[go: up one dir, main page]

EP1035194A3 - Use of comb polymers as soil release polymers - Google Patents

Use of comb polymers as soil release polymers Download PDF

Info

Publication number
EP1035194A3
EP1035194A3 EP00102085A EP00102085A EP1035194A3 EP 1035194 A3 EP1035194 A3 EP 1035194A3 EP 00102085 A EP00102085 A EP 00102085A EP 00102085 A EP00102085 A EP 00102085A EP 1035194 A3 EP1035194 A3 EP 1035194A3
Authority
EP
European Patent Office
Prior art keywords
oder
bis
und
aryl
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00102085A
Other languages
German (de)
French (fr)
Other versions
EP1035194B1 (en
EP1035194A2 (en
Inventor
Johannes Dr. Becherer
Frank-Peter Di. Lang
Bernhard Dr. Mees
Roman Dr. Morschhäuser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Produkte Deutschland GmbH
Original Assignee
Clariant GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant GmbH filed Critical Clariant GmbH
Publication of EP1035194A2 publication Critical patent/EP1035194A2/en
Publication of EP1035194A3 publication Critical patent/EP1035194A3/en
Application granted granted Critical
Publication of EP1035194B1 publication Critical patent/EP1035194B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Verwendung von Kammpolymeren, erhalten durch Kondensation von

  • a) einer Polycarbonsäure oder einem Polyalkohol,
  • b) einem oder mehreren gegebenenfalls durch Sulfogruppen substituierten Polyalkoholen mit 2 bis 4 OH-Gruppen oder Polyglykolen der Formel HO-(XO)a-H, worin X C2H4 und/oder C3H7 und a eine Zahl von 2 bis 35, vorzugsweise 2 bis 5 bedeutet,
  • c) einer oder mehreren gegebenenfalls sulfonierten C2-C10-Dicarbonsäuren und
  • d) einer oder mehreren Verbindungen der Formeln NH2R, NHR2, ROH, R1COOH, HO(XO)b-H, HO(CH2CH2)dSO3K worin R C1-C22-Alkyl oder C6-C10-Aryl, R1 C1-C22-Alkyl, C1-C22-Sulfoalkyl, C6-C10-Aryl oder C6-C10-Sulfoaryl, X C2H4 und/oder C3H7, b eine Zahl von 3 bis 40, vorzugsweise 3 bis 20, d eine Zahl von 1 bis 10, vorzugsweise 1 bis 4 und K ein Kation bedeuten, als Schmutzlösepolymere.
    • Use of comb polymers obtained by condensing
  • a) a polycarboxylic acid or a polyalcohol,
  • b) one or more polyalcohols which are optionally substituted by sulfo groups and have 2 to 4 OH groups or polyglycols of the formula HO- (XO) a -H, where XC 2 H 4 and / or C 3 H 7 and a is a number from 2 to 35 , preferably means 2 to 5,
  • c) one or more optionally sulfonated C 2 -C 10 dicarboxylic acids and
  • d) one or more compounds of the formulas NH 2 R, NHR 2 , ROH, R 1 COOH, HO (XO) b -H, HO (CH 2 CH 2 ) d SO 3 K in which RC 1 -C 22 alkyl or C 6 -C 10 aryl, R 1 C 1 -C 22 alkyl, C 1 -C 22 sulfoalkyl, C 6 -C 10 aryl or C 6 -C 10 sulfoaryl, XC 2 H 4 and / or C 3 H 7 , b is a number from 3 to 40, preferably 3 to 20, d is a number from 1 to 10, preferably 1 to 4 and K is a cation, as soil release polymers.

    • EP00102085A 1999-02-16 2000-02-03 Use of comb polymers as soil release polymers Expired - Lifetime EP1035194B1 (en)

    Applications Claiming Priority (2)

    Application Number Priority Date Filing Date Title
    DE19906367A DE19906367A1 (en) 1999-02-16 1999-02-16 Use of comb polymers as protective release polymers
    DE19906367 1999-02-16

    Publications (3)

    Publication Number Publication Date
    EP1035194A2 EP1035194A2 (en) 2000-09-13
    EP1035194A3 true EP1035194A3 (en) 2002-01-02
    EP1035194B1 EP1035194B1 (en) 2004-09-15

    Family

    ID=7897617

    Family Applications (1)

    Application Number Title Priority Date Filing Date
    EP00102085A Expired - Lifetime EP1035194B1 (en) 1999-02-16 2000-02-03 Use of comb polymers as soil release polymers

    Country Status (5)

    Country Link
    US (1) US6255274B1 (en)
    EP (1) EP1035194B1 (en)
    JP (1) JP4731656B2 (en)
    DE (2) DE19906367A1 (en)
    ES (1) ES2228311T3 (en)

    Families Citing this family (38)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    DE10131371A1 (en) * 2001-06-28 2003-01-16 Clariant Gmbh Use of quaternized (meth) acrylic acid dialkylaminoalkyl esters as soil release polymers for hard surfaces, and a process for their preparation
    JP2002505360A (en) * 1998-03-07 2002-02-19 バイヤースドルフ・アクチエンゲゼルシヤフト Sulphonated comb polymers and preparations based on such sulphonated comb polymers, in particular hair cosmetic preparations
    US7390432B2 (en) * 1998-06-30 2008-06-24 Sandia Corporation Enhanced formulations for neutralization of chemical, biological and industrial toxants
    DE19942302A1 (en) * 1999-09-04 2001-03-08 Beiersdorf Ag Sulfonated comb polymers with selected lithium / sodium ratio and preparations, in particular hair cosmetic preparations based on such sulfonated comb polymers
    WO2002018475A1 (en) * 2000-08-31 2002-03-07 Beiersdorf Ag Silicon-modified, sulphonated comb polymers and preparations, especially hair care preparations based on said silicon-modified, sulphonated comb polymers
    DE10104991A1 (en) * 2001-02-03 2002-08-08 Clariant Gmbh Microencapsulated biologically active ingredients containing a water-soluble or water-dispersible comb polymer
    JP2002265996A (en) * 2001-03-14 2002-09-18 Toyo Riken Kk Agent for cleaning stainproof treatment of hydrophobic hard surface and method for cleaning stainproof treatment
    JP2002292329A (en) * 2001-04-02 2002-10-08 Toyo Riken Kk Method for lustering and stainproofing treatment of hard surface
    US20040261194A1 (en) * 2003-06-27 2004-12-30 The Procter & Gamble Company Fabric article treating system
    DE102005027604A1 (en) * 2005-06-15 2006-12-28 Clariant Produkte (Deutschland) Gmbh Cleaning agent for hard surfaces
    DE102007013217A1 (en) 2007-03-15 2008-09-18 Clariant International Ltd. Anionic Soil Release Polymers
    GB0704933D0 (en) * 2007-03-15 2007-04-25 Reckitt Benckiser Nv Detergent composition
    US7828907B2 (en) * 2007-05-09 2010-11-09 Ecolab Inc. Detergent component for preventing precipitation of water hardness and providing soil removal properties
    US8361953B2 (en) * 2008-02-08 2013-01-29 Evonik Goldschmidt Corporation Rinse aid compositions with improved characteristics
    US8444768B2 (en) * 2009-03-27 2013-05-21 Eastman Chemical Company Compositions and methods for removing organic substances
    US8309502B2 (en) * 2009-03-27 2012-11-13 Eastman Chemical Company Compositions and methods for removing organic substances
    US8614053B2 (en) 2009-03-27 2013-12-24 Eastman Chemical Company Processess and compositions for removing substances from substrates
    DE102009020299A1 (en) 2009-05-07 2010-11-11 Clariant International Ltd. Comb polymers and their use in detergents and cleaners
    CA2795464C (en) 2010-04-01 2014-07-15 Evonik Degussa Gmbh Fabric softener active composition
    AP4034A (en) 2010-04-01 2017-02-12 Evonik Degussa Gmbh Fabric softener active composition
    WO2011134835A1 (en) 2010-04-28 2011-11-03 Evonik Degussa Gmbh Textile softening composition
    US8507425B2 (en) 2010-06-29 2013-08-13 Evonik Degussa Gmbh Particulate fabric softener comprising ethylenediamine fatty acid amides and method of making
    EP2652112A1 (en) * 2010-12-17 2013-10-23 The Procter and Gamble Company Cleaning compositions with polyoxyalkylene-oxide capped polyalkylene-oxide-polycarboxylate comb polymers
    CN103608380B (en) 2011-06-15 2016-08-31 巴斯夫欧洲公司 There is the branched polyester of sulfonate groups
    US8846599B2 (en) 2011-06-15 2014-09-30 Basf Se Branched polyesters with sulfonate groups
    WO2013113453A1 (en) 2012-01-30 2013-08-08 Evonik Industries Ag Fabric softener active composition
    PL2847307T3 (en) 2012-05-07 2016-10-31 Fabric softener active composition and method for making it
    US9029268B2 (en) 2012-11-21 2015-05-12 Dynaloy, Llc Process for etching metals
    DE102013207778A1 (en) * 2013-04-29 2014-10-30 Cht R. Beitlich Gmbh Comb polymers as detergency booster for detergents and cleaners
    BR102014025172B1 (en) 2013-11-05 2020-03-03 Evonik Degussa Gmbh METHOD FOR MANUFACTURING A TRIS- (2-HYDROXYETHYL) -METHYLMETHYL ESTER OF FATTY ACID AND ACTIVE COMPOSITION OF SOFTENING CLOTHES
    UA119182C2 (en) 2014-10-08 2019-05-10 Евонік Дегусса Гмбх ACTIVE FABRIC SOFTWARE
    US9828571B2 (en) * 2015-06-05 2017-11-28 Illinois Tool Works, Inc. Heavy duty laundry detergent
    DE102016003544A1 (en) 2016-03-22 2017-09-28 Weylchem Wiesbaden Gmbh Polyester, process for their preparation and their use
    EP3489340A1 (en) 2017-11-28 2019-05-29 Clariant International Ltd Renewably sourced soil release polyesters
    ES3006139T3 (en) 2018-05-24 2025-03-17 Clariant Int Ltd Soil release polyesters for use in detergent compositions
    DE102020006977A1 (en) 2020-11-13 2022-05-19 WeylChem Performance Products GmbH Aqueous-alcoholic polyester compositions, detergents and cleaning agents containing these and their use
    DE102022002248A1 (en) * 2022-06-21 2023-12-21 WeylChem Performance Products GmbH Polyester, detergents and cleaning agents containing them and their use
    JP2025152093A (en) * 2024-03-28 2025-10-09 日華化学株式会社 Manufacturing method for water-repellent textile products

    Citations (6)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    WO1995002029A1 (en) * 1993-07-08 1995-01-19 The Procter & Gamble Company Detergent compositions comprising soil release agents
    US5691298A (en) * 1994-12-14 1997-11-25 The Procter & Gamble Company Ester oligomers suitable as soil release agents in detergent compositions
    US5700386A (en) * 1996-08-08 1997-12-23 The Procter & Gamble Company Process for making soil release polymer granules
    US5843878A (en) * 1993-07-08 1998-12-01 Procter & Gamble Company Detergent compositions comprising soil release agents
    DE19735715A1 (en) * 1997-08-18 1999-02-25 Huels Chemische Werke Ag Amphiphilic polymer useful as soil-release polymer
    DE19909757A1 (en) * 1998-03-07 1999-09-16 Beiersdorf Ag Water-soluble or -dispersible comb polymers used in hair cosmetics, e.g. hair spray, lacquer, setting foam or styling gel

    Family Cites Families (6)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    FR2464538A1 (en) 1979-08-28 1981-03-06 Commissariat Energie Atomique STANDARD DEVICE FOR THE EMISSION OF FISSION PRODUCTS FOR SHEAT BREAK DETECTION IN A NUCLEAR REACTOR
    US4427557A (en) 1981-05-14 1984-01-24 Ici Americas Inc. Anionic textile treating compositions
    CZ248694A3 (en) 1992-04-13 1995-05-17 Procter & Gamble Use of modified polyesters for washing fabrics containing cotton
    ES2129077T3 (en) 1992-07-31 1999-06-01 Procter & Gamble USE OF MODIFIED POLYESTERS FOR THE ELIMINATION OF GREASE FROM TEXTILE GENERES.
    AU7256494A (en) 1993-07-08 1995-02-06 Procter & Gamble Company, The Detergent compositions comprising soil release agents
    JPH08208830A (en) * 1995-02-03 1996-08-13 Sanyo Chem Ind Ltd Hydrophilic elastomer and resin composition for molding

    Patent Citations (6)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    WO1995002029A1 (en) * 1993-07-08 1995-01-19 The Procter & Gamble Company Detergent compositions comprising soil release agents
    US5843878A (en) * 1993-07-08 1998-12-01 Procter & Gamble Company Detergent compositions comprising soil release agents
    US5691298A (en) * 1994-12-14 1997-11-25 The Procter & Gamble Company Ester oligomers suitable as soil release agents in detergent compositions
    US5700386A (en) * 1996-08-08 1997-12-23 The Procter & Gamble Company Process for making soil release polymer granules
    DE19735715A1 (en) * 1997-08-18 1999-02-25 Huels Chemische Werke Ag Amphiphilic polymer useful as soil-release polymer
    DE19909757A1 (en) * 1998-03-07 1999-09-16 Beiersdorf Ag Water-soluble or -dispersible comb polymers used in hair cosmetics, e.g. hair spray, lacquer, setting foam or styling gel

    Also Published As

    Publication number Publication date
    JP4731656B2 (en) 2011-07-27
    EP1035194B1 (en) 2004-09-15
    US6255274B1 (en) 2001-07-03
    JP2000239365A (en) 2000-09-05
    DE19906367A1 (en) 2000-08-17
    DE50007720D1 (en) 2004-10-21
    EP1035194A2 (en) 2000-09-13
    ES2228311T3 (en) 2005-04-16

    Similar Documents

    Publication Publication Date Title
    EP1035194A3 (en) Use of comb polymers as soil release polymers
    ATE206210T1 (en) CONTAINING FLUORESCENT DYE, PYRYLIUM SALTS OR SIMILAR SALTS, DETECTION METHOD OF NUCLEIC ACID BY USE OF THE SAME
    DE2236036C3 (en) Diphosphinic acid ester
    RU96107773A (en) Method of producing N-amino-1-hydroxyalkylidene-1, 1-bisphosphonic acid
    Alberti et al. Derivatives of α-zirconium phosphate with two different functional groups
    DE3867512D1 (en) 1,4-DISUBSTITUTED PIPERAZINE COMPOUNDS, THEIR PRODUCTION AND THEIR USE.
    EP0302359A3 (en) Positive photo-sensitive compositions
    Shinkai et al. Synthesis and inclusion properties of" neutral" water-soluble calixarenes.
    KR940014402A (en) Hybrid Crystals of Sulfonated Diketopyrrolopyrrole
    ATE402183T1 (en) MULTIMER FORMS OF MONO- AND BIS-ACYLPHOSPHINE OXIDES
    DD204932A5 (en) PROCESS FOR PRODUCING SOLID, FIBER-FORMING POLYESTERS
    EP0433220A3 (en) Substituted naphthalocyanine and its use
    PT79172A (en) METHOD FOR PRODUCING NUCLEASIDALKYL ARALKYL AND ANYL PHOSPHONITES AND PHOSPHONATES
    EP0538189A3 (en) Process for the preparation of esters of hydroxyphenyl carboxylic acids
    Ehde et al. Multicomponent polyanions. 45: A multinuclear NMR study of vanadate (V)-oxalate complexes in aqueous solution
    DE102004015401A1 (en) Machine dishwashing detergent
    ATE47709T1 (en) PROCESS FOR THE PRODUCTION OF ALDEHYDE.
    EP0291853A3 (en) Thienon compounds
    EP0332068A3 (en) Process for preparing azacycloalkane-2,2-diphosphonic acids
    PT69846A (en) METHOD FOR PRODUCING LIGHT-TABILIZED PHOSPHORUS-ACID POLYESTERS
    Beddoes et al. Phosphite complexes of copper (II) carboxylates and their derivatives. Crystal structure of penta-µ-acetato-bis (triethyl phosphite) tricopper-(I, II)
    EP1262227A3 (en) Mixture of emulsifiers for emulsion polymerisation
    EP0306875A3 (en) Process for the preparation of 5-methyl butyrolactone
    ES2101673T3 (en) USE OF PHOSPHANES AND / OR DIPHOSPHANES IN THE MANUFACTURE OF PLASTICS BASED ON ISOCYANATE.
    KR970074787A (en) Substituted diphosphines and methods for their preparation

    Legal Events

    Date Code Title Description
    PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

    Free format text: ORIGINAL CODE: 0009012

    AK Designated contracting states

    Kind code of ref document: A2

    Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

    AX Request for extension of the european patent

    Free format text: AL;LT;LV;MK;RO;SI

    PUAL Search report despatched

    Free format text: ORIGINAL CODE: 0009013

    AK Designated contracting states

    Kind code of ref document: A3

    Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

    AX Request for extension of the european patent

    Free format text: AL;LT;LV;MK;RO;SI

    17P Request for examination filed

    Effective date: 20020702

    AKX Designation fees paid

    Free format text: AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

    17Q First examination report despatched

    Effective date: 20030701

    GRAP Despatch of communication of intention to grant a patent

    Free format text: ORIGINAL CODE: EPIDOSNIGR1

    GRAS Grant fee paid

    Free format text: ORIGINAL CODE: EPIDOSNIGR3

    RBV Designated contracting states (corrected)

    Designated state(s): BE CH DE ES FR GB IT LI

    GRAA (expected) grant

    Free format text: ORIGINAL CODE: 0009210

    AK Designated contracting states

    Kind code of ref document: B1

    Designated state(s): BE CH DE ES FR GB IT LI

    REG Reference to a national code

    Ref country code: GB

    Ref legal event code: FG4D

    Free format text: NOT ENGLISH

    Ref country code: CH

    Ref legal event code: EP

    REG Reference to a national code

    Ref country code: IE

    Ref legal event code: FG4D

    Free format text: GERMAN

    REF Corresponds to:

    Ref document number: 50007720

    Country of ref document: DE

    Date of ref document: 20041021

    Kind code of ref document: P

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: IT

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20050203

    GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

    Effective date: 20050127

    REG Reference to a national code

    Ref country code: ES

    Ref legal event code: FG2A

    Ref document number: 2228311

    Country of ref document: ES

    Kind code of ref document: T3

    REG Reference to a national code

    Ref country code: IE

    Ref legal event code: FD4D

    ET Fr: translation filed
    PLBE No opposition filed within time limit

    Free format text: ORIGINAL CODE: 0009261

    STAA Information on the status of an ep patent application or granted ep patent

    Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

    26N No opposition filed

    Effective date: 20050616

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: PFA

    Owner name: CLARIANT PRODUKTE (DEUTSCHLAND) GMBH

    Free format text: CLARIANT GMBH#BRUENINGSTRASSE 50#65929 FRANKFURT AM MAIN (DE) -TRANSFER TO- CLARIANT PRODUKTE (DEUTSCHLAND) GMBH#BRUENINGSTRASSE 50#65929 FRANKFURT AM MAIN (DE)

    REG Reference to a national code

    Ref country code: FR

    Ref legal event code: CD

    PGRI Patent reinstated in contracting state [announced from national office to epo]

    Ref country code: IT

    Effective date: 20091201

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: PCOW

    Free format text: NEW ADDRESS: PATENT MANAGEMENT INDUSTRIEPARK HOECHST / G 860, 65926 FRANKFURT AM MAIN (DE)

    REG Reference to a national code

    Ref country code: FR

    Ref legal event code: PLFP

    Year of fee payment: 17

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: CH

    Payment date: 20151210

    Year of fee payment: 17

    Ref country code: GB

    Payment date: 20151207

    Year of fee payment: 17

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: FR

    Payment date: 20151229

    Year of fee payment: 17

    Ref country code: ES

    Payment date: 20151210

    Year of fee payment: 17

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: IT

    Payment date: 20151223

    Year of fee payment: 17

    Ref country code: DE

    Payment date: 20151210

    Year of fee payment: 17

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: BE

    Payment date: 20160121

    Year of fee payment: 17

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: BE

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20170228

    REG Reference to a national code

    Ref country code: DE

    Ref legal event code: R119

    Ref document number: 50007720

    Country of ref document: DE

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: PL

    GBPC Gb: european patent ceased through non-payment of renewal fee

    Effective date: 20170203

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: CH

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20170228

    Ref country code: LI

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20170228

    REG Reference to a national code

    Ref country code: FR

    Ref legal event code: ST

    Effective date: 20171031

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: DE

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20170901

    Ref country code: FR

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20170228

    REG Reference to a national code

    Ref country code: BE

    Ref legal event code: MM

    Effective date: 20170228

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: IT

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20170203

    Ref country code: GB

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20170203

    REG Reference to a national code

    Ref country code: ES

    Ref legal event code: FD2A

    Effective date: 20180704

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: ES

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20170204