückseite auf eine Oberfläche eines Behältnisses, insbesondere eine nach außen gekrümmte Fläche einer Flasche, wobei eine Vielzahl von mit der Kleberbeschichtung versehener gestapelter Etiketten in einem Etikettenmagazin angeordnet sind, die Behältnisse relativ zum Etikettenmagazin gefördert werden, sowie eine Einrichtung zum Benetzen des jeweiligen Behältnisses oder des aus dem Etikettenmagazin zu entnehmenden Etiketts mit der Flüssigkeit vorgesehen ist; wobei dieses Verfahren dadurch gekennzeichnet ist, dass das Behältnis und das im Etikettenmagazin befindliche, zu entnehmende Etikett unmittelbar in Kontakt zueinander gebracht werden und das Behältnis das Etikett aus dem Magazin zieht.From the aspect of the described prior art, the invention further relates to a method for automatically applying a liquid-sensitive adhesive coating label to a surface of a container, in particular an outwardly curved surface of a bottle, wherein a plurality of stacked labels provided with the adhesive coating are arranged in a label magazine, the containers are conveyed relative to the label magazine, and a device for wetting the respective container or to be taken from the label magazine Label is provided with the liquid; wherein this method is characterized in that the container and the label magazine located in the label to be removed are brought directly into contact with each other and the container pulls the label out of the magazine.

Bei diesem Verfahren ist es somit nicht erforderlich, die gemäß dem Stand der Technik erforderlichen Verfahrensschritte mittels der Leimwalze, der Paletten und des Greiferzylinders zu vollziehen. Statt dessen werden, bei aktivierter Kleberbeschichtung, die Etiketten unmittelbar auf das Behältnis aufgebracht. Grundsätzlich ist es dabei nur erforderlich, dass die Behältnisse relativ zum Etikettenmagazin befördert werden. Es wird allerdings unter dem Aspekt der Prozesssicherheit und des baulichen Aufwands als vorteilhaft angesehen, wenn das Etikettenmagazin stationär ist und die Behältnisse, insbesondere Flaschen, am Etikettenmagazin vorbeibewegt werden. Die Bewegung stellt sich auf besonders einfache Art und Weise als Abrollbewegung des Behälters auf der Rückseite des Etiketts dar. So handelt es sich bei dem Behälter vorzugsweise um einen zylindrischen Körper, insbesondere eine Flasche, vor allem eine Bierflasche. Dieser wird um seine Zylinderachse gedreht. Auf besonders einfache Art und Weise lässt sich die Kleberschicht aktivieren, wenn das Behältnis zuvor mit Flüssigkeit besprüht wird, insbesondere in dem Bereich der Oberfläche des Behälters, das der Aufnahme des Etiketts dient, und anschließend dieser Bereich des Behälters in Kontakt mit der Rückseite des Etiketts gebracht wird.In this method, it is thus not necessary to carry out the process steps required according to the prior art by means of the glue roller, the pallets and the gripper cylinder. Instead, with activated adhesive coating, the labels are applied directly to the container. Basically, it is only necessary that the containers are transported relative to the label magazine. However, it is considered advantageous from the aspect of process reliability and structural complexity if the label magazine is stationary and the containers, in particular bottles, are moved past the label magazine. The movement presents itself in a particularly simple manner as a rolling movement of the container on the back of the label. Thus, the container is preferably a cylindrical body, in particular a bottle, especially a beer bottle. This is rotated about its cylinder axis. In a particularly simple manner, the adhesive layer can be activated if the container is previously sprayed with liquid, in particular in the region of the surface of the container which serves to receive the label, and then this region of the container in contact with the back of the label is brought.

Allerdings besteht grundsätzlich auch die Möglichkeit, die aus dem Stand der Technik bekannten Vorrichtungen zum Etikettieren im erfindungsgemäßen Sinne umzurüsten. Unter diesem Aspekt wird vorgeschlagen, dass das im Etikettenmagazin befindliche, zu entnehmende Etikett von einem Entnahmeglied entnommen wird, dessen Oberfläche mit Flüssigkeit benetzt ist, das Entnahmeglied das im Bereich der Kleberschicht an diesem haftende Etikett an den Etikettierzylinder übergibt, derart, dass die der Kleberschicht abgewandte Seite des Etiketts an diesem anliegt, sowie der Etikettierzylinder mit dem Etikett in Kontakt mit dem Behältnis gebracht wird und den Behälter mit dem Etikett ausstattet. Bei dem Entnahmeglied handelt es sich somit, im Sinne der vorstehenden Beschreibung zum Stand der Technik, um die Palette, bei dem Etikettierzylinder um den Greiferzylinder. Demzufolge wird bei dieser Verfahrensweise nicht die Flüssigkeit auf den Behälter oder die Rückseite des im Etikettenmagazin befindlichen Etiketts aufgebracht, mit dem ein trockenes Behältnis vorzugsweise in Kontakt gelangt, sondern es wird Flüssigkeit statt der Leimwalze quasi über eine Flüssigkeitsauftragswalze auf die Palette übertragen, die das Etikett benetzt und aus dem Etikettmagazin herauszieht. Von dort wird das Etikett, mit bereits aktivierter Kleberbeschichtung dem Greiferzylinder zugeführt und mittels diesem auf das Behältnis, insbesondere die Flasche, geklebt. Als besonderes vorteilhaft wird es angesehen, wenn der Bereich des Entnahmeglieds, der dem Benetzen des Etiketts dient, als Schwamm, Gummi oder dergleichen ausgebildet oder mit einer Oberflächenstruktur versehen ist. Die Flüssigkeitsauftragswalze ist den Anforderungen des Mediums Flüssigkeit statt des Mediums Leim bei Verwendung einer Leimwalze anzupassen.However, in principle it is also possible to convert the known from the prior art devices for labeling in accordance with the invention. In this aspect, it is proposed that the located in the label magazine to be removed label is removed from a removal member whose surface is wetted with liquid, the withdrawal member in the region of the adhesive layer on this adherent label to the labeling cylinder, such that the adhesive layer the opposite side of the label is applied to this, and the labeling cylinder is brought with the label in contact with the container and the container with the label equips. The removal member is thus, in the sense of the above description of the prior art, the pallet, in the labeling cylinder to the gripper cylinder. Accordingly, in this procedure, the liquid is not applied to the container or the back of the label in the label magazine with which a dry container preferably comes in contact, but it is liquid instead of the glue roller quasi transferred via a liquid applicator roll on the pallet containing the label wets and pulls out of the label magazine. From there, the label, with already activated adhesive coating fed to the gripper cylinder and glued by means of this on the container, in particular the bottle. It is regarded as particularly advantageous if the region of the withdrawal member which serves for wetting the label is formed as a sponge, rubber or the like or provided with a surface structure. The liquid applicator roll is to be adapted to the requirements of the medium liquid instead of the medium glue when using a glue roller.

In der nachfolgenden, einzigen Figur ist der grundsätzliche Aufbau einer Etikettiervorrichtung für die angesprochene direkte Etikettierung beispielhaft veranschaulicht.In the following, single figure, the basic structure of a labeling device for the addressed direct labeling is exemplified.

Flaschen 1, insbesondere Bierflaschen laufen auf einem Endlosband 2, das mit Drehtellern 3 versehen ist, an einem Etikettenmagazin 4 vorbei. Dieses Etikettenmagazin 4 nimmt die Vielzahl von Etiketten auf, die auf deren Rückseite mit der flüssigkeitssensitiven Kleberbeschichtung versehen sind. Die Förderrichtung des Endlosbandes ist mit dem Pfeil A, die Drehrichtung der jeweiligen Flasche 1 auf dem zugeordneten Drehteller 3 mit dem Pfeil B veranschaulicht. Kurz vor Erreichen des Etikettenmagazins 4 wird die jeweilige Flasche 1 mittels eines Benetzungsaggregates 5 in dem Bereich, an dem das Etikett positioniert werden soll, mit Benetzungsflüssigkeit 6 besprüht. Erst im Bereich des Etikettenmagazins 4 wird die Flasche 1 gedreht. Durch die Abrollbewegung der Flasche 1 auf dem zur Ausgabe am Etikettenmagazin 4 anstehenden Etikett nimmt die direkt benetzte nasse Flasche 1 das speziell behandelte Etikett auf. Der Figur zu entnehmen, dass die Flaschen 1, die das Etikettenmagazin 4 passiert haben, mit einem Etikett 7 ausgestattet sind.Bottles 1, especially beer bottles run on an endless belt 2, which is provided with turntables 3, past a label magazine 4. This label magazine 4 receives the plurality of labels provided on the back side thereof with the liquid-sensitive adhesive coating. The conveying direction of the endless belt is illustrated by the arrow A, the direction of rotation of the respective bottle 1 on the associated turntable 3 with the arrow B. Shortly before reaching the label magazine 4, the respective bottle 1 is sprayed with wetting liquid 6 by means of a wetting unit 5 in the area where the label is to be positioned. Only in the area of the label magazine 4, the bottle 1 is rotated. As a result of the rolling movement of the bottle 1 on the label waiting for dispensing on the label magazine 4, the directly wetted wet bottle 1 receives the specially treated label. The Figure It can be seen that the bottles 1, which have passed the label magazine 4, are equipped with a label 7.

Claims (14)

Etikett mit flüssigkeitssensitiver Kleberbeschichtung auf dessen Rückseite, dadurch gekennzeichnet, dass die Kleberbeschichtung auf natürlichen Biopolymeren sowie deren Derivaten und / oder synthetischen Polymeren, die mit Flüssigkeit aktivierbar sind, basiert.Label with liquid-sensitive adhesive coating on the back, characterized in that the adhesive coating based on natural biopolymers and their derivatives and / or synthetic polymers which are activatable with liquid based. Etikett nach Anspruch 1, dadurch gekennzeichnet, dass das Etikett durch ein Papier oder eine poröse Folie, insbesondere Kunststofffolie, und die flüssigkeitssensitive Kleberbeschichtung gebildet ist.Label according to claim 1, characterized in that the label is formed by a paper or a porous film, in particular plastic film, and the liquid-sensitive adhesive coating. Etikett nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass für die Kleberbeschichtung Caseine, Proteine, Alginate, Gelatine, Galactoman- , nane, Stärke, Chitin und deren Derivate, Vinylalkohol (VAL), Vinylacetat (VAC), Acrylsäure und deren Derivate, Carboxymethylcellulose (CMC) Verwendung finden.Label according to claim 1 or 2, characterized in that for the adhesive coating caseins, proteins, alginates, gelatin, galactoman, nane, starch, chitin and their derivatives, vinyl alcohol (VAL), vinyl acetate (VAC), acrylic acid and its derivatives, carboxymethylcellulose (CMC) find use. Etikett nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Kleberbeschichtung aus 60 - 100, vorzugsweise 70 - 95, insbesondere 80 - 95 % eines Stärkederivats und 0 - 40, vorzugsweise 5 - 30, insbesondere 5 - 20 % eines als Verdicker wirkenden, auf natürlicher oder synthetischer Basis beruhenden Polymer besteht.Label according to one of claims 1 to 3, characterized in that the adhesive coating of 60 - 100, preferably 70 - 95, in particular 80 - 95% of a starch derivative and 0 - 40, preferably 5 - 30, in particular 5 - 20% of a thickener acting, based on natural or synthetic based polymer. Etikett nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass die Kleberbeschichtung einen Feststoffgehalt von 10 bis 70, vorzugsweise 10 bis 40, insbesondere 20 bis 30 % besitzt.Label according to one of claims 1 to 4, characterized in that the adhesive coating has a solids content of 10 to 70, preferably 10 to 40, in particular 20 to 30%. Etikett nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass die Kleberbeschichtung eine Viskosität von 200 - 4000, vorzugsweise 400 - 3000, insbesondere 800 - 2500 mPas (Brookfield) besitzt.Label according to one of claims 1 to 5, characterized in that the adhesive coating has a viscosity of 200-4000, preferably 400-3000, in particular 800-2500 mPas (Brookfield). Etikett nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass die Kleberbeschichtung mit Wasser oder einem Wasser-Alkohol-Gemisch aktivierbar ist, insbesondere das Wasser bzw. das Gemisch mit einem Netzmittel und / oder einem Verdickungsmittel versehen ist.Label according to one of claims 1 to 6, characterized in that the adhesive coating with water or a water-alcohol mixture can be activated, in particular the water or the mixture is provided with a wetting agent and / or a thickener. Verfahren zur Herstellung eines Etikettenpapiers mit flüssigkeitssensitiver Kleberbeschichtung auf der Rückseite, dadurch gekennzeichnet, dass die Kleberbeschichtung bei der Papierherstellung, Papierveredelung, in Lackiermaschinen oder in Druckmaschinen auf das Etikett aufgebracht wird.A process for producing a label paper with liquid-sensitive adhesive coating on the back, characterized in that the adhesive coating is applied to the label in papermaking, paper finishing, in painting or printing presses. Verfahren zum automatischen Aufbringen eines Etiketts mit flüssigkeitssensitiver Kleberbeschichtung auf dessen Rückseite auf eine Oberfläche eines Behältnisses, insbesondere eine nach außen gekrümmte Oberfläche eines Behältnisses, vorzugsweise einer Flasche, wobei eine Vielzahl von mit der Kleberbeschichtung versehener, gestapelter Etiketten in einem Etikettenmagazin angeordnet sind, die Behältnisse relativ zum Etikettenmagazin gefördert werden, sowie eine Einrichtung zum Benetzen des jeweiligen Behältnisses oder des aus dem Etikettenmagazin zu entnehmenden Etiketts mit der Flüssigkeit vorgesehen ist, dadurch gekennzeichnet, dass das Behältnis und das im Etikettenmagazin befindliche zu entnehmende Etikett unmittelbar in Kontakt zueinander gebracht werden und das Behältnis das Etikett aus dem Etikettenmagazin zieht.A method for automatically applying a label with liquid-sensitive adhesive coating on the back of a container surface, in particular an outwardly curved surface of a container, preferably a bottle, wherein a plurality of provided with the adhesive coating, stacked labels are arranged in a label magazine, the containers are provided relative to the label magazine, and a means for wetting the respective container or of the label magazine to be removed label is provided with the liquid, characterized in that the container and the label magazine located in the label to be removed are brought directly into contact with each other and the Container pulls the label from the label magazine. Verfahren nach Anspruch 9, dadurch gekennzeichnet, dass das Behältnis gedreht wird und hierbei auf der Rückseite des Etiketts abrollt.A method according to claim 9, characterized in that the container is rotated and thereby unrolls on the back of the label. Verfahren nach Anspruch 9 oder 10, dadurch gekennzeichnet, dass das Behältnis mit Flüssigkeit besprüht wird, insbesondere in dem Bereich der Oberfläche des Behältnisses, das der Aufnahme des Etiketts dient, besprüht wird.A method according to claim 9 or 10, characterized in that the container is sprayed with liquid, in particular in the region of the surface of the container, which serves to receive the label, is sprayed. Verfahren nach Anspruch 9, dadurch gekennzeichnet, dass das in dem Etikettenmagazin befindliche, zu entnehmende Etikett von einem Entnahmeglied entnommen wird, dessen Oberfläche mit Flüssigkeit benetzt ist, das Entnahmeglied das im Bereich der Kleberbeschichtung an diesem haftende Etikett an einen Etikettierzylinder übergibt, derart, dass die der Kleberbeschichtung abgewandte Seite des Etiketts an diesem anliegt, sowie der Etikettenzylinder mit dem Etikett in Kontakt mit dem Behältnis gebracht wird und den Behälter mit dem Etikett ausstattet.A method according to claim 9, characterized in that the label located in the label to be removed label is removed from a removal member, the surface of which is wetted with liquid, the withdrawal member in the region of the adhesive coating on this adherent label to a labeling cylinder, such that the adhesive coating facing away from the side of the label rests against this, and the label cylinder is brought with the label in contact with the container and the container with the label equips. Verfahren nach Anspruch 12, dadurch gekennzeichnet, dass der Bereich des Entnahmeglieds, der dem Benetzen des Etiketts dient, als Schwamm, Gummi oder dergleichen ausgebildet oder mit einer Oberflächenstruktur versehen ist.A method according to claim 12, characterized in that the region of the withdrawal member, which serves to wet the label, is formed as a sponge, rubber or the like or provided with a surface structure. Verwendung eines Etiketts gemäß der Ansprüche 1 bis 7 zum Etikettieren von einer Oberfläche aus Glas, Weißblech, Aluminium, Polyethylenterephthalat (PET), Polyvinylchlorid (PVC), Polyolefine (Polyethylen (PE), Polypropylen (PP)), Polystyrol (PS) oder daraus bestehenden Verbundstoffen.Use of a label according to claims 1 to 7 for labeling of a surface of glass, tinplate, aluminum, polyethylene terephthalate (PET), polyvinyl chloride (PVC), polyolefins (polyethylene (PE), polypropylene (PP)), polystyrene (PS) or thereof existing composites.
EP05002687A 2005-02-09 2005-02-09 Label with a fluid-sensitive adhesive coating, use of such a label, method for automatic application of a label with a fluid-sensitive adhesive coating and method of manufacturing a label paper Expired - Lifetime EP1690795B1 (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
ES05002687T ES2298873T3 (en) 2005-02-09 2005-02-09 LABEL WITH LIQUID SENSITIVE ADHESIVE LAYER, USE OF A LABEL OF THIS TYPE, PROCEDURE FOR THE AUTOMATIC APPLICATION OF A LABEL WITH LIQUID SENSITIVE LAYER AS WELL AS PROCEDURE FOR THE MANUFACTURE OF A LABEL PAPER.
AT05002687T ATE381489T1 (en) 2005-02-09 2005-02-09 LABEL WITH A LIQUID-SENSITIVE ADHESIVE COATING, USE OF SUCH A LABEL, METHOD FOR AUTOMATICALLY APPLYING A LABEL WITH A LIQUID-SENSITIVE ADHESIVE COATING AND METHOD FOR PRODUCING A LABEL PAPER
DE502005002285T DE502005002285D1 (en) 2005-02-09 2005-02-09 Liquid-sensitive adhesive coating label, use of such a label, method for automatically applying a label with liquid-rich adhesive coating, and method for producing a label paper
EP05002687A EP1690795B1 (en) 2005-02-09 2005-02-09 Label with a fluid-sensitive adhesive coating, use of such a label, method for automatic application of a label with a fluid-sensitive adhesive coating and method of manufacturing a label paper
PL05002687T PL1690795T3 (en) 2005-02-09 2005-02-09 Label with a fluid-sensitive adhesive coating, use of such a label, method for automatic application of a label with a fluid-sensitive adhesive coating and method of manufacturing a label paper
SI200530182T SI1690795T1 (en) 2005-02-09 2005-02-09 Label with a fluid-sensitive adhesive coating, use of such a label, method for automatic application of a label with a fluid-sensitive adhesive coating and method of manufacturing a label paper
RU2007133713/12A RU2416826C2 (en) 2005-02-09 2006-01-24 Label with liquid-sensitive adhesive layer
US11/883,655 US20080226907A1 (en) 2005-02-09 2006-01-24 Label Comprising a Liquid-Sensitive Adhesive Coating, Use of Such a Label, Method for Automatically Applying a Label Comprising a Liquid-Sensitive Adhesive Coating, and Method for the Production of a Label Paper
JP2007556511A JP2008533511A (en) 2005-02-09 2006-01-24 Label with a liquid sensitive adhesive coating, use of such a label, method for automatically mounting a label with a liquid sensitive adhesive coating, and method for producing label paper
PCT/EP2006/000572 WO2006084567A1 (en) 2005-02-09 2006-01-24 Label comprising a liquid-sensitive adhesive coating, use of such a label, method for automatically applying a label comprising a liquid-sensitive adhesive coating, and method for the production of a label paper
BRPI0606777-8A BRPI0606777B1 (en) 2005-02-09 2006-01-24 LABEL SENSITIVE ADHESIVE COATING AND USE
KR1020077018070A KR20070101308A (en) 2005-02-09 2006-01-24 Labels with a liquid sensitive adhesive coating, use of these labels, automatic application of labels with a liquid sensitive adhesive coating, and methods of making label paper
MX2007008915A MX2007008915A (en) 2005-02-09 2006-01-24 Label comprising a liquid-sensitive adhesive coating, use of such a label, method for automatically applying a label comprising a liquid-sensitive adhesive coating, and method for the production of a label paper.
CNA200680004366XA CN101128360A (en) 2005-02-09 2006-01-24 Label with liquid-sensitive adhesive coating, application of such label, method for automatically applying such label with liquid-sensitive adhesive coating, and method for producing label paper
ZA200706551A ZA200706551B (en) 2005-02-09 2007-08-07 Label comprising a liquid-sensitive adhesive coating, use of such a label, method for automatically applying a label comprising a liquid-sensitive adhensive coating, and method for the production of a label paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP05002687A EP1690795B1 (en) 2005-02-09 2005-02-09 Label with a fluid-sensitive adhesive coating, use of such a label, method for automatic application of a label with a fluid-sensitive adhesive coating and method of manufacturing a label paper

Publications (2)

Publication Number Publication Date
EP1690795A1 true EP1690795A1 (en) 2006-08-16
EP1690795B1 EP1690795B1 (en) 2007-12-19

Family

ID=34933664

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05002687A Expired - Lifetime EP1690795B1 (en) 2005-02-09 2005-02-09 Label with a fluid-sensitive adhesive coating, use of such a label, method for automatic application of a label with a fluid-sensitive adhesive coating and method of manufacturing a label paper

Country Status (15)

Country Link
US (1) US20080226907A1 (en)
EP (1) EP1690795B1 (en)
JP (1) JP2008533511A (en)
KR (1) KR20070101308A (en)
CN (1) CN101128360A (en)
AT (1) ATE381489T1 (en)
BR (1) BRPI0606777B1 (en)
DE (1) DE502005002285D1 (en)
ES (1) ES2298873T3 (en)
MX (1) MX2007008915A (en)
PL (1) PL1690795T3 (en)
RU (1) RU2416826C2 (en)
SI (1) SI1690795T1 (en)
WO (1) WO2006084567A1 (en)
ZA (1) ZA200706551B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008037764A1 (en) * 2006-09-29 2008-04-03 Kuraray Europe Gmbh Use of water-soluble polyvinyl alcohol as an adhesive for plastic labels
DE102009059911A1 (en) * 2009-12-21 2011-06-22 INATEC GmbH, 40764 Method and device for labeling containers, labeled container and self-adhesive label therefor, and method and apparatus for producing such a label
US8142604B2 (en) * 2007-11-26 2012-03-27 Exxonmobil Oil Corporation Labeling method
US8939538B2 (en) 2011-08-04 2015-01-27 Nulabel Technologies, Inc. Liner-free label printer with label adhesive activation

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150021395A1 (en) * 2010-11-23 2015-01-22 Axon Tubular Products, Inc. Thin mount rfid tagging systems
US20120126008A1 (en) * 2010-11-23 2012-05-24 Merrick Systems Inc. Thin mount rfid tagging systems
US8334336B2 (en) * 2011-02-07 2012-12-18 Nulabel Technologies, Inc. Fluid activatable adhesives and fluids for activating same for use with liner-free labels
WO2013058273A1 (en) * 2011-10-19 2013-04-25 株式会社ユポ・コーポレーション Water-activated sheet, water-activated label using said sheet, production method for said label, label adhering device using said label, and adherend for said label
CN102616000B (en) * 2012-04-10 2015-05-20 上海美声服饰辅料有限公司 Roller type water coating backing-paper-free label printing machine
CN102627039B (en) * 2012-04-10 2014-12-10 上海美声服饰辅料有限公司 Water spray type water coating backing-paper-free label printer
CN102627160B (en) * 2012-04-10 2014-03-26 上海美声服饰辅料有限公司 Automatic water spreading device for bottomless paper label
CN102615999B (en) * 2012-04-10 2015-05-06 上海美声服饰辅料有限公司 Portable printing machine for bottomless paper label
CN102616001B (en) * 2012-04-10 2015-09-16 上海美声服饰辅料有限公司 Conveyer belt is coated with the bottomless paper label printer of water
JP6124995B2 (en) * 2012-04-26 2017-05-10 テイエンセ スイケラフイナデリユ ナムローゼ フェンノートシャップ Adhesive composition
CN102899001B (en) * 2012-10-12 2015-11-11 华南理工大学 A kind of preparation method of water-soluble non-setting adhesive
CN103290723B (en) * 2013-05-06 2015-08-19 青州金青云新材料有限公司 The back of the body of a kind of beer label aluminized paper, aluminized paper is coated with rewetting coating and productive method of aluminized paper
CN104908447B (en) * 2015-06-09 2017-04-19 上海美声服饰辅料有限公司 Backing-paper-free label printing machine
CN104842664B (en) * 2015-06-09 2017-07-04 上海美声服饰辅料有限公司 A kind of unpowered upper water printing machine for bottomless paper label
DE102015223398A1 (en) * 2015-11-26 2017-06-01 Krones Aktiengesellschaft Labeling process for containers

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE504476C (en) * 1930-08-05 Schaeffler Maschinenfabrik Geb Labeling machine for bottles or the like.
EP0159286A2 (en) * 1984-04-17 1985-10-23 Töpfer Kulmbach GmbH Label and procedure and device for fastening a label and procedure and device for taking off a label
DE8703630U1 (en) * 1987-03-11 1987-04-23 Krones Ag Hermann Kronseder Maschinenfabrik, 8402 Neutraubling Gluing device for wrap-around labels
US5321933A (en) * 1992-03-03 1994-06-21 Alfill Getranketechnik Gmbh Method of and apparatus for applying labels to containers
WO1997043744A1 (en) * 1996-05-10 1997-11-20 Nordenia Technologies Gmbh Labels and process for ecologically-sound labelling of plastic containers and removal of labels therefrom

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2137169A (en) * 1936-06-10 1938-11-15 Levey Harold Alvin Medicinal dressing material
SU430144A1 (en) * 1972-02-14 1974-05-30 Э. К. Пийро , Л. В. Тийкма Таллинский политехнический институт METHOD OF MAKING LABELS
US4837285A (en) * 1984-03-27 1989-06-06 Medimatrix Collagen matrix beads for soft tissue repair
GB2273044B (en) * 1992-12-02 1997-04-09 Pacific Chem Co Ltd Medicinal patches for percutaneous administration
JP3619839B2 (en) * 1998-12-08 2005-02-16 独立行政法人 国立印刷局 Glue-coated paper for stamps and method for producing the same
JP2004090275A (en) * 2002-08-29 2004-03-25 Meinan Mach Works Inc Method for bonding remoistening sheet member
JP2004209830A (en) * 2002-12-26 2004-07-29 Shigeki Morimoto Manufacturing method for stretchable leather workpiece
JP2006168355A (en) * 2004-11-18 2006-06-29 Yupo Corp In-mold molded body with label and label for in-mold

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE504476C (en) * 1930-08-05 Schaeffler Maschinenfabrik Geb Labeling machine for bottles or the like.
EP0159286A2 (en) * 1984-04-17 1985-10-23 Töpfer Kulmbach GmbH Label and procedure and device for fastening a label and procedure and device for taking off a label
DE8703630U1 (en) * 1987-03-11 1987-04-23 Krones Ag Hermann Kronseder Maschinenfabrik, 8402 Neutraubling Gluing device for wrap-around labels
US5321933A (en) * 1992-03-03 1994-06-21 Alfill Getranketechnik Gmbh Method of and apparatus for applying labels to containers
WO1997043744A1 (en) * 1996-05-10 1997-11-20 Nordenia Technologies Gmbh Labels and process for ecologically-sound labelling of plastic containers and removal of labels therefrom

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008037764A1 (en) * 2006-09-29 2008-04-03 Kuraray Europe Gmbh Use of water-soluble polyvinyl alcohol as an adhesive for plastic labels
US8142604B2 (en) * 2007-11-26 2012-03-27 Exxonmobil Oil Corporation Labeling method
DE102009059911A1 (en) * 2009-12-21 2011-06-22 INATEC GmbH, 40764 Method and device for labeling containers, labeled container and self-adhesive label therefor, and method and apparatus for producing such a label
WO2011085790A3 (en) * 2009-12-21 2012-09-13 Rwr Patentverwaltung Gbr Method and device for labeling containers, labeled container and self-adhesive label therefor, and method and device for producing such a label
US8939538B2 (en) 2011-08-04 2015-01-27 Nulabel Technologies, Inc. Liner-free label printer with label adhesive activation

Also Published As

Publication number Publication date
ATE381489T1 (en) 2008-01-15
CN101128360A (en) 2008-02-20
ZA200706551B (en) 2010-05-26
ES2298873T3 (en) 2008-05-16
EP1690795B1 (en) 2007-12-19
WO2006084567A1 (en) 2006-08-17
US20080226907A1 (en) 2008-09-18
RU2416826C2 (en) 2011-04-20
SI1690795T1 (en) 2008-06-30
BRPI0606777A2 (en) 2009-12-01
PL1690795T3 (en) 2008-05-30
KR20070101308A (en) 2007-10-16
JP2008533511A (en) 2008-08-21
DE502005002285D1 (en) 2008-01-31
RU2007133713A (en) 2009-03-27
BRPI0606777B1 (en) 2018-06-05
MX2007008915A (en) 2007-12-11

Similar Documents

Publication Publication Date Title
EP1690795B1 (en) Label with a fluid-sensitive adhesive coating, use of such a label, method for automatic application of a label with a fluid-sensitive adhesive coating and method of manufacturing a label paper
DE69837773T2 (en) Process for producing a laminate and articles made therefrom
EP0149135A2 (en) Self-adhesive flat items removable without a trace
EP1522568B1 (en) Adhesive and use thereof
DE69920421T2 (en) ADHESIVE LABEL AND PLASTIC VESSEL WITH ADHESIVE LABEL
WO2007077036A1 (en) Method for applying a label and labelling installation
DE29708409U1 (en) Stick-on label section
DE4211510A1 (en) Recyclable, printable adhesive tape for packaging - has sized sodium kraft paper substrate, water-sensitive silicone-free release coat and opt. a soft primer on the other side etc.
EP0825298B1 (en) Method of simultaneously coating the upper and lower sides of a paper substrate
AU599945B2 (en) Process for imparting a surface coating to films
AT248858B (en) Method and device for the continuous production of individual cardboard blanks with a smooth, glossy coating
EP0860489A2 (en) Repulpable adhesive tape
EP1742846B1 (en) Method and installation for applying bubble- and inclusion-free film labels
DE1594221A1 (en) Adhesive film and process for the production thereof
EP2516279A2 (en) Method and device for labeling containers, labeled container and self-adhesive label therefor, and method and device for producing such a label
DE60103971T2 (en) Method for sticking plastic labels to water-repellent containers by means of water-based label applicators
DE19634022C2 (en) Use of water-activatable adhesives for labeling plastic containers, and methods for labeling them
DE102006043494A1 (en) Release agent for facilitating the removal of sections of sheet material, e.g. wallpaper, from a substrate by cohesive rupture of an adhesive comprises ammonium strearate
DE3504164A1 (en) Process and apparatus for equipping vessels or the like with labels
DE29824883U1 (en) Paper and film laminate for the graphics and packaging industries comprises a hot melt adhesive between a synthetic film and a paper or card layer which may be printed
EP2794283A1 (en) Method for producing a print carrier
DE10351252A1 (en) Aqueous adhesive for temporary adhesion of laminate pieces, e.g. labels or wallpaper, to substrates, containing cleaving agent, preferably metal soap, to allow subsequent remove of laminate without tearing
WO2008037764A1 (en) Use of water-soluble polyvinyl alcohol as an adhesive for plastic labels
DE1569879C (en)
EP3284582B1 (en) Method of manufacturing a plastic collapsible tube with a label

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA HR LV MK YU

17P Request for examination filed

Effective date: 20070212

AKX Designation fees paid

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

17Q First examination report despatched

Effective date: 20070419

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REF Corresponds to:

Ref document number: 502005002285

Country of ref document: DE

Date of ref document: 20080131

Kind code of ref document: P

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: ISLER & PEDRAZZINI AG

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20080327

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2298873

Country of ref document: ES

Kind code of ref document: T3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20071219

REG Reference to a national code

Ref country code: PL

Ref legal event code: T3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080419

ET Fr: translation filed
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20071219

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20071219

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080519

REG Reference to a national code

Ref country code: IE

Ref legal event code: FD4D

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20071219

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080228

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20071219

26N No opposition filed

Effective date: 20080922

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080320

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20071219

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080319

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LU

Payment date: 20090216

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CZ

Payment date: 20090204

Year of fee payment: 5

Ref country code: NL

Payment date: 20090217

Year of fee payment: 5

Ref country code: PL

Payment date: 20090126

Year of fee payment: 5

Ref country code: SI

Payment date: 20090202

Year of fee payment: 5

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20071219

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20090408

Year of fee payment: 5

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20080620

BERE Be: lapsed

Owner name: PAPIERFABRIKEN CHAM-TENERO A.G.

Effective date: 20100228

REG Reference to a national code

Ref country code: NL

Ref legal event code: V1

Effective date: 20100901

REG Reference to a national code

Ref country code: SI

Ref legal event code: KO00

Effective date: 20100917

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100209

Ref country code: SI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100210

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100901

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100228

REG Reference to a national code

Ref country code: PL

Ref legal event code: LAPE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100209

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100209

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 12

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 13

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20190320

Year of fee payment: 15

Ref country code: GB

Payment date: 20190218

Year of fee payment: 15

Ref country code: IT

Payment date: 20190225

Year of fee payment: 15

Ref country code: FI

Payment date: 20190219

Year of fee payment: 15

Ref country code: CH

Payment date: 20190218

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: TR

Payment date: 20190204

Year of fee payment: 15

Ref country code: SE

Payment date: 20190218

Year of fee payment: 15

Ref country code: FR

Payment date: 20190218

Year of fee payment: 15

Ref country code: AT

Payment date: 20190219

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20190424

Year of fee payment: 15

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 502005002285

Country of ref document: DE

REG Reference to a national code

Ref country code: FI

Ref legal event code: MAE

REG Reference to a national code

Ref country code: SE

Ref legal event code: EUG

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 381489

Country of ref document: AT

Kind code of ref document: T

Effective date: 20200209

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20200209

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200209

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200210

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200209

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200229

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200229

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200209

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200229

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200901

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20210705

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200210

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200209

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200209