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EP1642961A1 - Wasch- und Reinigungsmitteltabletten - Google Patents

Wasch- und Reinigungsmitteltabletten Download PDF

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Publication number
EP1642961A1
EP1642961A1 EP05077208A EP05077208A EP1642961A1 EP 1642961 A1 EP1642961 A1 EP 1642961A1 EP 05077208 A EP05077208 A EP 05077208A EP 05077208 A EP05077208 A EP 05077208A EP 1642961 A1 EP1642961 A1 EP 1642961A1
Authority
EP
European Patent Office
Prior art keywords
solid
semi
surfactant
tablet
solid region
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05077208A
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English (en)
French (fr)
Inventor
Lubertus Henricus Torn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Priority to EP05077208A priority Critical patent/EP1642961A1/de
Publication of EP1642961A1 publication Critical patent/EP1642961A1/de
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0078—Multilayered tablets

Definitions

  • This invention relates to detergent compositions in the form of shaped bodies, usually referred to as tablets, which are suitable for use in laundry washing, conditioning or softening treatment and/or in automatic dishwashing, which include a solid tablet body and a semi-solid region wherein the majority of surfactant is included.
  • Detergent compositions in dishwashing will generally contain a surfactant to be active in the cleaning process.
  • the surfactant generally contributes to soil removal and stabilisation of especially oily soil in the wash water.
  • the surfactants may adsorb on the surface of objects to be cleaned which contributes to improved rinsing and drying.
  • Detergents in tablet form have advantages over powdered products in that they do not require measuring and are thus easier to handle and dispense into the washload.
  • Tablets of a cleaning composition are generally made by compressing or compacting a quantity of the composition in particulate form.
  • surfactant is present in the tablet detergent composition it will act mostly in the cleaning phase as soon as the tablet has disintegrated leading to release of the surfactant.
  • the surfactant For specific functionality of the surfactant, especially reduction of filming and spotting after and during the rinse phase, it is desired to control the release of surfactant from the detergent composition, especially from a detergent composition in tablet form.
  • WO-A-03/006592 it is desired that the surfactant survives the washing cycle and is predominantly released in the rinse cycle.
  • this is solved by including surfactant in an enclosure that is adapted to be capable of delaying the release of its contents until when or after the temperature in the dishwashing process has reached the cloud point of said surfactant.
  • the invention provides a detergent composition in the form of a tablet, which includes a semi-solid region and a solid tablet body, wherein the detergent composition comprises surfactant in an amount of from 2 to 8 wt%, and wherein 50 to 100 wt% of the surfactant is present in the semi-solid region and wherein the level of surfactant is from 20 to 49 wt% in the semi-solid region.
  • the detergent composition according to the invention is in the form of a tablet comprising at least a semi-solid region and a solid tablet body.
  • This extent of release of surfactant into an aqueous medium from the detergent composition may be determined by generally known chromatographic analysis.
  • the majority of surfactant is present in the semi-solid region.
  • the preferred amount of surfactant in the solid tablet body is from 10 to 40 wt% on total weight of the surfactant.
  • the amount of surfactant present in the semi-solid region is from 60 to 80 wt% on total surfactant.
  • the total amount of surfactant in the detergent composition from 2 to 8 wt% on total detergent weight.
  • the semi-solid region includes surfactants at a level of 30 to 49 wt% based on the weight of the semi-solid region, more preferred 35 to 45 wt%.
  • the level of surfactants in the tablet body is less than 10 wt% (based on the total weight of the tablet body), more preferably from 0.1 to 5 wt%, most preferably from 0.5 to 2 wt% on total weight of the tablet body.
  • Suitable surfactants are preferably selected from nonionic surfactants and anionic surfactants. Optionally some cationic surfactant is present but this is not preferred for machine dishwash applications.
  • the surfactant is a nonionic surfactant.
  • all the above weight ranges apply to the nonionic surfactant.
  • Suitable nonionic surfactant compounds which may be used include in particular the reaction products of compounds having a hydrophobic group and a reactive hydrogen atom, for example, aliphatic alcohols, acids, amides or alkyl phenols with alkylene oxides, especially ethylene oxide.
  • Nonionic surfactant compounds are alkyl (C 8-22 ) phenol-ethylene oxide condensates, the condensation products of linear or branched aliphatic C 8-20 primary or secondary alcohols with ethylene oxide, and products made by condensation of ethylene oxide with the reaction products of propylene oxide and ethylene-diamine.
  • the primary and secondary alcohol ethoxylates especially the C 9-11 . and C 12-15 primary and secondary alcohols ethoxylated with an average of from 5 to 20 moles of ethylene oxide per mole of alcohol.
  • Preferred non-ionic surfactants for use in machine dishwashing tablets are low to non-foaming nonionic surfactants containing ethylene oxide and/or propylene oxide residues.
  • suitable low to non-foaming ethoxylated straight-chain alcohols which are preferred nonionic surfactants in machine dishwashing are the Plurafac LF series ex BASF, the Synperonic series ex ICI; the Lutensol® LF series, ex BASF, and the Triton® DF series, ex Rohm & Haas.
  • end-capped ethoxylated alcohols available as the SLF 18B series from Olin.
  • the dehypon® surfactants ex Cognis are also examples of suitable surfactants.
  • the composition comprises anionic surfactant.
  • Synthetic (i.e. non-soap) anionic surfactants are well known to those skilled in the art.
  • Preferred examples include alkylbenzene sulphonates, particularly sodium linear alkylbenzene sulphonates having an alkyl chain length of C 8 -C 15 ; olefin sulphonates; alkyl ether sulphates; fatty acids of isethionates; alkane sulphonates; dialkyl sulphosuccinates; fatty acid ester sulphonates, and primary alkyl sulphates having an alkyl chain length of C 8-18 .
  • the semi-solid region of the tablet is preferably a separate layer of the tablet.
  • the region could also have other forms, such as a core or insert.
  • the semi-solid region is preferably a single discrete part of the tablet but may also be a limited number (for example say 1 to 5) discrete semi-solid parts.
  • each of these semi-solid parts are at least 1 gram, also preferably each of these semi-solid parts is substantially of the same composition. If reference is made to the composition or weight of the semi-solid region it is understood that this concerns the total weight and composition of these semi-solid parts.
  • compositions which are one the one hand solid enough to retain their shape at ambient temperature but which are not completely solid.
  • a suitable test to check if a composition can be considered as semi-solid is described and illustrated in WO03/104380.
  • a cylindrical tablet of the composition to be tested with a diameter of 45 mm and a height of 20 mm is compressed radially between the plates of a material testing machine until the tablet fractures.
  • the plates contact the tablet but do not apply force to it.
  • Force is applied to compress the tablet, with the vertical speed of the upper plate being 25 mm/minute.
  • the testing machine measures the applied force (F), and also the displacement (x) of the plates towards each other as the tablet is compressed.
  • the distance (y) between the plates before force is applied which is the diameter of the tablet, is also known.
  • the tablet cracks and the applied force needed to maintain the displacement drops. Measurement is discontinued when the applied force needed to maintain the displacement has dropped by 25% from its maximum value.
  • the maximum force is the force at failure (F f ).
  • Semi-solid compositions are characterised by a ratio of F f to E b of less than 1.0, more preferably from 0.1 to 0.9, most preferably from 0.2 to 0.6, while traditional tablets of compacted particulate materials are generally characterised by a ratio of F f to E b of more than 1, more generally more than 1.25, or even more than 1.5, up to for example 6.
  • the semi-solid region preferably also comprises a soap, more preferred at a level of 2 to 10 wt% based on the weight of the semi-solid region. It was found that the inclusion of soap is preferred to further delay the release of non-ionic surfactant from the semi-solid region.
  • the soap may act as a structurant, forming a network wherein surfactant is present.
  • the preferred amount of soap in the semi-solid region is from 4 to 7 wt%.
  • Any suitable soap may be used, including synthetic soaps, but neutralised fatty acids are highly preferred. The latter were found to lead to desired fine networks that may contribute to the delayed release of surfactant.
  • the soap is a (partially) hardened fatty acid soap.
  • Preferred soaps have an iodine value of less than 10, preferably less than 5, more preferred less than 3.
  • the fatty acid chain length is preferably from 16 to 18 carbon atoms.
  • the soaps may be neutralised by any common base such as inorganic base e.g. sodium or potassium hydroxide or organic base.
  • the preferred soaps are sodium soaps derived from naturally occurring fatty acids, for example, the fatty acids from coconut oil, beef tallow, sunflower or hardened rapeseed oil.
  • the semi-solid region of the tablet comprises diluent materials such as polyethyleneglycol or (mono-) or (di-) propyleneglycol.
  • Di-propyleneglycol is a preferred diluent material.
  • the level of these diluents is from 10 to 70 wt %, more preferably from 15 to 60 wt%, most preferably from 40 to 55 wt% based on the weight of the semi-solid region.
  • the semi-solid region preferably comprises no or only low levels of water.
  • the level of water is less than 20 wt% based on the weight of the semi-solid region, more preferably less than 15 wt%, most preferably from 2 to 10 wt%.
  • the tablet body according to the invention is a solid which can, for example, be prepared by compression or melting.
  • the tablet body is a compacted particulate composition.
  • the solid tablet body is preferably a single discrete part of the tablet but may also be composed of a limited number (for example 1 to 5) of solid parts, such as separate layers in the tablet.
  • each of these solid parts has a weight of at least 8 grams, also preferably each of these solid parts are substantially of the same composition. If reference is made to the composition or weight of the solid tablet body it is understood that this concerns the total weight and composition of these solid parts.
  • the solid tablet body preferably comprises ingredients of the tablet other than surfactants.
  • these ingredients are builders, bleach systems, enzymes etc.
  • the builders in the tablet are predominantly present in the solid tablet body.
  • the bleach system is predominantly present in the solid tablet body.
  • the enzymes are predominantly present in the solid tablet body.
  • the term "predominantly present” refers to a situation in which at least 90 wt% of an ingredient is present in the solid tablet body, more preferably more than 95 wt%, most preferably more than 98 wt%.
  • the detergent composition comprises a barrier layer between the solid tablet body and the semi-solid region.
  • the barrier layer is formed from a hydrated polymeric material interposed between the semi-solid region and the solid tablet body.
  • Suitable polymeric materials for forming the barrier layer should meet a number of functional requirements, such as good water-solubility, coherent film formation and good adhesion to the semi-solid region and the solid tablet body.
  • Organic polymeric materials are preferred.
  • suitable organic polymeric materials include homopolymers and copolymers of vinyl alcohol, homopolymers and copolymers of vinylpyrrolidone, polyethylene glycols, sulfophenol methallyl ether and sodium methallyl sulfonate, and polycarboxylate polymers.
  • Preferred organic polymeric materials are polycarboxylate polymers.
  • Polycarboxylate polymers suitable for forming the barrier layer according to the invention are preferably polymers of unsaturated monocarboxylic acids and/or unsaturated dicarboxylic acids.
  • Suitable monocarboxylic monomers include acrylic, methacrylic, vinylacetic, and crotonic acids; suitable dicarboxylic monomers include maleic, fumaric, itaconic, mesaconic and citraconic acids and their anhydrides.
  • the polymers may also contain units derived from non-carboxylic monomers, preferably in minor amounts.
  • Suitable polymers are sulphonated terpolymers of acrylic acid, methyl methacrylate and hydrophobically modified polyacrylates.
  • Polycarboxylate polymers suitable for forming the barrier layer according to the invention generally have a weight average molecular weight from about 1,000 to about 400,000 Daltons.
  • homopolymers of acrylic acid and copolymers of acrylic and maleic acids are particularly preferred.
  • Commercially available examples of such materials are the acrylic/maleic copolymers available from BASF as the Sokalan (Trade Mark) CP series and the polyacrylates available from BASF as the Sokalan® PA Series.
  • Specific examples are Sokalan ® CP5 and preferably Sokalan ® PA 25Cl.
  • the polymers are available as powders and granules.
  • the total weight of barrier layer in a tablet according to the invention will preferably range from 0.1 to 15wt%, preferably from 2 to 10wt%, more preferably from 5 to 8wt% (by total weight of barrier layer based on the total weight of the tablet) .
  • Tablets according to this invention are particularly suitable for laundry or for automatic dishwashing.
  • surfactant is constitutes from 2 to 8wt%, more preferably from 2 to 6 wt% by total weight of surfactant based on the total weight of the tablet composition, and is likely to consist of nonionic surfactant specified above, either alone or in admixture with anionic surfactant.
  • the surfactants are further described above.
  • Tablets according to the invention or regions thereof may contain a so-called builder which serves to remove or sequester calcium and/or magnesium ions in the water.
  • the builder is preferably present in the tablet body to enable quick release of builder. Without wishing to be bound by any theory, it is believed that the delayed release of surfactant, especially nonionic-surfactant, from the semi-solid region in a system where the builder is already present may lead to improved cleaning properties of the detergent composition.
  • the solid tablet body In a most preferred embodiment, from 70 to 100 wt% of the total builder is present in the solid tablet body.
  • the amount of it generally ranges from 5 to 80wt%, more likely from 15 to 80wt% by total weight of detergency builder based on the total weight of the tablet composition.
  • Non-phosphorus water-soluble water-softening builders may be organic or inorganic.
  • Inorganics that may be present include zeolites, layered silicates, alkali metal (generally sodium) carbonate; while organics include polycarboxylate polymers, such as polyacrylates, acrylic/maleic copolymers, and acrylic phosphonates, monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono- di- and trisuccinates, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates, nitrilotriacetates and hydroxyethyliminodiacetates.
  • Tablet compositions preferably include polycarboxylate polymers, more especially polyacrylates and acrylic/maleic copolymers which have some function as water-softening agents and also inhibit unwanted deposition onto fabric from a laundry wash liquor or onto glass from an automatic dishwash liquor.
  • the category of water-soluble phosphorus-containing inorganic builders includes the alkali-metal orthophosphates, metaphosphates, pyrophosphates and polyphosphates.
  • Specific examples of inorganic phosphate detergency builders include sodium and potassium tripolyphosphates, orthophosphates and hexametaphosphates.
  • Sodium tripolyphosphate is a preferred phosphorus-containing builder for automatic dishwashing tablets. This exists in hydrated, anhydrous or partially hydrated form, and mixtures of these forms may be used to regulate the speed of tablet disintegration and dissolution.
  • Preferred water-softening builders are sodium tripolyphosphate, sodium citrate, sodium carbonate and sodium silicate.
  • the detergent composition may also comprise softening materials.
  • softening material is used herein for purposes of convenience to refer to materials which provide softening and/or conditioning benefits to fabrics in the wash cycle of a home or automatic laundering machine or in a manual wash process.
  • the compositions preferably comprise from 10 to 95% by weight of softening material (active ingredient), based on the total weight of the composition, more preferably 15 to 75% by weight, most preferably 20 to 50% by weight, e.g. 22 to 45% by weight.
  • the softening material comprises preferably at least one cationic softening material such as quaternary ammonium fabric softening material.
  • the quaternary ammonium fabric softening material has two C12-28 alkyl or alkenyl groups connected to the nitrogen head group, preferably via at least one ester link. It is more preferred if the quaternary ammonium material has two ester links present.
  • the average chain length of the alkyl or alkenyl group is at least C14, more preferably at least C16. Most preferably at least half of the chains have a length of C18.
  • alkyl or alkenyl chains are predominantly linear.
  • Especially preferred materials are di-alkenyl esters of triethanol ammonium methyl sulphate and N-N-di(tallowoyloxy ethyl) N,N-dimethyl ammonium chloride.
  • Commercial examples include Tetranyl AHT-1 (di-hardened oleic ester of triethanol ammonium methyl sulphate 80% active), AT-1(di-oleic ester of triethanol ammonium methyl sulphate 90% active), L5/90 (palm ester of triethanol ammonium methyl sulphate 90% active), all ex KaoTM.
  • unsaturated quaternary ammonium materials include RewoquatTM WE15 (C10-C20 and C16-C18 unsaturated fatty acid reaction products with triethanolamine dimethyl sulphate quaternised 90 % active), ex WitcoTM Corporation.
  • compositions include 1,2 bis[tallowoyloxy]-3-trimethylammonium propane chloride and 1,2-bis[oleyloxy]-3-trimethylammonium propane chloride, the method of preparation thereof are, for example, described in US 4137180 (Lever Brothers) of which the contents are incorporated herein.
  • these materials also comprise small amounts of the corresponding monoester, as described in US 4137180.
  • the composition When the detergent composition is to be used as a solid rinse conditioner, the composition may be as described in WO03/083027.
  • suitable solid rinse conditioners are described in EP-A-0 234 082, EP-A-0 111 074, EP-A-0 111 074, WO 92/18593, EP-B1-0 568 297, US-A-5 259 964, EP-A-0 107 479 (Unilever), EP-A-0 267 999 (Unilever), JP-A-06 306 769, JP-A-62 057 639 (Lion), JP-A-02 182 972, US-A-4 814 095, GB-A-2 348 435.
  • Another class of softening materials are fabric softening clays.
  • Such clays include the montmorillonite- containing clays which have swelling properties (in water) and which are of smectite structure.
  • the best of the smectite clays for use in the present invention is bentonite and the best of the bentonites are those which have a substantial swelling capability in water, such as the sodium and potassium bentonites.
  • Such swelling bentonites are also known as western or Wyoming bentonites, which are essentially sodium bentonite.
  • Other bentonites, such as calcium bentonite are normally non-swelling and usually are, in themselves, unacceptable as fabric softening agents.
  • non-swelling bentonites exhibit even better fabric softening in combination with organic fatty softener materials than do the swelling bentonites, provided that there is present in the softening composition, a source of alkali metal or other solubilising ion, such as sodium (which may come from sodium hydroxide, added to the composition, or from sodium salts, such as builders and fillers, which may be functional components of the composition).
  • a source of alkali metal or other solubilising ion such as sodium (which may come from sodium hydroxide, added to the composition, or from sodium salts, such as builders and fillers, which may be functional components of the composition).
  • a source of alkali metal or other solubilising ion such as sodium (which may come from sodium hydroxide, added to the composition, or from sodium salts, such as builders and fillers, which may be functional components of the composition).
  • sodium which may come from sodium hydroxide, added to the composition, or from sodium salts, such as builders and fillers, which may be
  • the bentonites employed may be produced in the United States of America, such as Wyoming bentonite, but also may be obtained from Europe, including Italy and Spain, as calcium bentonite, which may be converted to sodium bentonite by treatment with sodium carbonate, or may be employed as calcium bentonite.
  • other montmorillonite-containing smectite clays of properties like those of the bentonites described may be substituted in whole or in part for the bentonites described herein and similar fabric softening results will be obtained.
  • the swellable bentonites and similarly operative clays are of ultimate particle sizes in the micron range, e.g., 0.01 to 20 microns and of actual particle sizes in the range of No's. 100 to 400 sieves, preferably 140 to 325 sieves, U.S. Sieve Series.
  • the bentonite and other such suitable swellable clays may be agglomerated to larger particle sizes too, such as 60 to 120 sieves, but such agglomerates are not preferred unless they include the organic fatty softener materials too (in any particulate products).
  • the initial bentonite starting material is selected to have relatively low gelling and swelling properties.
  • the starting material bentonite is selected to have the following initial properties: (a) a montmorillonite content of at least 85%; and (b) when the bentonite is activated with sodium ions, dried and ground to particles, the ground particles do not swell more than about 2.5 fold over a period of 24 hours when added to deionized water at room temperature.
  • the ground particles of bentonite for purposes of determining swelling herein are particles at least 90% of equal to or less than about 75 microns in diameter.
  • a main component which may be used in combination with the fabric softening clay is an organic fatty softener.
  • the organic softener can be anionic, cationic or nonionic fatty chains (C 10 -C 22 preferably C 12 -C 18 )
  • Anionic softeners include fatty acids soaps.
  • Preferred organic softeners are nonionics such as fatty esters, ethoxylated fatty esters, fatty alcohols and polyols polymers.
  • the organic softener is most preferably a higher fatty acid ester of a pentaerythritol compound, which term is used in this specification to describe higher fatty acid esters of pentaerythritol, higher fatty acid esters of pentaerythritol oligomers, higher fatty acid esters of lower alkylene oxide derivatives of pentaerythritol and higher fatty acid esters of lower alkylene oxide derivatives of pentaerythritol oligomers.
  • Pentaerythritol compound abbreviated as PEC herein, which description and abbreviation may apply to any or all of pentaerythritol, oligomers, thereof and alkoxylated derivatives thereof, as such, or more preferably and more usually, as the esters, as may be indicated by the context.
  • the oligomers of pentaerythritol are preferably those of two to five pentaerythritol moieties, more preferably 2 or 3, with such moieties being joined together through etheric bonds.
  • the lower alkylene oxide derivatives thereof are preferably of ethylene oxide or propylene oxide monomers, dimers or polymers, which terminate in hydroxyls and are joined to the pentaerythritol or oligomer of pentaerythritol through etheric linkages.
  • At least one of the PEC OH groups and preferably at least two, e.g., 1 or 2 to 4 are esterified by a higher fatty acid or other higher aliphatic acid, which can be of an odd number of carbon atoms.
  • the higher fatty acid esters of the pentaerythritol compounds are preferably partial esters. And more preferably there will be at least two free hydroxyls thereon after esterification (on the pentaerythritol, oligomer or alkoxyalkane groups). Frequently, the number of such free hydroxyls is two or about two but sometimes it may by one, as in pentaerythritol tristearate.
  • the higher aliphatic or fatty acids that may be employed as esterifying acids are those of carbon atom contents in the range of 8 to 24, preferably 12 to 22 and more preferably 12 to 18, e.g., lauric, myristic, palmitic, oleic, stearic and behenic acids.
  • Such may be mixtures of such fatty acids, obtained from natural sources, such as tallow or coconut oil, or from such natural air materials that have been hydrogenated. Synthetic acids of odd or even numbers of carbon atoms may also be employed. Of the fatty acids lauric and stearic acids are often preferred, and such preference may depend on the pentaerythritol compound being esterified.
  • Suitable detergent compositions containing clay include those described in US-A 6 291 421 and US-A- 6 670 320.
  • Tablets according to the invention may contain bleach activators, also referred to as bleach precursors.
  • bleach precursors include peracetic acid precursors, for example, tetraacetylethylene diamine (TAED), and perbenzoic acid precursors.
  • TAED tetraacetylethylene diamine
  • the quaternary ammonium and phosphonium bleach activators disclosed in US 4751015 and US 4818426 (Lever Brothers Company) are also of interest.
  • Another type of bleach activator which may be used, but which is not a bleach precursor is a transition metal catalyst as disclosed in EP-A-458397, EP-A-458398 and EP-A-549272.
  • a bleach stabiliser (heavy metal sequestrant) may also be present such as ethylenediamine tetramethylene phosphonate and diethylenetriamine pentamethylene phosphonate.
  • Tablets according to the invention may contain one of the detergency enzymes well known in the art for their ability to degrade and aid in the removal of various soils and stains.
  • Suitable enzymes for fabrics include the various proteases, cellulases, lipases, amylases, and mixtures thereof, which are designed to remove a variety of soils and stains from fabrics.
  • suitable proteases are Maxatase (Trade Mark), as supplied by Genencor, and Alcalase (Trade Mark), and Savinase (Trade Mark), as supplied by Novo Industri A/S, Copenhagen, Denmark.
  • Enzymes for dish washing are lipases, amylases and proteases.
  • the enzymes most commonly used in machine dishwashing compositions are amylolytic enzymes.
  • the composition also contains a proteolytic enzyme. Examples of suitable enzymes are Duramyl® and Theramyl® ex Novozymes.
  • Detergency enzymes are commonly employed in the form of granules, optionally with a protective coating, in an amount generally ranging from 0.1 to 5.0wt% by total weight of enzyme based on the total weight of the tablet composition.
  • a chelating agent for metal ions may be present in the composition. If present it is preferable that the level of chelating agent is from 0.5 to 3wt% by total weight of chelating agent based on the total weight of the tablet composition. It can function to stabilise bleach against premature decomposition catalysed by transition metals and/or to inhibit calcium carbonate scale formation.
  • Preferred chelating agents include organic phosphonates, amino carboxylates, polyfunctionally-substituted compounds, and mixtures thereof.
  • Particularly preferred chelating agents are organic phosphonates such as ⁇ -hydroxy-2 phenyl ethyl diphosphonate, ethylene diphosphonate, hydroxy 1,1-hexylidene, vinylidene 1,1 diphosphonate, 1,2 dihydroxyethane 1,1 diphosphonate and hydroxy-ethylene 1,1 diphosphonate. Most preferred is hydroxy-ethylene 1,1 diphosphonate, 2 phosphono-1,2,4 butanetricarboxylic acid or salts thereof.
  • Fabric washing tablets may include fabric softeners and/or anti-redeposition agents such as linear sodium carboxymethylcellulose, straight-chain polyvinyl pyrrolidone and the cellulose ethers such as methyl cellulose and ethyl hydroxyethyl cellulose.
  • Machine dishwashing tablets may include polymers to inhibit filming and polymers to inhibit spotting on glassware.
  • the invention in a most preferred embodiment relates to a detergent composition in the form of a tablet, which includes a semi-solid region and a solid tablet body, wherein the detergent composition comprises nonionic surfactant, and wherein 50 to 100 wt% of the nonionic surfactant is present in the semi-solid region and wherein the tablet is further characterised in that the total amount of non-ionic surfactant is from 2 to 8 wt% on total weight of the detergent composition, and the semi-solid region comprises from 30 to 49 wt% of nonionic surfactant on the weight of that region and further from 4 to 7 wt% of a soap on the weight of the semi-solid region.
  • compositions preferably comprise a barrier layer as described above.
  • this invention provides a method of making a detergent composition in the form of a tablet, (i.e. shaped body), in which the tablet includes a semi-solid region and a solid tablet body.
  • Tablets according to the invention are preferably manufactured by a process comprising the steps of:
  • Steps (a) and (b) can be in any order, although preferably the particulate composition is first introduced into the tablet mould, followed by positioning of the admixture of polymeric material and hydrated salt in the mould.
  • the particulate composition is flattened or pre-compressed before introducing the admixture of polymeric material and hydrated salt (step (b)).
  • the particulate composition is pre-compressed at a force of 0.01 to 5 kN/cm 2 before introducing the admixture of polymeric material and hydrated salt.
  • the co-compression in step (c) takes place at a force of from 0.1 to 20 kN/cm 2 .
  • the co- compression in step (c) can advantageously be at a force of 0.01 to 10 kN/cm 2 , more preferably 2 to 8 kN/cm 2 .
  • the semi-solid region in step (d) may be prepared by mixing of its constituent ingredients.
  • the pressure for preparing the semi-solid region may range from 0 to 5 kN/cm 2 , preferably from 0.01 to 5 kN/cm 2 .
  • the application of the semi-solid region in step (d) may take place by spraying or under the application of a co-compression force. Such co-compression may suitably take place at a force of from 0.1 to 20 kN/cm 2 .
  • Tabletting machinery able to carry out the manufacture of tablets of the invention is known, for example suitable tablet presses are available from Carver and from Korsch.
  • the size of a tablet will suitably range from 8 to 160 grams, preferably from 10g to 60g, depending on the conditions of intended use.
  • the tablets may be of any shape such as rectangular, cubic or cylindrical. However, for ease of packaging they are preferably blocks of substantially uniform cross-section, such as cylinders, shapes or cuboids.
  • the overall density of a tablet for fabric washing preferably lies in a range from 1040 or 1050gm/litre preferably at least 1100gm/litre up to 1400gm/litre.
  • the tablet density may well lie in a range up to no more than 1350 or even 1250gm/litre.
  • the overall density of a tablet for machine dishwashing or as a bleaching additive may range up to 1700gm/litre and will often lie in a range from 1300 to 1550gm/litre.
  • a powder composition having the ingredients as shown in Table 1 below was prepared and pre-compressed at a pressure of 0.25 kN/cm 2 on a Carver Laboratory press, to form about 20 gram tablets.
  • Table 1 Ingredient wt% Sodium tripolyphosphate 69.5 Sodium Carbonate 3.0 Non-ionic surfactant (SLF 18B, ex Olin ) 1.5 Oxygen bleach 15.0 Sulfonated copolymer 3.5 Bleach activator 2.5 Protease 2.5 Amylase 0.9 Bleach catalyst 1.0 Diphosphonate 1.0 Perfume, Dye 0.1 Total: 100.0
  • the semi-solid composition having the ingredients as shown in Table 2 below was prepared by mixing, heating the mixture to 80°C and spraying into moulds on top of the solid tablet body.
  • Table 2 Ingredient Parts by weight Nonionic surfactant 40 Tallow soap (neutralised by NaOH) 6 Di-propyleneglycol 48 Water to 100

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
EP05077208A 2004-10-01 2005-09-26 Wasch- und Reinigungsmitteltabletten Withdrawn EP1642961A1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP05077208A EP1642961A1 (de) 2004-10-01 2005-09-26 Wasch- und Reinigungsmitteltabletten

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP04077705 2004-10-01
EP04077999 2004-11-01
EP05077208A EP1642961A1 (de) 2004-10-01 2005-09-26 Wasch- und Reinigungsmitteltabletten

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3325591B1 (de) 2015-07-23 2020-09-02 Henkel AG & Co. KGaA Mehrphasiges geschirrspülmittel umfassend einen tensid-kern

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999027067A1 (en) * 1997-11-26 1999-06-03 The Procter & Gamble Company Detergent tablet
WO2000004122A1 (de) * 1998-07-15 2000-01-27 Henkel Kommanditgesellschaft Auf Aktien Verfahren zur herstellung mehrphasiger wasch- und reinigungsmittelformkörper
EP1134281A1 (de) * 1997-08-02 2001-09-19 The Procter & Gamble Company Waschmitteltablette
WO2003104380A1 (en) * 2002-06-11 2003-12-18 Unilever N.V. Detergent tablets

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1134281A1 (de) * 1997-08-02 2001-09-19 The Procter & Gamble Company Waschmitteltablette
WO1999027067A1 (en) * 1997-11-26 1999-06-03 The Procter & Gamble Company Detergent tablet
WO2000004122A1 (de) * 1998-07-15 2000-01-27 Henkel Kommanditgesellschaft Auf Aktien Verfahren zur herstellung mehrphasiger wasch- und reinigungsmittelformkörper
WO2003104380A1 (en) * 2002-06-11 2003-12-18 Unilever N.V. Detergent tablets

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3325591B1 (de) 2015-07-23 2020-09-02 Henkel AG & Co. KGaA Mehrphasiges geschirrspülmittel umfassend einen tensid-kern

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