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EP1228185A1 - Detergents liquides non aqueux comprenant des particules basse densite solubles dans l'eau - Google Patents

Detergents liquides non aqueux comprenant des particules basse densite solubles dans l'eau

Info

Publication number
EP1228185A1
EP1228185A1 EP00952617A EP00952617A EP1228185A1 EP 1228185 A1 EP1228185 A1 EP 1228185A1 EP 00952617 A EP00952617 A EP 00952617A EP 00952617 A EP00952617 A EP 00952617A EP 1228185 A1 EP1228185 A1 EP 1228185A1
Authority
EP
European Patent Office
Prior art keywords
low
density
particles
aqueous
aqueous liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP00952617A
Other languages
German (de)
English (en)
Inventor
Yousef Georges Aouad
Christopher John Lienhart
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of EP1228185A1 publication Critical patent/EP1228185A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents
    • C11D11/02—Preparation in the form of powder by spray drying
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents
    • C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0004—Non aqueous liquid compositions comprising insoluble particles

Definitions

  • This invention relates to liquid laundry detergent products which are non-aqueous in nature and which are in the form of stable dispersions of water-soluble particulate material and preferably also include other materials such as bleaching agents and/or conventional detergent composition adjuvants.
  • Liquid laundry detergent products offer a number of advantages over dry, powdered or particulate laundry detergent products.
  • Liquid laundry detergent products are readily measurable, speedily dissolved in wash water, non-dustmg, are capable of being easily applied in concentrated solutions or dispersions to soiled areas on garments to be laundered and usually occupy less storage space than granular products. Because liquid laundry detergents are usually considered to be more convenient to use than granular laundry detergents, they have found substantial favor with consumers.
  • liquid laundry detergents have a number of advantages over granular laundry detergent products, there are also disadvantages entailed m using them.
  • laundry detergent composition components which may be compatible with each other in granular products may tend to interact or react with each other in a liquid, and especially in an aqueous liquid, environment.
  • Components such as peroxygen bleaches and bleach precursors can be especially difficult to incorporate into liquid laundry detergent products with an acceptable degree of compositional stability.
  • Poor compositional stability may cause some active ingredients to react with each other prematurely in the product which can cause physical instabilities such as phase splitting, sedimentation and solidification. This premature reaction may also cause chemical instabilities which can lead to product discoloration or color change, oxygen gas liberation, oxidation of sensitive ingredients (especially enzymes) and eventually detersive performance loss.
  • Non-aqueous liquid laundry detergent compositions have been disclosed m Hepworth et al., U.S. Patent 4,615,820, Issued October 17, 1986; Schultz et al., U.S. Patent 4,929,380, Issued May 29, 1990; Schultz et al., U.S.
  • detergent ingredients such as builders and alkalinity sources (i.e. buffers) are not generally soluble in most non-aqueous solvents and because these ingredients are typically denser than the liquid matrix of a non-aqueous detergent composition, they have a tendency to separate out of liquid detergent products and form sediments on the bottom of the detergent container between their manufacture and usage by the consumer. This segregation can in turn have an adverse affect on product aesthetics, usage instructions, pourabihty, dispensability, stability and in particularly on the overall cleaning effectiveness.
  • non-aqueous liquid laundry detergent compositions comprising ingredients (e.g. builders, alkalinity sources) which are insoluble in the non-aqueous detergent liquid without the undesirable separation and segregation phenomena discussed above. Accordingly, it is a benefit of the present invention to provide non- aqueous liquid laundry detergent compositions which have excellent cleaning and detersive performance without displaying deleterious separation and segregation phenomena.
  • ingredients e.g. builders, alkalinity sources
  • non-aqueous liquid laundry detergent compositions may contain ingredients which are insoluble in the liquid matrix of the detergent composition, without the undesirable separation and segregation of said insoluble ingredients by including, in addition to the insoluble ingredients, low-density particles which reduce the tendency of the insoluble ingredient particulates to separate out of the laundry detergent composition and sediment to the bottom of the detergent container.
  • the low-density particles themselves are composed of a binding agent as well as one or more ingredients which are insoluble m the non-aqueous liquid matrix.
  • the non-aqueous liquid detergent compositions according to a first aspect of the present invention comprise from about 49% to about 99.95% by weight of the composition of a surfactant-contammg non-aqueous liquid phase; and from about 0.05 % to about 51 % by weight of the composition of a suspended solid particulate phase.
  • the suspended solid particulate phase in particular, comprises low-density particles which are composed of a binding agent and materials selected from the group consisting of an alkalinity source, a chelant, a builder and mixtures thereof.
  • the present invention further encompasses a process for continuously preparing low- density particles comprising the steps of continuously mixing water, water-soluble binder and one or more particle ingredients to form an aqueous solution; and then subsequently drying the solution in a spray-dryer to from low-density particles having a substantially spherical shape and a particle size from about 1 ⁇ m to 120 ⁇ m.
  • the low-density particles of the present invention may also be used as one of the constituent detergent particles of a granular detergent .
  • non-aqueous or “anhydrous” are used synonymously and both describe a fluid in which the water content is less than about 5 %.
  • non-aqueous detergent compositions herein preferably comprise from about 1% to 50% by weight, more preferably from about 29% to 44% by weight, of suspended solid particulate material which is dispersed and suspended within the liquid phase.
  • An essential component of the liquid detergent compositions of the present invention is the inclusion of low-density particles, the particles are dried in such a way that they are completely or partially hollow.
  • the low-density particles reduce the tendency of other solid particulate ingredients to separate out of the laundry detergent composition and form a sediment layer on the bottom of the detergent composition container.
  • the low-density particles are themselves less dense than the surrounding, non-aqueous surfactant-rich liquid matrix; hence they are referred to throughout this application as "low-density particles."
  • a first explanation for the benefits provided by the low-density particles is that they provide a counteracting resistance to the sedimentation of the adjuvant particles As the adjuvant particles flow downward at a rate go ⁇ erned by Stokes' Law they come into physical contact with the low-density particles which impede their further downward movement until the adjuvant particles can migrate around the outer surface of the low-density particles. Thus the low-density particles form an obstacle field which considerably reduces the rate of sedimentation of the adjuvant particles. The detailed path that individual adjuvant particles take through this obstacle field may be calculated using an analysis based on Brownian Motion or Ismg Model calculations.
  • the low-density particles of the present invention are preferably constructed from material which is insoluble in the non-aqueous surfactant-rich liquid phase of the present invention but soluble m pure water.
  • the low-density particles are preferably partially or completely hollow particles formed through the spray-drymg processes desc ⁇ bed below; microspheres are an especially preferred form of the low-density particle.
  • Nonlimitmg examples of such hollow microspheres are commercially available as EXPANCEL® microspheres
  • EXPANCEL® microspheres For further discussion of microspheres, see “Microencapsulation” in Kirk-Othmer Encyclopedia of Chemical Technology, Third Edition, Volume 16, pages 628-651 (John Wiley & Sons, Inc., 1979); and Hollow and Solid Spheres and Microspheres Science and Technology Associated With Their Fabrication and Application, Transactions of the Materials Research Society, Volume 372, Edited by David L Wilcox Sr., et al , (Materials Research Society Press: Greentree, PA, 1995), both of which are hereby incorporated by reference.
  • Such hollow microspheres can be expanded, partially or wholly, to about 5 microns to about 50 microns when they are exposed to sufficient temperatures, such as from about 60-80 °C
  • These microspheres may be expanded prior to the drying step or during the drying step of the present invention.
  • the ingredients from which the low-density particle of the present invention are made include organic and inorganic builder material, alkalinity source material and other particle ingredient components such as polymers, binding agents and chelants For greater clarification, these particle ingredients are set-forth below in more detail B. Coatings for Low-Density Particles
  • Builder material which serves to counteract the effects of calcium, or other ion, water hardness encountered during laundering/bleaching use of the compositions herein can form part of the coating on the low-density coated particles
  • examples of such materials include the alkali metal, citrates, succinates, malonates, fatty acids, carboxymethyl succmates, carboxylates, polycarboxylates and polyacetyl carboxylates.
  • Specific examples include sodium, potassium and lithium salts of oxydisuccmic acid, melhtic acid, benzene polycarboxyhc acids and citric acid.
  • organic phosphonate type sequestering agents such as those which have been sold by Monsanto under the Dequest tradename and alkanehydroxy phosphonates. Citrate salts are highly preferred.
  • Suitable organic builders include the higher molecular weight polymers and copolymers known to have builder properties.
  • such materials include approp ⁇ ate sodium salts of polyacryhc acid, polymaleic acid, and polyacryhc/polymaleic acid copolymers and their salts, such as those sold by BASF under the Sokalan trademark which have molecular weight ranging from about 5,000 to 100,000.
  • These salts may also serve as a desiccant, moisture sink or water scavenger m the non-aqueous liquid detergent compositions herein.
  • Another suitable type of organic builder comprises the water-soluble salts of higher fatty acids, i.e., "soaps.”
  • these include alkali metal soaps such as the sodium, potassium, ammonium, and alkylolammonmm salts of higher fatty acids containing from about 8 to about 24 carbon atoms, and preferably from about 12 to about 18 carbon atoms Soaps can be made by direct sapomfication of fats and oils or by the neutralization of free fatty acids
  • Particularly useful are the sodium and potassium salts of the mixtures of fatty acids derived from coconut oil and tallow, i.e., sodium or potassium tallow and coconut soap
  • Inorganic or P-contammg detergent builders include, but are not limited to, the alkali metal, ammonium and alkanolammomum salts of polyphosphates (exemplified by the tripolyphosphates, pyrophosphates, and glassy polymeric meta-phosphates), phosphonates, phytic acid, silicates, carbonates (including bicarbonates and sesquicarbonates), sulphates, and alummosilicates.
  • non-phosphate builders are required in some locales.
  • compositions herein function surprisingly well even in the presence of the so-called “weak” builders (as compared with phosphates) such as citrate, or in the so-called “underbuilt” situation that may occur with zeolite or layered silicate builders.
  • silicate builders are the alkali metal silicates, particularly those having a S ⁇ 2:Na2 ⁇ ratio in the range 1.6: 1 to 3.2: 1 and layered silicates, such as the layered sodium silicates described m U.S. Patent No. 4,664,839, issued May 12, 1987 to H. P. Rieck NaSKS- 6® is the trademark for a crystalline layered silicate marketed by Hoechst (commonly abbreviated herein as "SKS-6"). Unlike zeolite builders, the Na SKS-6 silicate builder does not contain aluminum NaSKS-6 has the delta-Na2S ⁇ 5 morphology form of layered silicate.
  • SKS-6 is a highly preferred layered silicate for use herein, but other such layered silicates, such as those having the general formula NaMS ⁇ x ⁇ 2 x + ⁇ y ⁇ O wherein M is sodium or hydrogen, x is a number from 1.9 to 4, preferably 2, and y is a number from 0 to 20, preferably 0 can be used herein.
  • Various other layered silicates from Hoechst include NaSKS-5®, NaSKS- 7® and NaSKS-11®, as the alpha, beta and gamma forms.
  • delta-Na2S ⁇ 5 (NaSKS-6 form) is most preferred for use herein.
  • Other silicates may also be useful such as for example magnesium silicate, which can serve as a crispenmg agent in granular formulations, as a stabilizing agent for oxygen bleaches, and as a component of suds control systems.
  • carbonate builders are the alkaline earth and alkali metal carbonates as disclosed m German Patent Application No. 2,321,001 published on November 15, 1973.
  • Alummosi cate builders are useful m the present invention.
  • Alummosihcate builders are of great importance in most currently marketed heavy duty granular detergent compositions, and can also be a significant builder ingredient in liquid detergent formulations.
  • Alummosihcate builders include those having the empirical formula:
  • alummosihcate ion exchange materials are commercially available. These alummosilicates can be crystalline or amorphous in structure and can be naturally-occurring alummosilicates or synthetically derived. A method for producing alummosihcate ion exchange materials is disclosed in U.S. Patent No. 3,985,669, Krummel, et al, issued October 12, 1976. Preferred synthetic crystalline alummosihcate ion exchange materials useful herein are available under the designations Zeolite A, Zeolite P (B), Zeolite MAP and Zeolite X. In an especially preferred embodiment, the crystalline alummosihcate ion exchange material has the formula:
  • the alummosihcate has a particle size of about 0.1-10 microns in diameter.
  • insoluble organic detergent builders can generally comprise from about 1% to 20% by weight of the total non-aqueous liquid detergent compositions herein.
  • a further material which can form part of the coating on the low-density coated particles is a material which serves to render aqueous washing solutions formed from such compositions generally alkaline in nature.
  • Such materials may or may not also act as detergent builders, i.e., as materials which counteract the adverse effect of water hardness on detergency performance.
  • alkalinity sources examples include water-soluble alkali metal carbonates, bicarbonates, borates, silicates and metasihcates.
  • water-soluble phosphate salts may also be utilized as alkalinity sources. These include alkali metal pyrophosphates, orthophosphates, polyphosphates and phosphonates. Of all of these alkalinity sources, alkali metal carbonates such as sodium carbonate are the most preferred.
  • the alkalinity source if in the form of a hydratable salt, may also serve as a desiccant, moisture sink or water scavenger in the non-aqueous liquid detergent compositions herein.
  • the presence of an alkalinity source which is also a desiccant may provide benefits in terms of chemically stabilizing those composition components such as the peroxygen bleaching agent which may be susceptible to deactivation by water.
  • the alkalinity source will generally comprise from about 1% to 25% by weight of the total non-aqueous liquid detergent compositions herein. Such materials, while water-soluble, will generally be insoluble m the non- aqueous detergent compositions herein.
  • the low-density coated particles may also be coated with other particle ingredient components which serve both functionally detersive and structural purposes.
  • a desirable structural ingredient is a water soluble binding agent Alkylene ammomethylene phosphonic acids or water soluble salts thereof which can serve as an binding agent to hold together the coating materials which encapsulate the outer surface of the microsphere.
  • these acids and their corresponding salts can also serve as a chelant which serves to chelate metal ions, e.g., iron and/or manganese, within the detergent compositions herein.
  • Such chelatmg agents thus serve to form complexes with metal impurities m the composition which would otherwise tend to deactivate composition components such as the peroxygen bleaching agent
  • Useful chelatmg agents can include ammo carboxylates, phosphonates, ammo phosphonates, polyfunctionally-substituted aromatic chelatmg agents and mixtures thereof.
  • Ammo carboxylates useful as optional chelatmg agents include ethylenediammetetraacetates, N-hydroxyethyl-ethylenediammetriacetates, nitrilotriacetates, ethylene-diamme tetrapropionates, t ⁇ ethylenetetraammehexacetates, diethylenetriammepentaacetates, ethylenediammedisuccmates and ethanol diglycines.
  • the alkali metal salts of these materials are preferred.
  • Ammo phosphonates are also suitable for use as chelatmg agents in the compositions of this invention when at least low levels of total phosphorus are permitted in detergent compositions, and include ethylenediammetetrakis (methylene-phosphonates) as DEQUEST.
  • these ammo phosphonates do not contain alkyl or alkenyl groups with more than about 6 carbon atoms.
  • Preferred chelatmg agents include hydroxy-ethyldiphosphomc acid (HEDP), diethylene triamme penta acetic acid (DTP A), ethylenediamme disuccmic acid (EDDS) and dipicolinic acid (DP A) and salts thereof.
  • the chelatmg agent may, of course, also act as a detergent builder du ⁇ ng use of the compositions herein for fabric laundering/bleaching.
  • a preferred example of the chelant is Diethylene Triamme Penta Methyl Phosphonic Acid (DTMPA) which is available commercially under the name DEQUEST Grade 2066 from the Monsanto Company.
  • DTMPA Diethylene Triamme Penta Methyl Phosphonic Acid
  • Suitable binding agents include polymeric compounds such as water soluble maleic/acrylic copolymers (particularly a 40% male ⁇ c/60% acrylic blend), water soluble polyacrylates of molecular weights from about 2000 to about 5000 (particularly molecular weights of around 4500)
  • organic polymers such as polyethylene glycol with a molecular weight of between 1000 and 6000 and polyvmylpyrohdone, particularly crosslmked polyvmylpyrohdone such as those sold under the trade name POLYPLASDONE XLTM or KOLLIDON CL TM If utilized as all or part of the suspended particulate solid phase, these other components will generally comprise from about 1% to 25% by weight of the total non-aqueous liquid detergent compositions herein Any of the above desc ⁇ bed materials can also serve as desiccants, moisture sinks or water scavengers when used in the non-aqueous liquid detergent Method Aspect
  • the present invention also provides a method for preparing the low-density particles of the present invention.
  • a method wherein the first step of the process entails continuously mixing and optionally heating an aqueous solution containing the water-soluble binder, as well as one or more particle ingredients in a mixer to form a homogenous solution-slurry is provided
  • particle ingredients will form the shell of the low-density particle which is preferably a spherical hollow particle or hollow microsphere.
  • the particle ingredients are added to the aqueous solution in sufficient amounts so that the final low- density particulate product will comprise from about 1 % to about 95 % of an alkalinity source, from about 1 % to about 95 % of a builder component and from about 1 % to about 95 % of binding agents and other low-density particle ingredient components (e.g. chelants and polymers).
  • the aqueous solution will comprise from about 10% to about 70%, preferably from about 20% to about 60%, more preferably from about 30% to about 50% water.
  • a suitable mixer for this process step is one consisting essentially of a horizontal, hollow static cylinder having a centrally mounted rotating shaft around which several plough-shaped blades are attached
  • An impeller stirrer is particularly suitable.
  • the resulting homogenous aqueous solution-slurry is then fed into the heated chamber of a spray-tower where it is dried to from the low-density particles.
  • the low-density particles are dried in such a way that they are completely or partially hollow (i.e. voids or cavities are formed inside).
  • Completely or partially hollow particles can be formed by one of four separate mechanisms:
  • Air trapped in the solution -slurry contributes to air spaces within the droplet.
  • One or more spray drying techniques in one or more spray-drymg towers may be used to make detergent compositions in accordance with the instant invention and any standard spray drying techniques may be used to execute the processes described herein.
  • Many suitable spray drying techniques and spray drying equipment is discussed in are discussed K. Masters, Spray Drying Handbook 5 th Edition, Longman, New York, which is hereby incorporated by reference. It is preferred that the process be carried out using a rotary-disk atomizer and a co-current flow spray dryer.
  • the inlet temperature of the spray-dryer is from about 200 °C to about 700°C and the outlet temperature is from about 100°C to about 160°C.
  • Pulse drying comprises introducing a substance to be dried, such as the low-density particles of the present invention, into a heated, flowing, drying medium m the presence of acoustic energy to significantly reduce the moisture content of the substance being processed.
  • Nonlimitmg examples of pulse drying processes are desc ⁇ bed in U.S. Pat. No. 4,226,668 issued Oct. 7, 1980 to F. A. Ferguson, U.S. Patent No. 4,859,248 issued August 22, 1989 to Thaler et al., and in "Pulse Combustion Lowers Drying Costs" (Chemical Engmee ⁇ ng, Dec. 10, 1984 pp.
  • a pulse drying process generally comprises a cyclical pattern of detonations, which preferably occur at about 250 times per second, which provide a high energy, broad-band, accoustic wave front. This some energy causes rapid, efficient dispersion of the low-density particles.
  • the sonic waves are thought to "vibrate" each low-density particle, facilitating heat and mass transfer.
  • the hot jet gases used to produce the pulses can reach 1371 °C (2500 °F) in temperature
  • residence time in this turbulent zone is very short, only several milliseconds, so that the actual system temperature of the low-density particles is preferably much lower— about 149 °C (300 °F) maximum. It is the combination of high thermal and sonic energy which disrupts the low-density particles, maximizes surface area, encourages efficient heat transfer, and, thus, provides the physical environment for drying the low-density particles.
  • the low-density microspheres after the expansion and coating ingredient enrobing which the microspheres are subjected, the low-density microspheres have a particle size of from about 1 ⁇ m to about 100 ⁇ m, preferably from about 5 ⁇ m to about 75 ⁇ m
  • the low-density coated particles of the present invention will have a density of less than about 1.6 g/ml, preferably less than about 1.2 g/ml, more preferably less than about 1.0 g/ml. The density is determined by the use of a helium pyncnometer.
  • the low-density particles and the processes for producing them which are disclosed in the present invention can also be used in the manufacture of granular detergent products, particularly for use as a base granule.
  • the use of the low-density particles in a granular detergent offers several advantages, notably narrow particle size and density distribution and an attractive uniform spherical shape
  • the narrow particles size distribution is particularly important because it allows more control over the granular detergent morphology and also increases the efficiency, by reducing the recycling and reprocessing of fines (particulates which are too small to be included in a granular detergent) and overs (particulates which are too large to be included in a granular detergent).
  • the low-density particles When the low-density particles are to be used as a particulate component m the manufacture of a granular detergent composition, then after the low-density particle is formed by the process described above, the particles may be admixed with other detergent particulates to form a granular detergent product.
  • the other detergent components as well as the processes for admixing are all well-known to those skilled in the art.
  • the low-density particles may be made from a variety of granulate ingredients, the granulate ingredients being selected from the group consisting of surfactants, builders, alkalinity sources, binding agents, bleaching agents, bleach activators, suds suppressors, dye -transfer inhibitors and mixtures thereof. Most preferably the low-density particles are made from surfactants and builders. Adiuvant Particulates
  • adjuvant particles refers to all other suspended solid phase particles besides the low-density particles described above.
  • particulate material will range in size from about 0.1 to 1500 microns, more preferably from about 0.1 to 900 microns. Most preferably, such material will range in size from about 5 to 200 microns.
  • these particles While the inclusion of these particles allows the formulator to include important detersive component which increase the efficacy of a detergent formulation, these particles also demonstrate a tendency to separate out from the liquid phase and form a layer of sediment on the bottom of a detergent container.
  • the low-density particles have been included m the present invention to counteract this tendency
  • the adjuvant particulate material utilized herein can comprise one or more types of detergent composition components which in particulate form are substantially insoluble in the non-aqueous liquid phase of the composition.
  • Such materials include peroxygen bleaching agents, bleach activators, organic detergent builders as well as other detergent components Suitable peroxygen bleaching agents, bleach activators and detergent builders are discussed in greater detail in other parts of this application These adjuvant particulates are discussed in greater detail under the heading "Solid Particulate Material” in the copendmg provisional application of Jean-Paul boutique et al., entitled “Detergent Compositions
  • the surfactant-contammg, non-aqueous liquid phase will generally comprise from about 49% to 99.95% by weight of the detergent compositions herein. More preferably, this liquid phase is surfactant-structured and will comprise from about 52% to 98.9% by weight of the compositions. Most preferably, this non-aqueous liquid phase will comprise from about 55% to 70% by weight of the compositions herein.
  • Such a surfactant-contammg liquid phase will frequently have a density of from about 0.6 to 1.4 g/cc, more preferably from about 0.9 to 1.3 g/cc.
  • the liquid phase of the detergent compositions herein is preferably formed from one or more non-aqueous organic diluents into which is mixed a surfactant structuring agent which is preferably a specific type of anionic surfactant-contammg powder, (a) Non-aqueous Organic Diluents
  • the major component of the liquid phase of the detergent compositions herein comp ⁇ ses one or more non-aqueous organic diluents.
  • the non-aqueous organic diluents used m this invention may be either surface active, I e., surfactant, liquids or non-aqueous, non-surfactant liquids referred to herein as non-aqueous solvents.
  • the term "solvent” is used herein to connote the non-surfactant, non-aqueous liquid portion of the compositions herein While some of the essential and or optional components of the compositions herein may actually dissolve m the "solvenf-contammg liquid phase, other components will be present as particulate mate ⁇ al dispersed within the "solvent" -containing liquid phase. Thus the term “solvent” is not meant to require that the solvent material be capable of actually dissolving all of the detergent composition components added thereto.
  • the non-aqueous liquid diluent component will generally comprise from about 50% to 100%, more preferably from about 50% to 80%, most preferably from about 55% to 75%, of a structured, surfactant-contammg liquid phase
  • the liquid phase of the compositions herein i.e., the non-aqueous liquid diluent component
  • the non-aqueous liquid diluent component will comprise both non-aqueous liquid surfactants and non-surfactant non-aqueous solvents l
  • Non-aqueous Surfactant Liquids Suitable types of non-aqueous surfactant liquids which can be used to form the liquid phase of the compositions herein include the alkoxylated alcohols, ethylene oxide (EO)- propylene oxide (PO) block polymers, polyhydroxy fatty acid amides, alkylpolysaccharides, and the like.
  • Such normally liquid surfactants are those having an HLB ranging from 10 to 16.
  • R 1 (C m H 2m O) n OH wherein R* is a Cg - C j g alkyl group, m is from 2 to 4, and n ranges from about 2 to 12.
  • the alkoxylated fatty alcohols will be ethoxylated materials that contain from about 2 to 12 ethylene oxide moieties per molecule, more preferably from about 3 to 10 ethylene oxide moieties per molecule.
  • the alkoxylated fatty alcohol materials useful in the liquid phase will frequently have a hydrophihc-hpophihc balance (HLB) which ranges from about 3 to 17. More preferably, the HLB of this material will range from about 6 to 15, most preferably from about 8 to 15.
  • HLB hydrophihc-hpophihc balance
  • liquid surfactants suitable for use in the present invention may be found in the copendmg provisional application of Jean-Paul boutique et al., entitled “Detergent Compositions Comprising Improved Hydrotropes", filed on August 23, 1999 and having P&G Case No 7694P2.
  • the amount of total liquid surfactant m the preferred surfactant-structured, non-aqueous liquid phase herein will be determined by the type and amounts of other composition components and by the desired composition properties.
  • the liquid surfactant can comprise from about 35% to 70% of the non-aqueous liquid phase of the compositions herein. More preferably, the liquid surfactant will comprise from about 50% to 65% of a non-aqueous structured liquid phase. This corresponds to a non-aqueous liquid surfactant concentration in the total composition of from about 15% to 70% by weight, more preferably from about 20% to 50% by weight, of the composition.
  • low foaming surfactants such as conventional secondary alkyl sulfate surfactants which are those materials which have the sulfate moiety distributed randomly along the hydrocarbyl "backbone" of the molecule as well as mid- chain branched surfactants which are mid-cham branched primary alkyl sulfate surfactants and mid-chain branched primary alkyl alkoxoxylated sulfate surfactants having an average of greater than 14.5 carbon atoms.
  • conventional secondary alkyl sulfate surfactants which are those materials which have the sulfate moiety distributed randomly along the hydrocarbyl "backbone" of the molecule as well as mid- chain branched surfactants which are mid-cham branched primary alkyl sulfate surfactants and mid-chain branched primary alkyl alkoxoxylated sulfate surfactants having an average of greater than 14.5 carbon atoms.
  • mid-cham branched surfactants are discussed in greater detail in the copendmg application of Malcolm Dodd et al., entitled “Processes for Making a Granular Detergent Composition Containing Mid-Cham Branched Surfactants," having P&G Case No 6869P, serial no. 60/061,876, filed on October 10, 1997, hereby incorporated by reference.
  • Nonionic surfactants also generally low foaming surfactants
  • the liquid phase of the detergent compositions herein may also comprise one or more non-surfactant, non-aqueous organic solvents.
  • non-surfactant non-aqueous liquids are preferably those of low polarity
  • low-polarity liquids are those which have little, if any, tendency to dissolve one of the preferred types of particulate material used in the compositions herein, i.e., the peroxygen bleaching agents, sodium perborate or sodium percarbonate.
  • Suitable types of low-polarity solvents useful in the non-aqueous liquid detergent compositions herein do include non-vicinal C/j-Cg alkylene glycols, alkylene glycol mono lower alkyl ethers, lower molecular weight polyethylene glycols, lower molecular weight methyl esters and amides, and the like.
  • a preferred type of non-aqueous, low-polarity solvent for use m the compositions herein comprises the non-vicmal C ⁇ Cg branched or straight chain alkylene glycols
  • Materials of this type include hexylene glycol (4-methyl-2,4-pentaned ⁇ ol), 1,6-hexanediol, 1,3-butylene glycol and 1,4-butylene glycol. Hexylene glycol is the most preferred.
  • non-aqueous, low-polarity solvent for use herein comprises the mono-, di-, t ⁇ -, or tetra- C2-C3 alkylene glycol mono C2-Cg alkyl ethers
  • the specific examples of such compounds include diethylene glycol monobutyl ether, tetraethylene glycol monobutyl ether, dipropolyene glycol monoethyl ether, and dipropylene glycol monobutyl ether.
  • Diethylene glycol monobutyl ether, dipropylene glycol monobutyl ether and butoxy-propoxy-propanol (BPP) are especially preferred.
  • Compounds of the type have been commercially marketed under the tradenames Dowanol, Carbitol, and Cellosolve.
  • non-aqueous, low-polarity organic solvent useful herein comp ⁇ ses the lower molecular weight polyethylene glycols (PEGs). Such materials are those having molecular weights of at least about 150. PEGs of molecular weight ranging from about 200 to 600 are most preferred.
  • Yet another preferred type of non-polar, non-aqueous solvent comprises lower molecular weight methyl esters Such materials are those of the general formula. R i -C(0)-OCH3 wherein R! ranges from 1 to about 18 Examples of suitable lower molecular weight methyl esters include methyl acetate, methyl propionate, methyl octanoate, and methyl dodecanoate
  • non-aqueous, generally low-polarity, non-surfactant organic solvent(s) employed should, of course, be compatible and non-reactive with other composition components, e.g., bleach and/or activators, used m the liquid detergent compositions herein.
  • a solvent component is preferably utilized in an amount of from about 1% to 70% by weight of the liquid phase.
  • a non-aqueous, low-polarity, non-surfactant solvent will comprise from about 10% to 60% by weight of a structured liquid phase, most preferably from about 20% to 50% by weight, of a structured liquid phase of the composition Utilization of non-surfactant solvent in these concentrations in the liquid phase corresponds to a non-surfactant solvent concentration in the total composition of from about 1% to 50% by weight, more preferably from about 5% to 40% by weight, and most preferably from about 10% to 30% by weight, of the composition. in) Blends of Surfactant and Non-surfactant Solvents
  • the ratio of surfactant to non-surfactant liquids e.g., the ratio of alcohol alkoxylate to low polarity solvent, withm a structured, surfactant-contammg liquid phase can be used to vary the rheological properties of the detergent compositions eventually formed.
  • the weight ratio of surfactant liquid to non-surfactant organic solvent will range about 50:1 to 1:50. More preferably, this ratio will range from about 3.1 to 1 :3, most preferably from about 2:1 to 1:2.
  • the non-aqueous liquid phase of the detergent compositions of this invention is prepared by combining with the non-aqueous organic liquid diluents hereinbefore described a surfactant which is generally, but not necessarily, selected to add structure to the non-aqueous liquid phase of the detergent compositions herein.
  • a surfactant which is generally, but not necessarily, selected to add structure to the non-aqueous liquid phase of the detergent compositions herein.
  • Structuring surfactants can be of the anionic, nomonic, cationic, and/or amphote ⁇ c types. Structuring surfactants are discussed in greater detail in the copendmg provisional application of Jean-Paul boutique et al., entitled “Detergent Compositions Comprising Improved Hydrotropes", filed on August 23, 1999 and having P&G Case No.
  • the detergent compositions herein can, and preferably will, contain various other optional components. Some of the following optional components will be found m the present compositions in the suspended solid phase, while others will be m the surfactant-rich liquid phase.
  • the optional components may either dissolve in the liquid phase or may be dispersed within the liquid phase in the form of fine particles or droplets.
  • the detergent compositions herein may also optionally contain one or more types of inorganic detergent builders beyond those listed above that also function as alkalinity sources.
  • optional inorganic builders can include, for example, alummosilicates such as zeolites. Alummosihcate zeolites, and their use as detergent builders are more fully discussed in Corkill et al., U.S. Patent No. 4,605,509; Issued August 12, 1986, the disclosure of which is incorporated herein by reference. Also crystalline layered silicates, such as those discussed in this '509 U S. patent, are also suitable for use in the detergent compositions herein. If utilized, optional inorganic detergent builders can comprise from about 2% to 15% by weight of the compositions herein. (b) Optional Enzymes
  • Enzymes can be included in the formulations herein for a wide variety of fabric laundering purposes, including removal of protem-based, carbohydrate-based, or t ⁇ glyce ⁇ de- based stams; for the prevention of refugee dye transfer; and for fabric restoration. It is believed that the addition of the special hydrotropes described above will enhance the performance of enzymes in a detergent composition. This is because as the hydrotropes increase the rate of dissolution of the detergent composition, the rate at which enzymes come into contact with water and are activated will also increase and the corresponding detersive benefits provided by activated enzymes will also increase This behavior is seen in both aqueous and non-aqueous detergent compositions.
  • the enzymes to be incorporated include proteases, amylases, hpases, mannanase, cellulases, and peroxidases, as well as mixtures thereof. Other types of enzymes may also be included. They may be of any suitable origin, such as vegetable, animal, bacterial, fungal and yeast origin. However, their choice is governed by several factors such as pH-activity and/or stability optima, thermostabihty, stability versus active detergents, builders and so on In this respect bacterial or fungal enzymes are preferred, such as bacterial amylases and proteases, and fungal cellulases.
  • Enzymes are normally incorporated at levels sufficient to provide up to about 5 mg by weight, more typically about 0 01 mg to about 3 mg, of active enzyme per gram of the composition. Stated otherwise, the compositions herein will typically comprise from about 0.001% to about 5%, preferably 0.01%-1.0% by weight of a commercial enzyme preparation. Protease enzymes are usually present in such commercial preparations at levels sufficient to provide from 0.005 to 0.1 Anson units (AU) of activity per gram of composition.
  • AU Anson units
  • proteases are the subtihsms which are obtained from particular strains of Bacillus subtihs and Bacillus licheniforms. Another suitable protease is obtained from a strain of Bacillus, having maximum activity throughout the pH range of 8-12, developed and sold by Novo Industries A/S under the registered trade name ESPERASE®. The preparation of this enzyme and analogous enzymes is described in British Patent Specification No. 1,243,784 of Novo Industries A S. Proteolytic enzymes suitable for removing protem-based stams that are commercially available include those sold under the tradenames ALCALASE® and SAVINASE® by Novo Industries A/S (Denmark) and MAXATASE® by International Bio- Synthetics, Inc.
  • proteases include Protease A (see European Patent Application 130,756, published January 9, 1985) and Protease B (see European Patent Application Serial No. 87303761.8, filed April 28, 1987, and European Patent Application 130,756, Bott et al, published January 9, 1985).
  • Amylases include, for example, amylases described in British Patent Specification No. 1,296,839 (Novo Industries A S), RAPID ASE®, International Bio-Synthetics, Inc. and TERMAMYL®, Novo Industries A/S.
  • Mannanases include the following three mannans-degrading enzymes : EC 3.2.1.25 : ⁇ - mannosidase, EC 3.2.1.78 : Endo-l,4- ⁇ -mannos ⁇ dase, referred therein after as "mannanase” and EC 3.2.1.100 : 1,4- ⁇ -mannob ⁇ os ⁇ dase (IUPAC Classification- Enzyme nomenclature, 1992 ISBN 0-12-227165-3 Academic Press).
  • the non-aqueous liquid phase of the present invention may also optionally contain a chelatmg agent which serves to chelate metal ions, e.g., iron and/or manganese, within the detergent compositions herein.
  • a chelatmg agent which serves to chelate metal ions, e.g., iron and/or manganese, within the detergent compositions herein.
  • Suitable chelatmg agents are those described above under the heading entitled “Low-Density Particles.”
  • the chelatmg agent if employed, can comprise from about 0.1% to 4% by weight of the compositions herein. More preferably, the chelatmg agent will comprise from about 0.2% to 2% by weight of the detergent compositions herein.
  • Suitable suds suppressers are discussed in greater detail m the copendmg provisional application of Jean-Paul boutique et al., entitled “Detergent Compositions Comprising Improved Hydrotropes", filed on August 23, 1999 and having P&G Case No. 7694P2, incorporated above
  • compositions of the present invention may also include one or more materials effective for inhibiting the transfer of dyes from one fabric to another during the cleaning process. These agents may be included either in the nonaqueous surfactant-contammg liquid phase or in the solid particulate material. Such materials are discussed in greater detail m the copendmg provisional application of Jean-Paul boutique et al., entitled “Detergent Compositions Comprising Improved Hydrotropes", filed on August 23, 1999 and having P&G Case No. 7694P2, incorporated above.
  • the present invention may also include materials which could be added to laundry products that would associate themselves with the fibers of the fabrics and textiles laundered using such products and thereby reduce or minimize the tendency of the laundered fabric/textiles to deteriorate m appearance.
  • Any such detergent product additive material should, of course, be able to benefit fabric appearance and integrity without unduly interfering with the ability of the laundry product to perform its intended function.
  • fabric appearance benefits can include, for example, improved overall appearance of the laundered fabrics, reduction of the formation of pills and fuzz, protection against color fading, improved abrasion resistance, etc.
  • PEI 600 E20 polyethyleneimine
  • E is an ethyleneoxy unit having the formula:
  • m has an average value of about 20.
  • an average value of 20 is that sufficient ethylene oxide or other suitable reagent is reacted with the polyethyleneimine starting material to fully ethoxylate each N-H unit to a degree of 20 ethoxylations.
  • N-H unit hydrogen atoms will be replaced by less than 20 ethoxy units and some will be replaced by more than 20 ethoxy units, therefore, the average of the number of ethoxylations is 20.
  • the units which make up the polyalkyleneimme backbones are primary amme units having the formula:
  • the indices w, x, and y have values such that the average molecular weight of the polyethyleneimine backbone prior to modification is about 600 daltons.
  • each branch chain must terminate in a primary amme unit, therefore the value of the index w is y + 1 in the case where no cyclic amme backbones are present.
  • the average molecular weight for each ethylene backbone unit, -NCH 2 CH 2 -, is approximately 43 daltons.
  • the polyammes of the present invention can be prepared, for example, by polyme ⁇ zmg ethyleneimme in the presence of a catalyst such as carbon dioxide, sodium bisulfite, sulfu ⁇ c acid, hydrogen peroxide, hydrochloric acid, acetic acid, etc.
  • a catalyst such as carbon dioxide, sodium bisulfite, sulfu ⁇ c acid, hydrogen peroxide, hydrochloric acid, acetic acid, etc.
  • a catalyst such as carbon dioxide, sodium bisulfite, sulfu ⁇ c acid, hydrogen peroxide, hydrochloric acid, acetic acid, etc.
  • Specific methods for preparing these polyamme backbones are disclosed in U.S. Patent 2,182,306, Ul ⁇ ch et al., issued December 5, 1939; U.S. Patent 3,033,746, Mayle et al., issued May 8,1962; U.S. Patent 2,208,095, Esselmann et al., issued July 16,1940; U.S. Patent 2,
  • Suitable fabric care agents for use in the present detergent compositions include dye maintenance polymers.
  • One example of such a polymer is the Adduct of Imidazole- epichlorohydrm:
  • the detergent compositions herein may also optionally contain a polymeric material which serves to enhance the ability of the composition to maintain its solid particulate components in suspension.
  • a polymeric material which serves to enhance the ability of the composition to maintain its solid particulate components in suspension.
  • Such materials may thus act as thickeners, viscosity control agents and/or dispersing agents.
  • Such materials are frequently polymeric polycarboxylates but can include other polymeric materials such as polyvmylpyrrohdone (PVP) or polyamide resms.
  • Polymeric polycarboxylate materials can be prepared by polymerizing or copolyme ⁇ zmg suitable unsaturated monomers, preferably in their acid form.
  • Unsaturated monome ⁇ c acids that can be polymerized to form suitable polymeric polycarboxylates include acrylic acid, maleic acid (or maleic anhydride), fuma ⁇ c acid, ltacomc acid, aconitic acid, mesacomc acid, citraconic acid and methylenemalomc acid.
  • the presence m the polymeric polycarboxylates herein of monome ⁇ c segments, containing no carboxylate radicals such as vmylmethyl ether, styrene, ethylene, etc. is suitable provided that such segments do not constitute more than about 40% by weight of the polymer.
  • Particularly suitable polymeric polycarboxylates can be derived from acrylic acid.
  • acrylic acid-based polymers which are useful herein are the water-soluble salts of polymerized acrylic acid.
  • the average molecular weight of such polymers in the acid form preferably ranges from about 2,000 to 100,000, more preferably from about 2,000 to 10,000, even more preferably from about 4,000 to 7,000, and most preferably from about 4,000 to 5,000
  • Water-soluble salts of such acrylic acid polymers can include, for example, the alkali metal, salts
  • Soluble polymers of this type are known materials Use of polyacrylates of this type m detergent compositions has been disclosed, for example, Diehl, U.S. Patent 3,308,067, issued March 7, 1967. Such materials may also perform a builder function
  • Other suitable polymeric materials suitable for use as thickening, viscosity control and/or dispersing agents include polymers of: castor oil derivatives; polyurethane derivatives, and polyethylene glycol.
  • the optional thickening, viscosity control and/or dispersing agents should be present in the compositions herein to the extent of from about 0 1 % to 4% by weight. More preferably, such materials can comprise from about 0.1% to 2% by weight of the detergents compositions herein, (g) Optional Clay Soil Removal/ Anti-redeposition Agents
  • compositions of the present invention can also optionally contain water-soluble ethoxylated amines having clay soil removal and anti-redeposition properties.
  • soil materials can contain from about 0 01% to about 5% by weight of the compositions herein.
  • Clay Soil Removal and Anti-redeposition Agents are discussed m greater detail m the copendmg provisional application of the copendmg provisional application of Jean-Paul boutique et al., entitled “Detergent Compositions Comprising Improved Hydrotropes", filed on August 23, 1999 and having P&G Case No. 7694P2, incorporated above.
  • CMC carboxy methyl cellulose
  • the detergent compositions herein may also optionally contain bleach activators which are liquid in form at room temperature and which can be added as liquids to the liquid phase of the detergent compositions herein.
  • One such liquid bleach activator is glycerol triacetate, which serves as a solvent in the composition during storage but when released into the wash water solution is peroxidized and functions as a bleach activator.
  • Other examples of bleach activators include acetyl t ⁇ ethyl citrate (ATC) and nonanoyl valerolactam.
  • ATC acetyl t ⁇ ethyl citrate
  • Liquid bleach activators can be dissolved in the liquid phase of the compositions herein.
  • the detergent compositions herein may also optionally contain conventional brighteners, bleach catalysts, dyes and/or perfume materials.
  • Such brighteners, sihcone oils, bleach catalysts, dyes and perfumes must, of course, be compatible and non-reactive with the other composition components in the aqueous or non-aqueous liquid environment. If present, brighteners, dyes and/or perfumes will typically comprise from about 0.0001% to 2% by weight of the compositions herein.
  • the liquid detergent compositions herein can also contain from about 0 1% to 5%, preferably from about 0.1% to 2% by weight of a finely divided, solid particulate material which can include silica, e.g., fumed silica, titanium dioxide, insoluble carbonates, finely divided carbon, SD-3 bentone, clays, or combinations of these materials Clays are well known to those skilled in the art and are commercially available from companies such as Rheox. Fine particulate material of this type functions as a structure elasticizmg agent in the products of this invention. Such material has an average particle size ranging from about 7 to 40 nanometers, more preferably from about 7 to 15 nanometers. Such material also has a specific surface area which ranges from about 40 to 400m2/g.
  • a finely divided, solid particulate material which can include silica, e.g., fumed silica, titanium dioxide, insoluble carbonates, finely divided carbon, SD-3 bentone, clays, or combinations of these materials Clays are well known to
  • the finely divided elasticizmg agent material can improve the shipping stability of the liquid detergent products herein by increasing the elasticity of the surfactant-structured liquid phase without increasing product viscosity. This permits such products to withstand high frequency vibration which may be encountered du ⁇ ng shipping without undergoing undesirable structure breakdown which could lead to sedimentation the product.
  • Microspheres may be used m the present invention. Suitable microspheres may be made of one or more water-msoluble materials selected from the group consisting of: polymers; silicaceous materials; ceramics and mixtures thereof.
  • water-msoluble materials selected from the group consisting of: polymers; silicaceous materials; ceramics and mixtures thereof.
  • microspheres are available from Akzo-Nobel of Sweden under the trademark EXPANCEL®; PQ Corp. under the trade names PM 6545, PM 6550, PM 7220, PM 7228, EXTENDOSPHERES®, LUXSIL®, Q-CEL®, SPHERICEL®; and Mahnckrodt under the trademark ALBUMEX®.
  • Microspheres are discussed in greater detail in the copendmg provisional application of Jean-Paul boutique et al., entitled “Detergent Compositions Comprising Improved Hydrotropes", filed on August 23, 1999 and having P&G Case No. 7694P2, incorporated above. Methods for coating microspheres are discussed in the copendmg provisional application of Yousef Aouad et al., entitled “Nonaqueous Liquid Detergent with Wash-water soluble Low-Density Filler Particles", having P&G Case No. 7708P, and filed on August 10, 1999, which is hereby incorporated by reference. Biomate ⁇ al microspheres are also discussed in the copendmg provisional application of
  • the aqueous and non-aqueous liquid detergent compositions herein are m the form of bleaching agent and/or other materials in particulate form as a solid phase suspended in and dispersed throughout a surfactant-contammg, preferably structured, preferably non-aqueous liquid phase.
  • a surfactant-contammg preferably structured, preferably non-aqueous liquid phase.
  • the structured non-aqueous liquid phase will comprise from about 49% to 99.95%, more preferably from about 52% to 98.5%, by weight of the composition with the dispersed additional solid materials comprising from about 1% to 50%, more preferably from about 29% to 44%, by weight of the composition.
  • the particulate-contammg liquid detergent compositions of this invention are substantially non-aqueous (or anhydrous) m character. While very small amounts of water may be incorporated into such compositions as an impurity in the essential or optional components, the amount of free water should m no event exceed about 1% by weight of the compositions herein. More preferably, water content of the non-aqueous detergent compositions herein will comprise less than about 1% by weight.
  • the particulate-contammg non-aqueous liquid detergent compositions herein will be relatively viscous and phase stable under conditions of commercial marketing and use of such compositions. Frequently the viscosity of the compositions herein will range from about 300 to 8,000 cps, more preferably from about 1000 to 4,000 cps For purposes of this invention, viscosity is measured with a Cammed CSL2 Rheometer at a shear rate of 20 s ⁇ * . COMPOSITION PREPARATION AND USE
  • non-aqueous liquid detergent compositions are discussed in detail in Copendmg application of Jay I. Kahn et al., entitled "Preparation of Nonaqueous, Particulate- Contaimng Liquid Detergent Compositions with Surfactant-Structured Liquid Phase", having P&G Case No. 6150, serial no. 09/202,964, filed on December 23, 1998, which is hereby incorporated by reference.
  • An effective amount of the liquid detergent compositions herein added to water to form aqueous laundermg/bleachmg solutions can comprise amounts sufficient to form from about 500 to 10,000 ppm of composition in aqueous solution. More preferably, from about 800 to 8,000 ppm of the detergent compositions herein will be provided m aqueous washmg/bleachmg solution.
  • a 40 % solution of sodium carbonate, sodium citrate and diethylene triamme penta methyl phosphonic acid present in the ratio of 10/3/3 was prepared. This solution was then passed through a spray tower equipped with a rotary atomizer operating at 15,000 RPM. The spray-tower is operating with co-current stream of hot air, an mlet temperature of approximately 205°C to 220°C and an outlet temperature of approximately 95°C to 105°C. Passing the solution through the spray tower results in the formation of a low-density coated particle.
  • the total product had an average density of 1.0822 g/ml with a standard deviation of 0.0261 g/ml; an average bulk density of 536 g/1 with a standard deviation of 18 g/1; and a average moisture content of 1.3 % with a standard deviation of 0.4%.
  • a 40 % solution of sodium carbonate, sodium citrate and diethylene triamme penta methyl phosphonic acid present in the ratio of 10/3/3 was prepared. This solution was then passed through a spray tower equipped with a pulse drying chamber (drum). The pulses of hot gases entering the drying chamber are at a temperature of about 1000 °C. Passing the solution through the spray tower results in the formation of a low-density coated particle.
  • the total product had an average density of 1.0822 g/ml with a standard deviation of 0.0261 g/ml; an average bulk density of 536 g/1 with a standard deviation of 18 g/1; and a average moisture content of 1.3 % with a standard deviation of 0.4%.
  • Example I and/or II can then be added as a component in the following non-aqueous liquid detergent composition prepared m accordance with the present invention and which has the following overall composition:

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Abstract

L'invention concerne des compositions de détergent liquide non aqueux qui comprennent environ 49 à 99,95 % en poids d'une phase liquide non aqueuse contenant un tensioactif, et environ 0,05 à 51 % en poids d'une phase particulaire solide en suspension. La phase particulaire solide en suspension comprend des particules basse densité solubles dans l'eau composées d'un liant et de matières sélectionnés dans le groupe constitué par une source d'alcalinité, un produit chélatant, un renforçateur et leurs mélanges. Selon l'invention, ceux des ingrédients qui sont insolubles dans la phase liquide riche en tensioactif peuvent être incorporés dans la phase liquide sans ségrégation ou séparation indésirable.
EP00952617A 1999-08-10 2000-08-08 Detergents liquides non aqueux comprenant des particules basse densite solubles dans l'eau Withdrawn EP1228185A1 (fr)

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US14805499P 1999-08-10 1999-08-10
US14799699P 1999-08-10 1999-08-10
US148054P 1999-08-10
US147996P 1999-08-10
US15043199P 1999-08-24 1999-08-24
US150431P 1999-08-24
PCT/US2000/021572 WO2001011003A1 (fr) 1999-08-10 2000-08-08 Detergents liquides non aqueux comprenant des particules basse densite solubles dans l'eau

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US6835702B2 (en) 2000-11-07 2004-12-28 Ecolab Inc. Compositions and methods for mitigating corrosion of applied color designs
WO2002038715A2 (fr) * 2000-11-07 2002-05-16 Ecolab Inc. Compositions et procedes d'attenuation de la corrosion de motifs en couleur appliques
US7008915B2 (en) 2001-08-07 2006-03-07 The Procter & Gamble Co. Liquid detergent compositions with low-density particles
FR2862134B1 (fr) 2003-11-12 2007-07-27 Sebia Sa Analyse et typage de proteines monoclonales par electrophorese capillaire et immunodeplacement
US7901696B2 (en) 2005-10-31 2011-03-08 J&J Consumer Companies, Inc. Cosmetic device comprising discrete elements
WO2008057113A1 (fr) * 2006-11-06 2008-05-15 Johnson & Johnson Consumer Companies, Inc. Dispositif cosmétique comportant des éléments discrets
GB0700925D0 (en) * 2007-01-18 2007-02-28 Reckitt Benckiser Nv Dosage element and a method of manufacturing a dosage element
DE102008047943A1 (de) * 2008-09-18 2010-03-25 Henkel Ag & Co. Kgaa Bleichmittel-haltiges Reinigungsmittel
JP2022091156A (ja) * 2020-12-08 2022-06-20 ライオン株式会社 液体洗浄剤組成物用の被覆粒子群、液体洗浄剤組成物及びこれらの製造方法

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US3615811A (en) * 1968-02-29 1971-10-26 Chemical Products Corp Carbonate compositions and process
US4767558A (en) * 1985-08-05 1988-08-30 Colgate-Palmolive Company Low phosphate or phosphate free nonaqueous liquid nonionic laundry detergent composition and method of use
EP0386868B1 (fr) * 1989-01-17 1995-09-20 Minerals Technologies Inc. Aggloméré de carbonate de calcium de faible densité
DE4213036A1 (de) * 1992-04-21 1993-10-28 Henkel Kgaa Granulares, alkalisches, phosphatfreies Reinigungsadditiv
WO1997000937A1 (fr) * 1995-06-20 1997-01-09 The Procter & Gamble Company Compositions detergentes non aqueuses contenant des particules
JPH11514030A (ja) * 1996-06-28 1999-11-30 ザ、プロクター、エンド、ギャンブル、カンパニー 前処理乾燥された成分入りの非水性粒子含有液体洗剤組成物の製造

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