EP1262591B1 - Abziehbare klebstoffbeschichtete Wandbekleidung - Google Patents
Abziehbare klebstoffbeschichtete Wandbekleidung Download PDFInfo
- Publication number
- EP1262591B1 EP1262591B1 EP01113463A EP01113463A EP1262591B1 EP 1262591 B1 EP1262591 B1 EP 1262591B1 EP 01113463 A EP01113463 A EP 01113463A EP 01113463 A EP01113463 A EP 01113463A EP 1262591 B1 EP1262591 B1 EP 1262591B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coating
- wall
- process according
- fabric
- dried coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 claims abstract description 59
- 238000000034 method Methods 0.000 claims abstract description 48
- 239000006185 dispersion Substances 0.000 claims abstract description 45
- 239000000126 substance Substances 0.000 claims abstract description 44
- 239000011521 glass Substances 0.000 claims abstract description 43
- 239000011248 coating agent Substances 0.000 claims abstract description 37
- 238000000576 coating method Methods 0.000 claims abstract description 37
- 239000011152 fibreglass Substances 0.000 claims abstract description 23
- 229920002472 Starch Polymers 0.000 claims abstract description 22
- 235000019698 starch Nutrition 0.000 claims abstract description 21
- 239000011230 binding agent Substances 0.000 claims abstract description 20
- 239000004816 latex Substances 0.000 claims abstract description 18
- 229920000126 latex Polymers 0.000 claims abstract description 18
- 239000008107 starch Substances 0.000 claims abstract description 18
- 239000000853 adhesive Substances 0.000 claims abstract description 16
- 230000001070 adhesive effect Effects 0.000 claims abstract description 15
- 239000012188 paraffin wax Substances 0.000 claims abstract description 12
- 239000006254 rheological additive Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 239000003365 glass fiber Substances 0.000 claims description 7
- 239000000049 pigment Substances 0.000 claims description 7
- 239000004971 Cross linker Substances 0.000 claims description 6
- 229920001592 potato starch Polymers 0.000 claims description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 6
- 150000002484 inorganic compounds Chemical class 0.000 claims description 5
- 229910010272 inorganic material Inorganic materials 0.000 claims description 5
- 229920002261 Corn starch Polymers 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000008120 corn starch Substances 0.000 claims description 3
- 239000003431 cross linking reagent Substances 0.000 claims description 3
- 239000004317 sodium nitrate Substances 0.000 claims description 3
- 235000010344 sodium nitrate Nutrition 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 239000002759 woven fabric Substances 0.000 claims description 2
- 238000010924 continuous production Methods 0.000 claims 2
- 239000004408 titanium dioxide Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 10
- 239000003973 paint Substances 0.000 description 7
- 239000012790 adhesive layer Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000010422 painting Methods 0.000 description 6
- 238000009472 formulation Methods 0.000 description 5
- 239000003292 glue Substances 0.000 description 5
- 238000004026 adhesive bonding Methods 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241000272194 Ciconiiformes Species 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 229940105329 carboxymethylcellulose Drugs 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical class [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229940088990 ammonium stearate Drugs 0.000 description 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical compound [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- -1 e.g. Chemical compound 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- BFMKFCLXZSUVPI-UHFFFAOYSA-N ethyl but-3-enoate Chemical compound CCOC(=O)CC=C BFMKFCLXZSUVPI-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical class O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000000914 phenoxymethylpenicillanyl group Chemical group CC1(S[C@H]2N([C@H]1C(=O)*)C([C@H]2NC(COC2=CC=CC=C2)=O)=O)C 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C7/00—Paperhanging
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C7/00—Paperhanging
- B44C7/02—Machines, apparatus, tools or accessories therefor
- B44C7/04—Machines, apparatus, tools or accessories therefor for applying adhesive
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0002—Wallpaper or wall covering on textile basis
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/16—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements of fibres or chips, e.g. bonded with synthetic resins, or with an outer layer of fibres or chips
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/08—Inorganic fibres
- D06N2201/082—Glass fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/02—Natural macromolecular compounds or derivatives thereof
- D06N2203/024—Polysaccharides or derivatives thereof
- D06N2203/028—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/02—Dispersion
- D06N2205/023—Emulsion, aqueous dispersion, latex
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
Definitions
- Wall coverings such as wallpaper based on paper sheet materials are known from GB-A-1,184,563 .
- pre-glued fiber glass wall-coverings having an adhesive layer which contains a polymeric latex binder are known from EP-A-1 035 187 .
- Fiberglass wall coverings offer an unique fire resistance, easy and uncomplicated handling and flexibility in use. They exhibit good abrasion resistance and appearance following 10 painting.
- fiberglass wall coverings of the prior art requires the use of special glues or adhesives with strong binding forces and require cost-intensive and time consuming painting procedures. In addition, fiberglass wall coverings cannot be removed or repainted without cost-intensive and time consuming procedures.
- the wall as well as the fabric must be treated with a special glue or adhesive.
- the commonly used wet adhesive is primarily based on a starch-solution and which always contains some latex binder, and must be rolled out or sprayed onto the wall and onto the fabric. After drying, the wallcovering must be painted twice. Between the first and the second painting step the wall and the wall-covering must be dried.
- the paints most commonly used are standard interior wall paints, i.e. various types of latex paints.
- the woven glass fabric is often impregnated with a water-based formulation which contains mainly starch, binder and inorganic cross-linker.
- the finished wall-covering typically contains up to 25 weight percent of such chemicals.
- the surface structure of the glass wall covering When re-decorating a wall, the surface structure of the glass wall covering must be filled out with a filler and sanded at least twice to get a smooth surface. This method requires filler materials, equipment and skills and results in a dusty working area.
- a method to remove used glass wall coverings from the wall is by using chemicals. These chemicals penetrate the paint and dissolve the glue. After that treatment the glass fiber weave can be stripped off the wall. This method is also available using special glue/paint system to make the stripping process easier. Both methods require chemicals, which are normally irritant to the skin, and which creates a wet and messy environment.
- DE 198 11 152 describes painted or printed glass wall coverings with an self-sticking backing. Such systems, however, cannot be removed from the wall without the use of chemicals.
- EP 0 909 850 describes a finished wall covering with a multicolor print and a self adhesive backing.
- self-adhesive wall coverings are relatively expensive because they require additional production steps, e.g. the covering of the adhesive layer prior to use.
- the handling of such wall coverings when applied to the wall is completely different than standard application procedures.
- the glass weave has the same properties as standard glass fiber wall coverings, in particular, excellent fire resistance
- the present invention relates to a process for forming claim 1.
- the present invention utilizes fiberglass fabrics in woven rolled form, other fiberglass fabrics such as a nonwoven mat may be used.
- Figure 1 depicts a process for applying a customary coating to a glass fabric from an aqueous dispersion.
- the glass fabric is a woven product that incorporates fiber glass yarn.
- the weave is typically a simple pattern of up to eight shafts.
- the weave is produced, for example, on Dornier weaving machines, Rapiers or Air-Jets, in typically two or three meter widths for collecting on roll beams of typically 1,500-6,000 meters of untreated woven fiberglass fabric.
- Many fiberglass yarns may be selected for use when producing the woven materials for use in the present invention.
- Preferred yarns include, for the warp direction continuous C-glass or E-glass of 9 - 10 ⁇ m (microns,) and 139 - 142 with 315 - 340 ends per meter.
- An alternative warp yarn is continuous C-glass or E-glass of 6 - 9 ⁇ m (micron), 34 - 68 tex with 680 ends per meter.
- a preferred glass is discontinuous spun E-glass or C-glass, 8 - 11 ⁇ m (micron), 165 - 550 tex with 170 - 600 ends per meter.
- An alternative weft yarn includes continuous volumized E-glass or C-glass of 8 - 11 ⁇ m (microns), 165 - 550 tex with 170 - 600 ends per meter.
- the present invention is also applicable to nonwoven glass fabrics, such as mat products. These can be produced, for example, by conventional wet-laid processes such as those described in U.S. Patent Nos. 4,112,174 ; 4,681,802 and 4,810,576 .
- the glass fabric 1, preferred in roll form is fed to a first impregnation bath 2, typically with the aid through rollers 3 and conventional conveyance means so as to contact on both surfaces a bath of the chemical dispersion.
- a transfer or pick up roll may convey the first chemical dispersion to the glass fabric surfaces.
- a preferred first chemical dispersion includes the components identified in Table 1 below where concentration are provided on a weight basis.
- double side rotary screens may be used to apply the chemicals to the glass fabric 1.
- the chemical dispersion is then supplied to the interior of the two rotating screens and applied to the glass fabric by contact with the rotating screens.
- Table 1 Starch binder 10-70 % of dry substance Latex binder 20-80% of dry substance Inorganic cross-linker 0-15 % of dry substance Pigments 10-30% of dry substance
- starch binders or CMCs carboxy-methyl cellulose
- CMCs carboxy-methyl cellulose
- the polymeric latex binders are preferably copolymers of vinyl acetate and acrylics, e.g., ethylvinyl acetate and styrene acrylics.
- PVAs polyvinyl acetate
- other polymeric latex binders can also be used.
- Cross-linkers are agents that are reactive towards certain functional groups located primarily on the polymeric latex binder. Cross-linkers preferably are used in a concentration of 3 to 12 percent on a dry basis to improve important characteristics such as film formation, hydrophobicity, wet strength, etc. These reactive agents can be either organic or inorganic types, e.g., be based on zirconium, urea/formaldehyde or glyoxal derivatives. Zirconium cross-linking agents are preferred.
- the preferred formulation is the most cost effective and technically functional.
- the mixture is preferably water based, and has a dry substance percentage of between 5 and 20 weight percent, preferably between 10 and 12 weight percent in the chemical dispersion.
- white pigments colored pigments can also be added or used to create colored fabrics as well.
- the fabric may be conveyed to a drying means 4, which in the preferred embodiment of Figure 1 utilizes steam heated cylinders 5. After drying the fabric can be cut into desired width, and collected for subsequent secondary treatment. A fabric length of 1,000 and 6,000 meters of treated fabric can be collected into rolls at a batching stand 6 between. Alternatively, the subsequent application steps can be carried out on a continuous basis.
- This first impregnation step adds additional volume and opacity to the glass fabric. This leads to a pre-painted fabric which requires only one single painting step by the end-user. The time consuming second paint which is usually necessary for glass fabrics can be omitted.
- FIG 2 a preferred method of applying the separation layer to one side only of the fabric is shown.
- a rotating screen 11 such as available from Stork, may be used to apply the chemicals to the glass fabric 12.
- the chemical dispersion 14 is supplied to the interior of the rotating screen 11.
- the dispersion is applied to the glass fabric by contact with the rotating screen.
- the chemicals can also be applied by a transfer or pick-up roller without any drawbacks.
- a preferred chemical dispersion mixture consists of those components set out in Table 2 below.
- Table 2 Paraffin dispersion 80-99% of dry substance Rheology modifier 1-20% of dry substance
- the paraffin dispersion is free of metal salts.
- Alternatives to the Paraffin dispersion include stearates, specifically calcium silicate, sodium stearate, zinc stearate, ammonium stearate, fluoro carbons and other hydrophobical agents, i.e. chemicals with a water repellant effect.
- the paraffin dispersion preferably contains ethylene paraffin wax with molecule chain lengths of C 20-34.
- the aqueous dispersion typically contains up to 40% paraffin and includes some commonly used dispergating and stabilizing agents.
- a rheology modifier may be used to stabilize and to enhance the processability of the paraffin wax dispersion resulting in a separation layer on one side of the glass fabric.
- Rheology modifiers can be selected from the known groups of acrylic thickeners, poly-urethane thickeners or cellulose thickeners.
- 10 - 60g of the dispersion per square meter is sufficient to obtain an optimum adhesion strength combined with moderate tear forces.
- the wanted tear force can be adjusted by the amount of the applied dispersion. It also depends on the type and structure of the used fabrics.
- the optimum adhesion strength is necessary to obtain the same wear resistance and the same fire resistance as standard glass fiber wall covering.
- the fabric may be conveyed to a drying means, which in the preferred embodiment of Figure 2 is depicted as air dryers 16.
- a drying means which in the preferred embodiment of Figure 2 is depicted as air dryers 16.
- heated cylinders can be used without any drawbacks.
- the fabric can be cut collected for subsequent secondary treatment.
- the subsequent application step can be carried out on a continuous basis.
- a third chemical treatment follows. This can be done as an "online" process in a continuous manner. It can, however, also be carried out as a separate process.
- a rotating screen 11 such as available from Stork, may be used to apply the chemicals to the glass fabric 12.
- the chemical dispersion 14 is supplied to the interior of the rotating screen. The dispersion is applied to the glass fabric by contact with the rotating screen.
- the chemicals can also be applied by pick-up roller without any drawbacks.
- a preferred chemical dispersion mixture consists of those components set out in Table 3 below.
- Table 3 Starch 70-100% of dry substance Inorganic compounds 0-25 % of dry substance Color additives 0-5 % of dry substance
- the starch component that is present may be derived from potato, corn or wheat starches. A combination potato starch and corn starch is most preferred.
- Inorganic compounds may be added to improve the functionality and appearance of the chemical treatment and the resulting product, e.g., opacity and water absorbability.
- An example of a compound to improve the latter is sodium nitrate, or other hygroscopic Compounds.
- Opacity can be obtained from a variety of fillers and pigments, preferably based on dioxide, aluminum hydroxide, calcium carbonate, and other inorganic salts.
- 10 - 50 g of the adhesive of Table 3 per square meter is sufficient to obtain an optimum adhesion strength.
- the necessary amount of adhesive depends on the type and texture of the used fabrics.
- the optimum adhesion strength is necessary to obtain the same performance as standard glass fiber wall covering.
- the fabric may be conveyed to a drying means, which in the preferred embodiment of Figure 2 is depicted as air dryers 16.
- a drying means which in the preferred embodiment of Figure 2 is depicted as air dryers 16.
- heated cylinders can be used without any drawbacks.
- the fabric After drying, the fabric is commonly cut into desired width, and collected for subsequent secondary treatment, for example, into rolls at a batching stand 18 of between 1,000 and 6,000 meters of treated weave.
- This third chemical treatment is a one-side coating with the dried gluing material which is placed on top of the first and second layer. It leads to an adhesive layer which faces the wall.
- a colored additive enables the end-user to distinguish between the front side and the pre-glued back side of the wall covering
- the suggested adhesive layer does not contain any latex components. Instead it is formulated from two different starches types, originating from different crops. The usage of these two starches allows the combination of an excellent tack with a very good film formation. Using this formulation the resulting adhesive force between the wall and the wall covering is superior to that of the normal wall covering system. This renders redundant the use of standard polymeric latex binder.
- the starch formulation mentioned in the paragraph above quickly absorbs the water applied to the surface.
- a small additional quantity of inorganic compound is recommended. The functioning of this compound results in a pre-activating of the starch formulation, i.e. making the starch more quickly accessible for the water.
- the product of the novel process described above is typically supplied to an end user in roll form having a length of approximately 50 meters for application to a wall of other interior structures. After cutting the layers to the desired length only water must be sprayed or otherwise applied onto the pre-glued fiberglass wall-covering of the present invention. Dipping the fabric in a water bath is not necessary and even not recommended. When exposed to water the adhesive layer swells rapidly and becomes sticky. Only water is needed when attaching the fabric to the wall which offers a significant advantage for the end-user.
- the wetted fabric can be attached to
- the wall within minutes and the opposite surface can be painted immediately afterwards. A separate drying step is not necessary. All types of paints which can be used for standard fiberglass wall coverings can be applied to the novel product. Only one painting steps is necessary to achieve the desired result leading to significant time and cost savings.
- the product has the same fire resistance rating as standard fiber glass weaves and exhibit a superior adhesion to the wall.
- the wall covering can be easily removed from the wall.
- the novel product can be simply lifted off the wall a few centimeters at the highest or lowest point by using a knife or similar tool and then pulled by hand from the wall.
- a glass woven fabric consisting of 139 tex texturized warp yarns with 34 yarns/10cm and 165 tex texturized glass staple fiber yarns with 190 yarns per meter is produced and is coated and impregnated on both sides with a aqueous chemical dispersion comprising 25% of a potato starch, 47% of acrylic latex binder, 6% of zirconium cross linker, and 22% of a white titanium oxide pigment on a dry basis.
- a second chemical dispersion is applied to one side using rotary screens.
- the second dispersion contains, based on dry substance, 95% paraffin wax and 5% of a rheology modifier.
- a third chemical dispersion is applied on top of the second layer.
- the dispersion contains 60% potato starch, 30% corn starch, 7% sodium nitrate, and 3% of a colorant on dry basis.
- the third dispersion next is dried to form the third coating that is capable of serving as an adhesive for the attachment of the resulting wall covering following the simple application of water by spraying to the third dried coating. All concentrations are expressed on a dry weight basis.
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- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Finishing Walls (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Claims (22)
- Verfahren zum Bilden einer vorgeleimten, abziehbaren Glasfaserwandverkleidung, Folgendes umfassend:(I) Bereitstellen eines Glasfaserflächengebildes,(II) Bilden einer ersten getrockneten Beschichtung auf beiden Seiten des Glasfaserflächengebildes, die aus einer wässrigen Dispersion aufgebracht wird, welche Stärke und ein polymeres Latexbindemittel umfasst,(III) anschließendes Bilden einer zweiten getrockneten Beschichtung auf der ersten getrockneten Beschichtung auf nur einer Seite des Glasflächengebildes, die aus einer chemischen Dispersion aufgebracht wird, welche Paraffin und Rheologiemodifizierer umfasst, wobei die zweite getrocknete Beschichtung in der Lage ist, das Entfernen der Wandverkleidung von der Wand zu ermöglichen, und(IV) anschließendes Bilden einer dritten getrockneten Beschichtung auf der zweiten getrockneten Beschichtung des Glasflächengebildes, die aus einer wässrigen Dispersion aufgebracht wird, die in Abwesenheit eines polymeren Latexbindemittels zwei verschiedene Stärken von unterschiedlichen Feldfrüchten umfasst, wobei die dritte getrocknete Beschichtung in der Lage ist, im angefeuchteten Zustand als Klebstoff zur Befestigung der entstandenen Wandverkleidung an der Wand zu dienen.
- Verfahren nach Anspruch 1, wobei das Glasfaserflächengebilde ein Gewebe ist.
- Verfahren nach Anspruch 1, wobei das Glasfaserflächengebilde ein Vlies ist.
- Verfahren nach Anspruch 1, wobei das Glasfaserflächengebilde in Rollenform vorliegt.
- Verfahren nach Anspruch 1, wobei die Stärkekomponente der ersten Beschichtung Kartoffelstärke ist.
- Verfahren nach Anspruch 1, wobei die polymere Latexbindemittelkomponente der ersten Beschichtung ein Acryllatexbindemittel ist.
- Verfahren nach Anspruch 1, wobei die wässrige Dispersion der ersten getrockneten Beschichtung ein Vernetzungsmittel aufweist.
- Verfahren nach Anspruch 7, wobei das Vernetzungsmittel der ersten Beschichtung ein Zirkonvernetzer ist.
- Verfahren nach Anspruch 1, wobei die wässrige Dispersion der ersten Beschichtung außerdem ein Pigment aufweist.
- Verfahren nach Anspruch 9, wobei das Pigment der ersten Beschichtung Titandioxid ist.
- Verfahren nach Anspruch 1, wobei die Dispersion der zweiten Beschichtung eine Mischung aus Paraffin und Rheologiemodifizierern umfasst.
- Verfahren nach Anspruch 1, wobei die Dispersion der zweiten Beschichtung zu 80 - 99 % der Trockensubstanz Paraffin und zu 1 - 20 % Rheologiemodifizierer umfasst.
- Verfahren nach Anspruch 1, wobei die dritte chemische Dispersion Stärke umfasst.
- Verfahren nach Anspruch 13, wobei die Stärkekomponente der dritten Beschichtung eine Mischung aus Kartoffelstärke und Maisstärke ist.
- Verfahren nach Anspruch 1, wobei die wässrige Dispersion der dritten Beschichtung eine anorganische Verbindung aufweist, die zur Verbesserung der Wasserabsorptionsfähigkeit der dritten getrockneten Beschichtung dient.
- Verfahren nach Anspruch 15, wobei die anorganische Verbindung Natriumnitrat ist.
- Verfahren nach Anspruch 1, wobei die wässrige Dispersion der dritten Beschichtung kein Latexbindemittel aufweist.
- Verfahren nach Anspruch 1, wobei die wässrige Dispersion der ersten und zweiten Beschichtung in einem kontinuierlichen Verfahren aufgebracht wird, wobei das Trocknen unmittelbar nach dem Kontakt mit den Dispersionen erfolgt.
- Verfahren nach Anspruch 1, wobei die wässrige Dispersion der ersten, zweiten und dritten Beschichtung in einem kontinuierlichen Verfahren aufgebracht wird.
- Wandverkleidung, die mit dem Verfahren nach Anspruch 1 gebildet ist und die nach dem einfachen Aufbringen von Wasser durch Aufsprühen auf die dritte getrocknete Beschichtung ohne weiteres an der Wand befestigt werden kann.
- Wandverkleidung, die mit dem Verfahren nach Anspruch 1 gebildet ist und die leicht von der Wand entfernt werden kann.
- Glasfaserrollenware, die mit einem Verfahren nach Anspruch 1 gebildet ist und die ein Glasfaserflächengebilde umfasst, das mit einer ersten getrockneten Beschichtung imprägniert und beschichtet ist, und die zwei zusätzliche Schichten aufweist, die auf eine der Oberflächen des Flächengebildes aufgebracht sind, wobei die erste aufgebrachte zusätzliche Schicht als Trennschicht fungiert, wenn das Flächengebilde von einem Substrat entfernt wird, und die zweite aufgebrachte zusätzliche Schicht als vorgeleimte Schicht fungiert, wenn sie befeuchtet und an einem Substrat befestigt wird.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01113463A EP1262591B1 (de) | 2001-06-02 | 2001-06-02 | Abziehbare klebstoffbeschichtete Wandbekleidung |
| AT01113463T ATE529566T1 (de) | 2001-06-02 | 2001-06-02 | Abziehbare klebstoffbeschichtete wandbekleidung |
| DK01113463.2T DK1262591T3 (da) | 2001-06-02 | 2001-06-02 | Aftagelig forlimet vægbeklædning |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01113463A EP1262591B1 (de) | 2001-06-02 | 2001-06-02 | Abziehbare klebstoffbeschichtete Wandbekleidung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1262591A1 EP1262591A1 (de) | 2002-12-04 |
| EP1262591B1 true EP1262591B1 (de) | 2011-10-19 |
Family
ID=8177626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP01113463A Expired - Lifetime EP1262591B1 (de) | 2001-06-02 | 2001-06-02 | Abziehbare klebstoffbeschichtete Wandbekleidung |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP1262591B1 (de) |
| AT (1) | ATE529566T1 (de) |
| DK (1) | DK1262591T3 (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12398497B2 (en) | 2020-03-09 | 2025-08-26 | Owens Corning Intellectual Capital, Llc | Coating formulation for curtain coating fibrous non-woven mats |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10324472A1 (de) | 2003-05-30 | 2004-12-30 | Henkel Kgaa | Klebstoffbeschichtete Tapete |
| DE202009002456U1 (de) * | 2009-02-20 | 2009-04-30 | Vitrulan Textilglas Gmbh | Faservlies für einen Wand- oder Deckenbelag |
| EP2339054A1 (de) | 2009-12-22 | 2011-06-29 | Johns Manville Europe GmbH | Glasfaserwandverkleidung |
| PL397431A1 (pl) * | 2011-12-15 | 2013-06-24 | Flugger Spólka Z Ograniczona Odpowiedzialnoscia | Pokryty filc szklany oraz sposób otrzymywania |
| FR3039170B1 (fr) * | 2015-07-24 | 2017-08-11 | Normalu | Toile en fibre de verre apte a etre mise sous tension et procede pour la realisation d'une telle toile |
| EP4585745A1 (de) * | 2024-01-10 | 2025-07-16 | Saint-Gobain Adfors | Glasfaserwandabschlusssystem |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1184563A (en) | 1966-09-28 | 1970-03-18 | Wall Paper Manufacturers Ltd | Wall Coverings. |
| GB1229811A (de) * | 1967-03-04 | 1971-04-28 | ||
| DE1924409A1 (de) * | 1969-05-13 | 1971-08-19 | Pickhardt & Siebert | Abziehbare Tapete |
| DE2302890C3 (de) * | 1973-01-20 | 1982-05-19 | E. Holtzmann & Cie. Ag, 7566 Weisenbach | Verfahren zur Herstellung eines abziehbaren Tapetenpapiers |
| JPS5237935A (en) * | 1975-09-20 | 1977-03-24 | Suzuka Toryo Kk | Method for sticking wall paper |
| DE19640624A1 (de) | 1996-10-01 | 1998-04-09 | Niels Wendland | Glasfasergewebetapete |
| DE29718222U1 (de) | 1997-10-14 | 1999-02-18 | Sauer, Wigbert H., 71229 Leonberg | Textilglasgewebebahn |
| DE19811152A1 (de) | 1998-03-14 | 1999-09-16 | Werner Abend | Wetterbeständige Außentapete |
| FR2790716B1 (fr) | 1999-03-08 | 2001-05-11 | Mermet Sa | Toile a peindre destinee a former un revetement d'une surface interieure de batiment |
-
2001
- 2001-06-02 EP EP01113463A patent/EP1262591B1/de not_active Expired - Lifetime
- 2001-06-02 AT AT01113463T patent/ATE529566T1/de not_active IP Right Cessation
- 2001-06-02 DK DK01113463.2T patent/DK1262591T3/da active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12398497B2 (en) | 2020-03-09 | 2025-08-26 | Owens Corning Intellectual Capital, Llc | Coating formulation for curtain coating fibrous non-woven mats |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1262591A1 (de) | 2002-12-04 |
| DK1262591T3 (da) | 2012-02-13 |
| ATE529566T1 (de) | 2011-11-15 |
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